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2005

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Articles 1171 - 1200 of 3074

Full-Text Articles in Engineering

Stereo Vision Algorithm Using Propagation Of Correspondences Along An Array Of Cameras, Danyan Ganjali May 2005

Stereo Vision Algorithm Using Propagation Of Correspondences Along An Array Of Cameras, Danyan Ganjali

Theses

One well known problem in stereo vision is the trade-off between precision and accuracy.

In a conventional two camera model, as the baseline separating the two cameras becomes smaller, the images that both cameras produce become more identical. This results in a more accurate set of correspondences, however at the same time causing less precise depth measurement due to the small angle used for triangulation. Similarly, in a larger baseline model, the depth measurement is more precise while the correspondences are not as accurate as of the shorter baseline model. This thesis proposes a method that promises to solve the …


Evaluation Of Unifac Group Interaction Parameters Usijng Properties Based On Quantum Mechanical Calculations, Hansan Kim May 2005

Evaluation Of Unifac Group Interaction Parameters Usijng Properties Based On Quantum Mechanical Calculations, Hansan Kim

Theses

Current group-contribution methods such as ASOG and UNIFAC are widely used for approximate estimation of mixture behavior but unable to distinguish between isomers. Atoms in Molecules (AIM) theory can solve these problems by using quantum mechanics and computational chemistry to compute atomic contributions to molecular properties and to intermolecular interactions. Rigorously defined properties available through AIM theory and new functional group definitions are used for the UNIFAC model to predict the behavior of various mixtures. Results are presented for various mixtures with nine regressed global parameters to optimize model's predictive capability. The results are also compared to analogous results for …


Non-Linear Digital Control Of A Mckibben Muscle System, Surinkumar Patel May 2005

Non-Linear Digital Control Of A Mckibben Muscle System, Surinkumar Patel

Theses

McKibben muscles are pneumatic actuators that have potential application in the rehabilitation of persons with physical impairments. These actuators have been known to exhibit similarities in human musculoskeletal systems. In order to better understand and improve the closed - loop control of these pneumatic muscles, a physical joint model was constructed with an agonist and an antagonist muscle operating under non-linear control. With the use of LabVIEW software, compliant McKibben air muscles and Flock-of-Birds sensor, the author was able to implement and compare a standard bang-bang controller and experimental non-linear digital Proportional (P) controller. The feedback mechanism is based on …


Ambulatory Biopotential Measurement, Lakshmi Chitra Penugonda May 2005

Ambulatory Biopotential Measurement, Lakshmi Chitra Penugonda

Theses

Biopotential signals measure the electrical activity of different parts of the body. Conventional bedside monitors only provide information about the body under restricted conditions. Observation and documentation of biopotential signal during daily activities and the relation to patient symptoms may be important factors for clinical decision-making. Ambulatory monitoring helps to monitor the biopotential signal of a patient in the natural environment. The effective ambulatory system can help a physician to diagnose the patient's abnormality.

In this project, a low cost and flexible ambulatory biopotential system, compared to the commercially available systems, was designed and tested. Concurrently a software program was …


Difference-Expansion Based Reversible Data Hiding And Its Steganalysis, Guangsen Tian May 2005

Difference-Expansion Based Reversible Data Hiding And Its Steganalysis, Guangsen Tian

Theses

A novel reversible data embedding method was reported in a recent IEEE journal article. The method was based on difference expansion (DE) technique. It used redundancy in digital images to achieve a high embedding capacity, while keeping visual distortion of the stego-image low. In this thesis, this technique was studied and experimentally evaluated. An effective steganalysis scheme for this DE-based reversible data embedding method was proposed, which used 12-dimensional feature vectors and a Bayes Classifier. The proposed steganalysis scheme steadily achieved a correct classification rate of 99%.


Performance Of Multi-User Codes In Wireless Communications, Muhammad Tauseef Ulislam May 2005

Performance Of Multi-User Codes In Wireless Communications, Muhammad Tauseef Ulislam

Theses

Multi-user codes are a widely used in transmitting user data from base station to mobile station and vice versa. In wireless communications a signal received by a mobile station goes through different fading channels resulting. These multi-paths add constructively and destructively with different delays and attenuation at the mobile station. The autocorrelation and cross correlation properties of the Multi-user codes play a significant role in extracting the user data from the signal corrupted by multipath fading channel.

