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Full-Text Articles in Engineering

The Drivers And Barriers To Customer Value Creation: Issues And Prespectives In The Marble Sector Smes Of North-West Frontier Province, Pakistan, Muhammad Noman Jul 2007

The Drivers And Barriers To Customer Value Creation: Issues And Prespectives In The Marble Sector Smes Of North-West Frontier Province, Pakistan, Muhammad Noman

Business Review

The concept of value and, more specifically, customer value is of increasing interest to both academics and practitioners. Many see it as the next source of competitive advantage. Like other regions of the country, the North-West Frontier Province of Pakistan has a presence of SMEs in many sectors. A major one amongst these is the marble sector; characterized by two sub-sectors, marble mining and marble processing. A review of various studies in the marble sector reveals that about 70 percent of marble reserves in Pakistan are being wasted due to poor mining and processing techniques. The situation is further aggravated …

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Adaptive Iir Filters For Single Interference Suppression In A Bpsk Ds Cdma System In Rayleigh Fading Channel, Aloys Mvuma Jun 2007

Adaptive Iir Filters For Single Interference Suppression In A Bpsk Ds Cdma System In Rayleigh Fading Channel, Aloys Mvuma

Tanzania Journal of Engineering and Technology (TJET)

In this paper, effect of a single narrow-band interference (NBI) on bit error rate (BER) performance for a binary phase shift keying (BPSK) synchronous direct-sequence code-division multiple access (DS CDMA) communication system operating in a frequency nonselective Rayleigh fading channel is analyzed. Second-order adaptive infinite impulse response (IIR) notch filters with plain gradient algorithm (GA) for suppression of NBI in the DS CDMA system are proposed. A general closed-form BER expression for the DS CDMA system with NBI suppression second order adaptive IIR notch filters is derived based on the standard Gaussian approximation (SGA) method. BER expressions are then derived …

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Optimal Utilization Of Timber Poles As Structural Members Of Formwork, Ladislaus Lwambuka Jun 2007

Optimal Utilization Of Timber Poles As Structural Members Of Formwork, Ladislaus Lwambuka

Tanzania Journal of Engineering and Technology (TJET)

Timber poles of the type “Mirunda” are commonly used in East Africa as formwork support structures for casting of reinforced concrete slabs, beams and canopies. It is also widely known that the “Mirunda” poles as structural members of formwork are massively used without any structural consideration and guidance. This common practice has resulted into wastage of natural resources and escalated construction costs. This study has attempted to establish the load bearing capacity of randomly selected “Mirunda” poles through laboratory testing. Using an existing construction site as a case study, the results have been used to establish the actual number of …

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Software Engineering: A Fundamental Approach To Automate And Interface Medical Electronic Systems With Computers In Healthcare Systems, Hashim Twaakyondo Jun 2007

Software Engineering: A Fundamental Approach To Automate And Interface Medical Electronic Systems With Computers In Healthcare Systems, Hashim Twaakyondo

Tanzania Journal of Engineering and Technology (TJET)

The cost for application software and propriatry standards (i.e. data structure and formats) required for storing clinical datasets from electronic device cause the use of time-consuming paper-based documentation and/or the transfer of electronic lab records manually to the PC database systems in Mother-Offspring Malaria Study (MOMS) Laboratory Unit located in Morogoro Regional Hospital, Tanzania. We have explored the ability to extract laboratory results from Haematology analyzer machine for easy management, access and storage. The methodology and tools used during the study includes; site survey and hands-on practice for requirement engineering, visual basic 6.0 for interface design and Microsoft Access for …

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Program For The Analysis Of Plane Trusses, John Makunza Jun 2007

Program For The Analysis Of Plane Trusses, John Makunza

Tanzania Journal of Engineering and Technology (TJET)

