Engineering Commons^™

A New Method For Preparing Self-Assembled Lipid Bilayers On Pt Electrode, Peng Diao, Dian-Lu Jiang, Xiao-Li Cui, Deng-Ping Gu, Ru-Ting Tong

Journal of Electrochemistry

A new method for preparing Pt-supported bilayer lipid membrane (Pt-BLM) on Pt electrode cleaned by high power ultrasound was reported. The reported method was convenient, costing less platinum and could be used to form large-area Pt-BLM as compared with the traditional Pt-wire-cutting method. The electrical properties of Pt-BLM were studied using electrochemical impedance spectroscopy and cyclic voltammetry. Experimental results showed that the values of membrane capacitance and the voltammetric characteristics were consistent with those of Pt-BLM prepared by traditional method.

Direct Electrolysis Of Seawater On Conducting Film For Microbial Anticorrosion 1. Simulation And Measurement Technique, Wei-Ling Hu, Ling-Ling Wu, Jing Zhou, Jing-Xin Li, Jin Luo, Zhong-Hua Lin

Journal of Electrochemistry

Based on the electrochemical micro probe and the weak signal detection technique, simulated test and measurement system were set up by the use of four-electrode cell(including a micro electrode), bipotentiostat, lock-in amplifier and three-dimensional micro manipulating device. Based on the system, the micrometer scale concentration distribution of trace hypochlorite, which is produced by direct electrolysis of seawater on the conducting film for preventing microbial corrosion has been obtained for the first time. Both relationships between concentration of hypochlorite and its reduction current, which is termed an working curve, and between the reduction current of hypochlorite and measured time are reported.

A Study Of The Corrosion On Bronze, Hong-Fan Zhu, Hao Zhou

Journal of Electrochemistry

The bronze is the treasure in chinese metallic antique, which was typified by product in Shang-Zhou period (three thousands years ago). Because of corrosion, archaeological messages, such as inscription and pattern on the surface of bronze, would be damaged then the value of bronze antique decreased. The bronze disease is a common disease which forms powdery rust on the surface of bronze in atmospheric environment, the powdery rust emerge from under incrusted rust, then spreads, and eventually leads to bronze damaged. This paper investigates the bronze disease. According to the chemical and electrochemical tests in simulated occluded cell, the variation …

Electrochemical Synthesis Of Fes Electrode And Its Behavior Measurement, Cong-Sheng Guan

Journal of Electrochemistry

The Potential for the electrochemical synthesis of FeS electrode has been obtained by cyclic voltammetry. FeS electrodes were synthesiaed by controlling Fe electrode at -1.0 V in LiCl-KCl-Li₂S and Li(FClI)-Li₂S melts and their behavior were measured also. The FeS electrode synthesized in molten Li(FClI)-Li₂S has the best charge and discharge properties.

Deactivation Of Nickel Oxide/Hydroxide To Electrooxidation Of H2Po2 Anions On Nickel Electrodes In Alkaline Solutions, Tai-Xiang Jiang, Hui-Huang Wu

Journal of Electrochemistry

Electrooxidation of hypophosphite anions on polycrystalline nickel in alkaline solutions has been investigated by cyclic voltammetry and open circuit potential measurements. The results are explained based on the mechanism that the first step of hypophosphite oxidation is the adsorption of hypophosphite ions on nickel, followed by the homolysis of its hydrogen bond with the formation of radicals. The oxidation of hypophosphite on nickel in alkaline medium occurs at lower potentials between ca. -0.8 V— -1.1 V (SCE) and phosphite ion is the only oxidation product. There is no indication of hypophosphite oxidation at higher potentials. Severe deactivation of the surface …

Structural And Electrochemical Studies On Lithium Manganese Oxide Containing Li+ Prepared By Hydrothermal Method For Lithium Ion Batteries, De-Yao Liu, Jin-Kua You, Wei Chu, Yong Yang, Zu-Geng Lin

Journal of Electrochemistry

In this paper, Todorokite manganese oxides containing Li⁺ with large tunnel structure (sample M5) have been synthesized by hydrothermal methods from natural manganese oxide nano fiber (sample M4). The structure and composition of the samples were characterized and analyzed by XRD, ICP, TGA and DTA. Its electrochemical behavior as a cathode materials for rechargeable lithium ion insertion were studied by galvanostatic charge/discharge measurements. XRD results show that the sample M4 is mainly composed of Birnessite and Vernadite structure. Although the sample M4 shows a high initial capacity of approximately 150 mAh/g, its performances decrease gradually over 30 cycles. It …

The Techniques Of The Paired Electrosynthesis, Hong-Kun Zhang, Deng-Ping Gu

Journal of Electrochemistry

In this Paper, we introduce our work on paired electrosynthesis. In conjunction with our research practice, we introduce electrolytic conditions,such as material of electrode ,courrent density and electrolytic temperature etc,as reference for researcher. We categorize the paired electrosynthesis techniques to widen our view on the paired electroorganic synthesis and to promote the deveopments of paired electrosynthesis techniques.

