Engineering Commons^™

Modeling Diverse Physics Of Nanoparticle Self-Assembly In Pulsed Laser-Irradiated Metallic Films, Mikhail Khenner

Mathematics Faculty Publications

Presents physics behind dewetting of thin liquid films and mathematical/computational modeling tools (Educational/Research presentation for senior physics majors).

Stability Of A Strongly Anisotropic Thin Epitaxial Film In A Wetting Interaction With Elastic Substrate, Mikhail Khenner, Wondimu T. Tekalign, Margo S. Levine

Mathematics Faculty Publications

The linear dispersion relation for longwave surface perturbations, as derived by Levine et al. Phys. Rev. B 75, 205312 (2007) is extended to include a smooth surface energy anisotropy function with a variable anisotropy strength (from weak to strong, such that sharp corners and slightly curved facets occur on the corresponding Wulff shape). Through detailed parametric studies it is shown that a combination of a wetting interaction and strong anisotropy, and even a wetting interaction alone results in complicated linear stability characteristics of strained and unstrained films.

Stability Of A Strongly Anisotropic Thin Epitaxial Film In A Wetting Interaction With Elastic Substrate, Mikhail Khenner, Wondimu Tekalign, Margo Levine

Mathematics Faculty Publications

The linear dispersion relation for longwave surface perturbations, as derived by Levine et al. Phys. Rev. B 75, 205312 (2007) is extended to include a smooth surface energy anisotropy function with a variable anisotropy strength (from weak to strong, such that sharp corners and slightly curved facets occur on the corresponding Wulff shape). Through detailed parametric studies it is shown that a combination of a wetting interaction and strong anisotropy, and even a wetting interaction alone results in complicated linear stability characteristics of strained and unstrained films.

Development Of A Friction Testing Apparatus For Demoulding Force Prediction, Kevin Delaney, David Kennedy, G. Bissacco

Conference Papers

Friction between replication tools and replicated parts determines the force required to demould the part and also the stresses which develop in both the tool and the part during the demoulding process. Standardized equipment and procedures have been developed which strive to improve the repeatability and reproducibility of friction tests. Specific test standards, describing sled-type tests, include JIS K 7125, ISO 8295 and ASTM D1894. However these tests do not produce results which are representative of the conditions typically found within replication tools such as injection moulds or embossing tools. This paper reviews how this challenge has been addressed by …

High Frequency Thermally Actuated Single Crystalline Silicon Micromechanical Resonators With Piezoresistive Readout, Amir Rahafrooz

Electronic Theses and Dissertations

Over the past decades there has been a great deal of research on developing high frequency micromechanical resonators. As the two most common and conventional MEMS resonators, piezoelectric and electrostatic resonators have been at the center of attention despite having some drawbacks. Piezoelectric resonators provide low impedances that make them compatible with other low impedance electronic components, however they have low quality factors and complicated fabrication processes. In case of electrostatic resonators, they have higher quality factors but the need for smaller transductions gaps complicates their fabrication process and causes squeezed film damping in Air. In addition, the operation of …

Reinforced Chitosan-Based Heart Valve Scaffold And Utility Of Bone Marrow-Derived Mesenchymal Stem Cells For Cardiovascular Tissue Engineering, Mohammad Z. Albanna

Wayne State University Dissertations

Recent research has demonstrated a strong correlation between the differentiation profile of mesenchymal stem cells (MSCs) and scaffold stiffness. Chitosan is being widely studied for tissue engineering applications due to its biocompatibility and biodegradability. However, its use in load-bearing applications is limited due to moderate to low mechanical properties. In this study, we investigated the effectiveness of a fiber reinforcement method for enhancing the mechanical properties of chitosan scaffolds. Chitosan fibers were fabricated using a solution extrusion and neutralization method and incorporated into porous chitosan scaffolds. The effects of different fiber/scaffold mass ratios, fiber mechanical properties and fiber lengths on …

Scanning Capacitance Spectroscopy On N+-P Asymmetrical Junctions In Multicrystalline Si Solar Cells, Chun-Sheng Jiang, Jennifer T. Heath, Helio R. Moutinho, Mowafak M. Al-Jassim

