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Articles 2251 - 2280 of 2359

Full-Text Articles in Engineering

A Finite-Difference Method For Pseudo-Two-Dimensional Boundary Value Problems, Z. Mao, Ralph E. White Jan 1994

A Finite-Difference Method For Pseudo-Two-Dimensional Boundary Value Problems, Z. Mao, Ralph E. White

Faculty Publications

A finite-difference method is presented for solving pseudo-two-dimensional boundary-value problems. The sparse and nearly block tridiagonal properties of the matrices generated by using the finite-difference method for problems of this type are fully utilized and maintained, which yields a method that is highly efficient in the use of storage space and computation. An example shows that the central process unit time required by the method is significantly less than that required by an alternative method.

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Development Of Strength Theories For Random Fiber Composites, Victor Giurgiutiu Jan 1994

Development Of Strength Theories For Random Fiber Composites, Victor Giurgiutiu

Faculty Publications

A ressessment of existing theories for calculating the strength of random and quasi-random fiber composites is presented. Fundamental aspects regarding the physical model, macromechanics analysis, fiber distribution functions, generalized failure criterion, and progressive versus sudden failure models are covered first. Progressive ductile failure, progressive brittle failure, and sudden brittle failure are treated in detail. In each case, the original theory is briefly reviewed, and then its extensions accompanied by numerical examples are presented. Several limitations originally imposed by Hahn, such as the monotonically nonincreasing requirement on the failure strain curve, are lifted and the mathematical formulations are generalized. Some common …

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Effect Of Proton Diffusion, Electron Conductivity, And Charge-Transfer Resistance On Nickel Hydroxide Discharge Curves, John W. Weidner, Paul Timmerman Jan 1994

Effect Of Proton Diffusion, Electron Conductivity, And Charge-Transfer Resistance On Nickel Hydroxide Discharge Curves, John W. Weidner, Paul Timmerman

Faculty Publications

Constant-current discharge curves for the nickel hydroxide electrode are simulated assuming resistances due to diffusion of protons and conduction of electrons through the nickel hydroxide film, and charge-transfer resistance at the film/electrolyte interface contribute to the polarization losses of the electrode. Good qualitative agreement is observed between the model predictions and experimental discharge curves. The results suggest that polarization losses due to diffusional limitations of protons is a critical factor in determining the characteristics of the discharge curve. Ohmic resistance has a significant effect on the discharge curves at the end of discharge, and charge-transfer resistance is a minor contributor …

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Theoretical Analysis Of The Discharge Performance Of A Niooh/H2 Cell, Z. Mao, P. De Vidts, Ralph E. White, John Newman Jan 1994

Theoretical Analysis Of The Discharge Performance Of A Niooh/H2 Cell, Z. Mao, P. De Vidts, Ralph E. White, John Newman

Faculty Publications

A mathematical model is presented for the discharge of a NiOOH/H2 cell. This model includes diffusion and migration in the electrolyte phase as well as proton diffusion and ohmic drop across the solid active material in the porous nickelelectrode. A theoretical analysis of the cell performance is presented for different design parameters using this model. It is predicted that proton diffusion in the solid active material is the main factor in limiting the cell voltage and the utilizationof the active material. It is also predicted that use of a thick nickel electrode is an effective method for increasing electrode …

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Thermal Characteristics Of A Nickel-Hydrogen Battery, Junbom Kim, T. V. Nguyen, Ralph E. White Jan 1994

Thermal Characteristics Of A Nickel-Hydrogen Battery, Junbom Kim, T. V. Nguyen, Ralph E. White

Faculty Publications

The maximum allowable temperature difference inside a nickel-hydrogen battery to avoid water relocation was calculated by using a graphical method together with a vapor pressure vs. temperature correlation equation for water vapor over potassium hydroxide solution. An equation was developed for this maximum allowable temperature difference for vessel-wall temperatures from 0 to 30°C and potassium hydroxide concentrations from 20 to 32%. A heat-generation equation for the nickel-hydrogen battery was used to investigate the effect of the location of heat generation on the maximum temperature in the cell and the temperature distribution in the cell.

