Engineering Commons^™

The Structural And Magnetic Properties Of Nio/Mn(Ni)-Oxide Magnetic Heterostructured Nanocrystals Synthesized Under Varying Ph Values, Abdullah Al Shafe

Graduate Theses/Dissertations

The role of pH on the structural, morphological, and magnetic properties of hydrothermally synthesized NiO-based magnetic heterostructured nanocrystals (MHNCs) is investigated. The NiO nanocrystals were synthesized using a two-step thermal decomposition process whereas the deposition of the surrounding Mn-based phases was accomplished by hydrothermal means at pH values ranging from 2.4 to 7.0. The resulting heterostructured nanocrystals consist of inverted AFM-FiM NiO/±Mn_xNi_1-xO/±Mn₃O₄ bimagnetic/trimagnetic systems. A complete characterization of the MHNCs was carried using XRD, TEM, EDS, MPMS magnetometry and XPS analysis. Structural investigations revealed predominantly faceted MHNCs ranging in size from 24-30 nm …

Investigation Of Various Techniques For Controlled Void Formation In Fiberglass/Epoxy Composites, Donald A. Klosterman, Charles Browning, Issa Hakim, Kyle Lach

Chemical and Materials Engineering Faculty Publications

The effect of porosity in composite materials has been studied for years due to its deleterious effects on mechanical properties, especially matrix dominated properties. Currently there is an increasing use of composites in infrastructure worldwide, for example bridge components, residential and building structures, marine structures such as piers and docks, and large industrial chemical tanks. Most of these applications use fiberglass composites. Unfortunately, most of the published literature has focused on carbon fiber composites, in which fiber diameter and gas-fiber interactions are different than fiberglass composites. Therefore, the present study was undertaken to revisit the effect of porosity but specifically …

Single Molecule Super-Resolution Microscopy Study On The Precision With Which Dna Nanostructures Can Orient Fluorescent Dyes, Brett Michael Ward

Boise State University Theses and Dissertations

DNA nanotechnology enables the rapid, programmable self-assembly of novel structures and devices at the nanoscale. Utilizing the simplicity of Watson-Crick base pairing, DNA nanostructures are capable of assembling a variety of nanoparticles in arbitrary configurations with relative ease. Several emerging opto-electronic systems require a high degree of control of both the position and orientation of component fluorescent molecules, and while DNA nanostructures have demonstrated these capabilities, the precision with which DNA can orient fluorescent molecules is not well understood. Determining these bounds is critical in establishing the viability of DNA nanotechnology as a method of assembling fluorescent molecular networks.

In …

Mxenes As Flow Electrodes For Capacitive Deionization Of Wastewater, Naqsh E. Mansoor

Boise State University Theses and Dissertations

The energy-water nexus poses an integrated research challenge, while opening up an opportunity space for the development of energy efficient technologies for water remediation. Capacitive Deionization (CDI) is an upcoming reclamation technology that uses a small applied voltage applied across electrodes to electrophoretically remove dissolved ionic impurities from wastewater streams. Similar to a supercapacitor, the ions are stored in the electric double layer of the electrodes. Reversing the polarity of applied voltage enables recovery of the removed ionic impurities, allowing for recycling and reuse. Simultaneous materials recovery and water reclamation makes CDI energy efficient and resource conservative, with potential to …

Hydrothermal Reaction Synthesis And Characterization Of Zns:Ag Scintillator, Yuchen Shao

All Theses

Thisworkaims at the development of a reactive ultrafiltration membrane scintillator for rapid activity determination and isotopic quantification of waterborne special nuclear materials (SNMs) based on ZnS:Ag. The effects of the pH of the precursor solution on ZnS:Ag synthesized under various conditions of temperature and time by the hydrothermal reaction synthesis method (200℃ for 6 hours, pH from 1 to 12; 100℃ for 2 hours, pH from 7 to 12;60℃ for 6 hours, pH from 7 to 12) were investigated. Samples were characterized on their structure, morphology and luminescence by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), photoluminescence (PL) …