The ‘TRAP - TRuss Analysis Program’ can assist engineers in the analysis of plane truss-type structures, as well as prove an excellent basis for understanding the “finite – element” method. The Program is completely menu-driven, with all nodes, elements, and load data entered through an input file. TRAP includes plotting for displaying the truss geometry in its original shape showing all nodes and support points. In the analysis process, firstly the structure data; e.g number of nodes, elements, materials and supports are to be defined. Secondly, element properties and support constraints have to be specified. Finally, nodal global loads are …

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Preliminary Estimates Of Building Cost And The Lowest Evaluated Tender, Harriet Eliufoo Jun 2007

Preliminary Estimates Of Building Cost And The Lowest Evaluated Tender, Harriet Eliufoo

Tanzania Journal of Engineering and Technology (TJET)

The paper has investigated and established to what extent are preliminary estimates of building costs close to the lowest evaluated tender and how geographical proximity influences the variance between preliminary estimate and the lowest evaluated tender. A multiple case study constituting 43 building projects in Tanzania were statistically analysed covering a period from 1995- 1999. Findings reveal a significant variance exists between the quantity surveyor’s preliminary estimate figure and the lowest evaluated tender; and that the variance between the quantity surveyor’s figure and the bidder is small when the proposed building project is geographically closer to the quantity surveyor’s base. …

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Nyumba Ya Mungu Reservoir System Simulation By Using Hec-Ressim Model, Deogratias Mulungu Jun 2007

Nyumba Ya Mungu Reservoir System Simulation By Using Hec-Ressim Model, Deogratias Mulungu

Tanzania Journal of Engineering and Technology (TJET)

This research paper focused on estimating effective water and optimization of the NyM reservoir for storage conservation and hydropower generation. Several models were used in the study: the Rainfall-Runoff model, GFFS was used to fill in missing data, and the HEC-ResSim Model and the NWBM for reservoir system simulation and water balance respectively. The effective inflows to the NyM reservoir were determined using HEC-ResSim model and the NWBM used to check the total water loss in the system. For the reservoir system simulation, the HEC-ResSim model was used to estimate water loss through irrigation abstractions in Kikuletwa and Ruvu reaches …

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Socio-Economic Impacts Of Water Scarcity In Dar Es Salaam, Tanzania, Shadrack Mwakalila Jun 2007

Socio-Economic Impacts Of Water Scarcity In Dar Es Salaam, Tanzania, Shadrack Mwakalila

Tanzania Journal of Engineering and Technology (TJET)

Drought and the resulting low water levels in rivers exacerbate water scarcity conditions in Dar es Salaam city. The result is frequent water rationing in areas served with piped water, sometimes for days or weeks, and low water pressure, which leads residents to resort to other less safe and sometimes more expensive water sources. The frequent and current response to the inadequate piped water supply in Dar es Salaam has been the use of groundwater resources. There are both public and private bore-holes and wells drilling companies in Dar es Salaam.. This paper therefore, presents some socio-economic impacts of water …

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Oaming Characteristics Of The Food-Industry Biological Wastewater Treatment Plant, Samwel V. Manyele Jun 2007

Oaming Characteristics Of The Food-Industry Biological Wastewater Treatment Plant, Samwel V. Manyele

Tanzania Journal of Engineering and Technology (TJET)

Intensive foaming observed during aeration of the aerobic food industry wastewater treatment plant is presented. This study was conducted to establish the foaming characteristics using a pilot three-phase fluidized bed bioreactor (TPFBB). A fluidization column (0.2 m i.d. and 6 m high) was used. The TPFBB was loaded with variable masses of novel biomass support particles (BSP). Wastewater samples collected from a plant processing both vegetable oil (VOPWW) and soap (SPWW) were immediately introduced in the TPFBB for aeration. The characteristics studied include: variation of foam volume with time, foam multiplicity, foaming and foam collapse rates. The SPWW produced excessive …

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Modeling And Control Of A New 1/4t Servo-Hydraulic Vehicle Active Suspension System, Jyh-Chyang Renn, Tsung-Han Wu Jun 2007

Modeling And Control Of A New 1/4t Servo-Hydraulic Vehicle Active Suspension System, Jyh-Chyang Renn, Tsung-Han Wu