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The Role Of Thallium As A Hydrogen Entry Promoter On Cathodically Polarized Hy-130 Steel, G. Zheng, Branko N. Popov, Ralph E. White Jan 1994

The Role Of Thallium As A Hydrogen Entry Promoter On Cathodically Polarized Hy-130 Steel, G. Zheng, Branko N. Popov, Ralph E. White

Faculty Publications

Hydrogen permeation experiments were carried out to investigate the effect of thallium on hydrogen entry into HY-130steel. These experiments show that the presence of thallium ions in an electrolyte drastically increase the hydrogen entry rate. The hydrogen entry efficiency and hydrogen surface coverage were increased by a factor of 10 and 6, respectively. In order to fit the permeation experimental data, the Iyer-Pickering-Zamanzadeh (I-P-Z) hydrogen permeation model was modified by including a mass-transfer term in the discharging equation. The relationship between hydrogen permeation and the hydrogen evolution reaction were investigated and new relationships were obtained.

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On Stationary And Moving Interface Cracks With Frictionless Contact In Anisotropic Bimaterials, Xiaomin Deng Dec 1993

On Stationary And Moving Interface Cracks With Frictionless Contact In Anisotropic Bimaterials, Xiaomin Deng

Faculty Publications

The asymptotic structure of near-tip fields around stationary and steadily growing interface cracks, with frictionless crack surface contact, and in anisotropic bimaterials, is analysed with the method of analytic continuation, and a complete representation of the asymptotic fields is obtained in terms of arbitrary entire functions. It is shown that when the symmetry, if any, and orientation of the anisotropic bimaterial is such that the in-plane and out-of-plane deformations can be separated from each other, the in-plane crack-tip fields will have a non-oscillatory, inverse-squared-root type stress singularity, with angular variations clearly resembling those for a classical mode II problem when …

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Declarative Representations Of Multiagent Systems, Munindar P. Singh, Michael N. Huhns, Larry M. Stevens Oct 1993

Declarative Representations Of Multiagent Systems, Munindar P. Singh, Michael N. Huhns, Larry M. Stevens

Faculty Publications

This paper explores the specification and semantics of multiagent problem-solving systems, focusing on the representations that agents have of each other. It provides a declarative representation for such systems. Several procedural solutions to a well-known test-bed problem are considered, and the requirements they impose on different agents are identified. A study of these requirements yields a representational scheme based on temporal logic for specifying the acting, perceiving, communicating, and reasoning abilities of computational agents. A formal semantics is provided for this scheme. The resulting representation is highly declarative, and useful for describing systems of agents solving problems reactively.

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Low‐Cost Technique For Preparing N‐Sb2S3/P‐Si Heterojunction Solar Cells, O. Savadogo, K. C. Mandal Jul 1993

Low‐Cost Technique For Preparing N‐Sb2S3/P‐Si Heterojunction Solar Cells, O. Savadogo, K. C. Mandal

Faculty Publications

No abstract provided.

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Three Points Of Great Height On Elliptic Curves, Andrew Bremner, Duncan A. Buell Jul 1993

Three Points Of Great Height On Elliptic Curves, Andrew Bremner, Duncan A. Buell

Faculty Publications

We give three elliptic curves whose generators have great height, demonstrating along the way a moderately efficient method for finding such points.

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Mathematical Modeling Of The Formation Of Calcareous Deposits On Cathodically Protected Steel In Seawater, J. F. Yan, T. V. Nguyen, Ralph E. White, R. B. Griffin Jan 1993

Mathematical Modeling Of The Formation Of Calcareous Deposits On Cathodically Protected Steel In Seawater, J. F. Yan, T. V. Nguyen, Ralph E. White, R. B. Griffin

Faculty Publications

A first principle mathematical model of the formation of calcareous deposits on a cathodically protected steel rotatingdisk electrode in seawater is presented. The model includes equations which transport phenomena, electrochemical reactions,precipitation reactions, and a homogeneous reaction involved in the formation of calcareous deposits on an electrodesurface. Predicted concentration profiles show that a high concentration of OH– ions on the electrode surface leads to the formation of calcareous deposits. The calcareous deposits contain mostly CaCO3, but the initial deposits are predicted to contain more Mg(OH)2 than CaCO3. The predicted calcareous deposits on the electrode surface …