Alumina Ceramic Membrane Incorporated With Graphene Oxide Frameworks For Protein Recovery, Ishak Noor Fauziyah

Student Works (2020-2029)

Alumina ceramic membrane is undergoing rapid development and innovation for protein recovery process. However, the limitation of this membrane type is membrane fouling due to the deposition and adsorption of proteins on the surface and pore walls of the membranes. It is crucial to minimize membrane fouling by reducing interactions between protein and the membrane surface via surface modification technique. Thus, the main objective of this research is to develop an alumina membrane with enhanced antifouling property for protein recovery process. An alumina dope consisting of 57 wt.% alumina loading was used to fabricate two alumina membrane configurations; which are …

Microstructural Evolution And Mechanical Properties Of Ultra-Fine Grained Tubular Components Processed By Severe Plastic Deformation, Mesbah Mohsen

Student Works (2020-2029)

The lightweight alloys have been widely used in various engineering applications such as automotive, aerospace, construction, and biomedical industries due to their low densities, high ductility, formability, and facile machining. However, the emerging trend for materials with high mechanical strength and plasticity hampers the widespread application of these alloys. Over the last two decades, severe plastic deformation (SPD) has been introduced as a promising approach for enhancement of the mechanical performance of the lightweight alloys through microstructural manipulations and grain refinement. However, the SPD techniques have been extensively utilized for the fabrication of non-tubular geometries and the studies on the …

Formula Sae Monocoque Chassis Development, Kc Egger, Brian Ford, Kyle Nagao, Neal Sharma, Donovan Zusalim

Mechanical Engineering

Formula SAE is a collegiate competition hosted by SAE International with the primary goal being to design, manufacture, and race an open wheel race car. The Cal Poly Racing Formula SAE team strives for improvement every race season and has remained competitive as a result. The 2019-2020 management team determined that further research and development towards the chassis would yield the greatest performance benefit for future seasons, as the previous chassis platform limited packaging and mounting options for vehicle subsystems which interfaced with the chassis.

A redesign of the Cal Poly Racing Formula SAE team’s carbon fiber reinforced polymer monocoque …

Production And Characterization Of Uranium Sol Gel Surrogates Produced With Cerium Acetate And Cerium Nitrate, Matthew Brett Alford

All Dissertations

For the production of ceramic microspheres for future space travel, new methods of processing must be explored. The sol gel method proves promising for the production of uranium-based ceramic microspheres that are consistent enough in size and shape for such an application. A process for producing these microspheres has already been established, but there are avenues for improvement.

Handling of radioactive material like uranium is not always possible or warranted. As such, a non-radioactive surrogate that greatly resembles the processing of its actual radioactive counterpart. Herein this work a cerium-based surrogate is developed to closely resemble an already established process …

Development Of Bragg Fiber Sensor For Corrosion Detection, Cai Hui Tan

Student Works (2020-2029)

Steel corrosion has posed one of the major structural defects in the civil society today. Conventional methods for corrosion monitoring involve high maintenance cost and destructive methods with low accuracy. Recently, Fiber Bragg gratings (FBG) sensor with its high sensitivity in measuring strain and temperature have been widely studied and used in structural health monitoring (SHM). A non-destructive corrosion detection approach based on FBG sensors was developed and tested to monitor corrosion in this research work. The principle of FBG sensing is based on Bragg wavelength shifts that from the corrosion process that induced strain on the FBG due to …

Comparison Of Pressure-Assist Silver Sintering To Tin Silver Solder Alloy As Die Attach Material In High Power Semiconductor, Tolentino Erik Nino

Student Works (2020-2029)