Journal of Marine Science and Technology–Taiwan

Nowadays, the active suspension is the key technology for vehicles to achieve both ride comfort and control performance. In this paper, a new 1/4T servo-hydraulic vehicle active suspension system is developed and two control schemes are utilized. The first one is a conventional PID controller obtained from Ziegler-Nichols method and the second one is the neural network controller. Though these two controllers are quite simple and not new, it is still worth mentioning that this paper emphasizes on the engineering aspects including the design of a servo-hydraulic test rig, the implementation technology of the controllers and the subsequent experimental study. …

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Inverse Time Translational Symmetry Of The Wave Equation For Blatz-Ko Cylinders, Hin-Chi Lei, Sheng-Wei Chen Jun 2007

Inverse Time Translational Symmetry Of The Wave Equation For Blatz-Ko Cylinders, Hin-Chi Lei, Sheng-Wei Chen

Journal of Marine Science and Technology–Taiwan

The symmetries for the wave equation governing the radial deformations of circular cylinders composed of Blatz-Ko materials are studied. It is found that the wave equation possesses a special symmetry --- the inverse time translational symmetry (ITTS) named by us. We find that this special symmetry is not possessed by the wave equations for cylinders composed of other two compressible elastic materials. However, it appears again when we study the invariant properties of the wave equation governing radially deformed BlatzKo spheres and the one governing Blatz-Ko blocks in uniaxial tensile motion. We therefore infer that ITTS is a special property …

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Ultra-High Strength Steel Fiber Reinforced Concrete For Strengthening Of Rc Frames, Yung-Chih Wang, Ming-Gin Lee Jun 2007

Ultra-High Strength Steel Fiber Reinforced Concrete For Strengthening Of Rc Frames, Yung-Chih Wang, Ming-Gin Lee

Journal of Marine Science and Technology–Taiwan

Reinforced concrete (RC) structure strengthened with ultra-high steel fiber reinforced concrete (UFC) is introduced in the study. Interior RC beam-column joint sub-assemblages strengthened by means of joint replacement with UFC are tested cyclically to observe their seismic performance. Prior to frame testing, UFC mechanical properties, for example the compressive, flexural, rebar bonding, and slant shear strengths, and durability are examined and discussed. The material test results indicate that the UFC displays excellent performance in terms of mechanical and durable behavior. The frame test results show that the UFC-replaced joint frame behaves very well in seismic resistance. Its performance is even …

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Piv Measurements Of Exit Flow Field Of Centrifugal Fans With Conditional Sampling, Shun-Chang Yen, Jung-Hsuan Liu Jun 2007

Piv Measurements Of Exit Flow Field Of Centrifugal Fans With Conditional Sampling, Shun-Chang Yen, Jung-Hsuan Liu

Journal of Marine Science and Technology–Taiwan

In this research, we have experimented with two centrifugal fans with the same geometrical configuration. These two fans are designed to rotate at different speeds driven with the same voltage. The Particle Image Velocimetry (PIV) method is applied to measure the instantaneous flow fields at the near-exit region. The AMCA 210 wind tunnel is used to find the efficiency and the performance coefficients. The velocity vectors, streamlines, vorticity contours, velocity distributions, flow rate, and performances are also presented and discussed. We find that higher rotation speed yields better efficiency.

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An Experimental Study Of Wave Forces On Vertical Breakwater, Yung-Fang Chiu, Jaw-Guei Lin, Shang-Chun Chang, Yin-Jei Lin, Chia-Hsin Chen Jun 2007

An Experimental Study Of Wave Forces On Vertical Breakwater, Yung-Fang Chiu, Jaw-Guei Lin, Shang-Chun Chang, Yin-Jei Lin, Chia-Hsin Chen

