Engineering Commons^™

Defect Structure, Nonstoichiometry, And Phase Stability Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, M. M. Nasrallah, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

The dependence of the defect structure of Ca-doped YCrO₃ on oxygen activity and temperature was investigated by high temperature thermogravimetric measurements. Defect models developed from electrical conductivity data obtained in a previous study were used to interpret the thermogravimetric data. A correlation was found between the electrical conductivity and the thermogravimetric data which suggested that these data were concomitantly dependent on the acceptor dopant and oxygen vacancy dependance of the thermodynamic parameters. Kröger-Vink type diagrams showing the regions of stability with respect to oxygen activity and temperature were constructed. The TGA data show that Ca-doped YCrO₃ is even …

Effects Of Sample Orientation On The Corrosion Of Zinc In Ammonium Sulfate And Sodium Hydroxide Solutions, D. Abayarathna, Edward Boyd Hale, Thomas J. O'Keefe, Y. M. Wang, D. Radovic

Physics Faculty Research & Creative Works

The corrosion and electrochemical properties of three zinc single crystal surfaces with different orientations have been investigated. In near-neutral 1 M (NH₄)₂SO₄, the corrosion rates on all three surfaces were found to be similar. However, the SEM morphologies of the corresponding corroded surfaces were markedly different from each other, but consistent with preferential attack of {1120} surfaces. In alkaline 0.5 N NaOH solution, the three sample orientations showed significantly different reactivities, with the (1120) surface exhibiting the highest reactivity and corrosion rate. Here, passivation ultimately occurred and the difference in the corrosion performance of …

Properties Of Glass Fabric Reinforced Silicone Glazing For Solar Applications In Rural Areas, Mohammed A Ahmed Dabbour

Archived Theses and Dissertations

No abstract provided.

Positron Study Of Defects And Diffusion Induced Grain Boundary Migration In A Pb-Sn System, A. Belaidi, Hollis P. Leighly, H. Aourag, B. Khelifa, M. Oubadi, A. Elias

Materials Science and Engineering Faculty Research & Creative Works

The Pb-Sn system discloses a remarkable effect at the intermediate α → α + β phase boundary. The observation of the sharp transient peak in the S-parameter curve which is analogous to those found in thermal capacity curves is, as far as the authors are aware, unique in such positron measurements. This effect is interpreted in terms of positron trapping in defects associated with the strains accompanying the initial stage of transformation. This short note offers a new approach to the underlying phenomenon published in J. Phys. F. Met. Phys., 12 (1982) 813 by A. Belaidi, H. P. Leighly Jr. …

Compensation Modes In Counterdoped Rutile, M. M. Nasrallah, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

Thermogravimetric measurements were conducted on undoped, Nb⁵⁺ or Ta⁵⁺ donor-doped, and Al³⁺ acceptor doped rutile at 1000°C and 105-10-7 Pa oxygen activity. Nb⁵⁺ or Ta⁵⁺ doped rutile was counter doped by Al³⁺ in order to identify the role of Al³⁺ acceptor and its effect on donor doped rutile. Our results show that both dopants enter the lattice substitutionally for Ti⁴⁺, that Al³⁺ is as effective an acceptor as Nb⁵⁺ or that Ta⁵⁺ is effective as a donor, and the compensation occurs on a one-to-one basis. Earlier reports indicate …

Electrical Conductivity, Seebeck Coefficient And Defect Chemistry Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, Don M. Sparlin, M. M. Nasrallah

Materials Science and Engineering Faculty Research & Creative Works

The electrical transport behavior and defect structure of Ca-doped YCrO₃ were studied using electrical conductivity and Seebeck coefficient measurements as a function of oxygen activity and temperature. Defect models derived from the electrical conductivity data were found to adequately relate the concentration of charge carriers to the acceptor dopant and oxygen vacancy concentrations. Thermodynamic properties were calculated and found to be consistent with the model. Activation energy and carrier mobility data were also obtained. The analysis of the electrical conductivity, Seebeck and mobility data suggest that the conduction process in Ca-doped YCrO₃ occurs via the small polaron hopping …

Synthesis And Characterization Of Barium Lanthanum Titanates, Jyoti P. Guha

Materials Science and Engineering Faculty Research & Creative Works

Ternary compounds in the system BaO—TiO₂—La₂O₃ were prepared by the solid‐state reaction technique at temperatures between 1300° and 1400°C using precursor oxides as the starting materials. In an alternative processing technique, BaTiO₃ was reacted with appropriate proportions of prefabricated lanthanum titanates at 1350°C to obtain the compounds. Two compounds were identified in the TiO₂‐rich region of the system. The X‐ray powder diffraction pattern of a compound with a chemical composition BaLa₂Ti₃O₁₀ (BaO·La₂O₃·3TiO₂) is indexed on the basis of an orthorhombic unit …