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Parametric Studies Of The Formation Of Calcareous Deposits On Cathodically Protected Steel In Seawater, J. F. Yan, Ralph E. White, R. B. Griffin Jan 1993

Parametric Studies Of The Formation Of Calcareous Deposits On Cathodically Protected Steel In Seawater, J. F. Yan, Ralph E. White, R. B. Griffin

Faculty Publications

A first principle mathematical model has been used to study the effects of ocean environment and cathodic protection on the formation of calcareous deposits and their ability to reduce the cathodic current density. These parameters include applied potential, rotation speed, temperature, salinity, and depth. The results showed the applied potential strongly influences the formation of calcareous deposits and their ability to reduce the cathodic current density. Among the environmental factors, rotation speed has the most influence on the cathodic current density. Salinity slightly influences the cathodic current density over the range of interest. Temperature is much more influential than salinity …

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A Water And Heat Management Model For Proton-Exchange-Membrane Fuel Cells, Trung V. Nguyen, Ralph E. White Jan 1993

A Water And Heat Management Model For Proton-Exchange-Membrane Fuel Cells, Trung V. Nguyen, Ralph E. White

Faculty Publications

Proper water and heat management are essential for obtaining high-power-density performance at high energy efficiency for proton-exchange-membrane fuel cells. A water and heat management model was developed and used to investigate the effectiveness of various humidification designs. The model accounts for water transport across the membrane by electro-osmosis and diffusion, heat transfer from the solid phase to the gas phase and latent heat associated with water evaporation and condensation in the flow channels. Results from the model showed that at high current densities (> 1 A/cm2) ohmic loss in the membrane accounts for a large fraction of the …

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Surface Treatment For Mitigation Of Hydrogen Absorption And Penetration Into Aisi 4340 Steel, G. Zheng, Branko N. Popov, Ralph E. White Jan 1993

Surface Treatment For Mitigation Of Hydrogen Absorption And Penetration Into Aisi 4340 Steel, G. Zheng, Branko N. Popov, Ralph E. White

Faculty Publications

The effectiveness of underpotential deposition of Pb onto a membrane made of AISI 4340 steel on the reduction of the hydrogen evolution reaction on the membrane and the degree of hydrogen ingress into the membrane was determined. In the presence of a monolayer coverage of Pb on the membrane surface, the hydrogen evolution currents were reduced by a factor of two compared with the values obtained on bare steel, and the steady-state hydrogen permeation flux through the steel membranes was reduced by 71%.

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Impedance Spectroscopy As A Nondestructive Health Interrogation Tool For Lithium-Bcx Cells, Branko N. Popov, W. Zhang, E. C. Darcy, Ralph E. White Jan 1993

Impedance Spectroscopy As A Nondestructive Health Interrogation Tool For Lithium-Bcx Cells, Branko N. Popov, W. Zhang, E. C. Darcy, Ralph E. White

Faculty Publications

The objective of this investigation was to study the growth of thick passivating layers on the Li anode in Li/BCX(Li/SOCl2 + BrCl) cells which were stored for a period of 3 years. Impedance spectroscopy and equivalent circuit models were used to determine characterizing parameters for these cells. The equivalent circuit used for virgin cells includes a faradic contribution and diffusion of the electroactive species. The equivalent circuit for batteries stored 1 or 2 years includes the impedance of a metal/passive film interface, the resistance of the film, and the impedance of the passivating film/electrolyte interface. The equivalent circuit used …

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Using Electrochemical Impedance Spectroscopy As A Tool For Organic Coating Solute Saturation Monitoring, Branko N. Popov, Mohammed A. Alwohaibi, Ralph E. White Jan 1993

Using Electrochemical Impedance Spectroscopy As A Tool For Organic Coating Solute Saturation Monitoring, Branko N. Popov, Mohammed A. Alwohaibi, Ralph E. White

Faculty Publications

Electrochemical impedance spectroscopy (EIS) has been used to study the solute uptake for epoxy/phenolic (E/p) andepoxy/amine (E/a) thick-coated mild steel samples immersed for 160 days in 3.5 weight percent NaCl solution exposed to air. Samples with thicknesses of approximately 200 µm with an exposed surface area of 22.6 cm2 were used to follow solute saturation of the organic coating. Good agreement was obtained between the calculated and measured coating capacitance when, according to the diffusion equation, the coating capacitance was plotted against exposure time.