A Study Self-Passivation Of Passivie Film Of Stainless Steel In Vinylon Aldehyde Solution, Si-Fu Hu, Chuan-Bi Xu, Zhu-Qiu Cheng

Journal of Electrochemistry

Properties of self-passivation for the anodic passive film of 1Cr18Ni9Ti and the firsthand passive film of SUS 36 stainless steel in vinylon aldehyde solution(H₂SO₄(240 g/L)+Na₂SO₄(70 g/L)+HCHO(25 g/L)+[Fe³⁺](35.4 mg/L)+[Cl^-](240 mg/L) at 70 ℃ were studied by galvanostatic and potentiostatic polarization mesurements. The effects of compponents of vinylon aldehyde solution, i.e. Fe³⁺ and Cl^-, on the passivation behaviours of stainless steel have also been investigated. The experimental results showed there is a conversion zone of the active/passive state if the area ratio of active/passive state on these …

Influence Of Thiourea And Its Derivate On The Process Of Cathodic Electrodeposition Of Copper, Yun-Hui Dong, Ai-Hong Zou, Yun-Xia Zhao

Journal of Electrochemistry

The effects of thiourea and its derivate on the electrodeposition of copper from the dilute acid sulphate solutions have been studied by using potential sweep techniques at quasisteady state. Limiting current densities (I_d), exchange current densities (i₀) and α_n are obtained by data processing with the least square method. Thiourea has a depolarizing effect on the copper depositing at concentrations below 8 mg·L^-1, and a polarizing effect at higher concentration (>10 mg·L^-1), and it changes the mechanism of copper deposition reaction. Propenyltiourea and Phenylthiourea have a depolarizing effect on the …

Study On Synthesizing Of 2-Methylbutanoic Acid By Indirect Electrooxidation, Chong-Tao Zhao, Ze-Shan Zhu

Journal of Electrochemistry

The working conditions of synthesizing 2-methylbutanoic acid by oxidizing 2-methyl-1-butanol with tetrabutylammonium hydrosulfate (TBAS) or tetrabutylammonium perchlorate (TBAP) as phase transfer catalyst in sulfuric acid Cr(Ⅵ) oxidation medium was studied. The Cr(Ⅵ) oxidation medium could be electrolytic regenerated from Cr(Ⅲ), during above oxidation reaction. Under the optinum condition, the yield of 2-methylbutanoic acid is more than 95%.

The Ac-Impedance Analysis For Pluse Oxide Film Of Aluminium Alloy, Ai-Ling Du, Xi-Cheng Ma, He-Ming Zhang

Journal of Electrochemistry

Bode diagrams for aluminum PC (abbreviated from pulse current) oxide films were first obtained by AC-impedance measurements in a wide range of frequency. The experimental results show that different kinds of electrical equivalent circuits can be used for representing PC films and DC (abbreviated from direct current) oxide films separately, the main differences between them are their porous layers, the PC films are more even with little defects.Those are also verified by SEM and V-I characteristic curve measurements.

Calculation Of Corrosion Rate Of Passive Metals With Charge Curve Analysis Technique, Yuan-Sheng Zhang, Min Gong

Journal of Electrochemistry

This work contains two parts: (1) A charge curve equation having no appro-ximation for passivated metal corrosion systems is derived and compared with the routine charge curve equation, which is virtual only when the polarization is minim(linear range). (2) It is simpler to analyze charge curve data by from of charge differential equation than from charge curve equation. After the charge curve data are measured, the slope of charge curve is computed by numerical differentiation method, then the charge differential equation may be transformed to a set of linear equations using polynomial approximation. The electrochemical parameters of corrosion system would …

The Effects Of Metallic Cobalt Abbition On The Performance Of Pasted Nickel Electrodes, An-Bao Yuan, Jian-Qing Zhang, Wan-Chun Ding, Shao-An Cheng, Chu-Nan Cao