In-Situ Film Thickness Measurements For Real-Time Monitoring And Control Of Advanced Photoresist Track Coating Systems, Richard N. Savage, Thomas E. Metz, Horace O. Simmons

Materials Engineering

This paper explores the methodologies of real-time measurement of photoresist film thickness on silicon wafers using multi-wavelength reflection interferometry. Reflected light from the wafer's surface, containing the interference profile, is collected in-situ via a fiber optic cable and film thickness is determined in real-time via a pattern recognition algorithm. The instrumentation used to make this measurement and its application toward optimizing track performance during spin-coating and back are discussed. Data demonstrating basic thickness versus spin-time and thickness versus bake-time profiles acquired on-line without process disruption are presented along with its utilization toward minimizing process set-up and machine qualification. Moreover, the …

Surface Treatment Of Cast Iron By Adding Different Alloying Elements To Form Metallic Glass Structure Layer Using An Industrial Carbon Dioxide Laser, Mohammad Riahi

Dissertations and Theses @ UNI

Wear and corrosion are the two factors that make utilization of metals very costly. Extraordinary amount of time and money is spent to replace metallic parts affected by either wear or corrosion. Cast iron that is used very widely in a host of different industrial products is one such metal. Among the various methods used to improve the properties of metals, production of amorphous metals is highly noticeable. This process is done by treating the base metal in a certain technique which produces a metal that is more resistant to wear and corrosion.

This study was conducted to examine the …

An Analysis Of Reinforced Concrete Composites Utilizing Recycled Polyethylene Terephthalate Thermoplastic, Jaroslav V. Vaverka

Dissertations and Theses @ UNI

Removing plastic from landfills does not solve the solid waste problem entirely. Plastic products are difficult to recycle because, unlike aluminum or glass, the plastics used in food packaging cannot be reused for the same purpose. Among the commonly used plastic resins, polyethylene terephthalate (PET) has been widely adopted by the packaging industry. This research study was concerned with recycling of PET thermoplastic in concrete as a way to reduce the volume of solid waste.

Current surveys of recycling efforts reveal that existing PET recycling approaches have become inadequate. Solid waste management is stressing the eminent need for new recycling …

Micromechanics Of Granular Materials And Its Relation To Wave Velocity, Tarun K. Agarwal

Civil & Environmental Engineering Theses & Dissertations

The macro characters of the granular materials depend upon micromechanical parameters such as the void ratio, particle shape, contact force distribution, and initial state of the fabric of the assembly. Since it is difficult to evaluate these internal parameters from laboratory experiments, a macro measure is desired which depends directly on these internal parameters. One such measure has been shown to be dynamic shear modulus but it was incomplete in predicting directional changes in the internal parameters. Therefore, it is hypothesized here that the complete elastic moduli matrix will have more direct information about the internal parameters, especially the dynamic …

In-Line Photoresist Thickness Monitor, Richard N. Savage, Tom W. Batchelder, Kenneth M. Sautter, Gary H. Memovich

Materials Engineering

An in-line photoresist thickness measuring device wherein a plurality of projection optical fibers are disposed over a wafer processing track for illuminating portions of a wafer as the wafer proceeds along the track. The light scattered back from each illuminated portion is detected by a corresponding plurality of pickup optical fibers and communicated to an optical fiber multiplexer. The multiplexer sequentially selects the optical signal from each pickup optical fiber and communicates the light from the selected pickup optical fiber to a spectrometer. The spectrometer simultaneously diffuses the scattered light into a plurality of light bands, each light band having …

Method Of Processing Superconducting Materials And Its Products, Kenji Okazaki, Robert J. De Angelis, Charles E. Hamrin Jr.

Chemical and Materials Engineering Faculty Patents

A method for fabricating relatively dense monoliths of superconducting material and relatively dense composite monoliths of superconducting material and binder material. The method includes the steps of placing the material to be processed in a die. A relatively high pressure is then applied to the material. Substantially simultaneously, an electrical discharge is applied to the material. The discharge is of a relatively high voltage and current density to provide sharp bonding while maintaining the superconducting properties of the material in the monolith product. A product fabricated by the present method is also described.

