Open Access. Powered by Scholars. Published by Universities.®

Engineering Commons™

Open Access. Powered by Scholars. Published by Universities.®

2013

Discipline
Institution
Keyword
Publication
Publication Type
File Type

Articles 6751 - 6780 of 7289

Full-Text Articles in Engineering

Mitigation Of Ssr And Lfo With A Tcsc Based-Conventional Damping Controller Optimized By The Pso Algorithm And A Fuzzy Logic Controller, Hasan Gahramani, Akbar Lak, Murtaza Farsadi, Hossein Hosseini Jan 2013

Mitigation Of Ssr And Lfo With A Tcsc Based-Conventional Damping Controller Optimized By The Pso Algorithm And A Fuzzy Logic Controller, Hasan Gahramani, Akbar Lak, Murtaza Farsadi, Hossein Hosseini

Turkish Journal of Electrical Engineering and Computer Sciences

The subsynchronous resonance (SSR) phenomenon may occur when a steam turbine-generator is connected to a long transmission line with series compensation. Flexible AC transmission systems (FACTS) devices are widely applied to damp the SSR and low-frequency oscillation (LFO). A thyristor-controlled series capacitor (TCSC) is a commercially available FACTS device that was developed for damping the SSR and LFO. In this paper, 2 control methods for damping the SSR and LFO are added to the TCSC main controller in order to demonstrate that the SSR damping capability of the TCSC can be enhanced by proper modulation of the firing angle. The …


A Control Algorithm For A Simple Flywheel Energy Storage System To Be Used In Space Applications, Kutlay Aydin, Mehmet Ti̇mur Aydemi̇r Jan 2013

A Control Algorithm For A Simple Flywheel Energy Storage System To Be Used In Space Applications, Kutlay Aydin, Mehmet Ti̇mur Aydemi̇r

Turkish Journal of Electrical Engineering and Computer Sciences

Flywheels have been under consideration to be used for energy storage purposes in space applications to replace electrochemical batteries. An electrical machine is used as a motor to store kinetic energy when the solar energy is available, and then the stored energy is converted back to electrical energy by running the machine as a generator when the solar energy is no longer available. A control algorithm for these systems is proposed in this paper. The proposed method uses a current reference rather than a speed reference in the motor mode. A method is also suggested to properly determine the current …


Optimal Placement Of Pmus Using Improved Tabu Search For Complete Observability And Out-Of-Step Prediction, Amany El Zonkoly, Samah El Safty, Rana Maher Jan 2013

Optimal Placement Of Pmus Using Improved Tabu Search For Complete Observability And Out-Of-Step Prediction, Amany El Zonkoly, Samah El Safty, Rana Maher

Turkish Journal of Electrical Engineering and Computer Sciences

This paper proposes an optimization method for the optimal placement of phasor measurement units (PMUs) for the complete observability of power systems. The proposed method is based on numerical observability and artificial intelligence. The artificial intelligence algorithm used is the improved tabu search (ITS) algorithm. The ITS is used to find the optimal placement for the PMU to keep the system completely observable. In addition, the paper describes a predictive out-of-step (OOS) algorithm based on the observation of the voltage phase difference between the substations. The proposed optimal placement of the PMUs and the OOS algorithm is tested using the …


Anticipating The Friction Coefficient Of Friction Materials Used In Automobiles By Means Of Machine Learning Without Using A Test Instrument, Mustafa Ti̇mur, Fati̇h Aydin Jan 2013

Anticipating The Friction Coefficient Of Friction Materials Used In Automobiles By Means Of Machine Learning Without Using A Test Instrument, Mustafa Ti̇mur, Fati̇h Aydin

Turkish Journal of Electrical Engineering and Computer Sciences

The most important factor for designs in which friction materials are used is the coefficient of friction. The coefficient of friction has been determined taking such variants as velocity, temperature, and pressure into account, which arise from various factors in friction materials, and by analyzing the effects of these variants on friction materials. Many test instruments have been produced in order to determine the coefficient of friction. In this article, a study about the use of machine learning algorithms instead of test instruments in order to determine the coefficient of friction is presented. Isotonic regression was selected as the machine …