The research is focused on pressure-assisted silver sintering material that is compared to tin silver solder alloy paste as used in power electronics. Material characterization, electrical tests, and reliability tests were conducted in the experiment. After drying process, it was observed that the Ag sintering paste height was reduced to approximately 40 percent. Die attach shear test showed that the average reading is about from 200 to 600 grams which are already enough to hold the dice before proceeding to the pressure sintering process. X-ray revealed that the void percent for SnAg paste sample is about 1.5 percent while pressure-assist …

Synthesis And Characterization Of Bimetallic Gold-Silver (Au-Ag) Nanocatalyst Via Seed Colloid Technique, Berahim Nurafaliana

Student Works (2020-2029)

In the present study, unique catalysts of monometallic gold (Au), silver (Ag) and bimetallic gold-silver (Au-Ag) nanoparticles (NPs) were prepared with different size or diameters by the citrate-thermal reduction and the seed colloidal techniques, respectively. The catalytic nanoparticles were characterized by various advanced analytical techniques such as Ultraviolet-visible spectroscopy (UV-vis), zeta potential, electron dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), High-angle annular dark-field (HAADF) scanning transmission-electron microscopy (STEM) imaging and the energy dispersive spectroscopy (EDS) elemental mapping. The catalytic performance of the nanoparticles were ascertained through the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) in …

Synthesis And Characterization Of Self-Cleaning Hydrophobic Organic Coating, Abdul Jaafar Amirul Syafiq

Student Works (2020-2029)

Three self-cleaning coating systems namely Polydimethylsiloxane (PDMS)/Sylgard, PDMS/3-Aminopropyltriethoxysilane (APTES) (tagged as A1) and A1 blended with nano-Calcium Carbonate (CaCO3) have been synthesised on glass substrates via dip-coating and spray-coating techniques. All of the prepared coatings were dried under ambient condition before being subjected to characterisations and testing(s). The effect of various weight percentages of Sylgard resin that are 5wt.% (S1 coating), 10wt.% (S2 coating), 15wt.% (S3 coating), and 20 wt.% (S4 coating) on the hydrophobicity, self-cleaning property, anti-fog performance and mechanical property of PDMS/Sylgard coating have been discussed in the first section of this thesis. The PDMS/Sylgard coated glass substrates …

Mechanism Of Compaction With Wrinkle Formation During Automatic Stitching Of Dry Fabrics And The Size Effect Of Compression Molded Discontinuous Fiber-Reinforced Composites, Anibal Benjamin Beltran Laredo

Mechanical & Aerospace Engineering Theses & Dissertations

With an ever-increasing demand for composites, more ways of manufacturing them are becoming popular and widely used. Stitching of dry fabrics is an efficient method for improving delamination resistance. Discontinuous fiber reinforced composites can be used as a lightweight alternative material for metals through a process of compression molding, which allows for complex shape manufacturing while offering structural grade mechanical properties.

This study demonstrates how the stitching of dry fabrics can be adapted to more complex surfaces. The consequences of stitching of curvilinear surfaces can result in defect formation. Therefore, to understand the physical formation of possible defects, experimental characterization …

U.S. Greenhouse Gas Emission Bottlenecks: Prioritization Of Targets For Climate Liability, Alexis Pascaris, Joshua M. Pearce

Michigan Tech Publications, Part 1

Due to market failures that allow uncompensated negative externalities from burning fossil fuels, there has been a growing call for climate change-related litigation targeting polluting companies. To determine the most intensive carbon dioxide (CO₂)-emitting facilities in order prioritize liability for climate lawsuits, and risk mitigation strategies for identified companies as well as their insurers and investors, two methods are compared: (1) the conventional point-source method and (2) the proposed bottleneck method, which considers all emissions that a facility enables rather than only what it emits. Results indicate that the top ten CO₂ emission bottlenecks in the U.S. …

The Influence Of The Reference Area Of Aileron On The N2xx Aircraft Using Computational Fluid Dynamics, Siti Nur Rahmah, Gaguk Jatisukamto, Hary Sutjahjono