Journal of Electrochemistry

The Ni-foam pasted nickel electrodes prepared by coprecipitated Ni_1-XZn_X(OH)₂ with and without cobalt power addition have been studied. The electrode with addition of metallic cobalt showed a higher performance both in discharge capacity and cycle life. It is known from the experiment results that the addition of Co can remarkably increase the active material utilization which is suggested to be improvement of discharge depth due to the conducting CoOOH formed in the first activation charging. The superior capacity during cycling could be attributed to the synergistic action of zinc and cobalt addition ,especially to the …

Electrodeposition Of Cerium-Based Coatings For Corrosion Protection Of Aluminum Alloys, James O. Stoffer, Thomas J. O'Keefe, Xuan Lin, Eric L. Morris, Pu Yu, Srinivas Pravin Sitaram

Chemistry Faculty Research & Creative Works

A process for enhancing the corrosion resistance of an aluminum-containing component with a cerium based coating. An aluminum-containing cathode and an oxygen- evolving anode are immersed in an electrolyte comprising water, solvent, oxidizing agent and cerium ions. An electrical current is passed through the electrolyte by applying electrical current to deposit a cerium based coating onto the cathode. An electrolyte for use in depositing a cerium based coating. An electrodeposited cerium-based coating. An aluminum aircraft structural component having a cerium-based coating thereon.

Models For Magnetoresistance In Tunnel Junctions, Shi C. Zhang, P. M. Levy

Materials Science and Engineering Faculty Research & Creative Works

We show there are putative pitfalls when one predicts the magnetoresistance of magnetic tunnel junctions (JMR) based on different toy models. Amongst them are the sensitivity of the MR to the details of the profile of the potential barrier between the metallic electrodes and the insulating barrier, and the common assumption of only one band of electrons. We indicate the ingredients that are necessary to obtain a more complete description of the JMR of magnetic tunnel junctions.

41st Rocky Mountain Conference On Analytical Chemistry

Rocky Mountain Conference on Magnetic Resonance

Final program, abstracts, and information about the 41st annual meeting of the Rocky Mountain Conference on Analytical Chemistry, co-sponsored by the Colorado Section of the American Chemical Society and the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 1-5, 1999.

Cell/Dendrite Distribution In Directionally Solidified Hypoeutectic Pb-Sb Alloys, S. P. O'Dell, G. L. Ding, Surendra N. Tewari

Chemical & Biomedical Engineering Faculty Publications

The alloys Pb-2.2 wt pet Sb and Pb-5.8 wt pet Sb were directionally solidified with three different thermal gradients of 40, 86, and 140 K cm(-1) at growth rates ranging from 0.6 to 30 mu m s(-1). A Gaussian peak amplitude analysis of the cell/dendrite spacing distribution shows a distinct peak corresponding to the nearest neighbors. The peaks corresponding to the second and the third nearest neighbor spacings are also brought out by this technique. The ratios of the second to the first nearest neighbor spacings and that of the third to the first neighbor spacings are 1.85 +/-: 0.11 …

Macrosegregation Caused By Thermosolutal Convection During Directional Solidification Of Pb-Sb Alloys, S. N. Ojha, G. L. Ding, Y. Lu, J. Reye, Surendra N. Tewari

Chemical & Biomedical Engineering Faculty Publications

Pb-2.2 and 5.8 wt pet Sb alloys were directionally solidified with a positive thermal gradient of 140 K cm(-1) at growth speeds ranging from 0.8 to 30 mu m s(-1), and then quenched to retain the mushy-zone morphology. Chemical analysis along the length of the directionally solidified portion and in the quenched melt ahead of the dendritic array showed extensive longitudinal macrosegregation, Cellular morphologies growing at smaller growth speeds are associated with larger amounts of macrosegregation as compared with the dendrites growing at higher growth speeds. Convection is caused, mainly, by the density inversion in the overlying melt ahead of …

Effect Of Temperature On Short-Term Creep Rupture Response In Polymer Matrix Pultruded Composites, Robert Harold Munson

Mechanical & Aerospace Engineering Theses & Dissertations

Polymer matrix pultruded composites have increasingly been used in applications where high strength-to-weight ratio and corrosion resistance are needed. Bridge and pier components are a couple of recent applications due the composite's resistance to corrosion from salt water. In applications of this sort, the material will commonly be subjected to sizable static loads while exposed to varying weather conditions. In using pultruded composites for these applications safely, a better understanding of the material's response to ambient conditions is necessary.