Classification Of Power Quality Disturbances Using S-Transform And Tt-Transform Based On The Artificial Neural Network, Sajad Jashfar, Saeed Esmaeili, Mehdi Zareian Jahromi, Mohsen Rahmanian Jan 2013

Classification Of Power Quality Disturbances Using S-Transform And Tt-Transform Based On The Artificial Neural Network, Sajad Jashfar, Saeed Esmaeili, Mehdi Zareian Jahromi, Mohsen Rahmanian

Turkish Journal of Electrical Engineering and Computer Sciences

The classification of power quality (PQ) disturbances to improve the PQ is an important issue in utilities and industrial factories. In this paper, an approach to classify PQ disturbances is presented. First, a signal containing one of the PQ disturbances, like sag, swell, flicker, interruption, transient, or harmonics, is evaluated using the proposed approach. Afterwards, S-transform and TT-transform are applied to the signal and an artificial neural network is used to recognize the disturbance using S-transform and TT-transform data, like the variance and mean values of S-transform and TT-transform matrices. The main features of the proposed approach are the real-time …


Bidding Strategy Of Generation Companies In A Competitive Electricity Market Using The Shuffled Frog Leaping Algorithm, Vijaya Kumar Jonnalagadda, Vinod Kumar Dulla Mallesham Jan 2013

Bidding Strategy Of Generation Companies In A Competitive Electricity Market Using The Shuffled Frog Leaping Algorithm, Vijaya Kumar Jonnalagadda, Vinod Kumar Dulla Mallesham

Turkish Journal of Electrical Engineering and Computer Sciences

In a competitive electricity market, generation companies need suitable bidding models to maximize their profit. Therefore, each supplier will bid strategically for choosing the bidding coefficients to counter the competitors' bidding strategies. In this paper, the optimal bidding strategy problem is solved using a novel algorithm based on the shuffled frog leaping algorithm (SFLA). It is a memetic metaheuristic that is designed to seek a global optimal solution by performing a heuristic search. It combines the benefits of the genetic-based memetic algorithm (MA) and the social behavior-based particle swarm optimization (PSO). This allows it to have a more precise search …


K-Means Algorithm With A Novel Distance Measure, Shadi Abudalfa, Mohammad Mikki Jan 2013

K-Means Algorithm With A Novel Distance Measure, Shadi Abudalfa, Mohammad Mikki

Turkish Journal of Electrical Engineering and Computer Sciences

In this paper, we describe an essential problem in data clustering and present some solutions for it. We investigated using distance measures other than Euclidean type for improving the performance of clustering. We also developed an improved point symmetry-based distance measure and proved its efficiency. We developed a k-means algorithm with a novel distance measure that improves the performance of the classical k-means algorithm. The proposed algorithm does not have the worst-case bound on running time that exists in many similar algorithms in the literature. Experimental results shown in this paper demonstrate the effectiveness of the proposed algorithm. We compared …


Interaction Analysis Of Multi-Function Facts And D-Facts Controllers By Mrga, Maghsood Mokhtari, Javad Khazaie, Daryoush Nazarpour, Morteza Farsadi Jan 2013

Interaction Analysis Of Multi-Function Facts And D-Facts Controllers By Mrga, Maghsood Mokhtari, Javad Khazaie, Daryoush Nazarpour, Morteza Farsadi

Turkish Journal of Electrical Engineering and Computer Sciences

With the growing application of flexible AC transmission systems (FACTS) and distributed FACTS (D-FACTS), the coordinating problem of FACTS and D-FACTS controllers in joint operation must be considered in modern power systems. The main purpose of this paper is to investigate the possible interaction that may occur between the distributed static series compensator (DSSC) and the static synchronous compensator (STATCOM) when they operate concurrently in the power system. The modified relative gain array (MRGA) is implemented to analyze the interactions. The application of MRGA for the effective design of multiobjective controllers of the STATCOM and DSSC is demonstrated by 2 …