The thesis presents a comparison of different Multi-user codes based on their autocorrelation and cross correlation properties. These codes are passed through a …


Analysis Of Acceleration And Deceleration During Cyclic Exercise, Jeena Vadi May 2005

Analysis Of Acceleration And Deceleration During Cyclic Exercise, Jeena Vadi

Theses

The Cyclic Exercise Protocol is a novel protocol that is designed to create a series of cyclic waves of exercise and recovery. This exercise protocol involves short bursts of exercise lasting for 60 seconds or less followed by a period of complete cardio recovery. This study involves the analysis of the acceleration and the deceleration regions of the cyclic exercise sessions. The objective of this study was to develop an algorithm to quantitatively analyze the acceleration and the deceleration regions of cyclic exercise sessions. The acceleration and the deceleration regions of cycles were split into three segments and each segment …


Evaluation Of Knox Group Contribution Parameters Using Quantum Based Molecular And Group Properties, Myriam Carrillo May 2005

Evaluation Of Knox Group Contribution Parameters Using Quantum Based Molecular And Group Properties, Myriam Carrillo

Theses

Thermodynamic property prediction through the group contribution methods has been improving. However, the approaches considered in the past present not only limitations on the physical basis but often have restrictions as to certain substances, such as isomers. A new group contribution method is proposed that uses AIM theory, which is based on computational chemistry and quantum mechanics, to overcome these limitations by treating each molecule individually. An evaluation of this method as applied to the Knox model is proposed and analyzed for Vapor Liquid Equilibrium (VLE) of mixtures with the help of nine global parameters that are obtained by correlation. …


Analysis Of Mhpdm Algorithm For Data Hiding In Jpeg Images, Pooja Gore May 2005

Analysis Of Mhpdm Algorithm For Data Hiding In Jpeg Images, Pooja Gore

Theses

In the recent years, there has been a great deal of interest in developing a secure algorithm for hiding information in images, or steganography. There has also been a lot of research in steganalysis of images, which deals with the detection of hidden information in supposedly natural images. The first section of this thesis reviews the steganography algorithms and steganalysis techniques developed in the last few years. It discusses the breadth of steganographic algorithms and steganalytic techniques, starting with the earliest, based on LSB flipping of the DCT coefficients, to more recent and sophisticated algorithms for data hiding and equally …


Microparticle Influenced Electroosmotic Flow, John M. Young May 2005

Microparticle Influenced Electroosmotic Flow, John M. Young

Theses and Dissertations

The influence of microparticles on electroosmotic flow was investigated experimentally and numerically. Experiments were conducted using four different particle types of varying chemical composition, surface charge and polarity. Each particle type was tested at five different volume fractions ranging from 0.001 – 0.025. With a constant applied electric field, positively charged particles enhanced the electroosmotic flow by as much as 850%. The enhancement depended on particle composition, size and concentration. For negatively charged particles, the bulk electroosmotic flow was retarded with the largest reductions being 35%. This occurred for the greatest negative paricle concentration studied. A final experimental study utilizing …


On Performance Analysis Of Optimal Diversity Combining With Imperfect Channel Estimation, Yong Peng May 2005

On Performance Analysis Of Optimal Diversity Combining With Imperfect Channel Estimation, Yong Peng

Theses

The optimal diversity combining technique is investigated for multipath Rayleigh and Ricean fading channel with additive white Gaussian noise where only imperfect channel knowledge is available at the receiver. The non-observable estimation error contributes as an additive source of noise which is not white. Therefore, the optimal combining weight is derived taking into consideration the imperfect channel knowledge.

The bit error rate for BPSK modulation over correlated Rayleigh and Ricean fading channel is derived for minimum mean square channel estimation using pilot symbol assisted modulation. Analytical result and Monte-Carlo simulation are presented for specific channel and estimation models to demonstrate …


Enabling Cost Aware Routing With Auctions In Wireless Ad-Hoc Networks, Ali Yuksel May 2005

Enabling Cost Aware Routing With Auctions In Wireless Ad-Hoc Networks, Ali Yuksel

Theses

Battery power is a precious resource in wireless ad-hoc networks, and most routing protocols that have been proposed so far do not generate cost efficient routes. In this thesis, a novel auction-based cost-aware routing scheme, called CARA, is presented. CARA is designed as an extension of the MAC layer, and is shown to improve the cost efficiency of existing ad-hoc routing protocols through dynamic power control, while introducing only minimal additional overhead. The MAC layer at each node is given the capability to run local sealed-bid second-price auctions for the user data packets that need to be transmitted, and to …


Multilevel Fusion Using Enhanced Feature Detection, Trond M. Ostrem, Samuel Peter Kozaitis May 2005

Multilevel Fusion Using Enhanced Feature Detection, Trond M. Ostrem, Samuel Peter Kozaitis

Electrical Engineering and Computer Science Faculty Publications

We combined images from different sensors based on the magnitude of multiscale products of the wavelet transform. Using the product of nondownsampled wavelet coefficients across scales, we formed a fusion rule between two images. In this way, the products represented features than were related to contrast. Therefore, using our approach allowed us to enhance the contrast of two images using a pixel-level fusion approach. In experiments, our approach compared favorably to using only a single level, or other methods using subjective tests.