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Galvanostatic Pulse And Pulse Reverse Plating Of Nickel-Iron Alloys From Electrolytes Containing Organic Compounds On A Rotating Disk Electrode, Branko N. Popov, Ken-Ming Yin, Ralph E. White Jan 1993

Galvanostatic Pulse And Pulse Reverse Plating Of Nickel-Iron Alloys From Electrolytes Containing Organic Compounds On A Rotating Disk Electrode, Branko N. Popov, Ken-Ming Yin, Ralph E. White

Faculty Publications

Linear sweep voltammetry, galvanostatic pulse, and pulse reverse techniques were used to study the plating of nickel-iron alloys in the presence of organic additives. The effects of pulse current densities, ip, reverse current densities, ir, rotation speed of disk electrode, and the presence of organic additives on deposition of nickel-iron alloys are evaluated. The observed phenomena can be explained by the concentration depletion of reactants (or products), and the surface coverage of the additives on the electrode. A new formulation of the plating bath is defined.

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Impedance Analysis For Oxygen Reduction In A Lithium Carbonate Melt: Effects Of Partial Pressure Of Carbon Dioxide And Temperature, Bhasker B. Dave, Ralph E. White, Supramaniam Srinivasan, A. John Appleby Jan 1993

Impedance Analysis For Oxygen Reduction In A Lithium Carbonate Melt: Effects Of Partial Pressure Of Carbon Dioxide And Temperature, Bhasker B. Dave, Ralph E. White, Supramaniam Srinivasan, A. John Appleby

Faculty Publications

Effects of partial pressure of carbon dioxide and temperature on oxygen reduction kinetics on a gold electrode in a lithium carbonate melt were examined using electrochemical impedance spectroscopic (EIS) and linear sweep voltammetric techniques. The impedance spectra were analyzed by a complex nonlinear least squares method, using the Randles-Ershler equivalent circuit model, to determine the electrode-kinetic and the mass-transfer parameters such as the charge-transfer resistance and the Warburg coefficient. The cyclic voltammetric measurements indicated that the oxygen reduction process in lithium carbonate melt is "reversible" up to 200 mV/s. The product DC0 determined by cyclic voltammetry agreed well …

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Thermal Analysis Of Spirally Wound Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White Jan 1993

Thermal Analysis Of Spirally Wound Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White

Faculty Publications

A thermal analysis of Li/BCX and high rate Li/SOCl2 cells is presented. The thermal model developed was used to study the effect of ambient temperature of discharge (0–40°C) on Li/BCX cells discharged at the same rate. The model predictions show that ambient temperature of discharge was critical in thermal management of the cell. For forced convection cooled cells, the model predicted that ambient temperature near room temperature (25°C) was required to achieve the lowest maximum temperature rise in the cell. Inclusion of the effects of reaction products to the model predictions showed that a constant composition assumption may be …

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Thermal Mathematical Modeling Of A Multicell Common Pressure Vessel Nickel-Hydrogen Battery, Junbom Kim, T. V. Nguyen, Ralph E. White Jan 1992

Thermal Mathematical Modeling Of A Multicell Common Pressure Vessel Nickel-Hydrogen Battery, Junbom Kim, T. V. Nguyen, Ralph E. White

Faculty Publications

A two-dimensional and time-dependent thermal model of a multicell common pressure vessel (CPV) nickel-hydrogen battery was developed. A finite element solver called PDE/Protran was used to solve this model. The model was used to investigate the effects of various design parameters on the temperature profile within the cell. The results were used to help find a design that will yield an acceptable temperature gradient inside a multicell CPV nickel-hydrogen battery. Steady-state and unsteady-state cases with a constant heat generation rate and a time-dependent heat generation rate were solved.

