Engineering Commons^™

Ghosts Of The Horseshoe, Heidi Rae Cooley, Richard Walker, Duncan Buell

Digital Projects

Ghosts of the Horseshoe (Ghosts) is a mobile interactive application that endeavors to bring into view--literally, on mobile micro screens (iPads and iPhones at present)--the largely unknown history of slavery at South Carolina College. It deploys game mechanics (i.e., ludic methods), as well as Augmented Reality (AR) and GPS functionality to generate awareness of and questioning about what otherwise seems ordinary: a grassy space at the center of a university campus. It organizes content into distinct but overlapping themes: (1) architectural ghosts (e.g., razed outbuildings); (2) human ghosts (e.g., un/named enslaved persons); and (3) the historic Wall delimiting the Horseshoe …

Electrochemical, Interfacial, And Surface Studies Of The Conversion Of Carbon Dioxide To Liquid Fuels On Tin Electrodes, Jingjie Wu

Theses and Dissertations

The electrochemical reduction of carbon dioxide (CO2) into liquid fuels especially coupling with the intermittent renewable electricity offers a promising means of storing electricity in chemical form, which reduces the dependence on fossil fuels and mitigates the negative impact of anthropogenic CO2 emissions on the planet. Although converting CO2 to fuels is not in itself a new concept, the field has not substantially advanced in the last 30 years primarily because of the challenge of discovery of structural electrocatalysts and the development of membrane architectures for efficient collection of reactants and separation of products. An efficient catalyst for the electrochemical …

Art Or Science?, Allison Marsh

Section 3: Imaging the Fast Moving

No abstract provided.

Self-Healing Catalysts: Co3O4 Nanorods For Fischer-Tropsch Synthesis, Cun Wen, Darrius D. Dunbar, Xin Zhang, Jochen A. Lauterbach, Jason R. Hattrick-Simpers

Faculty Publications

We combine kinetic and spectroscopic data to demonstrate the concept of a self-healing catalyst, which effectively eliminates the need for catalyst regeneration. The observed self-healing is triggered by controlling the crystallographic orientation at the catalyst surface.

Toward A Framework For Levels Of Robot Autonomy In Human-Robot Interaction, Jenay Beer, A. D. Fisk, W. A. Rogers

Faculty Publications

Autonomy is a critical construct related to human-robot interaction (HRI) and varies widely across robot platforms. Levels of robot autonomy (LORA), ranging from teleoperation to fully autonomous systems, influence the way in which humans and robots interact with one another. Thus, there is a need to understand HRI by identifying variables that influence—and are influenced by—robot autonomy. Our overarching goal is to develop a framework for LORA in HRI. To reach this goal, our framework draws links between HRI and human-automation interaction, a field with a long history of studying and understanding human-related variables. The construct of autonomy is reviewed …

Use Of In-Situ Tests To Identify Soil Behavior Type And Liquefaction Susceptibility Of Sccp Soils, Rajshekhar Sarkar

Theses and Dissertations

For many years, the Cone Penetrometer Test (CPT), Flat Plate Dilatometer Test (DMT) and Standard Penetration Test (SPT) have been used as in-situ tools to assess the liquefaction potential of soils. Given the importance of evaluating liquefaction potential in the South Carolina Coastal Plain (SCCP), research was conducted to study the soil behavior of soils prone to liquefaction, develop site specific correlations between SPT, DMT and CPT testing parameters and evaluate the liquefaction susceptibility of the soils in the SCCP. The SCCP sites studied in this thesis are Sampit (SAM), Gapway (GAP), Hollywood (HWD), Four Hole Swamp (FHS) and Fort …

Secure And Reliable Wireless Communication Through End-To-End-Based Solution, Hossen Asiful Mustafa

Theses and Dissertations

In the past few decades, network architectures and protocols are often designed to achieve a high throughput and a low latency. Security was rarely considered during the initial design phases. As a result, many network systems are insecure by design. Once they are widely deployed, the inherent vulnerabilities may be difficult to eliminate due to the prohibitive update cost. In this dissertation, we examine such types of vulnerabilities in various networks and design end-to-end-based solutions that allow end systems to address such loopholes.

