Engineering Commons^™

Additivity Of Strengthening Mechanisms In Ultrafine Grained Aluminum Alloy, Nilesh Kumar

Doctoral Dissertations

"Friction stir processing (FSP) has been used in the present work to obtain ultrafine grained (UFG) microstructure in a twin-roll cast (TRC) Al-Mg-Sc alloy. An attempt has been made to establish a correlation between processing, microstructure, and properties (mechanical) in UFG regime for this alloy system.

The effect of initial microstructural conditions and processing parameters (tool rotation rate) were shown to have a profound impact on the development of UFG microstructure. FSP led to a microstructure consisting of grains with an average grain size as small as 390 nm, having high angle grain boundaries and a completely random texture. The …

Stress Measurement And Development Of Zirconium Diboride-Silicon Carbide Ceramics, Jeremy Lee Watts

Doctoral Dissertations

"Research presented in this dissertation focused on the production of ZrB₂-SiC composites and their characterization; in particular their mechanical properties and thermally generated residual stresses. Thermally generated stresses were measured using Raman spectroscopy as well as both neutron and x-ray diffraction. For 70 vol% ZrB₂ - 30 vol% SiC composites neutron diffraction revealed that the SiC phase was under ~880 MPa compressive stress and the ZrB₂ phase was under ~450 MPa tension at room temperature. It was also discovered that stresses began to accumulate at ~1400 ⁰C upon cooling from the processing temperature (1900 ⁰C -2000 ⁰C). Raman spectroscopy and …

A Study On The Combined Effect Of Forging And Aging In Mg-Y-Re Alloy, S. K. Panigrahi, W. Yuan, R. S. Mishra, R. Delorme, B. Davis, R. A. Howell, K. Cho

Materials Science and Engineering Faculty Research & Creative Works

The combined effect of forging and aging on microstructural evolution and mechanical properties of a Mg-Y-RE alloy was studied in the present work by employing hardness measurements, tensile tests, optical microscopy (OM), scanning electron microscopy (SEM) and electron back scattered diffraction (EBSD) analysis. the -F temper treated bulk Mg-Y-RE alloy samples were subjected to forging for microstructural refinement and subsequent aging to maximize the strength-ductility combination. the forged samples combined with peak aging treatment (60 h at 180 °C) exhibited an excellent combination of high strength (388 MPa) and high ductility (23%). the combined effect of grain refinement, work hardening, …

Low Temperature Epitaxial Growth Of Ge Quantum Dot On Si (100) - (2×1) By Femtosecond Laser Excitation, Ali Oguz Er, Wei Ren, Hani E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

Low temperature epitaxy of Ge quantum dots on Si (100) - (2×1) by femtosecond pulsed laser deposition under femtosecond laser excitation was investigated. Reflection high-energy electron diffraction and atomic force microscopy were used to analyze the growth mode and morphology. Epitaxial growth was achieved at ∼70 °C by using femtosecond laser excitation of the substrate. A purely electronic mechanism of enhanced surface diffusion of the Ge adatoms is proposed. © 2011 American Institute of Physics. [doi:10.1063/1.3537813]

A Feasibility Study Of Model-Based Natural Ventilation Control In A Midrise Student Dormitory Building, Steven James Gross

Dissertations and Theses

Past research has shown that natural ventilation can be used to satisfy upwards of 98% of the yearly cooling demand when utilized in the appropriate climate zone. Yet widespread implementation of natural ventilation has been limited in practice. This delay in market adoption is mainly due to lack of effective and reliable control. Historically, control of natural ventilation was left to the occupant (i.e. they are responsible for opening and closing their windows) because occupants are more readily satisfied when given control of the indoor environment. This strategy has been shown to be effective during summer months, but can lead …

Phase Change Materials As A Thermal Storage Device For Passive Houses, Kevin Ryan Campbell

Dissertations and Theses

This study describes a simulation-based approach for informing the incorporation of Phase Change Materials (PCMs) in buildings designed to the "Passive House" standard. PCMs provide a minimally invasive method of adding thermal mass to a building, thus mitigating overheating events. Phase change transition temperature, quantity, and location of PCM were all considered while incrementally adding PCM to Passive House simulation models in multiple climate zones across the United States. Whole building energy simulations were performed using EnergyPlus from the US Department of Energy. A prototypical Passive House with a 1500 Watt electric heater and no mechanical cooling was modeled. The …