In this thesis, rectangular specimens of a polyester matrix glass reinforced pultruded composite sheet are subjected to both static tensile loading …

The Effect Of Platinum And Excess 211 Phase On The Loss Of The Liquid Phase In Melt Textured Yba₂Cu₃O₇₋ₓ, William C. Hicks, Fatih Dogan, Michael Strasik, Arthur C. Day, Kevin E. Mccrary

Materials Science and Engineering Faculty Research & Creative Works

Platinum is an important additive in YBa₂Cu₃O_7-x [123] powders for melt processing and growth of large, oriented crystals, but its role in liquid loss during the growth cycle is poorly understood. A series of experiments were conducted to determine how platinum effects liquid loss, and to study the solubility limit of platinum in 123. Both atomically mixed and solid state platinum sources were compared. Crystals were grown on a nonreactive setter so that liquid loss could be clearly distinguished by weight from reaction products with the setter. Based on weight loss studies there was little …

The Effect Of Platinum And Excess 211 Phase On The Loss Of The Liquid Phase In Melt Textured Yba2cu3o7-X, William C. Hicks, Fatih Dogan, M. Strasik, A. C. Day, Kevin E. Mccrary

Materials Science and Engineering Faculty Research & Creative Works

Platinum is an important additive in YBa₂Cu₃O_7-x [123] powders for melt processing and growth of large, oriented crystals, but its role in liquid loss during the growth cycle is poorly understood. A series of experiments were conducted to determine how platinum effects liquid loss, and to study the solubility limit of platinum in 123. Both atomically mixed and solid state platinum sources were compared. Crystals were grown on a nonreactive setter so that liquid loss could be clearly distinguished by weight from reaction products with the setter. Based on weight loss studies there was little …

Training Graduate Student Instructors Effectively: The University Of Michigan Model, Trevor S. Harding

Materials Engineering

No abstract provided.

Grain Oriented Crystallization, Piezoelectric, And Pyroelectric Properties Of (Baxsr₂ - X)Tisi₂O₈ Glass Ceramics, Jianping Zhang, Burtrand I. Lee, Robert W. Schwartz, Zhenya Ding

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Polar, nonferroelectric (BaxSr2 - x)TiSi2O8 glass ceramics with highly oriented crystallites were prepared by a gradient temperature heat treatment technique. The crystallization mechanism and microstructures of (BaxSr2 - x)TiSi2O8 glass ceramics were investigated by means of differential thermal analysis, x-ray diffraction and scanning electron microscopy, and the dielectric, piezoelectric and pyroelectric properties were investigated for various compositions. The results show that polar (BaxSr2 - x)TiSi2O8 glass ceramics have a low dielectric constant and a high hydrostatic figure of merit dh × gh = ~ 2500. This high hydrostatic figure of merit, along with other unique characteristics, such as no aging …

Development Of A Curved Layer Lom Process For Monolithic Ceramics And Ceramic Matrix Composites, Donald A. Klosterman, Richard P. Chartoff, Nora R. Osborne, George A. Graves, Allan Lightman, Gyoowan Han, Akos Bezewredi, Stan Rodrigues, Sung Pak, Gary Kalmanovich, Leon Dodin, Song Tu

Chemical and Materials Engineering Faculty Publications

A novel rapid prototyping technology incorporating a curved layer building style was developed. The new process, based on Laminated Object Manufacturing (LOM), was designed for efficient fabrication of curved layer structures made from ceramics and fiber reinforced composites. A new LOM machine was created, referred to as Curved Layer LOM. This new machine uses ceramic tapes and fiber prepregs as feedstocks and fabricates curved structures on a curved-layer by curved-layer basis. The output of the process is a three dimensional "green" ceramic that is capable of being processed to a seamless, fully dense ceramic using traditional techniques. A detailed description …

Oxygen And Phosphorus Coordination Around Iron In Crystalline Ferric Ferrous Pyrophosphate And Iron-Phosphate Glasses With Uo₂ Or Na₂O, C. H. Booth, P. G. Allen, J. J. Bucher, N. M. Edelstein, D. K. Shuh, G. K. Marasinghe, Mevlüt Karabulut, C. S. Ray, D. E. Day

Materials Science and Engineering Faculty Research & Creative Works

Fe K-edge x-ray absorption fine-structure (XAFS) measurements were performed on glass samples of (Fe3O4)0.3(P2O5)0.7 with various amounts of Na2O or UO2. Near-edge and extended-XAFS regions are studied and comparisons are made to several reference compounds. We find that iron in the base glass is ~25% divalent and that the Fe2+ coordination is predominantly octahedral, while Fe3+ sites are roughly split between tetrahedral and octahedral coordinations. Also, we measure roughly one FeñOñP link per iron. Substitution of Na2O or UO2 up to 15 mo1% primarily affects the first FeñO shell. The results are compared to data from the related material Fe3(P2O7)2.