Potential Fluctuations Of 7075 Aluminum Alloy Under Thin Electrolyte Layers, Su-Jing Chen, Qing-Ming Yuan, Jian-Ping He, Xiao-Lei Liu May 2005

Potential Fluctuations Of 7075 Aluminum Alloy Under Thin Electrolyte Layers, Su-Jing Chen, Qing-Ming Yuan, Jian-Ping He, Xiao-Lei Liu

Journal of Electrochemistry

Lens tissues adsorbing 3.5% sodium chloride solution were used to simulate thin electrolyte layers. The 7075 aluminum alloy was immersed under the thin electrolyte layers for 0, 4, 6, 8 and 12 h respectively. Then the fluctuations of natural-corrosion potentials of the alloy were monitored. The fluctuations of natural-corrosion potential were observed rather small in the initial corrosion stages after 6h immersion, and the positive peaks of potential appeared. However the amplitudes reached 20mV after 4h and 12h immersion. The RMS of natural-corrosion potentials decreased with corrosion time at first and then increased. It reached a minimum at 4 h. …


Application Of Nickel Foam Electrode For Electroreduction Intermediate Of Purine, Hui-Wen Yang, Xi-En Hu, Xue-Jun Wang May 2005

Application Of Nickel Foam Electrode For Electroreduction Intermediate Of Purine, Hui-Wen Yang, Xi-En Hu, Xue-Jun Wang

Journal of Electrochemistry

Nickel foam with weight uniformity, good porosity ,pore size and low resistivity as a three-dimensional cathode was used in a filter-press electrochemical reactor. The H2SO4 as supporting electrolyte, separator of cation ion exchange membrane, and the lead plate as an anode were used. The cyclic system consisted of electroreduction reactor, pump, store tank and ampere meter. NAU was electroreduced in the cathode chamber of the reactor. Purine intermediate was synthesized with DAU, and the results were compared with those of iron powder reduction process. A peak current in the electroreduction process was detected. The current density of …


Ni-Mo-P Alloy By Electroless Deposition And Its Properties, Sen-Lin Wang, Xin-Ren Lan, Ting-Ting Huang, Jun-Mo Jin, Ji-Bei Ling, Zhi-Ming Chen May 2005

Ni-Mo-P Alloy By Electroless Deposition And Its Properties, Sen-Lin Wang, Xin-Ren Lan, Ting-Ting Huang, Jun-Mo Jin, Ji-Bei Ling, Zhi-Ming Chen

Journal of Electrochemistry

The electroless Ni-Mo-P alloy has been deposited from the alkaline bath containing boric acid as a buffer agent and sodium citrate as a complexing agent. The effect of deposition parameters, such as pH and concentration of (NH4)6Mo7O24·4H2O on the plating rate, the composition, the structure and the microhardness of the coating was examined. It was found that the presence of molybdenum has an inhibitory effect on the alloys deposition. As a consequence, the percentage of molybdenumin the Ni-Mo-P coatings never reaches high values, which was lower than 20 at%. It …


Using Electrodeposition To Fabricate Mould For Polymer Microfluidic Chip, Yi Luo, De-Nan Chu, Zhi-Feng Lou, Chong Liu, Li-Ding Wang May 2005

Using Electrodeposition To Fabricate Mould For Polymer Microfluidic Chip, Yi Luo, De-Nan Chu, Zhi-Feng Lou, Chong Liu, Li-Ding Wang

Journal of Electrochemistry

Many researches have been focused on polymer microfluidic chip in recent years and the mould plays an important role in its fabrication process. Using electrodepositingmethod to fabricate a metal mould for polymer microfluidic chip has been presented in this paper. An ultra-thick photoresist SU-8 was coated on a pretreated metal plate, after photolithography, nickel was electrodeposited in the patterned SU-8, then was removed the SU-8 to obtain a final metal mould. This methodreduces workload of electrodeposit largely. Applying counter current before deposit, adding additive to solution and vacuum anneal after demould have been used to improve the binding force between …


