Engineering Commons^™

Tin Sensitization For Electroless Plating, Xingfei Wei

Graduate Theses and Dissertations

The tin sensitization process has been used in electroless plating since 1940s Brenner and Riddell developed the electroless plating for surface metallization method. It was found to be an interesting topic to study tin sensitization for chemically controlling metal deposition on different substrates, because the tin sensitization process had critical effects on the electroless plated metal thin films. Nowadays electroless plating metal deposition is still an important method for depositing metals. It has a few advantages over the vapor deposition and electrodeposition method, such as work in an ambient condition, on nonconductive substrates, and without extra power input. Applying electroless …

An Experimental And Computational Evaluation Of The Importance Of Molecular Diffusion In Gas Gravity Currents, Jeremy Jac Herman

Graduate Theses and Dissertations

The accidental release of hazardous, denser-than-air gases during their transport or manufacture is a vital area of study for process safety researchers. This project examines the importance of molecular diffusion on the developing concentration field of a gas gravity current released into a calm environment. Questions which arose from the unexpectedly severe explosion in 2005 at Buncefield, England were of particular interest. The accidental overfilling of a large tank with gasoline on a completely calm morning led to a massive open air explosion. Forensic evidence showed that at the time of ignition, a vapor cloud, most of which now appears …

Effect Of Lightweight Aggregate Moisture Content On Internally Cured Concrete, Casey Jones

Graduate Theses and Dissertations

Putting an end to the rapid deterioration of concrete structures in the United States will only occur through the introduction of better materials and construction methods. The American Society of Civil Engineers (ASCE) reports the overall condition of concrete bridges in the United States to be a "C+". Though better than other areas of the infrastructure, there is still room for improvement in concrete bridges. One major area that may be improved is that of the concrete bridge deck. The bridge deck is comprised of the actual driving surface. It is subject to many deterioration mechanisms including freeze/thaw cycles, de-icing …

Evaluation Of Broiler Litter Heat Production During Windrowing & Nitrogen Based Gas Emission Mitigation Using Biofilter, Min Lei

Graduate Theses and Dissertations

Ammonia emission from animal feeding operations (AFOs) has negative effects on environment and animals' health. Thus measuring and mitigating ammonia emission from AFOs is important for environmental protection. In chapter I, different ammonia measurements were discussed and a mitigation technology- biofilter was represented.

In-house windrowing of built-up litter has been used by broiler producers to reduce pathogen loads and rejuvenate litter for the next flock. When litter is piled up for an extended period during downtime, heat generated by the litter pile can become a substantial heat source due to the metabolism of microorganisms. In chapter II, heat production rates …

Analysis Of Parameter Tuning On Energy Efficiency In Asynchronous Circuits, Justin Thomas Roark

Graduate Theses and Dissertations

Power and energy consumption are the primary concern of the digital integrated circuit (IC) industry. Asynchronous logic, in the past several years, has increased in popularity due to its low power nature. This thesis analyzes a collection of array multipliers with different parameters to compare two asynchronous design paradigms, NULL Convention Logic (NCL) and Multi-Threshold NULL Convention Logic (MTNCL). Several commercially available pieces of software and custom scripts are used to analyze the asynchronous circuits and their components to provide the energy consumption estimation on various parts of each circuit. The analysis of the software results revealed that MTNCL circuits …

Hybrid Nanostructured Textile Bioelectrode For Unobtrusive Health Monitoring, Pratyush Rai

Graduate Theses and Dissertations

Coronary heart disease, cardiovascular diseases and strokes are the leading causes of mortality in United States of America. Timely point-of-care health diagnostics and therapeutics for person suffering from these diseases can save thousands of lives. However, lack of accessible minimally intrusive health monitoring systems makes timely diagnosis difficult and sometimes impossible. To remedy this problem, a textile based nano-bio-sensor was developed and evaluated in this research. The sensor was made of novel array of vertically standing nanostructures that are conductive nano-fibers projecting from a conductive fabric. These sensor electrodes were tested for the quality of electrical contact that they made …

Design And Fabrication Of Inverter And Rectifier Modules For Indirect Matrix Converter Applications, Saikishore Talakokkula

Graduate Theses and Dissertations

In power converter applications, silicon carbide (SiC) power semiconductor devices are preferred over their silicon counterparts due to many advantages such as wide bandgap, high junction temperatures and low on-state resistance. The SiC devices provide reduced conduction and switching losses. Due to the above mentioned advantages the power conversion efficiency of SiC devices is better compared to that of silicon (Si) devices.