A Study On The Cathode Protection Potential Against Pitting Corrosion, Chun-Chun Xu, You-Ping Liu, Xiao-Bo Zhang, Xu-Hui Zhao

Journal of Electrochemistry

The methods have been developed to determine the protection potential against pitting corrosion. They are based on the theory that the pitting protection potential (E_p) is actually the transition potential of the direction of current between the occluded cell and the external surface (E_T). E_T lasts from -220 mV to -440 mV (SCE), the lowest of which can be considered as cathode protection potential. The E_p values determined with cyclic potentiodynamic polarization method is included in the E_T with above methods.

The Behaviors Of Capacity Loss Of Limn2O4 Cathodeat Elevated Temperatures, Xiao-Hong Hu, Han-Xi Yang, Xin-Ping Ai, Sheng-Xian Li, Xin-Lin Hong

Journal of Electrochemistry

The capacity loss of spinel LiMn₂O₄ cathode at elevated temperatures was evaluated by constant current charge-discharge methods and it was found that serious capacity loss and cycleability decrease occured at above 50, especially for the charged cells. The mechanisms for this phenomena were examined by atomic emission and infrared spectrometry of the electrolyte, XRD measurment of the cycled elecrode and microelectrode voltammetry of LiMn₂O₄ at room and elevated temperatures. The results showed that with increasing temperature, Mn and Li ions tended to redistribute partly in the spinel framework due to the disproportion of Mn …

Oxidation And Adsorption Of Deoxyribonucleic Acid At Highly Ordered Pyrolytic Graphite And Glass Carbon Electrode, Jian-Zhang Zhou, Ling-Ling Wu, Jin Luo, Zhong-Hua Lin

Journal of Electrochemistry

It is shown that calf thymus DNA (CT DNA) can be adsorbed at highly ordered pyrolytic graphite (HOPG) electrode and detected by differential pulse voltammetry (DPV) and electrochemical atomic force microscopy (ECAFM). It is found that controlled potential pre-polarization influences largely the adsorption of dsDNA while it has little influence on ssDNA. It is demonstrated that ECAFM is useful to exploit adsorption of DNA at HOPGE. The pattern of adsorption of DNA at HOPG electrode that fits best with the experimental data is proposed. The results aslo shows that UV/Vis reflection spectroscopy, which has not been used in studying electrochemical …

The Adsorption Stability Of Interface Corrosion Inhibitor, Fu-Xing Gan, Di-Hua Wang, Jin-Yun Zou

Journal of Electrochemistry

Some new results on the adsorption stability of interface corrosion inhibitor are presented. The concept of adsorption stability and the factors influencing the adsorption stability were discussed. It is shown that the anodic desorption potential can be employed to evaluate the adsorption stability of the inhibitor as an empirical character in some conditions. Electrochemical oscillations phenomena were observed for the first time on a rotating iron electrode in H₂SO₄ solution containing organic inhibitor in the active potential region. These potentiostatic current oscillations can occur under cathodic polarization, as well as under anodic plarization. The oscillation period, amplitude, …

Electrochemical Behavior Of Riboflavin On Glassy Carbon Electrode, Hong Li, Lin-Cai Jiang, Liang-Nian Ji

Journal of Electrochemistry

The electrochemical behavior of riboflavin(RF) on glassy carbon has been investigated by using potential sweep, rotating ring-disc electrode and the measurement of differential capacitance. It is shown that a single well-behaved oxidation-reduction wave corresponding to a reversible two-electrons reaction apears in medium of pH<6, and the adsorption of RFH₂ formed by electro-reduction is weak and hence its solubility is good. In medium of pH>6, there are two separating but overlapping partly oxidation-reduction waves corresponding to two-step one-electron reaction. The adsorptions of RFH and RFH₂ produced by reduction reactions in medium of 6