Understanding And Improving Lithium Ion Batteries Through Mathematical Modeling And Experiments, Rutooj D. Deshpande

Theses and Dissertations--Chemical and Materials Engineering

There is an intense, worldwide effort to develop durable lithium ion batteries with high energy and power densities for a wide range of applications, including electric and hybrid electric vehicles. For improvement of battery technology understanding the capacity fading mechanism in batteries is of utmost importance. Novel electrode material and improved electrode designs are needed for high energy- high power batteries with less capacity fading. Furthermore, for applications such as automotive applications, precise cycle-life prediction of batteries is necessary.

One of the critical challenges in advancing lithium ion battery technologies is fracture and decrepitation of the electrodes as a result …

New Media Icc Profiles Construction And Concerns, Reem El Asaleh

Dissertations

With the advent of the modern digital technology, users can now capture an image and reproduce it between different media, such as display it on LCD monitor or tablet computer, print it on desktop printer or send it to a printing press. The challenge has been then to maintain the accuracy of image colors during this reproduction, which has led to the development of Color Management Systems. Using these systems, the color reproduction across-media will be accomplished using device ICC profiles that describe each device’s color characterization data in a standardized format based on International Color Consortium (ICC) specifications.

ICC …

Growth And Characterization Of Nanoscale Thin Films, Erik Thomas Wolter

Honors Program Theses

Thin manganese films were grown by thermal evaporation in high vacuum. The growth rate was varied to determine how the growth rate affects the continuity of ultra-thin films. The resistance was measured with the two-point method in situ and the data was recorded digitally. The resistance was converted to resistivity and this was plotted against thickness. It was found that resistivity decreases exponentially as the film begins to form in islands. The film reaches a critical thickness as the islands coalesce and the data can then be fitted with Fuchs’ equation. The resistivity continues to decrease but the minimum resistivity …

Synthesis And Characterization Of Carbon Magnetic Nanoparticles, Sunilsingh Gusain

Material Science and Engineering Theses - Archive

Carbon incorporated iron nanoparticles (Fe-CNPs) were successfully synthesized using ultrasonic cavitation in Benzene. This novel method of carbon nanoparticle (CNP) synthesis is a very cost-effective and versatile as one can easily tune the microstructure and magnetic properties by varying few parameters, for e.g. voltage. The Fe-CNP complexes are produced due to the electric plasma discharge generated between the electrodes in an ultrasonic cavitation field of liquid benzene. The constituent of the CNPs can be easily modified by different choice of electrode materials- iron and graphite. The resultant Fe-CNPs were characterized by high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy to …

Precise Control Of Highly Ordered Arrays Of Nested Semiconductor/Metal Nanotubes, Diefeng Gu, Helmut Baumgart, Kandabara Tapily, Pragya Shrestha, Gon Namkoong, Xianyu Ao, Frank Müller

Electrical & Computer Engineering Faculty Publications

Lithographically defined microporous templates in conjunction with the atomic layer deposition (ALD) technique enable remarkable control of complex novel nested nanotube structures. So far three-dimensional control of physical process parameters has not been fully realized with high precision resolution, and requires optimization in order to achieve a wider range of potential applications. Furthermore, the combination of composite insulating oxide layers alternating with semiconducting layers and metals can provide various types of novel applications and eventually provide unique and advanced levels of multifunctional nanoscale devices. Semiconducting TiO₂ nanotubes have potential applications in photovoltaic devices. The combination of nanostructured semiconducting materials …

Nonuniformity In Lattice Contraction Of Bismuth Nanoclusters Heated Near Its Melting Point, A. Esmail, M. Abdel-Fattah, Hani E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The structural properties of bismuth nanoclusters were investigated with transmission high-energy electron diffraction from room temperature up to 525 ± 6 K. The Bi nanoclusters were fabricated by thermal evaporation at room temperature on transmission electron microscope grids coated with an ultrathin carbon film, followed by thermal and femtosecond laser annealing. The annealed sample had an average cluster size of ∼14 nm along the minor axis and ∼16 nm along the major axis. The Debye temperature of the annealed nanoclusters was found to be 53 ± 6 K along the [012] direction and 86 ± 9 K along the [110] …

Stabilisation Of Linear-Cavity Fibre Laser Using A Saturable Absorber, David Michel, Feng Xiao, Kamal Alameh

Research outputs 2011

We investigate the optimisation of the length of an un-pumped erbium doped fibre (EDF) in order to suppress amplifier noise in a linear-cavity fibre laser structure. The experimental results demonstrate the existence of an optimum length of the un-pumped EDF which eliminates noise due to high optical pumping powers, thus leading to a stable laser output.