Preparation, Characterization And Electrochemical Properties Of Nano Tio2-Cnt-Pt On Ti Substrate Complex Electrode, Dao-Bao Chu, De-Xiang Feng, Jin-Hua Zhang, Xiao-Hua Li May 2005

Preparation, Characterization And Electrochemical Properties Of Nano Tio2-Cnt-Pt On Ti Substrate Complex Electrode, Dao-Bao Chu, De-Xiang Feng, Jin-Hua Zhang, Xiao-Hua Li

Journal of Electrochemistry

The nanoTiO2-CNT-Pt on Ti substrate complex electrodes were prepared from precursor of (Ti(OEt)4) directly hydrolyzed and by cyclic voltammograms electroplating method . The XRD and SEM results showed that the nano TiO2 (anatase) particle sizes ranged 5~10 nm and the Pt nanoparticle (average size 9nm) dispersed uniformly on nanoTiO2-CNT film surface. The electrocatalytic activity of Ti/nanoTiO2-CNT-Pt electrode was investigated by cyclic voltammetry and chronopotentiogram. The results indicated that the Ti/nanoTiO2-CNT-Pt electrode exhibited very high electrocatalytic activity and stability for the electro-oxidation of methanol at room temperature. When Pt loading …


A Comparison On Structural Sensitive Adsorption Of Sb On Au Single Crystalline Electrodes, Jia-Wei Yang, Wang-Huo Shang, Qiong Wu, Bing-Wei Mao May 2005

A Comparison On Structural Sensitive Adsorption Of Sb On Au Single Crystalline Electrodes, Jia-Wei Yang, Wang-Huo Shang, Qiong Wu, Bing-Wei Mao

Journal of Electrochemistry

We compare the behaviors of irreversible adsorption of Sb(III) and its reduction, underpotential deposition of Sbon Au(111) and Au(100) as well as mutual interactions of the processes. Based on in-situ scanning tunneling microscopic and cyclic voltammetric results, the substrate structure not only influence anion adsorptionbehavior and thus the Sb adsorption structure, but also the stability of its own structure. On Au(111) surface,the irreversibly adsorbed dense and disordered SbO+ film structure remains after reduction of the film; while on Au(100)surface, due to the coadsorption of SO42-, an ordered(2×2)structure is formed after reduction. UPD of Sb on Au(111) …


The Preparation And Performance Of The Aqueous Matrix For Molten Carbonate Fuel Cells, Hua-Xin Lin, Mo-Jie Ceng, Bao-Lian Yi May 2005

The Preparation And Performance Of The Aqueous Matrix For Molten Carbonate Fuel Cells, Hua-Xin Lin, Mo-Jie Ceng, Bao-Lian Yi

Journal of Electrochemistry

PVA matrix of MCFC was prepared from the α-LiAlO2 powder, and polyvinylalcohol(PVA), Compared with the conventional PVB matrix, higher porosity, higher thermal weight loss and smaller maximum pore diameter were achieved for PVA matrix. Single cell was assembled with PVA matrix. At reaction gas pressure of 0.9 MPa, under reaction gas utilization of 20%, at 300 and 428.57 mA·cm-2, the cell voltage was 0.849 and 0.739 V respectively, and the output power density was 254.7 and 316.7 mW·cm-2 respectively, which are higher than those of the cell assembled with PVB matrix. During thermal cycles, the cell …


Fabrication Of Nano Capacitor And Its Electrical Properties, Ling Liu, Qin Zhou, Neng-Qin Jia, Zhi-Yu Jiang May 2005

Fabrication Of Nano Capacitor And Its Electrical Properties, Ling Liu, Qin Zhou, Neng-Qin Jia, Zhi-Yu Jiang

Journal of Electrochemistry

A step-by-step assembling method was developed for preparing nano capacitors using anodic aluminum oxide (AAO) membrane as templates. The nano capacitor consisted of three parts: electrochemically polymerized PPy electrode/ el ectrochemically precipitated porous TiO2 separator/chemically polymerized PPy electrode, and demonstrated the charge/discharge behavior as a typical electrochemical supercapacitor with good cyclic ability.


