Engineering Commons^™

Temporal Evaluation Of Corn Respiration Rates Using Pressure Sensors, Gagandeep Singh Ubhi

Graduate Theses and Dissertations

High respiration rate of a grain indicates faster degradation of its dry matter. Proper grain management requires chronological and precise measurements of carbon dioxide evolved from grain respiration during the postharvest storage duration. Therefore the main goal of this research was to develop a new technique that evaluates temporal corn respiration rate using pressure sensors. It was based on measuring pressure drop associated with the grain respiration in a closed container and using it to calculate the grain respiration rates.

Dry corn (Zea Mays L.) was procured from a local farmer and stored at 4ºC. Corn rewetting technique was applied …

Reduction In Recombination Current Density In Boron Doped Silicon Using Atomic Hydrogen, Matthew Garett Young

Graduate Theses and Dissertations

The solar industry has grown immensely in recent years and has reached a point where solar energy has now become inexpensive enough that it is starting to emerge as a mainstream electrical generation source. However, recent economic analysis has suggested that for solar to become a truly wide spread source of electricity, the costs still need to plummet by a factor of 8x. This demands new and innovative concepts to help lower such cost. In pursuit of this goal, this dissertation examines the use of atomic hydrogen to lessen the recombination current density in the boron doped region of n-type …

Infrared Energy Conversion In Plasmonic Fields At Two-Dimensional Semiconductors, Gregory Thomas Forcherio

Graduate Theses and Dissertations

Conversion of infrared energy within plasmonic fields at two-dimensional, semiconductive transition metal dichalcogenides (TMD) through plasmonic hot electron transport and nonlinear frequency mixing has important implications in next-generation optoelectronics. Drude-Lorentz theory and approximate discrete dipole (DDA) solutions to Maxwell’s equations guided metal nanoantenna design towards strong infrared localized surface plasmon resonance (LSPR). Excitation and damping dynamics of LSPR in heterostructures of noble metal nanoantennas and molybdenum- or tungsten-disulfide (MoS2; WS2) monolayers were examined by parallel synthesis of (i) DDA electrodynamic simulations and (ii) near-field electron energy loss (EELS) and far-field optical transmission UV-vis spectroscopic measurements. Susceptibility to second-order nonlinear frequency …

A Hybrid Partially Reconfigurable Overlay Supporting Just-In-Time Assembly Of Custom Accelerators On Fpgas, Zeyad Tariq Aklah

Graduate Theses and Dissertations

The state of the art in design and development flows for FPGAs are not sufficiently mature to allow programmers to implement their applications through traditional software development flows. The stipulation of synthesis as well as the requirement of background knowledge on the FPGAs' low-level physical hardware structure are major challenges that prevent programmers from using FPGAs. The reconfigurable computing community is seeking solutions to raise the level of design abstraction at which programmers must operate, and move the synthesis process out of the programmers' path through the use of overlays. A recent approach, Just-In-Time Assembly (JITA), was proposed that enables …

Sensitivity Of Diffuse Reflectance Spectroscopy To Dose- And Depth-Dependent Changes In Tumor Oxygenation After Radiation Therapy, Daria Semeniak

Graduate Theses and Dissertations

Along with chemotherapy, immunotherapy, and surgery, radiotherapy is one of the most common treatments used against cancer. Around 50% of all cancer patients undergo radiation therapy. While for some patients radiotherapy works efficiently and lead to a complete cancer disappearance, for others treatment outcome may be less favorable due to radioresistance processes happening within a tumor on the molecular level. Radioresistance remains a big challenge for modern oncology. The ability to identify radioresistance at the early stage of radiotherapy would help physicians to improve therapy efficiency. At the current moment, despite the rapid progress in cancer understanding and diagnostic modalities, …

Exploring Thermoresponsive Affinity Agents To Enhance Microdialysis Sampling Efficiency Of Proteins, Thaddeus Vasicek

Graduate Theses and Dissertations

Affinity agents increase microdialysis protein relative recovery, yet they have not seen widespread use within the microdialysis community due to their additional instrumentation requirements and prohibitive cost. This dissertation describes new affinity agents for microdialysis that require no additional instrumentation to use, have nearly 100% particle recovery, are 7 times more cost efficient than alternatives, and have low specificity enabling their use for a wide variety of proteins. Initially gold nanoparticles were chosen as an affinity ligand support due to their high surface area/volume ratio and colloidal stability. Poly (N-isopropylacrylamide) was immobilized to the gold nanoparticles, which served to sterically …