Garnet Multilayer Thin Film Structure With Magnetostatically-Altered And Improved Magnetic Properties Prepared By Rf Magnetron Sputtering, Mohammad Nur-E-Alam, Mikhail Vasiliev, Viacheslav Kotov, Kamal Alameh

Research outputs 2011

We prepare an all-garnet multilayer film structure by sandwiching a magneto-soft garnet material in between two magneto-hard garnet materials with high bismuth substitution levels using RF magnetron sputtering technique and investigate the microstructure and the effects of magnetostatic inter-layer coupling on magnetic properties. Both types of the Bi-substituted magneto-optic garnet materials used possess excellent optical, magnetic and magneto-optical properties suitable for the application in different new and emerging technologies in optics and photonics. Garnet layers of composition type Bi2Dy1Fe4Ga1O12 have strong perpendicular magnetic anisotropy and Bi1.8Lu1.2Fe3.6Al1.4O12 magneto-soft layer features magnetization behavior similar to that of in-plane magnetized films. The all-garnet …

Thermo-Physical Properties Measurement And Steel - Ceramic Shell Interactions In Investment Casting, Chirag Mahimkar

Masters Theses

"Investment casting is a process in which a ceramic shell is prepared on a wax or foam pattern. The wax is melted out or the foam is burnt out and the shell is sintered to have sufficient strength to withstand casting conditions. The investment casting process is very important as it produces near net shape castings which reduce the need for subsequent operations of castings like machining etc. Investment casting shells are subjected to a number of heating cycles during pattern removal, firing, preheating before pouring and finally during solidification. The thermo-physical properties of the shell play an important role …

Calcium Wire Ladle Treatment To Improve Cleanliness Of Centrifugal Cast Steel, Edith Yolanda Martinez Silva

Masters Theses

"Centrifugal casting provides the opportunity of combining large centrifugal forces and directional solidification to reduce non-metallic inclusions in the cast steel product. Calcium treatment in the ladle has the potential of reducing and modifying non-metallic inclusions to achieve better machinability and mechanical properties. The objective of this research is to analyze the combined effects of calcium wire ladle treatment and centrifugal casting on the number, size, composition and morphology of non-metallic inclusions in centrifugally cast steel products.

All experiments were completed at an industrial foundry. The experiments involved feeding calcium wire into the ladle after argon oxygen decarburization (AOD) and …

Effect Of Nickel On Castability Of Chromium Molybdenum Steel & The Dynamic Fracture Toughness Of Hy-130, Abhilash Dash

Masters Theses

"The fill lengths of Ni alloyed Cr-Mo steels obtained from fluidity studies (Paper 1) varied linearly with superheat. A 5% Ni steel showed a maximum fill length compared to other steels tested. Ni decreased the liquidus, solidus, and dendritic coherency temperature, but it did not have any significant effect on volume fraction (0.27-0.31) of the solid phase at the dendrite coherency point. The filling time obtained experimentally at 150 C⁰ superheat for 5% Ni steel (HY 130) was close to 1.4 s. For similar conditions, the predicted fill time using a Magmasoft model was close to 1.9 s. Modeling results …

Development Of Thermo-Regulating Fabric Using Phase Change Material (Pcm), Prasad S. Bhatkhande

Master's Theses and Doctoral Dissertations

This research study concentrates on use of phase change material (PCM) in textiles which can produce thermo-regulating characteristics to control body temperature useful for various daily wear and technical textiles. The latent heat which is released or absorbed during the process of phase change is studied and discussed in this research. The PCMs are encapsulated into tiny microcapsules to protect from washing out or abrasion. These microcapsules are bounded onto the fabric surface by using a binder. The microcapsules and their effectiveness are tested by using SEM, Optical Microscope, DSC and Comfort tester. The testing is further extended to the …

Rate-Dependent Stiffening And Strain Localization In Physically Associating Solutions, Kendra Erk, Kenneth R. Shull