Electrochemical Stability Of Pva Alkaline Gel Polymer Electrolyte Membranes, Jun-Hong Wang, Jian-Min Liu, Hua-Bin Yang, Zuo-Xiang Zhou May 2005

Electrochemical Stability Of Pva Alkaline Gel Polymer Electrolyte Membranes, Jun-Hong Wang, Jian-Min Liu, Hua-Bin Yang, Zuo-Xiang Zhou

Journal of Electrochemistry

Polyvinyl alcohol (PVA) alkaline polymer gel electrolyte (GPE) membranes were successfully prepared by a solution-casting technique and their electrochemical stabilities were investigated. The electrochemical impedance spectrum (EIS) results showed that the ionic conductivity of the PVA alkaline GPE membranes first increased with the increase of KOH content, then decreased with the further increase of KOH. When the weight percentage of the KOH in the PVA alkaline GPE membrane approached to 42%, it exhibitedthe highest ionic conductivity of 2.01×10-3 S/cm at room temperature (R.T.). The X-ray diffraction (XRD) results revealed that with the increase of KOH the crystalline of the …


A Preliminary Study Of Electrocrystallization Of Bismuth On Glassy Carbon, Min-Li Yang, Zhan-Jun Zhang May 2005

A Preliminary Study Of Electrocrystallization Of Bismuth On Glassy Carbon, Min-Li Yang, Zhan-Jun Zhang

Journal of Electrochemistry

The electrocrystallization of bismuth on glassy carbon electrodes (GCEs) from nitrate solutions was studied by cyclic voltammetry and chronoamperometry. Cyclic voltammograms exhibit a crossover between the cathodic and anodic branches, characteristic of the formation of bismuth nuclei on GCEs, and show that the bismuth electrocrystallization on GCEs is a diffusion-controlled reaction. The current transients were analyzed with the Scharifker and the Heerman equations. With the increaseof Bi3+ concentration, the non-dimensional plots leaned to the theoretical curve for 3D instantaneous nucleation and growth. The overpotential dependence of nucleation and growth mechanism was also found. With the increase of overpotential, the …


The Synthesis, Characteristics And Performance Of Cnt Composites As Anodic Materials In Litium-Ion Battery, Quan-Feng Dong, Ming-Sen Zheng, Zhen-Cai Huang, Ming-Gang Jin, Ya-Ding Zhan, Zu-Geng Lin May 2005

The Synthesis, Characteristics And Performance Of Cnt Composites As Anodic Materials In Litium-Ion Battery, Quan-Feng Dong, Ming-Sen Zheng, Zhen-Cai Huang, Ming-Gang Jin, Ya-Ding Zhan, Zu-Geng Lin

Journal of Electrochemistry

As an anodic material for lithium ion battery the carbon nano-tube (CNT) and some compounds based on tin have ever been investigated intensively. The fruited progress has not been made yet, however. In this paper the composites of CNT and Sn/SnO2 were synthesized employing two methods and characterized by SEM and XRD. And the electrochemical performance of the composites was investigated.


Preparation And Characterization Of Mcm-41/Pvdf-Hfp Composite Microporous Polymer Electrolytes For Li-Ion Batteries, Zuo-Feng Chen, Yan-Xia Jiang, Quan-Chao Zhuang, Quan-Feng Dong, Shi-Gang Sun May 2005

Preparation And Characterization Of Mcm-41/Pvdf-Hfp Composite Microporous Polymer Electrolytes For Li-Ion Batteries, Zuo-Feng Chen, Yan-Xia Jiang, Quan-Chao Zhuang, Quan-Feng Dong, Shi-Gang Sun

Journal of Electrochemistry

MCM-41/vinylidine fluoride-hexafluropropene copolymer (PVdF-HFP) composite microporous polymer electrolytes were prepared with mixed solvent of N, N-Dimethylformamide (DMF) and acetone. The influence of MCM-41 and nano-SiO2 on the porous structure of the microporous polymer electrolytes were studied with SEM. The results show that MCM-41 could take the place of the plasticizer in the process of making pores, and bring the preparation of microporous membranes easily. The preliminary electrochemical tests showed that the ion conductivity of composite microporous polymer electrolyte with 10% MCM-41 was about 10-3 S cm-1, and the performance of batteries was improved. The mesoporous MCM-41selected …


Investigation On Ru-Ti-Ir-Sn Oxide Anode Coatings For Electrolyzing Seawater, Ke Wang, Yan Han, Lei-Yuan Wang, Xiao-Ling Zhang, Yu-Pu Sun May 2005

Investigation On Ru-Ti-Ir-Sn Oxide Anode Coatings For Electrolyzing Seawater, Ke Wang, Yan Han, Lei-Yuan Wang, Xiao-Ling Zhang, Yu-Pu Sun

Journal of Electrochemistry

The anode coatings of Ru-Ti-Ir-Sn oxide with various compositions were prepared by thermal decomposition. The physical and electrochemical properties of the coatings were characterized by scanning electron microscope (SEM), energy dispersive X-ray detector (EDX), accelerated life, current efficiency, anti-Mn2+ contamination, polarization curveandcyclic voltammetry tests. The results showed thatthe anode coating with optimized formula possessed excellent overall properties for electrolyzing seawater.


