Engineering Commons^™

Fabrication And Characterization Of Amorphous/Nanocrystalline Thin Film Composite, Benjamin Seth Newton

Graduate Theses and Dissertations

Combining the absorption abilities of amorphous silicon and the electron transport capabilities of crystalline silicon would be a great advantage to not only solar cells but other semiconductor devices. In this work composite films were created using molecular beam epitaxy and electron beam deposition interchangeably as a method to create metallic precursors. Aluminum induced crystallization techniques were used to convert an amorphous silicon film with a capping layer of aluminum nanodots into a film composed of a mixture of amorphous silicon and nanocrystalline silicon. This layer was grown into the amorphous layer by cannibalizing a portion of the amorphous silicon …

Robust Network Interdiction With Invisible Interdiction Assets, Nail Orkun Baycik

Graduate Theses and Dissertations

We study a version of the shortest path network interdiction problem in which the follower seeks to find the shortest path on a given network and the leader seeks to maximize the follower's shortest path length by interdicting arcs. We consider placement of interdictions that are not visible to the follower; however, we seek to locate interdictions in a manner that is robust against the possibility that some interdiction locations become known to the follower. We formulate the problem as a bi-level program, and use the simulated annealing heuristic to identify high quality solutions. We apply our approach to investigate …

Comparing Virus Ultrafiltration Of Bacteriophages With Filtration Of Minute Virus Of Mice, Kent Smith

Graduate Theses and Dissertations

Industrial production of protein therapeutics demand rigorous testing and clearance of viruses. The U.S. Food and Drug Administration dictate the purity of pharmaceuticals with regards to viral contamination. As this testing is time consuming and expensive using mammalian cells and viruses, bacteriophages may provide a faster and cheaper alternative for membrane filtration processes. We used ultrafiltration membranes to filter protein solutions with viruses. Two bacteriophages were tested against membranes with two different pore sizes. These membranes were then tested by inverting the membrane's orientation. Flux measurements and log virus removal data were taken. Flux and log virus removal were seen …

Fabrication Of Single Nanowire Device Using Electron Beam Lithography, Thach Pham

Graduate Theses and Dissertations

One dimensional nanostructure materials such as nanowires have drawn many interests among the scientific community for a wide range of applications such as field-effect transistors [1], [2], inverters[3], light-emitting diode [1], lasers [4], nanosensors [5], [6], and photodetectors [7]... Comparing with the characterization of nanowire arrays, characterizing a single nanowire will definitely provide a better understanding on new nanowire properties due to simplified behaviors of devices. Although promising theories could be drawn from those results, fabrication of test structure for single nanowire measurements cannot be easily processed using standard microfabrication techniques. Therefore, electron beam lithography integrated with photolithography technique has …

Broadband Nanostructured Antireflection Coating For Enhancing Inas/Gaas Quantum Dots Solar Cells Performance, Jony C. Sarker

Graduate Theses and Dissertations

The broadband suppression in reflection is one of the primary focuses in high efficiency solar cell research. In this thesis, a moth-eye inspired nanostructure antireflection coating is fabricated on InAs/GaAs quantum dots solar cell in order to enhance the power conversion efficiency. The abrupt refractive index transition between air and GaAs surface is replaced by a tapering zinc oxide nanoneedle on planar tantalum pentoxide coating. The antireflection structure provides gradual reduction of refractive index away from the solar cell top surface.

The nanostructured antireflection coating is fabricated by utilizing chemical bath deposition of tapered zinc oxide nanoneedles on planar tantalum …

Infrared Energy Harvesting For Optoplasmonics From Nanostructured Metamaterials, Gregory Thomas Forcherio

Graduate Theses and Dissertations

Metamaterials exhibit unique optical resonance characteristics which permit precise engineering of energy pathways within a device. The ability of plasmonic nanostructures to guide electromagnetism offers a platform to reduce global dependence on fossil fuels by harvesting waste heat, which comprises 60% of generated energy around the world. Plasmonic metamaterials were hypothesized to support an exchange of energy between resonance modes, enabling generation of higher energy photons from waste infrared energy. Infrared irradiation of a metamaterial at the Fano coupling lattice resonance was anticipated to re-emit as higher energy visible light at the plasmon resonance. Photonic signals from harvested thermal energy …