Journal of Mechanical Engineering Science and Technology (JMEST)

Aileron is a control surface that functions as a regulator of roll motion. The movements of the ailerons are opposite to the left and right sides. Previous studies have shown that graphs of hinge moment coefficient (Chm) values increases with increasing angle of attack. This study is to determine the aerodynamic characteristics of aileron by combining the surface area of the vane into the aileron by varying the aileron’s deflection. The calculation is performed using a numerical method in two dimensions (2D) commercial CFD simulation software. The results of the study concluded that the hinge moment coefficient for modified airfoil …

Physical Behavior Of Thermally Affected Bronze And Brass, Samiul Kaiser, Mohammad Salim Kaiser

Journal of Mechanical Engineering Science and Technology (JMEST)

The physical behavior of thermally affected cast copper, aluminum bronze and brass has been studied by subjecting to heating isochronally for one hour at a range of 600°C. It shows that solid-solution hardening takes place into the Al added bronze and Zn added brass metal. Due to heating Al forms hard and brittle intermetallic of copper aluminates into the bronze metal which responses some age-hardening effects. The electrical conductivity of the metals increases initially through heat treatment due to stress relieving and finally decreases due to formation of intermetallic precipitates. The color of the heated samples are also studied through …

Performance Enhancement Of Shell And Tube Heat Exchanger On Parallel Flow With Single Segmental Baffle, Avita Ayu Permanasari, Poppy Puspitasari, Sukarni Sukarni, Retno Wulandari

Journal of Mechanical Engineering Science and Technology (JMEST)

The shell and tube heat exchanger was a tool to exchange the heat energy between fluids with different temperatures that occurred through direct or indirect contact. The energy exchange in fluids could be occurred with the same phase (liquid to liquid or gas to gas) or two fluids with different phase. To date, the process of heat transfer in the industrial field was crucial in machine work. Therefore, there were studies directed to optimize and develop the function and thermal performance of a heat exchanger by adding Baffles to the side of the shell. Vortex flow that occurs with the …

Hardness Evaluation On Ss 316l Joined With Gas Tungsten Arc Welding Under Constant Heat Treatment, Duwi Leksono, Imam Sudjono

Journal of Mechanical Engineering Science and Technology (JMEST)

The purpose of this study is to show the hardness of the GTAW welding results on SS 316L metal with surface heating during the welding process. Observations in this study used SS 316L material with heat temperature regulation on the metal surface of the welding process using heating variations of 100 ℃, 120 ℃ and 140 ℃. The welding process of SS 316L material used a welding joint model uses single V-type welding joint with an angle of 60°, a spacing of 2 mm, a root surface of 1 mm and a thickness of 5 mm. Vickers hardness test was …

The Effect Of Solution Treatment Temperature And Quenching Media Variation In Heat Treatment Process Cu-Zn-Al Shape Memory Alloys On Shape Memory Effect And Microstructures, Wikan Jatimurti, Monica Gayatri K, Mavindra Ramadhani, Rochman Rochiem

Journal of Mechanical Engineering Science and Technology (JMEST)

Shape memory alloys (SMAs) are metal alloys with a reversible ability to recover their shape at a certain temperature after being deformed. This ability referred to as Shape Memory Effect (SME). The application of SMAs such as Ni-Ti and Cu-Zn-Al alloys usually used on automotive, biomedical, etc. The commonly used SMA is Ni-Ti because of its superior SME properties than Cu-Zn-Al, even though the price is quite higher. The SME of Cu-Zn-Al might be improved by increasing the presence of the martensite phase in its microstructure by heat treatment. The heat treatment process given to Cu-21Zn-5Al alloy is a homogenizing, …

The Effect Of Heat Treatment To The Erosion Rate Of Brass Composite, Aminnudin Aminnudin, Solichin Solichin

Journal of Mechanical Engineering Science and Technology (JMEST)