Faculty Publications

We report on a scanning capacitance spectroscopy (SCS) study on the n⁺-p junction of multicrystalline silicon solar cells. We found that the spectra taken at space intervals of ∼10 nm exhibit characteristic features that depend strongly on the location relative to the junction. The capacitance-voltage spectra exhibit a local minimum capacitance value at the electrical junction, which allows the junction to be identified with ∼10-nm resolution. The spectra also show complicated transitions from the junction to the n-region with two local capacitance minima on the capacitance-voltage curves; similar spectra to that have not been previously reported in …

Extension Of A Progressive Failure, Energy Dissipation, Composite Tailoring Concept To A Healing Configuration, Shailesh Jayant Divey

Material Science and Engineering Theses - Archive

A composite failure tailoring concept that results in a yield type response under tension has been proposed, modeled, and experimentally verified in prior research. The concept capitalizes upon a sequential, progressive failure of a set of redundant load paths of tailored strength and length. It has been shown in prior publications that the concept is functional and by comparison with experimental results that the analytical models of response developed are accurate. The limits of performance of the proposed tailoring concept have recently been investigated via a parametric study using one of the response models developed and significant improvements have been …

Xanes And Ftir Study On Dried And Calcined Bones, Jayapradhi Rajendran

Material Science and Engineering Theses - Archive

The animal bones are common archeological finds and are helpful in understanding the human past. The bones undergo transformation when they are calcined. The cooked and cremated bones undergo different transformation, because of their difference in their temperatures. Various techniques are employed to characterize the bone. In this study, XANES and FTIR are used to characterize the dried and calcined bones of different species. The calcined bones are prepared at two different temperatures, which helps in understanding the difference between the cooked and cremated bones. The objective of this research is to comprehend the chemical property of the bone material …

Electrodeposition Of Nickel Sulfide And Its Thermal Oxidation For Photovoltaic Applications, Munteha Pac

Material Science and Engineering Theses - Archive

Alternative photovoltaic materials that feature natural abundance, low extraction and processing costs, and reasonable efficiency have to be found. In this respect, transition metal chalcogenides such as oxide and sulfide compounds of Ni; is studied because in addition to the features like abundance and cost, its electronic and optical properties vary dramatically by modifications in its stoichiometry. In addition to its low cost, and mature technology, electrochemical deposition method has many advantages over other methods since it allows direct deposition on conducting substrate and achieves good electrical contact and precise control of film thickness. Process of manufacturing Nickel Oxysulfide compound …

Synthesis And Characterization Of Platinum Based Catalysts For Fuel Cells, Sonam Patel

Material Science and Engineering Theses - Archive

Platinum (Pt) and platinum alloys have attracted wide attention as catalysts to attain high performance to increase the power density and reduce the component cost of polymer electrolyte membrane fuel cells (PEMFCs). Extensive research has been conducted in the areas of new alloy development and understanding of mechanisms of electrochemical oxygen reduction reaction (ORR). The durability of PEMFCs is also a major barrier to the commercialization of these fuel cells. Recent studies have suggested that potential cycling can gradually lead to loss of active surface area due to Pt dissolution and nanoparticle grain growth [1]. In this thesis we report …

Gold/ Copper Sulphide And Gold Nanoparticles For Application In Cancer Therapy, Santana Bala Lakshmanan

Material Science and Engineering Theses - Archive

The main goal of this research is to use Gold/ Copper Sulphide (Au/ CuS) and Gold nanoparticles (AuNPs) for improving the therapeutic effects in the treatment of cancer. One of the biggest successes in photothermal therapy is the use of AuNPs which however has its own drawbacks i.e. it is expensive and that the NIR absorption of Au nanostructures is from surface plasmon resonance which is dependent on the dielectric constant of the surrounding matrix. Thus, the plasmon absorption maxima would shift for in-vivo observations compared to in-vitro. Alternatively, Copper Sulphide (CuS) nanoparticles, developed recently, have also been used for …

Pulsatile Protein Release From A Thermoresponsive Hydrogel: Effect Of Device Architecture, Nanoparticle And Polymer Concentration Using Factorial Analyses, Shruti Gandhi

Material Science and Engineering Theses - Archive

A pulsatile thermo-responsive drug delivery device for wound healing applications was developed in this study and its drug release during 24 hours of thermal cycling was characterized. The device consisted of a temperature sensitive hydrogel of poly (N-isopropyl acrylamide-co-acrylamide) (PNIPAM-AAm) nanoparticles (LCST: 39-40°C) embedded in a poly (ethylene glycol) diacrylate (PEGDA) matrix inside a device made of poly (methyl methacrylate). The device had four different orifice geometries all with the same surface area of opening (5 mm2): slit, cross, circle and four-circle. Bovine serum albumin (BSA) was loaded onto the hydrogel as the model protein. The effect of the orifice …