This thesis studies the implementation of 1200V/17A Normally-off SiC JFETs for an indirect matrix converter (IMC) application. A discussion on the parasitic inductance optimization is presented based on the electromagnetic simulation results extracted from the Ansoft Q3D extractor. …

Parameterizing Analytical Models To Support An Empirically Based Warehouse Design Methodology, Lisa Thomas

Graduate Theses and Dissertations

Research in the area of warehouse design is characterized by a myriad of analytical models that address one, typically small and isolated, area of the warehouse. These models, although important in gaining insight into one question of warehouse design, are of limited value when one considers the larger question of overall warehouse design. Thus, research in the area of overall warehouse design typically consists of procedure-driven processes based on qualitative factors and not the quantifiable results of analytical models.

In contrast, practitioners have significant empirical data related to how a design alternative performs in an industry, a company, or a …

Structural Properties Of Ferroelectric Lead (Zirconium0.5,Titanium0.5)Oxygen3 Nanotube Array And Electronic Structure Of Lao Delta-Doped Strontium Titanate, Rajendra Prasad Adhikari

Graduate Theses and Dissertations

In this Dissertation we begin with two introductions on: 1) ferroelectricity and related phenomena, and 2) novel properties of Oxide electronics and the generation of two dimensional electron gas. We then give theoretical background of density functional theory (including LDA+U) and pseudopotentials. The first part of research work is about structural, polarization, and dielectric properties of ferroelectric Lead Zirconate Titanate (PZT) solid solution in the form of a nanotube array, embedded in a matrix medium of different ferroelectric strengths. We use the effective Hamiltonian derived from first-principles and finite-temperature Monte Carlo methods to determine the various properties. We revealed different …

Multiscale Study Of Batio3 Nanostructures And Nanocomposites, Lydie Louis Louis

Graduate Theses and Dissertations

Advancements in integrated nanoelectronics will continue to require the use of unique materials or systems of materials with diverse functionalities in increasingly confined spaces.

Hence, research on finite-dimensional systems strive to unearth and expand the knowledge of fundamental physical properties in certain key materials which exhibit numerous concurrent and exploitable functions.

Correspondingly, ferroelectric nanostructures, which particularly display a plethora of complex phenomena, prevalent in countless fields of research, are noteworthy candidates. Presently, however, the assimilation of zero-(0D) and one-dimensional (1D) ferroelectric into micro- or nano-electronics has been lagging, in part due to a lack of applied and fundamental studies but …

Characterization And Quantification Of Monomers, Oligomers, And By-Products From Switchgrass Hemicelluloses During Biomass Pretreatment, Kris Allan Bunnell

Graduate Theses and Dissertations

Production of fuels and chemicals from biomass is contingent upon economical release of carbohydrates from biomass. Carbohydrates can then be used for production of bio-based products using a biochemical conversion process. Pretreatment, the first step of the biochemical conversion process, has been suggested to be the most costly step of the conversion process. Thus, better understanding the behavior of biomass during pretreatment is imperative for an economically viable production of biofuels and chemicals. Elucidating the physicochemical properties of biomass and developing an understanding the depolymerization patterns of biomass during pretreatment will help progress towards this goal.

In this study, July- …

The Legitimation Of Novel Technologies: The Case Of Nanotechnology, Anastasia E. Thyroff

Graduate Theses and Dissertations

Nanotechnology is the control, manipulation, and application of matter on an atomic and molecular level. The technology is complex and confusing to consumers, and its long-term safety and effect on the human body, as well as the environment, are unknown. However, for the past decade, nanotechnology has been used to develop consumer products and food with novel and attractive attributes.