Molecular Dynamics Simulations Of Dna-Functionalized Nanoparticle Building Blocks On Gpus, Tyler Landon Fochtman

Graduate Theses and Dissertations

This thesis discusses massively parallel molecular dynamics simulations of nBLOCKs using graphical processing units. nBLOCKs are nanoscale building blocks composed of gold nanoparticles functionalized with single-stranded DNA molecules. To explore greater simulation time scales we implement our nBLOCK computational model as an extension to the coarse grain molecular simulator oxDNA. oxDNA is parameterized to match the thermodynamics of DNA strand hybridization as well as the mechanics of single stranded DNA and double stranded DNA. In addition to an in-depth review of our implementation details we also provide results of the model validation and performance tests. These validation and performance tests …

Characterization Of Coupled Gold Nanoparticles In A Sparsely Populated Square Lattice, Roy Truett French Iii

Graduate Theses and Dissertations

Metal nanoparticles deposited in regular arrays spaced at optical wavelengths support a resonance due to a coherent coupling between localized surface plasmon mode and lattice diffraction allowing for engineering of tunable devices for use in biological sensors, nanoantennae, and enhanced spectroscopy. Techniques such as electron beam lithography, focused ion beam lithography, nanosphere lithography, and nanoimprint lithography are used for fabrication but are limited by cost, device throughput, and small deposition. Polymer soft lithography and continuous dewetting of particles is a potentially viable alternative showing promise in all of those areas. This thesis developed the fabrication of a refined hydrophilic nanoimprinted …

Development Of A One Pass Microwave Heating Technology For Rice Drying And Decontamination, Deandrae Lynette Smith

Graduate Theses and Dissertations

An industrial microwave (MW) system operating at 915 MHz frequency was used to dry high moisture content (MC) (23% to 24% wet basis) medium-grain rough rice samples (cv. Jupiter). The rice beds were contained in a modified tray that accommodated up to 9 kg of rice separated by thin fiberglass mesh in 3 kg increments. Each layer of rice was fitted with fiber optic sensors connected to a real time data logger during MW treatments. It was determined that drying rice to a MC of 14% to 16% was feasible with the application of MW specific energy at 600 kJ/kg-grain …

Exploiting Hardware Abstraction For Parallel Programming Framework: Platform And Multitasking, Hongyuan Ding

Graduate Theses and Dissertations

With the help of the parallelism provided by the fine-grained architecture, hardware accelerators on Field Programmable Gate Arrays (FPGAs) can significantly improve the performance of many applications. However, designers are required to have excellent hardware programming skills and unique optimization techniques to explore the potential of FPGA resources fully. Intermediate frameworks above hardware circuits are proposed to improve either performance or productivity by leveraging parallel programming models beyond the multi-core era.

In this work, we propose the PolyPC (Polymorphic Parallel Computing) framework, which targets enhancing productivity without losing performance. It helps designers develop parallelized applications and implement them on FPGAs. …

Linear Quadratic Optimal Control For A Cascaded Converters-Based Microgrid, Amlam Niragire

Graduate Theses and Dissertations

There is a constant transformation of the electric grid due to an ongoing interest in the deployment of renewable energy resources and electric microgrid formation. This transformation, though advantageous in many ways, poses great challenges for the energy industry and there must be a constant improvement in modeling, simulation, analysis and control techniques in order to characterize and optimize the system design and operation. In this light, the scope of this thesis is focused on developing a linear model, analyzing the stability and designing an optimal linear quadratic regulator (LQR) for a microgrid system. The microgrid system used is inspired …

Service Consistency In Vehicle Routing, Kunlei Lian

Graduate Theses and Dissertations

This thesis studies service consistency in the context of multi-period vehicle routing problems (VRP) in which customers require repeatable services over a planning horizon of multiple days. Two types of service consistency are considered, namely, driver consistency and time consistency. Driver consistency refers to using the fewest number of different drivers to perform all of the visits required by a customer over a planning horizon and time consistency refers to visiting a customer at roughly the same time on each day he/she needs service. First, the multi-objective consistent VRP is defined to explore the trade-offs between the objectives of travel …

Applications Of Krylov Subspace And Balanced Truncation Model Order Reduction In Power Systems, Sebastian Emanuel Garrido

Graduate Theses and Dissertations

Dynamic representations of power systems usually result in the order of hundreds or even thousands of buses. Therefore, reduction of these dynamic representations is convenient. Two applications of model order reduction in power systems are discussed in this thesis. First, Krylov subspace-based method is applied to the IEEE-123 Node Test Feeder in the context of distribution-level power systems simulation. Second, a Balanced Truncation-based model reduction is implemented in the 3-Machine 9-Bus system for designing a power system controller in the context of generation- and transmission-level power systems.