The end-to-end argument was originally proposed to let end hosts implement application-specific functions rather than letting intermediate …

Classification Of Low Velocity Impactors Using Spiral Sensing Of Acousto-Ultrasonic Waves, Chijioke Agbasi

Theses and Dissertations

The non-linear elastodynamics of a flat plate subjected to low velocity foreign body impacts is studied, resembling the space debris impacts on the space structure. The work is based on a central hypothesis that in addition to identifying the impact locations, the material properties of the foreign objects can also be classified using acousto-ultrasonic signals (AUS). Simultaneous localization of impact point and classification of impact object is quite challenging using existing state-of-the-art structural health monitoring (SHM) approaches. Available techniques seek to report the exact location of impact on the structure, however, the reported information is likely to have errors from …

Bio-Inspired And Low-Content Polymer Cement Mortar For Structural Rehabilitation, Nima Zohhadi

Theses and Dissertations

Use of polymers as partial replacement for Portland cement in cement mortar and concrete can diminish several drawbacks of these composites such as low tensile strength and strain capacity, high permeability and low adhesion. Main reasons for the use of polymers are to improve damage tolerance, adhesion, and resistance to water permeation. Various polymers with a wide range of physical and mechanical properties have been used in fabrication of cementitious composites. Typical polymer content for such composites is 5% to 20% (by the weight of cement) for both mortar and concrete. There are also drawbacks associated with the use of …

Predictive Modeling Of Coupled Multi-Physics Systems: Ii. Illustrative Application To Reactor Physics, Dan Gabriel Cacuci, Madalina Corina Badea

Faculty Publications

This work presents paradigm applications to reactor physics of the innovative mathematical methodology for "predictive modeling of coupled multi-physics systems (PMCMPS)" developed by Cacuci (2014). This methodology enables the assimilation of experimental and computational information and computes optimally predicted responses and model parameters with reduced predicted uncertainties, taking fully into account the coupling terms between the multi-physics systems, but using only the computational resources that would be needed to perform predictive modeling on each system separately. The paradigm examples presented in this work are based on a simple neutron diffusion model, chosen so as to enable closed-form solutions with clear …

Transient Stability Enhancement Of Wind Farms Using Power Electronics And Facts Controllers, Hossein A. Mohammadpour

Theses and Dissertations

Nowadays, it is well-understood that the burning of fossil fuels in electric power station has a significant influence on the global climate due to greenhouse gases. In many countries, the use of cost-effective and reliable low-carbon electricity energy sources is becoming an important energy policy. Among different kinds of clean energy resources- such as solar power, hydro-power, ocean wave power and so on, wind power is the fastest-growing form of renewable energy at the present time. Moreover, adjustable speed generator wind turbines (ASGWT) has key advantages over the fixed-speed generator wind turbines (FSGWT) in terms of less mechanical stress, improved …

One-Step Production Of Long-Chain Hydrocarbons From Waste-Biomass-Derived Chemicals Using Bi-Functional Heterogeneous Catalysts, Cun Wen, Elizabeth A. Barrow, Jason R. Hattrick-Simpers, Jochen A. Lauterbach

Faculty Publications

n this study, we demonstrate the production of long-chain hydrocarbons (C₈₊) from 2-methylfuran (2MF) and butanal in a single step reactive process by utilizing a bi-functional catalyst with both acid and metallic sites. Our approach utilizes a solid acid for the hydroalkylation function and as a support as well as a transition metal as hydrodeoxygenation catalyst. A series of solid acids was screened, among which MCM-41 demonstrated the best combination of activity and stability. Platinum nanoparticles were then incorporated into the MCM-41. The Pt/MCM-41 catalyst showed 96% yield for C₈₊ hydrocarbons and the catalytic performance was stable …

Tuning The Underwater Oleophobicity Of Graphene Oxide Coatings Via Uv Irradiation, H. Li, Yi Huang, Y. Mao, W. Xu, Harry J. Ploehn, Miao Yu

Faculty Publications

Ultraviolet (UV) irradiation was utilized to gradually modify the chemistry and structure of graphene oxide (GO) flakes, as confirmed by XPS and AFM. Ultrathin GO coatings/membranes, made of UV-irradiated flakes, showed tunable underwater oleophobicity. UV-treated, superoleophobic GO membranes exhibited excellent antifouling capability for oil/water separation.