High Temperature Ltcc Based Sic Double-Sided Cooling Power Electronic Module, Hao Zhang

Graduate Theses and Dissertations

This objective of this dissertation research is to investigate a module packaging technology for high temperature double-sided cooling power electronic module application. A high-temperature wire-bondless low-temperature co-fired ceramic (LTCC) based double-sided cooling power electronic module was designed, simulated and fabricated. In this module, the conventional copper base plate is removed to reduce the thermal resistance between the device junctions to the heat sink and to improve the reliability of the module by eliminating the large area solder joint between the power substrate and the copper base plate. A low-temperature co-fired ceramic (LTCC) substrate with cavities and vias is used as …

The Design And Implementation Of A Multi-Chip Power Module Layout Synthesis Tool, Brett W. Shook

Graduate Theses and Dissertations

This thesis presents the design and implementation of a software tool, referred to as PowerSynth, which is used to synthesize multi-chip power module (MCPM) layouts and also aids in the overall design process. MCPMs allow power electronics systems to achieve higher efficiencies and reduced size, weight, and cost through the compact integration of devices into a single package. MCPM design is highly multidisciplinary which involves electrical, thermal, and mechanical performance considerations. Conventionally, the design process may require several iterations and multiple software modeling tools to create high performance MCPMs. The layout of an MCPM consists of a pattern of metal …

Understanding The Influence Of Interfacial Chemistry In Core, Core/Shell And Core/Shell/Shell Quantum Dots On Their Fluorescence Properties, Omondi Bernard Omogo

Graduate Theses and Dissertations

Colloidal semiconductor nanocrystals (quantum dots) have received a great deal of attention due to their superior size tunable properties and promising applications in many areas. Some of the most practical areas of their applications include light emitting diodes (LED), photovoltaic and biological studies. Synthetic methods of these crystals is becoming more established with new strategies being reported every now and then. However, quantitative studies connecting the processes at the interface, namely core-ligand, core-shell and shell-shells, to the overall quantum dots fluorescence properties are not well understood. Specifically for cores, relating surface-atoms interactions, solvents, ligands nature, density and functional groups on …

Identifying, Monitoring, Quantifying And Converting Algae To Bio-Fuels In Bio-Reactors, Alice C. Jernigan

Graduate Theses and Dissertations

Growing algae as a source for bio-fuels has become an area of interest due to concerns about global warming and the reliability and ecology of the production of fossil fuels. Dried algae harvested from a pilot water quality improvement technology at the Rockaway Wastewater Treatment Facility in New York were examined as a source of carbohydrates and lipids for the production of bio-fuels in bio-reactors. The length of storage time, storage conditions, sugar and lipid extraction processes, and fuel production were studied. The results show that if the algae is stored dry (0.015 g/g algae even after a year in …

Friction And Wear Of Polytetrafluoroethylene/Graphene Oxide Composite Thin Films, Justin Kyle Carter

Graduate Theses and Dissertations

Polytetrafluoroethylene (PTFE) is a commonly used solid lubricant due to its low coefficient of friction and chemical inertness. As a polymer, PTFE suffers from high wear and low adhesion to substrates limiting its use as a thin film. Thin PTFE films are ideal candidates for solid lubrication in micro-machines and bearing applications. The main goal of this work is to enhance the durability of thin PTFE films through the addition of few layered graphene oxide (GO) as filler. In order to address adhesion issues, the addition of an adhesive layer of polydopamine (PDA) between stainless steel substrates and thin PTFE …

Crack Growth Behavior Under Creep-Fatigue Conditions Using Compact And Double Edge Notch Tension-Compression Specimens, Santosh B. Narasimha Chary

Graduate Theses and Dissertations

The American Society for Testing and Materials (ASTM) has recently developed a new standard for creep-fatigue crack growth testing, E 2760-10, that supports testing compact specimens, C(T), under load controlled conditions. C(T) specimens are commonly used for fatigue and creep-fatigue crack growth testing under constant-load-amplitude conditions. The use of these specimens is limited to positive load ratios. They are also limited in the amount of crack growth data that can be developed at high stress intensity values due to accumulation of plastic and/or creep strains leading to ratcheting in the specimen. Testing under displacement control can potentially address these shortcomings …