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Comparison Of Heat-Fin Materials And Design Of A Common-Pressure-Vessel Nickel-Hydrogen Battery, Junbom Kim, Ralph E. White Jan 1992

Comparison Of Heat-Fin Materials And Design Of A Common-Pressure-Vessel Nickel-Hydrogen Battery, Junbom Kim, Ralph E. White

Faculty Publications

A two-dimensional, axisymmetric, and time-dependent thermal model was developed to study the temperature behavior of the cylindrically shaped common-pressure-vessel nickel-hydrogen cell. A differential-energy-balance equation was used as the governing equation. A finite-element software package called PDE/Protran was used to solve this model. Different materials such as copper, copper beryllium, silver, and sterling silver were compared as heat-fin materials. The heat-fin geometry (thickness and height) and spacing were tested to find a design that yielded an acceptable temperature gradient inside a nickel-hydrogen cell. Pulse heat-generation rates were tested and correlated with the time-dependent heat-generation cases.

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Mathematical Modeling Of A Primary Zinc/Air Battery, Z. Mao, Ralph E. White Jan 1992

Mathematical Modeling Of A Primary Zinc/Air Battery, Z. Mao, Ralph E. White

Faculty Publications

The mathematical model developed by Sunu and Bennion has been extended to include the separator, precipitation of both solid ZnO and K2Zn(OH)4, and the air electrode, and has been used to investigate the behavior of a primary Zn-Air battery with respect to battery design features. Predictions obtained from the model indicate that anode material utilizationis predominantly limited by depletion of the concentration of hydroxide ions. The effect of electrode thickness on anode material utilization is insignificant, whereas material loading per unit volume has a great effect on anode material utilization; a higher loading lowers both the …

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Removal Of Mercury From Waste Water: Large-Scale Performance Of An Ion Exchange Process, James A. Ritter, J. P. Bibler Jan 1992

Removal Of Mercury From Waste Water: Large-Scale Performance Of An Ion Exchange Process, James A. Ritter, J. P. Bibler

Faculty Publications

Duolite™ GT-73 ion exchange resin routinely reduces the mercury content of a waste water stream to less than the permitted level of 10 ppb. Effluent concentrations from the ion exchange facility (IEF) are consistently between 1 to 5 ppb, even though the feed contains a varying concentration of mercury (0.2 to 70 ppm). Two operational problems have been encountered at that facility, however. Firstly, the stated capacity of the resin for mercury was not being achieved. The abnormally low capacity was traced to analytical laboratory waste which was intermittently treated by the resin. That waste contained hydrochloric acid, stannous chloride, …

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Characterizations Of Antimony Tri‐Sulfide Chemically Deposited With Silicotungstic Acid, O. Savadogo, K. C. Mandal Jan 1992

Characterizations Of Antimony Tri‐Sulfide Chemically Deposited With Silicotungstic Acid, O. Savadogo, K. C. Mandal

Faculty Publications

No abstract provided.

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Parameter Sensitivity And Optimization Predictions Of A Hydrogen/Oxygen Alkaline Fuel Cell Model, Michael C. Kimble, Ralph E. White Jan 1992

Parameter Sensitivity And Optimization Predictions Of A Hydrogen/Oxygen Alkaline Fuel Cell Model, Michael C. Kimble, Ralph E. White

Faculty Publications

A mathematical model is used to predict parameter sensitivities and optimal design parameters for a hydrogen/oxygen alkaline fuel cell. A sensitivity analysis of the various transport and electrode kinetic parameters indicates which parameters have the most influence on the predicted current density and over which range of potentials these parameters affect the fuel-cell performance the most. This information can be used to decide which parameters should be optimized or determined more accurately through further modeling or experimental studies. The effect of various design parameters on the limiting current density are investigated to determine if optimal values exist for the parameters. …

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The Self-Discharge Of The Niooh/Ni(Oh)2 Electrode Constant Potential Study, Z. Mao, Ralph E. White Jan 1992

The Self-Discharge Of The Niooh/Ni(Oh)2 Electrode Constant Potential Study, Z. Mao, Ralph E. White

Faculty Publications

Hydrogen oxidation currents at a NiOOH/Ni(OH)2 electrode were measured directly at constant potentials for various hydrogen pressures and states of charge. It was found that the hydrogen oxidation current is linearly proportional to the hydrogen pressure at all electrode potentials and that the logarithm of the anodic current is a linear function of electrode potential. It was also found that hydrogen oxidation on the nickel substrate material was strongly inhibited by the presence of nickel hydroxide on the substrate surface. By comparing the currents for hydrogen oxidation and oxygen evolution on the NiOOH/Ni(OH)2 electrode and on a nickel …