Technological Upgradation Policies Of The Steel Industry And Impact Of The Steel Industry In The Indian Economy, K K Saxena, Binayak Rath

IIMB Management Review

In India, the iron and steel industry in general occupies an important Position among the manufacturing industries. The priorities attached to this sector can be explained from the Second Five Year Plan document which mentioned that the expansion of iron and steel industry has obviously the highest priority than other industries because the tempo of progress of the economy. Hence, Second Plan onwards the industry has made a rapid stride in our economy. A number of Integrated Steel Plants (ISPs) in the public sector have been set up to boost up production. Today these ISPs contribute a significant portion of …

Low Temperature Photoluminescence Study Of Holmium And Thulium Implanted Into Iii-V Semiconductors And Silicon, Eric Silkowski

Theses and Dissertations

Low temperature photoluminescence studies were performed on holmium implanted into InP, GaAs, and Si; and thulium implanted into AlGaAs, GaAs, and Si. Samples were annealed by the conventional furnace and rapid thermal techniques. None of the characteristic 4f emissions of holmium were found in the spectral region of .73 to 1.55 eV. AlGaAs:Tm showed strong thulium emissions in the .93 to 1.03 eV region. These emissions were studied and compared to those in GaAs:Tm. Low and high temperature annealed samples showed evidence of trivalent Tm centers. Temperature dependence studies showed that thulium 4f emissions were present above 200 K but …

Dendrite Tip Radii In Directionally Solidified Pb-8.4-Atmospheric-Percent-Au, Surendra N. Tewari

Chemical & Biomedical Engineering Faculty Publications

The cell/dendrite tip radii in directionally solidified Pb-8.4at.%Au have been investigated as a function of the growth speed and thermal gradient in the liquid at the tip. Dendrite growth models are not able to predict quantitatively the tip radii and tip compositions separately because of the occurrence of thermosolutal convection during growth. However, the relationship between the destabilizing solutal gradient, the stabilizing thermal gradient and the capillarity at the tip assumed using the ''marginal stability'' criterion is supported by the experimental data.

Feasibility Of Incorporation Of By-Pass Dust In Clay Bricks, Amr Aly Gamal El-Din

Archived Theses and Dissertations

No abstract provided.

Angle Of Arrival Detection Through Artificial Neural Network Analysis Of Optical Fiber Intensity Patterns, Scott Thomas

Theses and Dissertations

The optical sensors of United States Air Force reconnaissance vehicles, such as satellites, are subject to temporary or permanent blinding from hostile (or threat) laser radiation. By detecting and determining the angle of arrival (AOA) of the hostile radiation, the reconnaissance vehicle may be able to protect its optical sensors by taking evasive maneuvers or by shutting down the optical sensor (such as closing a shutter) until the threat has passed. In addition, the vehicle can relay information to its ground terminal allowing the intelligence community to determine the source of the hostile laser radiation. This thesis demonstrated that an …

Fluorescent Lifetime Measurements Of Rare Earth Elements In Gallium Arsenide, Danny J. Topp

Theses and Dissertations

Lifetime measurements of the excited states of three GaAs semiconductors doped with the rare earth elements Erbium (ER), Praseodymium (Pr) , and Thulium (Tm) has been studied using a pulsed nitrogen laser and germanium detector. The measurements were made with an experimental set up with a system response time of 0.34 micro seconds. A 330 milliwatt nitrogen laser with a wavelength of 3370 angstrums was used to excite transitions of the rare earth elements.

Characterization Of Barium Titanate As An Optical Amplifier, George A. Vogel

Theses and Dissertations

The introduction of two-beam coupling in photorefractive materials has resulted in an extensive amount of research into their use as optical processing/computing elements. This dissertation develops the theoretical equations for two-beam coupling in barium titanate as an optical amplifier. One of the factors which limits the optical gain in photorefractive crystals is the loss of pump beam power to the amplification of parasitic light (beam fanning). This parasitic light is produced by light scattered from the pump beam by imperfections on both the crystal face and within the crystal. Through the analysis of signal and noise amplification as functions of …

Investigation Of Damage Mechanisms In A Cross-Ply Metal Matrix Composite Under Thermo-Mechanical Loading, Joel J. Schubbe

Theses and Dissertations

Metal matrix composites (MMCs) are rapidly becoming strong candidates for high temperature and high stiffness structural applications such as the Advanced Tactical Fighter (ATF). This study systematically investigated the failure modes and associated damage in a cross-ply, [0/90]_2s SCS6/Ti-15-3 metal matrix composite under in-phase and out-of-phase thermomechanic fatigue. Initiation and progression of fatigue damage were recorded and correlated to changes in Young's Modulus of the composite material. Experimental results show an internal stabilization of reaction zone size but degradation and separation from constituent materials under extended cyclic thermal loading. Critical to damage were transverse cracks initiating in the 90° …