Assessing Trichloromethane Formation And Control In Algal-Stimulated Waters Amended With Nitrogen And Phosphorus, Clinton Mash

Graduate Theses and Dissertations

Nitrogen (N) and phosphorus (P) enrichments can stimulate algal growth in drinking water sources, which can cause increased production of disinfection byproduct (DBP) precursors. However, the effect of systematic N and P enrichments on DBP formation and control has not been adequately studied. In this work, we enriched samples from a drinking water source - sampled on April 5, May 30, and August 19, 2013 - with N and P to stimulate algal growth at N:P ratios covering almost five orders of magnitude (0.2-4,429). To simulate DBP-precursor removal processes at drinking water treatment plants (DWTPs), the samples were treated with …

Assessing The Impact Of Chlorine Residual On Trihalomethane And Haloacetonitrile Formation Under Chlorination And Chloramination Disinfection Regimes, Thien Duc Do

Graduate Theses and Dissertations

A disinfection byproduct (DBP) formation potential (FP) test can be used to indirectly measure the concentration of DBP precursors in natural waters, permitting assessment of various DBP-related treatment processes and control strategies. While these tests require a 7-day chlorine residual (CR) between 3-5 mg L^-1 as Cl², it is not well known if this recommended residual corresponds to the true DBPFP (i.e., the maximum concentrations) for trihalomethanes (THMs) and haloacetonitriles (HANs). In this study, THMs and HANs were quantified as a function of CR under three common disinfection regimes: (1) free chlorine at pH 7.0 (FC7), (2) …

Investigation Of The Effects Of Rapid Thermal Annealing On Mbe Grown Gaasbi/Gaas Heterostructures For Optoelectronic Devices, Perry C. Grant

Graduate Theses and Dissertations

High efficiency optoelectronic devices rely on high quality materials making up the device structure. The scope of this thesis investigates the effectiveness of rapid thermal annealing (RTA) at improving the material quality of GaAsBi/GaAs heterostructures. During the fabrication of a device, the contacts of the device had the rapid thermal annealing process accomplished to produce ohmic contacts and this research explored if this annealing treatment degraded the quantum wells that made up the active region of a device. To investigate these effects, a system to measure the photoluminescence of the material system was constructed utilizing Fourier Transform Infrared Spectroscopy. The …

Microfluidics Guided By Redox-Magnetohydrodynamics (Mhd) For Lab-On-A-Chip Applications, Vishal Sahore

Graduate Theses and Dissertations

Unique microfluidic control actuated by simply turning off and on microfabricated electrodes in a small-volume system was investigated for lab-on-a-chip applications. This was accomplished using a relatively new pumping technique of redox-magnetohydrodynamics (MHD), which as shown in this dissertation generated the important microfluidic features of flat flow profile and fluid circulation. MHD is driven by the body force, FB = j × B, which is the magnetic part of the Lorentz force equation, and its direction is given by the right hand rule. The ionic current density, j, was generated in an equimolar solution of potassium ferri/ferro cyanide by applying …

An Open Source, Line Rate Datagram Protocol Facilitating Message Resiliency Over An Imperfect Channel, Christina Marie Smith

Graduate Theses and Dissertations

Remote Direct Memory Access (RDMA) is the transfer of data into buffers between two compute nodes that does not require the involvement of a CPU or Operating System (OS). The idea is borrowed from Direct Memory Access (DMA) which allows memory within a compute node to be transferred without transiting through the CPU. RDMA is termed a zero-copy protocol as it eliminates the need to copy data between buffers within the protocol stack. Because of this and other features, RDMA promotes reliable, high throughput and low latency transfer for packet-switched networking. While the benefits of RMDA are well known and …

Monodentate, Bidentate And Photocrosslinkable Thiol Ligands For Improving Aqueous Biocompatible Quantum Dots, Hiroko Takeuchi