Performance Evolution Of A Newly Developed General-Use Hybrid Ais-Ann System: Aaa-Response, Seral Özşen, Sali̇h Güneş Jan 2013

Performance Evolution Of A Newly Developed General-Use Hybrid Ais-Ann System: Aaa-Response, Seral Özşen, Sali̇h Güneş

Turkish Journal of Electrical Engineering and Computer Sciences

In this study, we have developed a nonlinear recognition system in the artificial immune systems (AIS) field named `AaA-response (artificial neural network (ANN)-aided AIS-response)', which is different from previous AIS methods in that it uses a different modeling strategy in the formation of the memory response. Because it also uses ANNs in the determination of the correct output, it can be seen as a hybrid system that involves AIS and ANN approaches. Unlike the other AIS methods, AaA-response uses multiple system units (or antibodies) to form an output for a presented input. This property gives the proposed system the ability …


Cada: Channel And Delay Aware Scheduler For Real-Time Applications In Wimax Networks, Melek Oktay, Haci Ali̇ Mantar Jan 2013

Cada: Channel And Delay Aware Scheduler For Real-Time Applications In Wimax Networks, Melek Oktay, Haci Ali̇ Mantar

Turkish Journal of Electrical Engineering and Computer Sciences

Scheduling is the core of the worldwide interoperability for microwave access (WiMAX) technology that directly affects the performance of the network. In this study, we focus on scheduling and present a novel algorithm called the channel and delay aware scheduler (CADA) for real-time applications, such as voice over Internet protocol, video-on-demand, and video streaming. CADA has 2 important modules: wireless and network delay monitoring tools. The wireless module, including the compensation and channel state monitoring modules, increases the network throughput and provides fairness among all of the flows in the network. The network delay monitoring tool calculates the estimated network …


Improving Power Systems Operation Through Multiobjective Optimal Location Of Optimal Unified Power Flow Controller, Afshin Lashkar Ara, Ahad Kazemi, Mohammad Behshad Jan 2013

Improving Power Systems Operation Through Multiobjective Optimal Location Of Optimal Unified Power Flow Controller, Afshin Lashkar Ara, Ahad Kazemi, Mohammad Behshad

Turkish Journal of Electrical Engineering and Computer Sciences

This paper presents a multiobjective optimization methodology to find the optimal location for an optimal unified power flow controller (OUPFC) device. Moreover, the installation cost function of the OUPFC device is developed. The objective functions are the total fuel cost, power losses, and system loadability with and without the minimum cost of the OUPFC installation. The \varepsilon-constraint approach is implemented for the multiobjective mathematical programming formulation. The proposed algorithm is implemented in the IEEE 30- and 118-bus test systems. The solution procedure uses nonlinear programming to optimally locate the OUPFC incorporated in an optimal power flow problem considering these objective …


A 5-Bit 5 Gs/S Flash Adc Using Multiplexer-Based Decoder, Oktay Aytar, Ali̇ Tangel, Kudret Şahi̇n Jan 2013

A 5-Bit 5 Gs/S Flash Adc Using Multiplexer-Based Decoder, Oktay Aytar, Ali̇ Tangel, Kudret Şahi̇n

Turkish Journal of Electrical Engineering and Computer Sciences

This paper presents a 5-bit flash analog-to-digital converter design using the 0.18-\mu m Taiwan Semiconductor Manufacturing Company's CMOS technology library. The designed system consists of 2 main blocks, a comparator array, and a digital decoder. The digital decoder contains a latch, 1-of-N decoder, and fat-tree encoder units. The 1-of-N decoder is implemented using 2 \times 1 multiplexers. As a result, the active die area and the power consumption are reduced, in addition to an increase in the sampling frequency. The power supply voltage range for the overall system is \pm 0.9 V. For testing purposes, a ramp signal of between …


Using The Csm And Vsm Techniques To Speed Up The Ica Algorithm Without A Loss Of Quality, Mahdi Mahdikhani, Mohammad Hosein Kahaei Jan 2013

Using The Csm And Vsm Techniques To Speed Up The Ica Algorithm Without A Loss Of Quality, Mahdi Mahdikhani, Mohammad Hosein Kahaei