Since nanotechnology is still not well known, it is not legitimized; that is, it has not been deemed safe and accepted by society. However, the market for nanotechnology is in the legitimation process. It will take an entire network of …

Defining Characteristics Of An Integrated Stem Curriculum In K-12 Education, Vinson Robert Carter

Graduate Theses and Dissertations

The purpose of the study was to obtain consensus concerning the defining characteristics of integrated STEM (Science, Technology, Engineering, and Mathematics) curriculum. This study utilized a three round modified Delphi study to solicit recommendations from experts of STEM education in order to: 1) create a set of categorical and defining curricular components needed to develop and implement appropriate integrated STEM curriculum; 2) identify the characteristics that set integrated STEM education curriculum apart from single-discipline curricula; 3) discuss the components necessary to gauge whether an initiative, project, or curriculum should be referred to as integrated STEM education; and 4) examine whether …

Synthesis Of Platinum And Platinum-Copper Branched Nanoparticles For Electrooxidation Of Methanol, Eric Courtland Taylor

Graduate Theses and Dissertations

Platinum and Pt alloys are among the most important heterogeneous catalysts for many organic reactions and electrochemical reactions associated with the fuel cell technologies. How to reduce Pt usage while maintaining the performance of the catalysts becomes a subject for intensive research in materials chemistry. For heterogeneous catalysis, the catalytic reactivity and selectivity are strongly correlated with different crystallographic facets exposed on the surface. The facets with high-index planes whose Miller indices with at one is larger than unity are generally more active than those with low-index planes (e.g., {100}, {111}, and {110}). Tuning the morphology of the nanoparticles to …

High Voltage Direct Current Energy Transmission Using Modular Multilevel Converters, David Alejandro Guzman Pinzon

Graduate Theses and Dissertations

This thesis focus on high voltage direct current (HVdc) energy transmission using modular multilevel converter (MMC) based terminals. It provides a brief comparison between different HVdc technologies, focusing on voltage source converters (HVdc-VSC) with the MMC-based terminal emerging as the topology of choice for ratings less than 1 GW. The controllers for a two-terminal HVdc-link are analyzed and Matlab/Simulink^TM simulation models are presented. The simplified models and full Matlab/Simulink^TM based model are used to select the gains for the MMC controllers. Simulation results carried out on the full model validated the proposed methodologies. A new control technique that …

System Design And Motion Artifact Removal Algorithm Implementation For Ambulatory Women Ecg Measurement System:E-Bra System, Hyeokjun Kwon

Graduate Theses and Dissertations

Cardio Vascular Disease (CVD) leads to sudden cardiac death due to irregular phenomenon of the cardiac signal by the abnormal case of blood vessel and cardiac structure. For last three decades, there is an enhanced interest in research for cardiac diseases.. As a result, the death rate by cardiac disease in men has been falling gradually compared with relatively increasing the death rate for women due to CVD. The main reason for this phenomenon is due to the lack of seriousness to female CVD and different symptoms of female CVD compared with the symptoms of male CVD. Usually, because the …

Algae To Propellants: Biosynthesis Of 1,2-Propanediol From Algal Derived Sugars, Lauren Rachelle Merriman

Graduate Theses and Dissertations

Propylene glycol dinitrate (PGDN) is an important component used in the formulation of energetic materials. A renewable, environmentally-friendly and effective production technique for the production of 1,2-propanediol, an important precursor to PGDN, is desired. While fermentation of 1,2-propanediol has been achieved, it suffers from major limitations such as expensive feed sugars and relatively low yields. It is hypothesized that algae sugars could serve as a feedstock for the microbial synthesis of 1,2-propanediol, thereby reducing production costs and enhancing sustainability.

Algal biomass produced from an Algal Turf Scrubber® has proven to have significant potential as a source of fermentable materials. However, …

Electrical Design Considerations And Packaging Of Power Electronic Modules, Shijie Wang

Graduate Theses and Dissertations

A modern power electronic module can save significant energy usage in the power electronic systems by improving their switching efficiencies. One way to improve the efficiency of the power electronic module is to reduce its parasitic circuit elements. The purpose of this thesis is to investigate the mitigation of parasitic circuit elements in power electronic modules. General methods of mitigating parasitic inductances were analyzed by the Q3D Extractor and verified by the time-domain reflectometry (TDR) measurements. In most cases, the TDR measurement results closely matched those predicted by the Q3D Extractor. These methods were applied to design and analyze a …