Graduate Theses and Dissertations

Water-soluble Quantum Dots (QDs) are highly sensitive fluorescent probes that are often used to study biological species. One of the most common ways to render QDs water-soluble for such applications is to apply hydrophilic thiolated ligands to the QD surface. However, these ligands are labile and can be easily exchanged on the QD surface, which can severely limit their application. As one way to overcome this limitation while maintaining a small colloidal size of QDs, we developed a method to stabilize hydrophilic thiolated ligands on the surface of QDs through the formation of a crosslinked shell using a photocrosslinking approach. …

Attitudes And Behaviors In Online Communities: Empirical Studies Of The Effects Of Social, Community, And Individual Characteristics, Richard Kumi

Graduate Theses and Dissertations

Online communities and communities of practice bring people together to promote and support shared goals and exchange information. Personal interactions are important to many of these communities and one of the important outcomes of personal interactions in online communities and communities of practice is user-generated content. The three essays in the current study examines behavior motivation in online communities and communities of practice to understand how Social and personal psychological factors, and user-generated influence attitudes, intentions and behaviors in online communities.

The first essay addresses two research questions. First, how does Social capital influence exchange and combination behaviors in online …

Development And Evaluation Of Chitosan Particle Based Antigen Delivery Systems For Enhanced Antigen Specific Immune Response, Bhanuprasanth Koppolu

Graduate Theses and Dissertations

Particle-based vaccine delivery systems are under exploration to enhance antigen-specific immunity against safe but poorly immunogenic polypeptide antigens. Chitosan is a promising biomaterial for antigen encapsulation and delivery due to its ability to form nano- and microparticles in mild aqueous conditions thus preserving the antigenicity of loaded polypeptides. The objective of this work is to develop a chitosan particle based antigen delivery system for enhanced vaccine response. Chitosan particle sizes, which ranged from 300 nm to 3 ìm, were influenced by chitosan concentration, chitosan molecular weight and addition rate of precipitant salt. The composition of precipitant salt played a significant …

Analysis Of Social Networks In A Virtual World, Gregory Thomas Stafford

Graduate Theses and Dissertations

As three-dimensional virtual environments become both more prevalent and more fragmented, studying how users are connected via their avatars and how they benefit from the virtual world community has become a significant area of research. An in-depth analysis of virtual world Social networks is needed to evaluate how users interact in virtual worlds, to better understand the impact of avatar Social networks on the virtual worlds, and to improve future online Social networks.

Our current efforts are focused on building and exploring the Social network aspects of virtual worlds. In this thesis, we build a Social network of avatars based …

Zinc Oxide Nanorod Based Ultraviolet Detectors With Wheatstone Bridge Design, Arun Vasudevan

Graduate Theses and Dissertations

This research work, for the first time, investigated metal semiconductor-metal (MSM) zine oxide (ZnO) nanorod based ultra-violet (UV) detectors having a Wheatstone bridge design with a high

responsivity at room temperature and above, as well as a responsivity that was largely independent of the change in ambient conditions. The ZnO nanorods which acted as the sensing element of the detector were grown by a chemical growth technique. Studies were conducted to determine the effects on ZnO nanorod properties by varying the concentration of the chemicals used for the rod growth. These studies showed how the rod diameter and the deposition …

A Solar-Powered And Multi-Tiered Mesh Node For A Portable In Situ Emergency Response System, Adam Matthews

Graduate Theses and Dissertations

The aftermath of a natural disaster is typically characterized by lack of a reliable medium for dissemination of information to survivors. Current state-of-the-art emergency response systems rely on satellite radio-enabled devices, but survivors, unlike first responders, do not have access to such devices. To mitigate this problem, we present PERPETUU a solar-powered portable GIS microserver. The microserver node can be deployed in a disaster scene, and can serve maps to survivors viewable on browsers of off-the-shelf mobile systems. A key innovation in the design of the PERPETUU node is a multi-tiered hardware architecture-the system combines a low-power micro-controller, a medium-power …

Identifying Emerging Researchers Using Social Network Analysis, Syed Masum Billah

Graduate Theses and Dissertations

Finding rising stars in academia early in their careers has many implications when hiring new faculty, applying for promotion, and/or requesting grants. Typically, the impact and productivity of a researcher are assessed by a popular measurement called the h-index that grows linearly with the academic age of a researcher. Therefore, h-indices of researchers in the early stages of their careers are almost uniformly low, making it difficult to identify those who will, in future, emerge as influential leaders in their field. To overcome this problem, we make use of Social network analysis to identify young researchers most likely to become …