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Mathematical Modeling Of Cathodic Protection Using The Boundary Element Method With A Nonlinear Polarization Curve, J. F. Fan, S. N. R Pakalapati, T. V. Nguyen, Ralph E. White, R. B. Griffin Jan 1992

Mathematical Modeling Of Cathodic Protection Using The Boundary Element Method With A Nonlinear Polarization Curve, J. F. Fan, S. N. R Pakalapati, T. V. Nguyen, Ralph E. White, R. B. Griffin

Faculty Publications

The distributions of potential and current density around a cathodically protected pipeline in seawater were determined using the boundary element technique. A nonlinear polarization curve for a low carbon steel in artificial sea water was obtained from dc-potentiodynamic measurements and was fitted for use as the boundary condition on the pipe. The program was used to evaluate cases in which one or two aluminum sacrificial anodes are used to protect a low carbon steelpipe in seawater. The results show that the number of anodes, the sizes of the anodes, and the distance between the anodes and the cathode are of …

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Hydrogen Diffusion, Solubility, And Water Uptake In Dow's Short-Side-Chain Perfluorocarbon Membranes, Yu-Min Tsou, M. C. Kimble, Ralph E. White Jan 1992

Hydrogen Diffusion, Solubility, And Water Uptake In Dow's Short-Side-Chain Perfluorocarbon Membranes, Yu-Min Tsou, M. C. Kimble, Ralph E. White

Faculty Publications

Hydrogen gas diffusion coefficients and solubilities as well as water uptake values are reported for Dow's short-side-chain perfluoro-sulfonic and -carboxylic membranes of different equivalent weight (EW). The diffusion coefficients and solubilities were determined with an electrochemical test cell. Hydrogen solubility decreases with increasing EW in the lower EW range and tends to level off at higher EWs for both types of membranes. Both hydrogen solubility and diffusion coefficients of a sulfonic membrane with EW higher than 800 are higher than the corresponding values of a carboxylic membrane of similar EW. An unusual maximum is observed in the diffusion coefficient-EW plot …

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Calorimetric Determination Of The Thermoneutral Potential Of Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White, E. C. Darcy Jan 1992

Calorimetric Determination Of The Thermoneutral Potential Of Li/Bcx And Li/Socl2 Cells, E. E. Kalu, Ralph E. White, E. C. Darcy

Faculty Publications

Through a continuous recording of the cell voltage, heat flow, and current, the effective thermoneutral potential, Eetpof Li/BCX and Li/SOCl2 cells were determined in the temperature range, 0–60°C. The depth of discharge (DOD), temperature (T), and cell type (cell chemistry) affect the effective thermoneutral potential. The effective thermoneutral potential, Eetp differs from the classical thermoneutral potential of a cell because it takes into account the heat flow due to non-faradaic processes. The average effective thermoneutral potential at 25°C (determined by selecting the most constant region of Eetp vs. time of discharge) was 4.0 …

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Comparing Electrochemical Impedance Spectroscopy Methods For Estimating The Degree Of Delamination Of Organic Coatings On Steel, S. A. Mccluney, S. N. Popova, Branko N. Popov, Ralph E. White, R. B. Griffin Jan 1992

Comparing Electrochemical Impedance Spectroscopy Methods For Estimating The Degree Of Delamination Of Organic Coatings On Steel, S. A. Mccluney, S. N. Popova, Branko N. Popov, Ralph E. White, R. B. Griffin

Faculty Publications

Electrochemical impedance spectroscopy (EIS) was used to evaluate the degree of delamination of the epoxy primer Uniprime ED-41 electrocoated on phosphate-treated cold-rolled steel in 3.5% NaCl exposed to air. Specimens with coating thicknesses of 20.3 and 20.8 µm and surface areas of 78.5 cm2 were used. Coating parameters were obtained using a circuit-analog model. The area of delamination was estimated using several EIS parameters, including the pore resistance and the break point frequency. These values were compared to the corroded area determined visually. All methods considered exhibited a strong correlation over some or all of the range of …

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