School of Materials Engineering Faculty Publications

Model physically associating solutions of acrylic triblock copolymer molecules in a midblock-selective solvent displayed non-linear strain-stiffening behavior which transitioned to rapid strain softening during shear start-up experiments at reduced rates spanning almost four orders of magnitude. Softening was believed to result from the shear-induced formation of highly localized regions of deformation in the macromolecular network. This behavior was accurately captured by a model that incorporated the strain energy and relaxation behavior of individual network strands in the solution. Flow curves predicted from the model were non-monotonic, consistent with the onset of flow instabilities at high shear rates. The non-linear stress …

Fiber-Reinforced Calcium Sulfate Bone Cement Composites With Enhanced Bioactivity, Mechanical Properties And Controlled Biodegradability, Nuha Fathi Hussien

Theses

Hard tissues are natural composites of inorganic and organic components. The inorganic component is a basic Calcium phosphate; known as hydroxyapatite (HAp) while the organic is a natural polymer; known as collagen. The interlocking between the collagen nanofibers and the Hap nanocrystals growing on them offers the known unique mechanical stability of hard tissues. In case of partial fractures; bone or dental cements are often used. Cements such as polymethylmethacrylate (PMMA) has been long used in this regard. However, this polymer is classified as a bio inert material that can be accepted by the human body without having a positive …

Density Functional Theory Study On The Electronic Structure Of N- And P-Type Doped Srtio3 At Anodic Solid Oxide Fuel Cell Conditions, S. Suthirakun, Salai Cheettu Ammal, G. Xiao, Fanglin Chen, Hans-Conrad Zur Loye, Andreas Heyden

Faculty Publications

The electronic conductivity and thermodynamic stability of mixed n-type and p-type doped SrTiO3 have been investigated at anodic solid oxide fuel cell (SOFC) conditions using density functional theory (DFT) calculations. In particular, constrained ab initio thermodynamic calculations have been performed to evaluate the phase stability and reducibility of various Nb- and Ga-doped SrTiO3 at synthesized and anodic SOFC conditions. The density of states (DOS) of these materials was analyzed to study the effects of n- and p-doping on the electronic conductivity. In agreement with experimental observations, we find that the transformation from 20% Nb-doped Sr-deficient SrTiO3 to a non-Sr-deficient phase …

A Comparison Of Two Engineering Outreach Programs For Adolescents, Louis S. Nadelson, Janet M. Callahan

Materials Science and Engineering Faculty Publications and Presentations

There is continued growth and development of outreach programs designed to increase pre-college students’ awareness and understanding of engineering as a profession and as a career. These outreach programs vary in format and in the groups targeted for participation but maintain the same fundamental goal of increasing participant knowledge of engineering. Many of these outreach programs also maintain the implicit goal of increasing the participants' knowledge and attitudes toward college. The additional resources and funding that are commonly allocated to support outreach programs frequently involve documenting accountability which motivates evaluation of program impact. Therefore, many outreach events include program evaluation …

Mse News 2011, Department Of Materials Science And Engineering, Michigan Technological University

Department of Materials Science and Engineering Annual Reports

Table of Contents

• New Fund and Center: a Challenge, an Opportunity, and an Appeal from Chair Mark Plichta
• MSE Scientist: Positioned for Success with Unique Program
• Student Accomplishments and Awards
• Department News
• Alumni Updates

Polydimethylsiloxane Mechanical Properties Measured By Macroscopic Compression And Nanoindentation Techniques, Zhixin Wang

USF Tampa Graduate Theses and Dissertations

In this thesis, the relationship between the elastic modulus of PDMS and the base/agent ratio (the amount of crosslinking) is studied. Reliable macroscopic compression test instrument was developed. Preload method was applied for the nanoindentation flat punch test to develop full contact.

In chapter 2, an easy instrument setup for macroscopic compression test is described. A series of PDMS samples with different base/agent ratios were tested using the macroscopic compression method. The relationship between PDMS elastic modulus and its base/agent ratio was established.