Semi-Transparent Zno:Al/Cu2o Thin-Film Heterojunction Fabricated At Low Temperature: Effect Of An Intrinsic Zno Buffer Layer At The Junction, Yu-Nung Huang

Material Science and Engineering Theses - Archive

The Al-doped ZnO (AZO)/Cu2O semi-transparent heterojunction was realized by an RF sputtering at low temperature in this study. Specifically, the usage of a buffer layer in the junction structure has been found as a key factor influencing the carrier transport mechanisms and performance of the junction. First, the chemical bath deposition (CBD) has been utilized in depositing an intrinsic ZnO (i-ZnO) buffer layer in order to entirely avoid potential plasma damage from a subsequent sputter deposition process. Increasing pH of CBD solution was critical in delaying the formation of detrimental ZnOHx particles in the solution and the assistance of ultrasonication …

Development Of Multimodal Imaging System Combined With Laser Microbeam For Nanoscale Manipulation And Characterization., Ninad Ingle

Material Science and Engineering Theses - Archive

Optical microscopy has fascinated biologists for probing and observing cellular structure while performing scientific research. While numerous wide-field and scanning microscopic techniques are being developed for probing cellular structure and function with high spatial and temporal resolution, mapping of complete biochemical, material and structural properties of the cell in three dimensions requires integration of multiple microscopic imaging techniques. In this thesis, conventional phase contrast microscopy and epifluorescence microscopy techniques were combined with other imaging methods such as digital holography microscopy (DHM) also known as quantitative phase microscopy, atomic force microscopy (AFM), near-field scanning optical microscopy (NSOM), total internal reflection fluorescence …

Process-Dependent Microstructure And Severe Plastic Deformation In Sicp?? Reinforced Aluminum Metal Matrix Composites, Catalina Uribe-Restrepo

Electronic Theses and Dissertations

Discontinuously reinforced MMCs with optimized microstructure are sought after for exceptional high strain rate behavior. The microstructure evolution of a stir-cast A359 aluminum composite reinforced with 30 vol.% SiCp after isothermal anneal, successive hot-rolling, and high strain rate deformation has been investigated. Quantitative microstructural analysis was carried out for the as-cast, annealed (470°C, 538°C and 570°C) and successively hot rolled specimens (64, 75, 88, and 96% rolling reductions). Selected composites were also examined after high strain rate deformation. X-ray diffraction, optical microscopy, scanning electron microscopy and transmission electron microscopy were employed for microstructural characterization. The strength and ductility of the …

Observations On Braided Thin Wire Nucleate Boiling In Microgravity, Justin P. Koeln, Jeffrey C. Boulware, Heng Ban, Jr Dennison

Publications

A microgravity experiment was conducted on the Space Shuttle Endeavor (STS-108) to observe sustained nucleate boiling of water. Subcooled water was boiled with a single strand and a braid of three 0.16. mm diameter and 80. mm long Nichrome resistive wires. A CCD video camera recorded the experiment while six thermistors recorded the temperature of the fluid at various distances from the heating element. This paper reports experimental results in observations, measurements, and data analysis. Bubble explosions were found to take place shortly after the onset of boiling for both the single and braid of wires. The explosion may produce …

Stress-Strain Management Of Heteroepitaxial Polycrystalline Silicon Carbide Films, Christopher William Locke

USF Tampa Graduate Theses and Dissertations

Silicon carbide (SiC) is one of the hardest known materials and is also, by good fortune, a wide bandgap semiconductor. While the application of SiC for high-temperature and high-power electronics is fairly well known, its utility as a highly robust, chemically-inert material for microelectrical mechanical systems (MEMS) is only beginning to be well recognized. SiC can be grown on both native SiC substrates or on Si using heteroepitaxial growth methods which affords the possibility to use Si micromachining methods to fabricate advanced SiC MEMS devices.