System Analysis With Improved Thermo-Mechanical Fuel Rod Models For Modeling Current And Advanced Lwr Materials In Accident Scenarios, Ian Edward Porter

Theses and Dissertations

A nuclear reactor systems code has the ability to model the system response in an accident scenario based on known initial conditions at the onset of the transient. However, there has been a tendency for these codes to lack the detailed thermo-mechanical fuel rod response models needed for accurate prediction of fuel rod failure. This proposed work will couple today's most widely used steady-state (FRAPCON) and transient (FRAPTRAN) fuel rod models with a systems code TRACE for best-estimate modeling of system response in accident scenarios such as a loss of coolant accident (LOCA). In doing so, code modifications will be …

Implementation And Evaluation Of Fuel Creep Using Advanced Light-Water Reactor Materials In Frapcon 3.5, Spencer Carroll

Theses and Dissertations

As current reactors approach the end of their operable lifetime, new reactors are needed if nuclear power is to continue being generated in the United States. Some utilities have already began construction on newer, more advanced LWR reactors, which use the same fuel as current reactors and have a similar but updated design. Others are researching next generation (GEN-IV) reactors which have new designs that utilize alternative fuel, coolants and other reactor materials. Many of these alternative fuels are capable of achieving higher burnups and are designed to be more accident tolerant than the currently used UO2 fuel. However, before …

High Throughput Multi-Solution Genetic Algorithm (Htmga) For Identification Of Alternate Solutions In A Structural Model Updating Context, Muslum Kilinc

Theses and Dissertations

Model updating techniques seek to improve numerical models of existing structure by integrating experimental data from the structure. Many techniques use an error function that describes the differences between the numerical model and the experimental data. For example, if dynamic data is available, the error between experimental and numerical modal parameters can be used. Optimization techniques are used to identify the structural parameters that minimize this function. Most model updating techniques are interested in finding the global minima of the error function. However, one could argue that due to a number of factors, such as modeling errors and low sensor …

Modeling Of Chemical-Mechanical Couplings In Solid Oxide Cells And Reliability Analysis, Xinfang Jin

Theses and Dissertations

Solid oxide fuel cell (SOFC) has been well demonstrated as a promising clean energy conversion technology. For practical applications, the SOFC systems should have both good electrochemical performance and high reliability. The SOFCs are usually operated under very aggressive conditions, e.g., high temperatures (600-1000oC) and extremely low oxygen partial pressures (anode electrode). These aggressive operating conditions could lead to a variety of material system degradations, imposing great challenges on meeting lifetime requirement of SOFC commercial applications. It is therefore essential to increase the understanding of fundamental SOFC degradation mechanisms.

The basic structure of SOFCs is a positive electrode-electrolyte-negative electrode (PEN) …

Identifying Performance Criteria Of Fully Bioresorbable Scaffolds For Endovascular Applications, Jahid Ferdous

Theses and Dissertations

Background: Bioresorbable scaffolds (BRS) have revolutionized percutaneous coronary intervention in clinical cardiovascular medicine. As opposed to permanent alternatives such as metallic stents, BRS have an inherent potential to reduce the occurrence of untoward events such as vessel re-narrowing or thrombosis by virtue of undergoing complete and controlled resorption post- implantation. While BRS platforms demonstrate a clear potential to mitigate risk stemming from incomplete vessel healing, they introduce a new set of considerations to clinical safety and efficacy. Foremost among these issues is the fate of and biological response to material by-products that evolve throughout the scaffold degradation and erosion processes, …

Material Synthesis And Fabrication Method Development For Intermediate Temperature Solid Oxide Fuel Cells, Hanping Ding