First, for the IEEE-123 Node Test Feeder, a two-sided Arnoldi algorithm is proposed …

Morphology Controlled Synthesis Of Copper Based Multimetallic Nanostructures And Their Electrocatalytic Properties For Methanol Oxidation Reaction, Leanne Elizabeth Mathurin

Graduate Theses and Dissertations

This research focuses on the development of shape-controlled synthesis of Cu NM, Cu-based bimetallic and trimetallic nanostructures, and their electrocatalytic properties for methanol oxidation reaction (MOR). Copper nanomaterials (Cu NM) with specific surface facets can tailor their catalytic activity. Understanding reagents responsible for Cu NM growth is important for morphology-controlled synthesis of the nanostructures. This research studies the halide influence on Cu NM growth and morphology in an oil-based synthesis. The morphology of the Cu NM varies with the halide type (i.e., Cl-, Br-, I-), and the halide concentration. Additionally, the type of Cu precursor also influenced the morphology of …

Investigation Of Fes2 Nanoparticles For Use In Optoelectronic And Thermoelectric Applications, Rick Tefal Eyi Nkoghe

Graduate Theses and Dissertations

Iron pyrite (FeS2) is the most abundant sulfide material on earth. This material has been widely investigated by researchers because of its optical properties. However, it has been difficult to produce High efficiency FeS2 based solar cells. This is due to many different impurities that arise when making the materials. The ability to synthesize pure pyrite FeS2 material is therefore critical for applications.

Pure Iron pyrite nanocrystals were synthesized using hot injection by mixing sulfur with an iron precursor in the presence of an amine. To improve the stability, shorter ligands replaced the native amines ligands. The stability of the …

Short-Circuit Protection For Low-Voltage Dc Distribution Systems Based On Solid-State Circuit Breakers, Sharthak Munasib

Graduate Theses and Dissertations

Proper short-circuit protection in dc distribution systems has provided an austere challenge to researchers as the development of commercially-viable equipment providing fast operation, coordination and reliability still continues. The objective of this thesis is to analyze issues associated with short-circuit protection of low-voltage dc (LVDC) distribution systems and propose a short-circuit protection methodology based on solid-state circuit breakers (SSCBs) that provides fault-current limiting (FCL). Simulation results for a simplified notional 1-kVdc distribution system, performed in MATLAB/SIMULINKTM, would be presented to illustrate that SSCB solutions based on reverse-blocking integrated gate-commutated thyristors (RB-IGCT) are feasible for low-voltage dc distribution systems but requires …

Power Efficient High Temperature Asynchronous Microcontroller Design, Nathan William Kuhns

Graduate Theses and Dissertations

There is an increasing demand for dependable and efficient digital circuitry capable of operating in high temperature environments. Extreme temperatures have adverse effects on traditional silicon synchronous systems because of the changes in delay and setup and hold times caused by the variances in each device’s threshold voltage. This dissertation focuses on the design of the major functionality of an asynchronous 8051 microcontroller in Raytheon’s high temperature Silicon Carbide process, rated for operation over 300ºC. The microcontroller is designed in NULL Convention Logic, for which the traditional bus architecture used for data transfer would consume a large amount of power. …

Silicon Germanium Bicmos Comparator Designed For Use In An Extreme Environment Analog To Digital Converter, Benjamin Riley Sissons

Graduate Theses and Dissertations

This thesis demonstrates the process of creating a radiation hardened and extreme temperature operating comparator from start to finish in the 90 nm SiGe 9HP process node. This includes the entire design flow from examining comparator topologies, to designing the initial comparator circuits, to simulating the comparator over a temperature range of -196°C to 125°C, and finally the testing of the fabricated circuit. To verify the circuit would work at low temperatures, several new device models were created that could be used for simulations at -196°C. In addition to its properties as a standalone comparator, the circuit was also used …

Development Of An Oxygen Saturation Monitoring System By Embedded Electronics, Manikandan Venkatesan Gomathy

Graduate Theses and Dissertations

Measuring Oxygenation of blood (SaO2) plays a vital role in patient’s health monitoring. This is often measured by pulse oximeter, which is standard measure during anesthesia, asthma, operative and post-operative recoveries. Despite all, monitoring Oxygen level is necessary for infants with respiratory problems, old people, and pregnant women and in other critical situations.