Turkish Journal of Electrical Engineering and Computer Sciences

In blind source separation problems that are implemented based on the independent component analysis (ICA) algorithm, the separation speed and quality are related inversely. In this paper, the proposed algorithms eliminate this tradeoff by generating a faster separation while maintaining the quality. In the proposed algorithms, in each frequency bin and in all of the learning steps, the separation quality of the separating matrix is compared with another one that we define as a situated matrix, and the best matrix is considered as an initial separating matrix in the next learning step. In this paper, we propose 2 algorithms based …


Data Hiding In Digital Images Using A Partial Optimization Technique Based On The Classical Lsb Method, Feyzi̇ Akar, Yildiray Yalman, Hüseyi̇n Selçuk Varol Jan 2013

Data Hiding In Digital Images Using A Partial Optimization Technique Based On The Classical Lsb Method, Feyzi̇ Akar, Yildiray Yalman, Hüseyi̇n Selçuk Varol

Turkish Journal of Electrical Engineering and Computer Sciences

This paper presents a new partial optimization approach for the least significant bit (LSB) data hiding technique that can be used for protecting any secret information or data. A deterioration effect of as little as possible in an image is intended using the LSB data hiding technique and this is well realized utilizing the proposed partial optimization approach achieving the same data embedding bit rates. In the proposed approach, all of the image pixels are classified into 8 regions and then the 8 distinct ordering codings are applied to each region by the developed partial optimization encoder. Thus, the most …


Power Efficient Linear Transmitters Using Sigma-Delta Modulation With Switching Amplifiers, Tayfun Nesimoglu Jan 2013

Power Efficient Linear Transmitters Using Sigma-Delta Modulation With Switching Amplifiers, Tayfun Nesimoglu

Turkish Journal of Electrical Engineering and Computer Sciences

In conventional envelope elimination and restoration transmitters, the envelope information of the carrier is reconstructed by modulating the supply voltage of the switching amplifier. In this paper, it is shown that the supply voltage modulation introduces nonlinearity and reduces the average power efficiency of the transmitter. Here, novel transmitter architectures using sigma-delta--modulated carrier signals are proposed to overcome these shortcomings. The proposed architecture's and conventional envelope elimination and restoration transmitter's linearity and efficiency performances are compared at various oversampling rates and signal bandwidths. It is demonstrated that the proposed architectures may provide better linearity and efficiency than conventional envelope elimination …


Prediction Of Emissions And Exhaust Temperature For Direct Injection Diesel Engine With Emulsified Fuel Using Ann, Görkem Kökkülünk, Erhan Akdoğan, Vezi̇r Ayhan Jan 2013

Prediction Of Emissions And Exhaust Temperature For Direct Injection Diesel Engine With Emulsified Fuel Using Ann, Görkem Kökkülünk, Erhan Akdoğan, Vezi̇r Ayhan

Turkish Journal of Electrical Engineering and Computer Sciences

Exhaust gases have many effects on human beings and the environment. Therefore, they must be kept under control. The International Convention for the Prevention of Pollution from Ships (MARPOL), which is concerned with the prevention of marine pollution, limits the emissions according to the regulations. In Emission Control Area (ECA) regions, which are determined by MARPOL as ECAs, the emission rates should be controlled. Direct injection (DI) diesel engines are commonly used as a propulsion system on ships. The prediction and control of diesel engine emission rates is not an easy task in real time. Therefore, in this study, an …


A Low-Voltage And Low-Power Sinh-Domain Universal Biquadratic Filter For Low-Frequency Applications, Farooq Khanday, Nisar Shah Jan 2013

A Low-Voltage And Low-Power Sinh-Domain Universal Biquadratic Filter For Low-Frequency Applications, Farooq Khanday, Nisar Shah