Theses and Dissertations

Solid oxide fuel cells (SOFCs) are operated in high temperature conditions (750-1000 oC). The high operating temperature in turn may lead to very complicated material degradation issues, significantly increasing the cost and reducing the durability of SOFC material systems. In order to widen material selections, reduce cost, and increase durability of SOFCs, there is a growing interest to develop intermediate temperature SOFCs (500-750 oC). However, lowering operating temperature will cause substantial increases of ohmic resistance of electrolyte and polarization resistance of electrodes. This dissertation aimed at developing high-performance intermediate-temperature SOFCs through the employment of a series of layered perovskite oxides …

A Multiagent Approach Towards Solving Complex Problems Of Sociotechnical Systems, Hongying Du

Theses and Dissertations

Complex resource allocation problems arise due to complex human societies and scarce resources to be distributed. Scarce resources could be food, water, and energy. Meanwhile, the size of the problem, the intersection of different areas, and possible global consequences all add to the complexity of the problems, which makes it difficult for humans to solve the problems by themselves.

For all these reasons, humans need technical help to tackle complex problems. Since humans participating in the problems usually own part of the information about the problems, and no one may see the whole picture of the problems, it is natural …

Defect Mediated Electrochemical Hydrogenation Of Epitaxial Graphene: Towards Graphene Based Microbial Fuel Cells, Kevin Michael Daniels

Theses and Dissertations

Microbial fuel cells (MFCs) are seen as a promising complementary technology to alleviate the exponentially increasing worldwide energy demand. MFCs use bacteria to extract energy from biomass, where choice of electrode materials has a strong impact on energy extraction and efficiency. Graphene, a single monolayer of carbon with exceptional electrical conductivity and high surface area, is seen as a promising material with the potential of improving charge transfer and bacterial adhesion. To probe this reactivity, a novel means of hydrogenation of graphene by electrochemistry is demonstrated.

In this thesis, electrochemical hydrogenation of epitaxial graphene (EG), graphene grown on silicon carbide …

Isolation Of Natural Nrf2 Activators From American Ginseng, Akrm Abdalrahman

Theses and Dissertations

Nuclear factor erythroid-2 related factor 2 (Nrf2), a major transcription factor of the endogenous antioxidant defense system, has been proposed as a potential therapeutic target for the treatment of various diseases. However, a small molecule-driven Nrf2 signaling therapeutic approach remains to be established. Herein, we report one such possibility discovered by the bioassay-based fractionation of American ginseng. Since crude extract of American ginseng was found to suppress the expression of inducible nitric oxide synthase (iNOS) in lipopolysaccharide (LPS)-inflamed macrophages via activating Nrf2, we further fractioned the crude extract using solvents including hexane, dichloromethane, ethyl acetate, butanol, and water, and found …

High Frequency Ac Power Systems, Huaxi Zheng

Theses and Dissertations

High Frequency AC (HFAC) power systems - systems having frequencies higher than the usual 60 Hz - may have advantages in some applications, especially where small size and weight are important (aircraft, ships, etc), or where variable operating speed increases efficiency. While 400 Hz systems are widely used in aircraft, these generally do not include parallel-connected generators that operate at megawatt power levels, which is our domain of interest in this research. In particular, we are interested in micro-grid power systems in the 10-100 MW range, consisting of several generators operating in parallel at system frequencies above 60 Hz. This …

Measuring The Effectiveness Of Education For Sustainable Development Interventions For Effecting Change In Knowledge, Attitude And Behaviors Toward Sustainable Development, Christopher Robin Wilson

Theses and Dissertations

The question addressed by this study is whether an intervention involving a brief, focused seminar providing Sustainability Fundamental education can affect change in sustainability-centric behavior via measured change in attitude toward sustainability and/or change knowledge of sustainability fundamentals.