Journal of Marine Science and Technology–Taiwan

In this study, a series of hydraulic model tests with regular/ irregular waves was carried out in a wave flume to investigate the wave forces acting on a composite-type breakwater. Waves in front of the breakwater, wave pressures on the vertical wall and at the bottom of caisson were measured simultaneously. The maximum horizontal force and uplift force were calculated and compared with Goda’s wave force theories. The results had shown that Goda’s theories offer higher safety factor. However, the measured uplift force was smaller than Goda’s and nonzero at the land-side end of the bottom which might be caused …

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Study On The Characteristics Of Tiller Blade Shapes By Spray-Welding Hardening, Jain-Song Ju Jun 2007

Study On The Characteristics Of Tiller Blade Shapes By Spray-Welding Hardening, Jain-Song Ju

Journal of Marine Science and Technology–Taiwan

This study attempts to validate and analyze the mathematical models of the plowing dynamics and trajectory curve for tiller and cultivation blades of a rotary cultivator. Both blades are extensively used in Taiwan. The blade must be protected from intertwisting to ensure high efficiency and uniform resistance of the plow to soil. Theoretical and calculated cutting angles are found to be 85.88° and 84.28°, respectively, while the theoretical and calculated edge-curve angles are 59.70° and 58.31°. The present data confirmed that the tiller blades developed by local companies are suitable for the plowing environment in Taiwan. In order to reduce …

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Observer-Based Fuzzy Covariance Control For Discrete Nonlinear Systems, Wen-Jer Chang, Yi-Lin Yeh Jun 2007

Observer-Based Fuzzy Covariance Control For Discrete Nonlinear Systems, Wen-Jer Chang, Yi-Lin Yeh

Journal of Marine Science and Technology–Taiwan

In this paper, the practical covariance control theory is applied to incorporate the concept of variance constrained control for the discrete nonlinear systems using T-S fuzzy models. This paper focuses on the control problem of finding observed-state feedback gains for the discrete fuzzy controllers, which can achieve the common state covariance assignment. Finally, a numerical example will be used to show the simulation results of the present fuzzy control method and usefulness of the proposed approach.

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Bs News Jun 2007

Bs News

Building Services Engineering

No abstract provided.

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Adapting And Implementing The Scale Up Approach In Statics, Dynamics, And Multivariate Calculus, Lisa Benson, Sherrill Biggers, William Moss, Matthew Ohland, Marisa Orr, Scott Schiff Jun 2007

Adapting And Implementing The Scale Up Approach In Statics, Dynamics, And Multivariate Calculus, Lisa Benson, Sherrill Biggers, William Moss, Matthew Ohland, Marisa Orr, Scott Schiff

School of Engineering Education Faculty Publications

This study seeks to deliver and document more effective Statics and Dynamics instruction by implementing the Student-Centered Activities for Large Enrollment University Programs (SCALE-UP) model, in which large studio classes are taught with an emphasis on learning by guided inquiry instead of on listening. The project is also examining the benefit of integrating the content of the two traditional sequential courses and the parallel content in multivariable calculus. By tracking multiple sections taught using different approaches in different departments, the project’s experimental design plans to control for each of the changes being made simultaneously to understand the benefit of each.

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Catalysis Of Nano Tio2 For Horseradish Peroxidase, Ya-Qi Zhu, Hai Wu, Hiu Liu, Jie Ma May 2007

Catalysis Of Nano Tio2 For Horseradish Peroxidase, Ya-Qi Zhu, Hai Wu, Hiu Liu, Jie Ma

Journal of Electrochemistry

Horseradish peroxidase immobilized on the surface of titanium dioxide nanoparticles and nanotube modified glassy carbon electrode.The HRP direct electron transfer reaction was compared between TiO2 nanoparticles and nanotube GC electrode.The results demonstrated that the HRP on TiO2 nanotube /GC electrode could catalyze electron exchange reaction between electroactivity center of HRP and electrode.And the research of antibody labeled HRP provides a selected signal for antibody-antigen immunoassay.