Turkish Journal of Electrical Engineering and Computer Sciences

Sinh-domain CMOS filters have favorable properties, such as a wide dynamic range at low supply voltage, compactness, linearity, and low power consumption. These properties are becoming increasingly important for biomedical applications that require extremely low-power dissipation and neuromorphic circuits that attempt to reproduce the biophysics of biological neurons and synapses. In this paper, a low-voltage sinh-domain universal biquadratic filter circuit is introduced. The circuit, aside from permitting the independent adjustment of pole frequency (\omega_0) and the quality factor (Q), is free from matching conditions, capable of absorbing the shunt parasitic capacitances, amenable for monolithic integration, and composed of merely a …


Control Of Diesel Engines Mounted On Vehicles In Mobile Cranes Via Can Bus, Muci̇z Özcan, Hi̇dayet Günay Jan 2013

Control Of Diesel Engines Mounted On Vehicles In Mobile Cranes Via Can Bus, Muci̇z Özcan, Hi̇dayet Günay

Turkish Journal of Electrical Engineering and Computer Sciences

In this study, the aim was to lift loads that required more force using the infrastructure of existing vehicles. To this end, a truck-mounted diesel engine was selected to be used in mobile crane applications. A control system was designed and implemented to obtain the appropriate hydraulic force by accessing the diesel engine with a controller area network bus via an electronic control unit (ECU). For this purpose, hydraulic pumps to be used to operate the crane were mounted on the selected mobile diesel engine with an ECU. Firms that manufacture cranes in the world produce cranes with infrastructure. This …


Stopping Spam With Sending Session Verification, Ahmet Baran Jan 2013

Stopping Spam With Sending Session Verification, Ahmet Baran

Turkish Journal of Electrical Engineering and Computer Sciences

Spam has become one of the most significant problems for Internet communication and users today. The traditional filtering methods and signature-based spam blocking systems that have come into prominence recently fall short, as statistics demonstrate that spam further mounts up day after day. In this study, a new method is recommended to block spam mails. In this recommended method, a mail sending session is verified during mail envelope communication by adding small attachments to the simple mail transfer protocol, so spam mails can be blocked before leaving the sender domain or relay machine. Additionally, hijacked user accounts are able to …


Xor-Based Artificial Bee Colony Algorithm For Binary Optimization, Mustafa Servet Kiran, Mesut Gündüz Jan 2013

Xor-Based Artificial Bee Colony Algorithm For Binary Optimization, Mustafa Servet Kiran, Mesut Gündüz

Turkish Journal of Electrical Engineering and Computer Sciences

The artificial bee colony (ABC) algorithm, which was inspired by the foraging and dance behaviors of real honey bee colonies, was first introduced for solving numerical optimization problems. When the solution space of the optimization problem is binary-structured, the basic ABC algorithm should be modified for solving this class of problems. In this study, we propose XOR-based modification for the solution-updating equation of the ABC algorithm in order to solve binary optimization problems. The proposed method, named binary ABC (binABC), is examined on an uncapacitated facility location problem, which is a pure binary optimization problem, and the results obtained by …


Hybrid Spr Algorithm To Select Predictive Genes For Effectual Cancer Classification, Aruna Sundaram, Nandakishore Lellapalli Venkata, Rajagopalan Sarukai Parthasarathy Jan 2013

Hybrid Spr Algorithm To Select Predictive Genes For Effectual Cancer Classification, Aruna Sundaram, Nandakishore Lellapalli Venkata, Rajagopalan Sarukai Parthasarathy

Turkish Journal of Electrical Engineering and Computer Sciences

Designing an automated system for classifying DNA microarray data is an extremely challenging problem because of its high dimension and low amount of sample data. In this paper, a hybrid statistical pattern recognition algorithm is proposed to reduce the dimensionality and select the predictive genes for the classification of cancer. Colon cancer gene expression profiles having 62 samples of 2000 genes were used for the experiment. A gene subset of 6 highly informative genes was selected by the algorithm, which provided a classification accuracy of 93.5%.