In chapter 3, PDMS nanoindentation DMA tests provide stable data with different test control models. The storage …

Fabrication And Characterization Of Electrospun Cactus Mucilage Nanofibers, Yanay Pais

USF Tampa Graduate Theses and Dissertations

This work seeks to fabricate, optimize, and characterize nanofibers of cactus Opuntia ficus-indica mucilage and Poly (vinyl alcohol) (PVA) by electrospinning. Mucilage is a neutral mixture of sugars produced by cactus and PVA is a non-toxic, water-soluble, synthetic polymer, which is widely used as a co-spinning agent for polymers. Mucilage was extracted from the cactus pad and prepared for electrospinning by mixing with acetic acid. Two types of PVA were used differentiating in high and low molecular weights. Concentrations of PVA were varied to find an adequate threshold for fiber formation. Changing the ratio of PVA to cactus mucilage produced …

Stress Corrosion Cracking Evaluation Of Candidate High Strength Stainless Steels For Prestressed Concrete, Joseph Rogelio Fernandez

USF Tampa Graduate Theses and Dissertations

Prestressed concrete piles are commonly used to support over-water highway bridges in marine environments. The reinforcing steel within will ultimately be degraded via corrosion damage due to the penetration of chloride ions from sea water. The service life of these structures is, in part, dictated by the time required to diffuse chloride ions through the concrete cover and subsequently corrode the steel. Therefore, by slowing the rate of diffusion or increasing the chloride threshold of the steel (or both) an increased service life can be expected. This thesis focuses on the latter whereby stainless steel reinforcing alternatives were investigated to …

Interface Engineered Diamond Coatings For Dry Machining Applications, Humberto Arturo Gomez Vega

USF Tampa Graduate Theses and Dissertations

Several studies have been propose to improve the adhesion of diamond films on cemented carbide tool materials, however a systematic study in identifying the role of the factors that affect the final diamond adhesion and the resulting machining performance of the tool under real manufacturing conditions is still unexplored. CVD diamond film's extraordinary qualities bring little benefit if the film fails to adhere sufficiently to the substrate. Inadequate adhesion undermines tool performance and longevity, causing unpredictable behavior under load and possibly leading to unexpected failure of the tool in the production line. This dissertation investigates the effects of different surface …

Diamond Based-Materials: Synthesis, Characterization And Applications, Qiang Hu

USF Tampa Graduate Theses and Dissertations

The studies covered in this dissertation concentrate on the various forms of diamond films synthesized by chemical vapor deposition (CVD) method, including microwave CVD and hot filament CVD. According to crystallinity and grain size, a variety of diamond forms primarily including microcrystalline (most commonly referred to as polycrystalline) and nanocrystalline diamond films, diamond-like carbon (DLC) films were successfully synthesized. The as-grown diamond films were optimized by changing deposition pressure, volume of reactant gas hydrogen (H2) and carrier gas argon (Ar) in order to get high-quality diamond films with a smooth surface, low roughness, preferred growth orientation and high sp3 bond …

Growth And Characterization Of Thermoelectric Ba8Ga16Ge30 Type-I Clathrate Thin-Films Deposited By Pulsed Dual-Laser Ablation, Robert Harry Hyde

USF Tampa Graduate Theses and Dissertations

The on-going interest in thermoelectric (TE) materials, in the form of bulk and films, motivates investigation of materials that exhibit low thermal conductivity and good electrical conductivity. Such materials are phonon-glass electron-crystals (PGEC), and the multi-component type-I clathrate Ba₈Ga₁₆Ge₃₀ is in this category. This work reports the first investigation of Ba₈Ga₁₆Ge₃₀ films grown by pulsed laser deposition (PLD).

This dissertation details the in-situ growth of polycrystalline type-I clathrate Ba₈Ga₁₆Ge₃₀ thin-films by pulsed laser ablation. Films deposited using conventional laser ablation produced films that contained a …

Oxygen Diffusion Characterization Of Frp Composites Used In Concrete Repair And Rehabilitation, Chandra K. Khoe

USF Tampa Graduate Theses and Dissertations

Many independent studies have conclusively demonstrated that fiber reinforced polymers (FRP) slow down chloride-induced corrosion of steel in concrete. The mechanism for this slow down is not well understood but it has been hypothesized that FRP serves as a barrier to the ingress of chloride, moisture, and oxygen that sustain electrochemical corrosion of steel.

This dissertation presents results from an experimental study that determined the oxygen permeation rates of materials used in infrastructure repair. In the study, the oxygen permeation constants for epoxy, carbon and glass fiber laminates, concrete, epoxy-concrete and FRP-concrete systems were determined and a method developed to …