The control of film stress in heteroepitaxial silicon carbide films grown on polysilicon-on-oxide substrates has …

Fatigue Lifetime Approximation Based On Quantitative Microstructural Analysis For Air Plasma Sprayed Thermal Barrier Coatings, Carmen Bargraser

Electronic Theses and Dissertations

The durability of thermal barrier coatings (TBCs) affects the life of the hot section engine components on which they are applied. Fatigue is the general failure mechanism for such components and is responsible for most unexpected failures; therefore it is desirable to develop lifetime approximation models to ensure reliability and durability. In this study, we first examined the microstructural degradation of air plasma sprayed ZrO2-8wt.%Y2O3 TBCs with a low-pressure plasma sprayed CoNiCrAlY bond coat on an IN 738LC superalloy substrate. The durability of TBCs were assessed through furnace thermal cyclic tests carried out in air at 1100°C with a 1-, …

Supercritical Carbon Dioxide-Processed Resorbable Polymer Nanocomposites For Bone Graft Substitute Applications, Kevin Baker

Wayne State University Dissertations

Numerous clinical situations necessitate the use of bone graft materials to enhance bone formation. While autologous and allogenic materials are considered the gold standards in the setting of fracture healing and spine fusion, their disadvantages, which include donor site morbidity and finite supply have stimulated research and development of novel bone graft substitute materials. Among the most promising candidate materials are resorbable polymers, composed of lactic and/or glycolic acid. While the characteristics of these materials, such as predictable degradation kinetics and biocompatibility, make them an excellent choice for bone graft substitute applications, they lack mechanical strength when synthesized with the …

High Conductivity Solid Oxide Electrolyte Composite-Laminates Utilizing Scandia/Ceria Co-Doped Zirconia Core With Yttria Stabilized Zirconia Outer Skins, Jay Neutzler, Xinyu Huang, Joshua Sightler, Yan Chen, Nina Orlovskaya

Faculty Publications

Increasing the conductivity of electrolytes in lower temperature Solid Oxide Fuel Cells (SOFC) is of great importance. However, there are several challenges that are to be addressed, which include phase stability of electrolyte’s crystal structure, chemical stability in both oxidizing and reducing environments, and maintaining mechanical integrity and high ionic conductivity over time.

Effects Of Radiation-Induced Carbon Contamination On The Printing Performance Of Extreme Ultraviolet Masks, Yu-Jen Fan

Legacy Theses & Dissertations (2009 - 2024)

This dissertation investigates one of the remaining issues for extreme ultraviolet (EUV) lithography, the effects of radiation induced carbon contamination on the printing performance of patterned EUV masks. The impact of carbon contamination on EUV masks is significant due to the throughput loss and potential effects on imaging performance, and occurs when multilayer surfaces are exposed to EUV radiation with residual carbonaceous species present. Current carbon contamination research is primarily focused on the lifetime of the multilayer surfaces, determined by reflectivity loss and reduced throughput in EUV exposure tools. However, contamination on patterned EUV masks can cause additional effects on …

Effects Of Low Energy E-Beam Irradiation On Graphene And Graphene Field Effect Transistors And Raman Metrology Of Graphene On Split Gate Test Structures, Gayathri Rao

Legacy Theses & Dissertations (2009 - 2024)

Apart from its compelling performance in conventional nanoelectronic device geometries, graphene is an appropriate candidate to study certain interesting phenomenon (e.g. the Veselago lens effect) predicted on the basis of its linear electron dispersion relation. A key requirement for the observation of such phenomenon in graphene and for its use in conventional field-effect transistor (FET) devices is the need to minimize defects such as consisting of - or resulting from - adsorbates and lattice non-uniformities, and reduce deleterious substrate effects. Consequently the investigation of the origin and interaction of defects in the graphene lattice is essential to improve and tailor …

Synthesis, Processing And Characterization Of Silicon-Based Templated Nanowires, Jae Ho Lee

Legacy Theses & Dissertations (2009 - 2024)

Semiconductor and metallic nanowires have attracted substantial attention due to their wide variety of applications, ranging from nanoelectronics to energy storage devices. In particular, self-assembled silicon nanowires (SiNWs) may be an attractive alternative to conventionally processed planar silicon since SiNWs can potentially function as both the switch (i.e. transistor) and local interconnect (e.g. metal silicide nanowire) to form an inherently integrated nanoelectronic system. Also, hierarchical (branched) nanowire systems hold potential for catalysts or porous electrode applications for energy applications

Applying X-Ray Microscopy And Finite Element Modeling (Fem) To Identify The Mechanism Of Stress-Assisted Void Growth In Through Silicon Via (Tsv), Lay Wai Kong