Flow Velocity Measurement And Analysis Based On Froth Image Sift Features And Kalman Filter For Froth Flotation, Jinping Liu, Weihua Gui, Zhaohui Tang Jan 2013

Flow Velocity Measurement And Analysis Based On Froth Image Sift Features And Kalman Filter For Froth Flotation, Jinping Liu, Weihua Gui, Zhaohui Tang

Turkish Journal of Electrical Engineering and Computer Sciences

The flow velocity of flotation froth involves important information about the concentrate grade and the mineral recovery. It is significant to maintain the flow velocity of the froth at proper levels to achieve a good production performance in the machine vision-based process monitoring and control. However, the accurate velocity field measurement for the heavily deformed and seriously fragile froth bubbles is still a great challenge. Scale-invariant feature transform (SIFT) feature-based image matching provides an effective registration method for deformed objects, but most of the processing time would be wasted on the feature extraction and matching in irrelevant regions of the …


Abundance And Diversity Of Organohalide-Respiring Bacteria In Lake Sediments Across A Geographical Sulfur Gradient, Patrick J. Mcnamara, Benjamin B. Crary, Paige J. Novak, Mark J. Krzmarzick Jan 2013

Abundance And Diversity Of Organohalide-Respiring Bacteria In Lake Sediments Across A Geographical Sulfur Gradient, Patrick J. Mcnamara, Benjamin B. Crary, Paige J. Novak, Mark J. Krzmarzick

Civil and Environmental Engineering Faculty Research and Publications

Across the U.S. Upper Midwest, a natural geographical sulfate gradient exists in lakes. Sediment grab samples and cores were taken to explore whether this sulfur gradient impacted organohalide-respiring Chloroflexi in lake sediments. Putative organohalide-respiring Chloroflexi were detected in 67 of 68 samples by quantitative polymerase chain reaction. Their quantities ranged from 3.5 × 104 to 8.4 × 1010 copies 16S rRNA genes g−1 dry sediment and increased in number from west to east, whereas lake sulfate concentrations decreased along this west-to-east transect. A terminal restriction fragment length polymorphism (TRFLP) method was used to corroborate this inverse relationship, …


Quantification Of The Environmental Impact Of Titanium Dioxide Photocatalytic Pavements For Air Pollution Remediation, Heather Lee Dylla Jan 2013

Quantification Of The Environmental Impact Of Titanium Dioxide Photocatalytic Pavements For Air Pollution Remediation, Heather Lee Dylla

LSU Doctoral Dissertations

Photocatalytic concrete pavements are a promising technology for mobile source air pollution remediation, however before widespread application of this technology is realized many unanswered questions remain regarding its overall environmental impact. In response to these questions, the goal of this study was to increase the understanding of the environmental impact of photocatalytic concrete pavement highways. To achieve this goal, the objectives of this study were to (A) construct a model that evaluates the nitrogen oxides (NOx) reduction from photocatalytic pavements, (B) quantify the nitrates released from the photocatalytic degradation of NOx, and (C) identify and characterize pathways for TiO2 nanoparticle …


Silver Nanoparticles As Drug Delivery Systems, Ammar Tahseen Qureshi Jan 2013

Silver Nanoparticles As Drug Delivery Systems, Ammar Tahseen Qureshi

LSU Doctoral Dissertations

The goal of this project is to study the potential applications of silver nanoparticles (SNPs) in the medical device and pharmaceutical industries. Bone cements have been used in the orthopedic surgeries for many years to anchor prosthetics while filling up the spaces between the prostheses and bone. Antibiotics are an active component of bone cements but the increasing bacterial resistance to these antibiotics and difficulty of shaping and molding the bone cements increases the need for new antimicrobial biomaterials. Adult stem cell based regenerative therapies have been one of the most widely researched areas of tissue engineering. This is due …


Applications Of Antioxidant And Anti-Inflammatory Polymers To Inhibit Injury And Disease, David B. Cochran Jan 2013

Applications Of Antioxidant And Anti-Inflammatory Polymers To Inhibit Injury And Disease, David B. Cochran

Theses and Dissertations--Chemical and Materials Engineering

There is an undeniable link between oxidative stress, inflammation, and disease. Currently, approaches using antioxidant therapies have been largely unsuccessful due to poor delivery and bioavailability. Responding to these limitations, we have developed classes of polymer and delivery systems that can overcome the challenges of antioxidant and anti-inflammatory therapy. In our initial studies, nanoparticles of poly(trolox), a polymeric form of trolox, were surface-modified with antibodies. This modification allows for specific targeting to endothelial cells, affording controllable and localized protection against oxidative stress. We have shown these targeted nanoparticles bind, internalize, and provide protection against oxidative stress generation and cytotoxicity from …