Developing Process Control Experiments For Undergraduate Chemical Engineering Laboratories, Chase M. Swaffar

Graduate Theses and Dissertations

It is the intent of this work to develop a process control apparatus and series of experiments that will help students visualize the PID (Proportional-Integral-Derivative) control of a process and enhance their understanding of the subject. The apparatus is a computer-controlled PID mixing system that responds quickly to set point changes and process disturbances which are directly observable. The system can easily be simulated with a transfer function model in Matlab's Simulink, so that the controller can be optimized for the desired system response. Four experiments can be conducted with this system including: exploration of system modeling and controller optimization …

Distortion-Tolerant Communications With Correlated Information, Ning Sun

Graduate Theses and Dissertations

This dissertation is devoted to the development of distortion-tolerant communication techniques by exploiting the spatial and/or temporal correlation in a broad range of wireless communication systems under various system configurations. Signals observed in wireless communication systems are often correlated in the spatial and/or temporal domains, and the correlation can be used to facilitate system designs and to improve system performance. First, the optimum

node density, i.e., the optimum number of nodes in a unit area, is identified by utilizing the spatial data correlation in the one- and two-dimensional wireless sensor networks (WSNs), under the

constraint of fixed power per unit …

The Development Of A Traumatic Brain Injury Bioreactor, Zachery Heller

Graduate Theses and Dissertations

Approximately 1.7 million Americans experience a traumatic brain injury (TBI) each year. Concussive injuries are a subset of TBI in which blows to the head cause the brain to collide against the interior of the skull. Damage to the neurons, supporting cells, and surrounding extra cellular matrix resulting from these collisions can lead to permanent physical, cognitive, and psychological impairment. We believe the prevalence and clinical significance of concussive injures warrants research investment. To study brain injury following TBI, in vivo models have been the gold standard for TBI experiments. Although a valuable research alternative, animals are expensive, raise ethical …

A Reconfigurable Digital-To-Analog Converter With Supply Invariant Linearity, Nicholas J. Chiolino

Graduate Theses and Dissertations

A novel reconfigurable digital-to-analog converter (DAC) with supply independent linearity is presented. The process agnostic converter achieves wide supply range operation and re-configurability by being charge based. This converter consists of a 7-bit parallel digital input control core and an analog "summing" core utilizing charging capacitors with an operational transconductance amplifier in a voltage-follower configuration. This topology is highly configurable to allow for optimization across process voltages, step sizes and low power operation. The specification of the DAC is (1) supply independence (2) low power operation (3) operation up to 200 kHz and (4) conversion control through a DAC enable …

A Wide Bandgap Silicon Carbide (Sic) Gate Driver For High Temperature, High Voltage, And High Frequency Applications, Ranjan Raj Lamichhane

Graduate Theses and Dissertations

The potential of silicon carbide (SiC) for modern power electronics applications is revolutionary because of its superior material properties including substantially better breakdown voltage, power density, device leakage, thermal conductivity, and switching speed. Integration of gate driver circuitry on the same chip, or in the same package, as the power device would significantly reduce the parasitic inductance, require far less thermal management paraphernalia, reduce cost and size of the system, and result in more efficient and reliable electrical and thermal performance of the system.

The design of a gate driver circuit with good performance parameters in this completely new under-development …

Design, Fabrication And Characterization Of Plasmonic Fishnet Structures For The Enhancement Of Absorption In Thin Film Solar Cells, Sayan Seal

Graduate Theses and Dissertations

Incorporating plasmonic structures into the back spacer layer of thin film solar cells (TFSCs) is an efficient way to improve their performance. The fishnet structure; which is a tunable, plasmonic light scatterer is used to enhance light absorption. Unlike other plasmonic particles that have been previously suggested, the fishnet is an electrically connected wire mesh and does not result in electric field localization, hence it results in greater absorption in the intrinsic Si layer. Unlike other designs, the fishnet structure is placed in the back spacer layer of the TFSC, so it does not block any incident light. There is …