This paper discusses the process of calculating the level of oxygen in blood and heart-rate detection using a non-invasive photo plethysmography also called as pulsoximeter using the MSP430FG437 microcontroller (MCU). The probe uses infrared lights to measure and should be in physical contact with any peripheral points …

Modeling And Validation Of 4h-Sic Low Voltage Mosfets For Integrated Circuit Design, Shamim Ahmed

Graduate Theses and Dissertations

Silicon Carbide is a promising wide bandgap material and gradually becoming the first choice of semiconductor for high density and high efficiency power electronics in medium voltage range (500-1500V). SiC has also excellent thermal conductivity and the devices fabricated with the material can operate at high temperature (~ 400 ⁰C). Thus, a power electronic system built with SiC devices requires less cooling requirement and saves board space and cost. The high temperature applications of SiC material can also be extended to space exploration, oil and gas rigging, aerospace and geothermal energy systems for data acquisition, sensing and instrumentation and power …

Design And Test Of A Gate Driver With Variable Drive And Self-Test Capability Implemented In A Silicon Carbide Cmos Process, Matthew Barlow

Graduate Theses and Dissertations

Discrete silicon carbide (SiC) power devices have long demonstrated abilities that outpace those of standard silicon (Si) parts. The improved physical characteristics allow for faster switching, lower on-resistance, and temperature performance. The capabilities unleashed by these devices allow for higher efficiency switch-mode converters as well as the advance of power electronics into new high-temperature regimes previously unimaginable with silicon devices. While SiC power devices have reached a relative level of maturity, recent work has pushed the temperature boundaries of control electronics further with silicon carbide integrated circuits.

The primary requirement to ensure rapid switching of power MOSFETs was a gate …

Plasmon-Mediated Energy Conversion In Metal Nanoparticle-Doped Hybrid Nanomaterials, Jeremy Dunklin

Graduate Theses and Dissertations

Climate change and population growth demand long-term solutions for clean water and energy. Plasmon-active nanomaterials offer a promising route towards improved energetics for efficient chemical separation and light harvesting schemes. Two material platforms featuring highly absorptive plasmonic gold nanoparticles (AuNPs) are advanced herein to maximize photon conversion into thermal or electronic energy. Optical extinction, attributable to diffraction-induced internal reflection, was enhanced up to 1.5-fold in three-dimensional polymer films containing AuNPs at interparticle separations approaching the resonant wavelength. Comprehensive methods developed to characterize heat dissipation following plasmonic absorption was extended beyond conventional optical and heat transfer descriptions, where good agreement was …

Controlled Synthesis And Utilization Of Metal And Oxide Hybrid Nanoparticles, Cameron Cowgur Crane

Graduate Theses and Dissertations

This dissertation reports the development of synthetic methods concerning rationally-designed, hybrid, and multifunctional nanomaterials. These methods are based on a wet chemical, solution phase approach that utilizes the knowledge of synthetic organic and inorganic chemistry to generate building blocks in solution for the growth of nanocrystals and hybrid nanostructures. This work builds on the prior knowledge of shape-controlled synthesis of noble metal nanocrystals and expands into the challenging realm of the more reactive first row transition metals. Specifically, a microemulsion sol-gel method was developed to synthesize Au-SiO2 dimers as precursors for the synthesis of segmented heterostructures of noble metals that …

Influence Of Concrete Compressive Strength On Transfer And Development Lengths Of Prestressed Concrete, Alberto Teodoro Ramirez-Garcia

Graduate Theses and Dissertations

This research examines the relationship between concrete compressive strength and strand bond. The goal of this research was to develop an equation that relates strand bond to concrete compressive strength at strand release (approximately 1 day of age) and at 28 days of age, and those equations are presented in this investigation. Strand bond is assessed by measuring the transfer length and development length for prestressed beams cast in the laboratory. In the U.S., strand bond is predicted using transfer length and development length equations provided by the American Concrete Institute (ACI-318) Building Code and American Association of State and …

Selective Resistive Sintering: A Novel Additive Manufacturing Process, Austin Bryan Van Horn