Legacy Theses & Dissertations (2009 - 2024)

Fabricating through-silicon vias (TSVs) is challenging, especially for conformally filled TSVs, often hampered by the seam line and void inside the TSVs. Stress-assisted void growth in TSVs has been studied by finite element stress modeling and X-ray computed tomography (XCT). Because X-ray imaging does not require TSVs to be physically cross-sectioned, the same TSV can be imaged before and after annealing. Using 8 keV laboratory-based XCT, voids formed during copper electroplating are observed in as-deposited samples and void growth is observed at the void location after annealing. We hypothesize that the mechanism generating voids is hydrostatic stress-assisted void growth. Stresses …

Electron-Phonon Interactions And Quantum Confinement Effects On Optical Transitions In Nanoscale Silicon Films, Vimal Kumar Kamineni

Legacy Theses & Dissertations (2009 - 2024)

Theoretical studies have attributed the temperature dependence of the linear optical response (dielectric function) of bulk semiconductors to electron-phonon interactions and thermal expansion of the lattice. However, the role of phonons in the optical properties of nanoscale structures is often overlooked. This thesis systematically investigates the impact of both carrier confinement and electron-phonon interactions using nanoscale films of silicon in crystalline silicon quantum wells (c-Si QW). Spectroscopic ellipsometry (SE) is a linear optical technique used to of extract the dielectric function and thickness of very thin films. X-ray reflectivity (XRR) was used as the complementary thickness metrology method. The dielectric …

Investigation Of Novel Alumina Nanoabrasive And The Interactions With Basic Chemical Components In Copper Chemical Mechanical Planarization (Cmp) Slurries, Shravanthi Lakshmi Manikonda

Legacy Theses & Dissertations (2009 - 2024)

Chemical mechanical planarization (CMP) is an enabling process technology for IC fabrication to maintain global planarity across the wafer to satisfy lithographic depth of focus constraints. It also enables integration of materials that cannot be anisotropically etched, such as Cu. CMP utilizes nanoparticle abrasives in aqueous slurry to aid in planarization.

Energy Band Engineering Using Polarization Induced Interface Charges In Mocvd Grown Iii-Nitride Heterojunction Devices, Neeraj Tripathi

Legacy Theses & Dissertations (2009 - 2024)

Characteristics of III-nitride based heterojunction devices are greatly influenced by the presence of high density of polarization induced interface charges. Research undertaken in the current doctoral thesis demonstrates the effect of presence of one, three and six sheets of polarization induced charges in three different III-nitride based devices, namely in a photocathode, a high electron mobility transistor (HEMT) and a hyperspectral detector structure. Through a systematic set of experiments and theoretical modeling an in-depth study of the interaction between multiple sheets of polarization induced charges and their impact on energy band profile was undertaken. Various device designs were studied and …

Development Of High Band Gap Absorber And Buffer Materials For Thin Film Solar Cell Applications, Daniel Dwyer

Legacy Theses & Dissertations (2009 - 2024)

CuInGaSe₂ (CIGS) device efficiencies are the highest of the thin film absorber materials (vs. CdTe, α-Si, CuInSe₂). However, the band gap of the highest efficiency CIGS cells deviates from the expected ideal value predicted by models. Widening the band gap to the theoretically ideal value is one way to increase cell efficiencies. Widening the band gap can be accomplished in two ways; by finding a solution to the Ga-related defects which limit the open circuit voltage at high Ga ratios, or by utilizing different elemental combinations to form an alternative high band gap photoactive Cu-chalcopyrite (which includes …

Nucleation, Wetting And Agglomeration Of Copper And Copper-Alloy Thin Films On Metal Liner Surfaces, Stephanie Florence Labarbera

Legacy Theses & Dissertations (2009 - 2024)

One of the key challenges in fabricating narrower and higher aspect ratio interconnects using damascene technology has been achieving an ultra-thin (~2 nm) and continuous Cu seed coverage on trench sidewalls. The thin seed is prone to agglomeration because of poor Cu wetting on the Ta liner. Using in-situ conductance measurements, the effect of lowering the substrate temperature during Cu seed deposition has been studied on tantalum (Ta) and ruthenium (Ru) liner surfaces. On a Ta surface, it was found that lowering the deposition temperature to -65°C increases the nucleation rate of the Cu thin film, and reduces the minimum …