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Electrochemical Reduction Of Coals And The Oxygenic Functional Simulacrums Of Coals, Juan Lin, Zhao Wei May 2007

Electrochemical Reduction Of Coals And The Oxygenic Functional Simulacrums Of Coals, Juan Lin, Zhao Wei

Journal of Electrochemistry

Electrochemical reduction of coals and the oxygenic functional simulacrums of coals has been studied.In this process,tetrabutylammonium was used as supporting electrolyte.The coal and the deoxidized coal were extracted by methanol.Qualitative analysis of the deoxidized products and the extractives was carried out on gas chromatograph-mass spectrometer.The deoxidized products of the oxygenic functional simulacrums of coals were analysed quantitatively with gas chromatograph spectrometer.The results show that the oxygenic functional groups on the coals surface decrease and the translation ratios of the oxygenic functional simulacrums of coals need further increase after electrochemical reduction,.The electrochemical tests show simultaneously the kinetics equations of every related …

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Study On The Electricity Capability Of Ru((0.4-X))IrXTi(0.6)/Ti Electrode, Ling-Li Wang, Qiao Peng May 2007

Study On The Electricity Capability Of Ru((0.4-X))IrXTi(0.6)/Ti Electrode, Ling-Li Wang, Qiao Peng

Journal of Electrochemistry

The metal oxide anode of Ru(0.4-x)IrxTi0.6 has been prepared by thermal decomposition.The results indicate that,when the percent of IrO2 is 10%,the electrode has low chlorine potential,high oxygen potential and excellent catalyze selectivity;strengthen life is long with IrO2 content increased from 1.0h to 97h.It shows that the electrode anti-oxide corrosion perform is improved and intensifying life is long with addition of IrO2.The film and reaction resistance are all fall with the addition of IrO2.The addition of IrO2 is in favor of thin crystal and makes the film more roughness.

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Study On The Characteristics Of Vb(12) Modified Electrode By Electropolymerization, Hui-Ting Lian, Wen-Ji Wang May 2007

Study On The Characteristics Of Vb(12) Modified Electrode By Electropolymerization, Hui-Ting Lian, Wen-Ji Wang

Journal of Electrochemistry

Preparation of the VB12 modified electrode and its electrochemical characteristics were studied.The results showed that the VB12 after electroactivated is able to electopolymerize on the GC by cyclic voltammetry(CV)in the DMSO solution.Differential pulse voltmmetry(DPV)showed that the VB12 catalyzed the oxidation of NO2-,SO32-and NH2NH2.The catalytic peak for NO2-on the modified electrode was observed at 0.76V(vs.SCE),but on the unmodified GC which at 1.0V.The catalytic currents increased linearly with the concentration of NO2-from 1.6×10-6 to 4.3×10-4 mol·L-1 with a correlation coefficient …

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Determination Of Ddopamine And Ascorbate On Gold Nanoparticle And 4,4-Bis (Methanethiol) Biphenyl (Mtp) Self-Assembled Monolayer Modified Gold Electrode, Hai-Yan Wang, Peng Liu, Ye Wang, Bao-Kang Jin May 2007

Determination Of Ddopamine And Ascorbate On Gold Nanoparticle And 4,4-Bis (Methanethiol) Biphenyl (Mtp) Self-Assembled Monolayer Modified Gold Electrode, Hai-Yan Wang, Peng Liu, Ye Wang, Bao-Kang Jin

Journal of Electrochemistry

A new approach to construct an ampermetric biosensor was described.The 4,4-bis(methanethiol)biphenyl(MTP)is adsorbed on to a bare gold electrode to make self-assembled monolayers(MTP/Au SAMs).Then electrodeposited 2mg/mL HAuCl4 at-200 mV,NG/MTP/Au electrode was prepared.When a differential pulse voltammetric(DPV)technique was used,the peak separation between DA and AA is 155 mV.Hence,the selective determination of dopamine(DA)and ascorbate(AA)in the binary mixture system can be performed.Under the chosen conditions,the peak currents are correspondent linearly to the concentrations of DA and AA in the range of 5.0×10-7~1×10-4 mol·L-1 and 3.5×10-6~1.0×10-3mol·L-1,respectively.The correlation coefficients were 0.998.The detection limit were 1.5×10 …