Graduate Theses and Dissertations

Selective laser sintering (SLS) is one of the most popular 3D printing methods that uses a laser to pattern energy and selectively sinter powder particles to build 3D geometries. However, this printing method is plagued by slow printing speeds, high power consumption, difficulty to scale, and high overhead expense. In this research, a new 3D printing method is proposed to overcome these limitations of SLS. Instead of using a laser to pattern energy, this new method, termed selective resistive sintering (SRS), uses an array of microheaters to pattern heat for selectively sintering materials. Using microheaters offers significant power savings, significantly …

Soil Moduli Obtained From A Back Pressure Constant Rate Of Strain Bender Element Consolidation Apparatus, Yi Zhao

Graduate Theses and Dissertations

A back-pressure saturated, constant-rate-of-strain consolidation device was modified to incorporate bender elements (BP-CRS-BE) and thus allowed for shear wave measurements during consolidation tests. This newly fabricated system has many advantages over other previous or current devices: 1) it can be utilized not only for laboratory prepared soil samples but also for field sampled soils such as Shelby tube samples, and 2) continuous compression curves, and continuous values of vertical hydraulic conductivity and coefficient of consolidation can be acquired with a significant reduction in testing time. Soil modulus values such as shear modulus and constrained modulus are also able to be …

Identifying Damage, Predicting Expansion, And Determining The Effectiveness Of Sealers On Concrete Affected By Alkali-Silica Reaction And Freeze-Thaw, Matthew Caleb Waidner

Graduate Theses and Dissertations

Premature cracking of the barrier wall and pavement on I-49 south of Fayetteville, Arkansas due to a combination of Alkali-Silica Reaction (ASR) and freeze-thaw has led to ASR and freeze-thaw research at the University of Arkansas. Potential for further expansion (PFET), Damage Rating Index (DRI), and mitigation of freeze-thaw and ASR with sealers testing and results are contained herein. PFET results indicated that the pavement will not continue to expand from ASR. With other interstate pavements deteriorating prematurely throughout Arkansas, DRI has shown that most are damaged not only by ASR but by freeze-thaw too. Recommendations for freeze-thaw’s inclusion into …

Investigation Of The Optical Properties Of Pbse/Pbx Nanocrystals For Photodetector Applications, Haley Ann Morris

Graduate Theses and Dissertations

Lead selenide and lead selenide/lead sulfide core/shell nanocrystals were investigated for use in near infrared photodetectors. A colloidal synthesis method was used for both the core and core/shell configurations. The lead sulfide shell was examined in order to mitigate oxidation of the nanoparticle surface. Absorbance and photoluminescence spectra were measured at room temperature and 77 K, respectively. Transmission electron microscopy images were also obtained to confirm crystallography and size. Bulk lead selenide was simulated in WIEN2k utilizing the linear-augmented plane wave method of solving density functional theory to better understand the electronic structure of PbSe. The crystal structure, electron density, …

Examination Of Pseudomonas Fluorescence As A Recombinant Expression Host: Cloning, Expression, And Chromatography, Ahmed K.Ali Elmasheiti

Graduate Theses and Dissertations

In an effort to expand the pool of bacterium useful for biotechnology applications, Pseudomonas fluorescens, a common gram negative microbe, was examined for its ability to function in a recombinant setting. P. fluorescens is ubiquitous in nature and was initially identified as a soil bacterium found in dirt and is typically associated with plant material. Past literature indicates that it shared characteristics common to Escherichia coli and Bacillus subtilis, including simple growth conditions and potential cloning vectors, providing motivation to look into both the upstream and downstream characteristics of this bacterium. First, it was demonstrated that P. fluorescens could be …

Exploring The Production Of Extracellular Matrix By Astrocytes In Response To Mimetic Traumatic Brain Injury, Addison Walker

Graduate Theses and Dissertations

Following injury to the central nervous system, extracellular modulations are apparent at

the site of injury, often resulting in a glial scar. Astrocytes are mechanosensitive cells, which can create a neuroinhibitory extracellular environment in response to injury. The aim for this research was to gain a fundamental understanding of the affects a diffuse traumatic brain injury has on the astrocyte extracellular environment after injury. To accomplish this, a bioreactor culturing astrocytes in 3D constructs delivered 150G decelerations with 20% biaxial strain to mimic a traumatic brain injury. Experiments were designed to compare the potential effects of media type, number of …