Structure And Corrosion Electrochemical Properties Of Self-Assembled (3-Mercaptopropyl) Trimethoxysilane Films On Copper Electrode, Ling Huang, Ke-Fa Lin, Fang-Zu Yang, Shu-Kai Xu, Shao-Min Zhou May 2005

Structure And Corrosion Electrochemical Properties Of Self-Assembled (3-Mercaptopropyl) Trimethoxysilane Films On Copper Electrode, Ling Huang, Ke-Fa Lin, Fang-Zu Yang, Shu-Kai Xu, Shao-Min Zhou

Journal of Electrochemistry

A self-assembled monolayer of (3-mercaptopropyl) trimethoxysilane(MPTS) was formed on a electrochemical polished copper surface electrode. The corrosion protection abilities of the monolayer were evaluated in 5% NaCl solution using electrochemical linear polarization. The effects of deposition time and silane concentration on corrosion of copper were also discussed. The surface structure of MPTS films was measured by FT-IR and SEM. It was found that the corrosion resistance of copper was reduced markedly owing to the MPTS monolayers formation on copper. The MPTS monolayer retarded the reduction of dissolved oxygen and inhibited the growth of copper oxide in the NaCl solution. FT-IR …


Selective Electroless Copper Plating Micro-Pattern On Ceramics Without Sensitisation And Activation, Zhen-Lin Xu, Qi-Long Guo, Yi-Cheng Shen, Xiong-Chao Zhao, Yan-Ping Hong, Zhi-Jun Gu May 2005

Selective Electroless Copper Plating Micro-Pattern On Ceramics Without Sensitisation And Activation, Zhen-Lin Xu, Qi-Long Guo, Yi-Cheng Shen, Xiong-Chao Zhao, Yan-Ping Hong, Zhi-Jun Gu

Journal of Electrochemistry

The purpose of this article is to provide a new technology of electroless copper plating without palladium activation steps. By combining the technology of laser micro-etching with the new copper-plating bath, copper plating on ceramics was obtained. The experimental results showed that the solution used for copper electroless plating was stable and the copper coating obtained was bright, dense with good electrical conductivity.The line definition was about 40 μm. The electroless Cu films deposited from this system were gentle and required simple operating conditions.


Study On Synthesis Of M-Phenoxy Benzoic Acid By Electrolysis Oxidation Method, Wei Xu, Chong-Tao Zhao May 2005

Study On Synthesis Of M-Phenoxy Benzoic Acid By Electrolysis Oxidation Method, Wei Xu, Chong-Tao Zhao

Journal of Electrochemistry

The m-phenoxy benzoic acid was synthesized by oxidation m-phenoxy toluene using Cr(Ⅵ)as oxidation media, which was prepared by electrolysis oxidation of Cr(Ⅲ)in the electrochemical bath using Nafion 417 as a diaphragm, Pb-PbO2 as an anode and Pb as cathode. The effect factors on the electrochemical oxidation of Cr(Ⅲ)to Cr(Ⅵ)in this electrolysis were studied. Furthermore, the optimal conditions for electronic synthesis of m-phenoxy benzoic acid were also discussed.


The Effect Of Oxidant On Structure And Properties Of Pan/Ptfe Conducting Composite Membrane, Chang-Yuan Tao, Jing Chen, Jun Du, Cai-Xin Sun May 2005

The Effect Of Oxidant On Structure And Properties Of Pan/Ptfe Conducting Composite Membrane, Chang-Yuan Tao, Jing Chen, Jun Du, Cai-Xin Sun

Journal of Electrochemistry

The PAn/PTFE conducting composite membrane was prepared by means of in-situ permeating chemical polymerization, with (NH4)2S2O8 and Na3VO4 being used as an oxidant respectively. The polymerization-growth behavior of the aniline by using different oxidant was compared. In addition, the oxidant effect on the structure and properties of conducting composite membrane was discussed. The results of SEM micrographs, pore size distribution and electrochemical methods suggested that using either oxidants could also induce the product with small pore size and dense pore structure. Compared with (NH4)2S2O …