Cad Tool Design For Ncl And Mtncl Asynchronous Circuits, Vijay Mani Pillai

Graduate Theses and Dissertations

This thesis presents an implementation of a method developed to readily convert Boolean designs into an ultra-low power asynchronous design methodology called MTNCL, which combines multi-threshold CMOS (MTCMOS) with NULL Convention Logic (NCL) systems. MTNCL provides the leakage power advantages of an all high-Vt implementation with a reasonable speed penalty compared to the all low-Vt implementation, and has negligible area overhead. The proposed tool utilizes industry-standard CAD tools. This research also presents an Automated Gate-Level Pipelining with Bit-Wise Completion (AGLPBW) method to maximize throughput of delay-insensitive full-word pipelined NCL circuits. These methods have been integrated into the Mentor Graphics and …

Mitigating Shrinkage Cracking Of Concrete In Bridge Decks Through Internal Curing, Daniel Robert Goad

Graduate Theses and Dissertations

As the need for durable, long lasting infrastructure increases, new methods and techniques are being explored to prolong the service life of roads and bridges. One method to reduce shrinkage and early age cracking in concrete is internal curing. Internal curing supplies water to concrete, using pre-wetted lightweight aggregate (LWA), as needed throughout the process of hydration to reduce self desiccation, which leads to cracking. This research project analyzed two types of coarse LWA, expanded clay and expanded shale. The mixtures were developed specifically for use in bridge decks and adhered to specifications of the Arkansas State Highway and Transportation …

Variability In The Hydraulic Conductivity Of A Test Pad Liner System Using Different Testing Techniques, Matthew Jonathan Nanak

Graduate Theses and Dissertations

Historic methods (the time lag approach, the velocity approach, and the Z-t approach), utilized to reduce two stage borehole test data, were evaluated. Two of the historic methods provided viable results and were used for this research project. Additionally, these two methods are recommended for reducing two stage borehole test data in the future.

Flexible wall permeameter and soil index laboratory testing were conducted on the soil used to construct three environmentally controlled compacted clay liners (test pads) to develop a zone of acceptance (placement window). Using the results from the laboratory testing, two acceptance criterions were evaluated, while one …

Creep, Fatigue And Creep-Fatigue Interactions In Modified 9% Cr - 1% Mo (P91) Steels, Valliappa Kalyanasundaram

Graduate Theses and Dissertations

Grade P91 steel, from the class of advanced high-chrome ferritic steels, is one of the preferred materials for many elevated temperature structural components. Creep-fatigue (C-F) interactions, along with oxidation, can accelerate the kinetics of damage accumulation and consequently reduce such components' life. Hence, reliable C-F test data is required for meticulous consideration of C-F interactions and oxidation, which in turn is vital for sound design practices. It is also imperative to develop analytical constitutive models that can simulate and predict material response under various long-term in-service conditions using experimental data from short-term laboratory experiments. Consequently, the major objectives of the …

Return To Traffic Of Full Depth Reclamation Pavements, Robert Benjamin Hill

Graduate Theses and Dissertations

Full-Depth Reclamation (FDR) is a cost-effective rehabilitation treatment for deteriorated pavements. However, when using asphalt emulsion based rehabilitation techniques one of the most challenging aspects of FDR is determining when traffic can be returned to the rehabilitated pavement surface. Since asphalt emulsion mixtures need ample time for curing, they cannot be sealed with a surface layer until the water has evaporated from the rehabilitated layer. It is often not possible to keep the road closed until all of the water has evaporated and the surface layer is placed, therefore, at some point the traffic needs to be returned to the …

Reliability Analysis Of Social Networks, Kellie R. Schneider

Graduate Theses and Dissertations

The primary focus of this dissertation is on the quantification of actor interaction and the dissemination of information through Social networks. Social networks have long been used to model the interactions between people in various Social and professional contexts. These networks allow for the explicit modeling of the complex interrelations between relevant individuals within an organization and the role they play in the decision making process. This dissertation considers Social networks represented as network flow models in which actors have the ability to provide some level of influence over other actors within the network. The models developed incorporate performance metrics …

Plasmonic Nanostructures For The Absorption Enhancement Of Silicon Solar Cells, Nathan Matthias Burford