The Effects Of Ceria Addition On Aging And Sulfation Of Lean Nox Traps For Stand Alone And Lnt-Scr Applications, Vencon G. Easterling Jan 2013

The Effects Of Ceria Addition On Aging And Sulfation Of Lean Nox Traps For Stand Alone And Lnt-Scr Applications, Vencon G. Easterling

Theses and Dissertations--Chemical and Materials Engineering

THE EFFECTS OF CERIA ADDITION ON AGING AND SULFATION OF LEAN NOx TRAPS FOR STAND ALONE AND LNT-SCR APPLICATIONS

Model powder and fully formulated monolithic lean NOx trap (LNT) catalysts were used to investigate the effect of ceria on desulfation behavior. Temperature-programmed reduction (TPR) experiments (model catalysts) showed each of the oxide phases present is able to store sulfur and possesses distinct behavior (temperature at which desulfation occurs). La-CeO2 or CeO2-ZrO2-containing samples (monoliths) showed a greater resistance to deactivation during sulfation and required lower temperatures to restore the NOx storage efficiency to …


Characterization Of And Controlling Morphology Of Ultra-Thin Nanocomposites, Guy C. Laine Jan 2013

Characterization Of And Controlling Morphology Of Ultra-Thin Nanocomposites, Guy C. Laine

Theses and Dissertations--Chemical and Materials Engineering

Ultrathin film nanocomposites are becoming increasingly important for specialized performance of commercial coatings. Critical challenges for ultrathin film nanocomposites include their synthesis and characterization as well as their performance properties, including surface roughness, optical properties (haze, refractive index as examples), and mechanical properties. The objective of this work is to control the surface roughness of ultrathin film nanocomposites by changing the average particle size and the particle volume fraction (loading) of monomodal particle size distributions. This work evaluated one-layer and two-layer films for their surface properties. Monodispersed colloidal silica nanoparticles were incorporated into an acrylate-based monomer system as the model …


Influence Of Surface Modification On Properties And Applications Of Complex Engineered Nanoparticles, Binghui Wang Jan 2013

Influence Of Surface Modification On Properties And Applications Of Complex Engineered Nanoparticles, Binghui Wang

Theses and Dissertations--Chemical and Materials Engineering

Complex engineered nanoparticles (CENPs) are being used on various applications. Their properties are different from those of neat nanoparticles. The dissertation explores these differences from four aspects: 1) Modify carbon nanomaterials’ inert surfaces and investigate the effect on thermal and rheological behavior of their dispersions; 2) Generate self-assembly bi-layer structure of oxide nanoparticles via surface modification; 3) Study interaction between lysozyme and different surface-charged ceria nanoparticles; 4) Investigate the biodistribution and transformations of CENPs in biological media.

An environment-friendly surface modification was developed to modify surfaces of carbon nanomaterials for increasing their affinity to non-polar fluid. It can offset formation …


Structural Tailoring Of Nanoporous Metals And Study Of Their Mechanical Behavior, Lei Wang Jan 2013

Structural Tailoring Of Nanoporous Metals And Study Of Their Mechanical Behavior, Lei Wang

Theses and Dissertations--Chemical and Materials Engineering

Nanoporous (np) metals and alloys are the subject of increasing research attention due to their high surface-area-to-volume ratio. Numerous methods exist to create np metals, with dealloying being a common approach. By dissolving one or more elements from certain alloy systems, porous structure can be generated. Utilizing this method, multiple np metals, including np-Ni, np-Ir, and np-Au were created. By carefully adjusting precursor type and dealloying conditions for each system, nanoporous Ni/Ir/Au with different morphologies and even controllable ligament/pore size were achieved.

The mechanical behavior of porous materials is related to their fully dense counterparts by scaling equations. Established scaling …