Fracture Toughening Of High Pressure Sintered Diamond And Carbide Ceramics, P. D. Ownby

Materials Science and Engineering Faculty Research & Creative Works

High pressure sintered bodies of polycrystalline diamond or carbide ceramics are rendered more resistant to cracking by establishing dispersed, localized "stress centers" of submicron size particles of lonsdaleite, diamond, or other form of metastable, high density carbon which has the capability of transforming crystallographically to graphite in situ in the body. When an incipient crack in the body approaches entrapped metastable particles along its path, the crack promotes or permits transformation of the metastable particles to graphite particles, with concomitant increase in their size, thereby resisting further propagation of the crack.

Analysis Of The Static And Dynamic Stability Of Elastic Structures Using The Finite Element Method, Mohamed Hassan Gadallah

Archived Theses and Dissertations

No abstract provided.

Optical And High Electric Field Effects In Bulk Gallium Arsenide Switches, Randy Roush

Electrical & Computer Engineering Theses & Dissertations

During the past few years, bulk, photoconductive switching has become recognized as a viable topic for future research on moderate and high power switches. The two-pulse, or BOSS, concept relies on an excitation laser pulse, and a separate de-excitation pulse in conjunction with silicon doped, copper compensated, GaAs to create a variable temporal electrical pulse width. The research contained in this document provides information concerning the feasibility of the BOSS concept, as the switch is scaled to larger sizes, and higher voltage and current. The major concern will be the high voltage and current effects. The absorption length for 1064 …

Real-Time, In-Situ Measurement Of Film Thickness And Uniformity During Plasma Ashing Of Photoresist, Richard N. Savage, Horace Simmons, John T. Davies, Thomas Metz

Materials Engineering

This paper will discuss the performance of equipment which monitors and so controls photoresist thickness and uniformity during plasma ashing without interfering with the process. Practical monitoring of a subtractive process of this type is significantly more complex than monitoring deposition processes. An initial absolute thickness measurement is needed. In addition the device must view the layer through a luminous medium and cannot rely on simple optical interference fringe counting. The equipment is self-calibrating and sensitive to layers dnm thick. An application to partial plasma resist ashing in high uniformity equipment will be described. Application to other films (e. g. …

Method For Fabricating Or Modifying An Article Comprising The Removal Of A Polymer Coating, Bonnie Bachman, Elizabeth A. Hofstatter, Joan M. Ritter, Jerry J. Rubin

Economics Faculty Research & Creative Works

Disclosed is a method for removing poly-para-xylylene, its derivatives, and copolymers (collectively called "parylene") from bodies, including relatively large bodies such as printed circuit (PC) boards, that is capable of yielding relatively high removal rates. A body such as a PC board coated with parylene is placed into a reaction chamber downstream from a microwave plasma such that plasma discharge products generated by the microwave plasma react with the parylene, etching the parylene without exposing the body to bombardment by energetic ions and/or electrons. The plasma is generated from a gas mixture containing oxygen, a second gas, and optional additives …

Recent Applications Of Glass Science, Norbert J. Kreidl

Materials Science and Engineering Faculty Research & Creative Works

Recent, often exciting, applications of glass science include solid state batteries, electronic switches and memories, electrophotography, solar cells, microspheres for optical strengthening and medical uses, novel glass ceramics such as machinable and bioactive materials, solder glasses, composites, sol-gel glasses, gradient index optics, communication fibers, sensors, non-linear and active optics, and, perhaps, digital optics. The large field of special coatings is not covered in this review. © 1990.

Condensed Silica Fume Concrete, Mohamed Nagib Abou Zaid

Archived Theses and Dissertations

No abstract provided.

32nd Rocky Mountain Conference

Rocky Mountain Conference on Magnetic Resonance

Program and registration information for the 32nd annual meeting of the Rocky Mountain Conference, co-sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy and the Rocky Mountain Chromatography Discussion Group. Held in Denver, Colorado, July 29 - August 3, 1990.

Optical Switch, Richard N. Savage

Materials Engineering

An optical switch for transmitting light between a first location and a selected one of a plurality of second locations. The switch includes a mirror having a concave, reflective surface and an axis. The switch also includes a plurality of fiber optic cables, one of which is disposed at the first location and the remainder of which are disposed at the second locations, each cable having a light transmission face at their respective locations. The light transmission face at the first location is substantially parallel to the focal plane of the mirror. The light transmission face at each of the …