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Corrosion Electrochemical Behavior Of Aluminum Flake Pigmented Water-Borne Epoxy Coating On Carbon Steel In Nacl Solution, Li-Li Xue, Li-Kun Xu, Qing-Fen Li, Hong-Qing Song, Wen-Juan Zhou, Guang-Zhang Chen May 2007

Corrosion Electrochemical Behavior Of Aluminum Flake Pigmented Water-Borne Epoxy Coating On Carbon Steel In Nacl Solution, Li-Li Xue, Li-Kun Xu, Qing-Fen Li, Hong-Qing Song, Wen-Juan Zhou, Guang-Zhang Chen

Journal of Electrochemistry

The corrosion electrochemical behavior of a water-borne epoxy coating pigmented with aluminum flake on carbon steel with artificial scratch defect was studied in 3.5% NaCl solution using electrochemical impedance spectroscopy(EIS)and scanning vibrating electrode technique(SVET).The results indicated that the defect presented anodic electroactivity at the initial stage of immersion,which extended gradually with time from the scratch into the neighboring coating,lowering the coating impedance.With further immersion,however,the electroactivity of the coating/steel interface decreased significantly due to the self-repairing of the corrosion products,causing an obvious increase of the coating impedance.In the later period of immersion,more scattered electroactive areas appeared under the coating because of …

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Template Synthesis And Electrochemical Studies Of Ag(Core)Au(Shell) Nanowires, Li Ling, Ya-Xian Yuan, Min-Min Xu, Jian-Lin Yao, Ren-Ao Gu May 2007

Template Synthesis And Electrochemical Studies Of Ag(Core)Au(Shell) Nanowires, Li Ling, Ya-Xian Yuan, Min-Min Xu, Jian-Lin Yao, Ren-Ao Gu

Journal of Electrochemistry

Agcore Aushell nanowires with different thicknesses were prepared by combining template synthesis and chemical reduction method,and characterized by SEM and cyclic voltammetry(CV).The CV results revealed that the AgcoreAushell nanowires with pinhole were transferred to pinhole free structure after several potential scans.By using thiophenol(TP)and p-aminothiophenol(PATP)as probe,the surface enhanced Raman scattering(SERS)effect was investigated on the core-shell nanowires.The results indicated that AgcoreAushell nanowires could be served as a potential SERS substrate,and the difference in the spectral feature of PATP adsorbed onto Au and Ag nanowires enable us to diagnose the pinhole effect of core-shell nanowires by SERS.

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Electricity Generation From A Microbial Fuel Cell Employing Desulfovibrio Salexigens, Ping Ding, Hai-Bo Shao, Guang-Zhou Liu, Dong-Xia Duan, Ting Ma, Si-Jun Chen, Jian-Ming Wang, Jian-Qing Zhang May 2007

Electricity Generation From A Microbial Fuel Cell Employing Desulfovibrio Salexigens, Ping Ding, Hai-Bo Shao, Guang-Zhou Liu, Dong-Xia Duan, Ting Ma, Si-Jun Chen, Jian-Ming Wang, Jian-Qing Zhang

Journal of Electrochemistry

A microbial fuel cell of laboratory scale employing Desulfovibrio salexigens in lactate based seawater substrate was proposed.Electricity was continuously harvested after inoculation.During 20 days of fermentation/discharge,COD values of the substrate decreased by 61.7%,in which 9.81% was converted to electricity.