This study focused on applying and extending lessons from a previous exploration of the relationships between sustainable behavior and both attitude toward sustainability and knowledge of sustainability. The test involved determining whether brief, science-based sustainability fundamentals seminars are an effective intervention for affecting the favorable sustainable behavior of practicing engineers, defined as professionals engaged in engineering post-completion of their formal studies, in …

Synthesis And Reactivity Of Hy Zeolite-Supported Rhodium Complexes, Artem D. Vityuk

Theses and Dissertations

The growing interest in the design of heterogeneous analogs of highly active and selective homogeneous catalysts prompted researchers to invest significant efforts in understanding of synthetic pathways, structure, and reactivity of supported single-site metal complexes. Synthesis of catalytically active organometallic species on solid supports with properties resembling those of their homogeneous counterparts could offer the opportunities to perform efficiently the solution organic reactions by utilizing flow instead of batch reactors. In this regard, rhodium carbonyl complexes and their derivatives are viewed as very attractive candidates for heterogenization due to their extensive application as catalysts for variety of industrially important reactions. …

Volume Swing Frequency Response Method For Determining Mass Transfer Mechanisms In Microporous Adsorbents, Mohammad Iftekhar Hossain

Theses and Dissertations

Because of their numerous important applications in industrial catalytic, separation, and purification processes, miroporous materials have attracted considerable attention. Understanding the dynamic behavior of various gases in these porous materials is a critical step in designing, developing and effective operation of such kind of industrial processes. Frequency response (FR) methods have proven to be one of the best recently developed techniques and have been widely used to investigate kinetics behavior of various gas-solid systems due to their ability to discriminate among different rate limiting mechanisms. The current work has been focusing on the development of a volume swing frequency response …

Novel Conditioning Protocols Focusing On Oxygen Manipulation To Enhance Stem Cell Transplantation, Brandon William Hanna

Theses and Dissertations

Musculoskeletal tissue engineering involves the creation of multiple tissue types that interact together to form a particular function related to motion and maintaining the body's frame. In order to create a fully functional musculoskeletal system, a concrete method for the creation of the different tissue types must first be completed. Of the different tissue components related to the function of a musculoskeletal system, these studies deal with preconditioning circumstances of stem cells that will differentiate into cartilage and bone. These studies also deal with methods for the creation of functional bone and cartilage to be combined for the creation of …

Development Of A Pressure Swing Adsorption Process For Co2 Capture From Flue Gas Using Solid Amine Sorbents, Anahita Abdollahi Govar

Theses and Dissertations

Solid amines are comprised of adsorbent materials, like silica gel, that contain amine based organic compounds, either physically or chemically, attached within their pores. The major characteristic of these sorbents that makes them interesting for CO₂ capture from flue gas is that unlike zeolites they are not negatively affected by the presence of water. The current work has been focusing on the development of a novel PSA cycle for CO₂ capture from flue gas using a solid-amine sorbent composed of PEI physically immobilized on a commercial silica substrate. The goal was to achieve > 90% recovery and > 95 vol. …

Understanding Hydrothermal Carbonization Of Mixed Feedstocks For Waste Conversion, Xiaowei Lu

Theses and Dissertations

Hydrothermal carbonization (HTC) is an environmentally beneficial means to convert waste materials to value-added solid and liquid products with minimal greenhouse gas emission. Research is lacking on understanding the influence of critical process conditions on product formation and environmental implication associated with HTC of waste streams. This work was conducted to determine how reaction conditions and heterogeneous compound mixtures (representative of municipal wastes) influence hydrothermal carbonization processes. The specific experiments include: (1) determine how carbonization product properties are manipulated by controlling feedstock composition, process conditions, and catalyst addition; (2) determine if carbonization of heterogeneous mixtures follows similar pathways as that …

Heat Transfer Enhancement By Three-Dimensional Surface Roughness Technique In Nuclear Fuel Rod Bundles, Kang Liu

Theses and Dissertations

DISS_abstract> This thesis investigate thermal characteristic of a single-phase nano-fluid in a single heater element loop tester and provides a comparison between heat transfer enhancement results achieved using water as a coolant and using nano-fluids with different volume percentage. The experimental investigation is performed on two simulated nuclear fuel rods with two different types of modified outer surfaces roughness. The fuel rod surfaces modified are termed as two-dimensional surface roughness (square transverse ribbed surface) and three-dimensional surface roughness (Diamond shaped blocks). The nano-fluid used are 0.5% and 2% ZnO-Deionized water based nano-fluid. The maximum heat transfer co-efficient enhancement achieved compared …