Graduate Theses and Dissertations

In this work, computational investigation of plasmonic nanostructures was conducted using the commercial finite element electromagnetics solver Ansys® HFSS. Arrays of silver toroid nanoparticles located on the surface of an amorphous silicon thin-film absorbing layer were studied for particle sizes ranging from 20 nm to 200 nm in outer diameter. Parametric optimization by calculating an approximation of the photocurrent enhancement due to the nanoparticles was performed to determine optimal surface coverage of the nanoparticles. A comparison was made between these optimized nanotoroid arrays and optimized nanosphere arrays based on spectral absorption enhancement and potential photocurrent enhancement in an amorphous silicon …

Development Of A Pdms Based Micro Total Analysis System For Rapid Biomolecule Detection, Balaji Srinivasan Venkatesh

Graduate Theses and Dissertations

The emerging field of micro total analysis system powered by microfluidics is expected to revolutionize miniaturization and automation for point-of-care-testing systems which require quick, efficient and reproducible results. In the present study, a PDMS based micro total analysis system has been developed for rapid, multi-purpose, impedance based detection of biomolecules. The major components of the micro total analysis system include a micropump, micromixer, magnetic separator and interdigitated electrodes for impedance detection. Three designs of pneumatically actuated PDMS based micropumps were fabricated and tested. Based on the performance test results, one of the micropumps was selected for integration. The experimental results …

Gesture Based Home Automation For The Physically Disabled, Alexander Hugh Nelson

Graduate Theses and Dissertations

Paralysis and motor-impairments can greatly reduce the autonomy and quality of life of a patient while presenting a major recurring cost in home-healthcare. Augmented with a non-invasive wearable sensor system and home-automation equipment, the patient can regain a level of autonomy at a fraction of the cost of home nurses. A system which utilizes sensor fusion, low-power digital components, and smartphone cellular capabilities can extend the usefulness of such a system to allow greater adaptivity for patients with various needs. This thesis develops such a system as a Bluetooth enabled glove device which communicates with a remote web server to …

Design And Fabrication Of Nanofluidic Systems With Integrated Sensing Electrodes For Rapid Biomolecule Characterization, Taylor Bradley Busch

Graduate Theses and Dissertations

A transparent nanofluidic system with embedded sensing electrodes was designed and fabricated by integrating Atomic Force Microscopy (AFM) nanolithography, Focused Ion Beam (FIB) milling and metal deposition, and standard microfabrication processing. The fabrication process started with the evaporation of chrome/gold (Cr/Au) onto a Pyrex 7740 wafer followed by photolithography and wet etching of the microchannels. The wafer was patterned a second time to form Au microelectrodes with 15-45 micrometer separation gaps in the nanochannel region. Sensing electrodes (up to one micron wide) were then deposited using FIB to bridge the gaps. The nanochannels were realized through both AFM nanolithography and …

Directed Percolation And The Abstract Tile Assembly Model, Tyler Garrett Moore

Graduate Theses and Dissertations

Self-assembly is a process by which simple components build complex structures through local interactions. Directed percolation is a statistical physical model for describing competitive spreading processes on lattices. The author describes an algorithm which can transform a tile assembly system in the abstract Tile Assembly Model into a directed percolation problem, and then shows simulations of the aTAM which support this algorithm. The author also investigates two new constructs designed for Erik Winfree's abstract Tile Assembly Model called the NULL tile and temperature 1.5. These constructs aid the translation between self-assembly and directed percolation and may assist self-assembly researchers in …

Intermediate Band Solar Cells Based On Inas Quantum Dots Embedded In Ingaas Quantum Well, Ramesh Vasan

Graduate Theses and Dissertations

Intermediate band solar cells based on quantum dots and quantum wells with anti-reflection coating are investigated in this thesis. The demand for high efficient solar cells as an alternate source of energy is the main motivation for this research project. Intermediate band solar cells based on quantum dots were the subject of intensive research in recent years. High power conversion efficiency was predicted from InAs/GaAs intermediate band solar cells as the presence of InAs quantum dots increased the absorption below the band gap of the host material.

In this thesis, an attempt has been made to further increase the absorption …