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The Research Of Several Electrodes For Spe Water Electrolysis, Jian-Bo Meng, Ge Sang, Yan Xue, Wei Cao, Xiao-Qiu Ye May 2007

The Research Of Several Electrodes For Spe Water Electrolysis, Jian-Bo Meng, Ge Sang, Yan Xue, Wei Cao, Xiao-Qiu Ye

Journal of Electrochemistry

Performances of the IrRu/Nafion 117/PbAg,IrRu/Nafion 117/Ni,IrRu/Nafion 117/TiNi,Ag/Nafion 117/Ni and C/Nafion 117/PtRu for the SPE water electrolysis have been investigated.The order of the electrocatalysis activity for the anodic electrodes as mentioned above is IrRu>Ag>C,and that of cathodic electrode is Ni>PbAg>TiNi.While the stability of TiNi was much better than Ni,and that of PbAg is best.Moreover,the current efficiency was raised with the increase of current density.

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Study On The Contribution Of Cobalt Additives To Foam Nickel Electrodes, Xiao-Feng Li, Tong-Chi Xia, Shao-Peng Yi, Xiu-Juan Gu, Yu-Lin Song May 2007

Study On The Contribution Of Cobalt Additives To Foam Nickel Electrodes, Xiao-Feng Li, Tong-Chi Xia, Shao-Peng Yi, Xiu-Juan Gu, Yu-Lin Song

Journal of Electrochemistry

Two incorporation ways of the cobalt additives into foam nickel electrodes,i.e.the co-precipitated and admixed method are used.The results of X-ray diffraction(XRD),cyclic voltammetry,electrochemical impedance spectrum(EIS)and galvanostatic charge-discharge curves show that(Ⅰ)there is a decrease in intensity and increase in half peak breadths of the diffraction peaks of Ni(OH)2 with co-precipitated cobalt additive;(Ⅱ)the electrochemical activity of nickel hydroxide can be improved by both incorporation ways and the effect of admixed CoO is more notable;(Ⅲ)β-CoOOH derived from admixed CoO is not stable at lower potential,thus results in an irreversible capacity loss of nickel-metal-hydride(Ni-MH)battery after imposed overdischarged-state storage.

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Self Assemblying Kinetics Of Sodium Steareate At Castor Oil/Water Interface, Yong-Chun Zhu, Li-Na Tang, Hong-Guo Ji May 2007

Self Assemblying Kinetics Of Sodium Steareate At Castor Oil/Water Interface, Yong-Chun Zhu, Li-Na Tang, Hong-Guo Ji

Journal of Electrochemistry

The self assembly membrane(SAM)formation kinetics of sodium stearate at castor oil/water interface was studied by cyclic voltammetrry.At caster oil coated graphite-epoxy solid electrode surface,the SAM grows according to the Gaussian growth function with a rate constant of km=0.0006292(0.0000294)s-1,and maximum particle size at t0=3127s.The SAM of sodium stearate controls the growth and particle size of the deposited copper nano particles well,and forms a composite membrane of the SAM and copper nano particle.The growth mechanism of copper particle at oiled electrode or SAM modified oiled electrode is spherical growth,while it is the semi-spherical growth at bared graphite-epoxy solid phase electrode.Compared …

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Determination Of Tetracyclines Based On The Flow-Through Electrochemical Detection Cell With Nickel Electrode, Dan-Mei Pan, Rong-Zong Hu, Dong-Ping Wei, Hao-Dong Ding May 2007

Determination Of Tetracyclines Based On The Flow-Through Electrochemical Detection Cell With Nickel Electrode, Dan-Mei Pan, Rong-Zong Hu, Dong-Ping Wei, Hao-Dong Ding

Journal of Electrochemistry

The electrochemical responses to tetracycline at the nickel electrode in alkaline solution were compared with that of gold and glassy carbon electrode by voltammetry.The electrocatalytic oxidation characteristics of tetracycline at nickel electrode were discussed.Subsequently a flow-through amperometric detection cell with nickel as the working electrode was designed to detect tetracycline,oxytetracycline,and doxycycline.Standard calibration graphs for the tetracyclines yielded linear ranges of 0.1~15 mg/L.Detection limits(S/N=3)of 35,45 and 43 μg/L were obtained for tetracycline,oxytetracycline and doxycycline,respectively.The system was applied for the determination of the three antibiotics in single-component drug formulations.

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