Brass composites can be improved their mechanical properties by the heat treatment process. The improvement of the mechanical properties of this technique is expected to increase the resistance of the composite to erosion that occurs in the environment of flow water. Brass composites used are compositeswith fly ash 5, 10, 15, and 20%. The heat treatment process was carried out using electric furnace withoutprotective gas. Composite heat up to 350°C and 400°C for 30 min. and quenching with water. Before and after the erosion test, the weight of the test specimen was weighed with analytical scales. The treatment process affects …

Wavelength Decomposition Of Hybrid Additive Manufacturing Power Signals And Their Relationship With Surface Integrity, Xingtao Wang

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Additive Manufacturing (AM) has been a promising manufacturing technology in industrial applications and gained a massive amount of attention from researchers all over the world. Directed Energy Deposition (DED) is an AM process in which focused thermal energy is used to fuse materials by melting as they are deposited. One of the most significant challenges involved in current metal AM processes is improving repeatability and consistency. Substantial effort has already been invested in this area of research.

In this dissertation, a milling tool not only played a role in subtractive manufacturing but also acted as a method of monitoring the …

Protein And Polysaccharide-Based Fiber Materials Generated From Ionic Liquids: A Review., Christopher R Gough, Ashley Rivera-Galletti, Darrel A Cowan, David Salas-De La Cruz, Xiao Hu

College of Science & Mathematics Departmental Research

Natural biomacromolecules such as structural proteins and polysaccharides are composed of the basic building blocks of life: amino acids and carbohydrates. Understanding their molecular structure, self-assembly and interaction in solvents such as ionic liquids (ILs) is critical for unleashing a flora of new materials, revolutionizing the way we fabricate multi-structural and multi-functional systems with tunable physicochemical properties. Ionic liquids are superior to organic solvents because they do not produce unwanted by-products and are considered green substitutes because of their reusability. In addition, they will significantly improve the miscibility of biopolymers with other materials while maintaining the mechanical properties of the …

Methods Of Uncertainty Quantification For Physical Parameters, Kellin Rumsey

Mathematics & Statistics ETDs

Uncertainty Quantification (UQ) is an umbrella term referring to a broad class of methods which typically involve the combination of computational modeling, experimental data and expert knowledge to study a physical system. A parameter, in the usual statistical sense, is said to be physical if it has a meaningful interpretation with respect to the physical system. Physical parameters can be viewed as inherent properties of a physical process and have a corresponding true value. Statistical inference for physical parameters is a challenging problem in UQ due to the inadequacy of the computer model. In this thesis, we provide a comprehensive …

Nanohybrid Membrane Synthesis With Phosphorene Nanoparticles: A Study Of The Addition, Stability And Toxicity, Joyner Eke, Philip Alexander Mills, Jacob Ryan Page, Garrison P. Wright, Olga V. Tsyusko, Isabel C. Escobar

Center of Membrane Sciences Faculty Publications

Phosphorene is a promising candidate as a membrane material additive because of its inherent photocatalytic properties and electrical conductance which can help reduce fouling and improve membrane properties. The main objective of this study was to characterize structural and morphologic changes arising from the addition of phosphorene to polymeric membranes. Here, phosphorene was physically incorporated into a blend of polysulfone (PSf) and sulfonated poly ether ether ketone (SPEEK) doping solution. Protein and dye rejection studies were carried out to determine the permeability and selectivity of the membranes. Since loss of material additives during filtration processes is a challenge, the stability …

Synthesis, Self-Assembly And High-Pressure Properties Of Nanoparticles And Hybrid Nanocomposites, Lingyao Meng

Nanoscience and Microsystems ETDs

Nanoparticles have gained significant scientific interests owing to their unique structural dimensions, size- and shape-tunable properties, and numerous fascinating applications, from opto-electronics, sensor devices, to energy, environmental, and medical fields. Furthermore, the synergistic integration of other materials, including organic polymers, with nanoparticles provides new opportunities and strategies to obtain nanocomposites with superior properties and functionalities. While there is already significant research on the synthesis and characterizations of nanoparticles and hybrid nanocomposites, some research questions, such as how to design and control the interfacial morphology in polymer/nanoparticle hybrid nanocomposites, how to synthesize metal- organic framework (MOF) nanoparticles in well-defined and uniform …

High‐Tensile Strength, Composite Bijels Through Microfluidic Twisting, S. P. Kharal, Robert P. Hesketh, Martin F. Haase

Henry M. Rowan College of Engineering Departmental Research

Rope making is a millennia old technique to collectively assemble numerous weak filaments into flexible and high tensile strength bundles. However, delicate soft matter fibers lack the robustness to be twisted into bundles by means of mechanical rope making tools. Here, weak microfibers with tensile strengths of a few kilopascals are combined into ropes via microfluidic twisting. This is demonstrated for recently introduced fibers made of bicontinuous interfacially jammed emulsion gels (bijels). Bijels show promising applications in use as membranes, microreactors, energy and healthcare materials, but their low tensile strength make reinforcement strategies imperative. Hydrodynamic twisting allows to produce continuous …

Tacky Elastomers To Enable Tear-Resistant And Autonomous Self-Healing Semiconductor Composites, Song Zhang, Yu-Hsuan Cheng, Luke Galuska, Anirban Roy, Matthias Lorenz, Beibei Chen, Shaochuan Luo, Yen-Ting Li, Chih-Chien Hung, Zhiyuan Qian, Peter Blake Joseph St. Onge, Gage T. Mason, Lewis Cowen, Dongshan Zhou, Sergei I. Nazarenko, Robson F. Storey, Bob C. Schroeder, Simon Rondeau-Gagné, Yu-Cheng Chiu, Xiaodan Gu

Faculty Publications

Mechanical failure of π-conjugated polymer thin films is unavoidable under cyclic loading conditions, due to intrinsic defects and poor resistance to crack propagation. Here, the first tear-resistant and room-temperature self-healable semiconducting composite is presented, consisting of conjugated polymers and butyl rubber elastomers. This new composite displays both a record-low elastic modulus (

A Spatially Distributed Fiber-Optic Temperature Sensor For Applications In The Steel Industry, Muhammad Roman, Damilola Balogun, Yiyang Zuang, Rex E. Gerald Ii, Laura Bartlett, Ronald J. O'Malley, Jie Huang

Materials Science and Engineering Faculty Research & Creative Works

This paper presents a spatially distributed fiber-optic sensor system designed for demanding applications, like temperature measurements in the steel industry. The sensor system employed optical frequency domain reflectometry (OFDR) to interrogate Rayleigh backscattering signals in single-mode optical fibers. Temperature measurements employing the OFDR system were compared with conventional thermocouple measurements, accentuating the spatially distributed sensing capability of the fiber-optic system. Experiments were designed and conducted to test the spatial thermal mapping capability of the fiber-optic temperature measurement system. Experimental simulations provided evidence that the optical fiber system could resolve closely spaced temperature features, due to the high spatial resolution and …

Synthesis Of Carbide Ceramics Via Reduction And Carburization Of Oxyanions Adsorbed Onto An Activated Carbon Matrix, Grant Wallace

Graduate Theses & Non-Theses

Carbide ceramics rank high among the hardest and most chemically resistant materials. Their ability to resist physical and chemical attack under conditions where more traditional materials fail make them very desirable for a number of industrial applications. Their use is limited, however, due to the expensive and energy-intensive methods required to produce them commercially.

A more versatile and energy-efficient process for commercial carbide production has been developed by synthesizing micron/sub-micron carbide ceramic particles through the adsorption and subsequent carburization of anions on an activated carbon matrix. Oxyanion solutions containing sodium tungstate, sodium molybdate, or sodium metasilicate are adsorbed onto activated …