Engineering Commons^™

Corrosion Prevention Of Rebar In Concrete Due To Chloride, Y Srimahajariyaphong, S Niltawach

Journal of Metals, Materials and Minerals

In coastal and brackish areas, black rebar in concrete structures suffers from chloride corrosion which leads to spalling of the concrete. The Half Cell Potential Measurement technique has been applied to study the corrosion behavior of both black and galvanized deformed rebar in different concretes. Additives in the concretes vary from pozzolan, calcium nitrite, to pozzolan plus calcium nitrite. Rebar which has higher half cell potential possesses better corrosion resistance. It has been found that concrete cover thickness has no significant effect on the half cell potential of either rebar; that for both types of rebar, the half cell potential …

Separation Of Lycopene/Solvent Mixture By Chitosan Membranes, P Yodjun, K Soontarapa, C Eamchotchawalit

Journal of Metals, Materials and Minerals

Acetone in view of lower toxicity could be used as extracting solvent of lycopene in tomato paste instead of hexane. The studied chitosan membranes were uncrosslinked and crosslinked types. It was found that the membrane morphology could be changed from porous to dense structure by increasing evaporation temperature or time or by crosslinking. They showed hydrophilicity but not preferred to both acetone and lycopene. The lycopene/acetone mixture could be separated by using water swollen chitosan membrane in pervaporation process. It was found that all studied membranes; i.e., both uncrosslinked and ionically crosslinked membranes prepared at 40 to 60C for 2 …

Excitation-Induced Ge Quantum Dot Growth On Si(100)-2x1 By Pulsed Laser Deposition, Ali Oguz Er

Physics Theses & Dissertations

Self-assembled Ge quantum dots (QD) are grown on Si(100)-(2×1) with laser excitation during growth processes by pulsed laser deposition (PLD). In situ reflection-high energy electron diffraction (RHEED) and post-deposition atomic force microscopy (AFM) are used to study the growth dynamics and morphology of the QDs. A Q-switched Nd:YAG laser (λ = 1064 nm, 40 ns pulse width, 5 J/cm² fluence, and 10 Hz repetition rate) were used to ablate germanium and irradiate the silicon substrate. Ge QD formation on Si(100)-(2×1) with different substrate temperatures and excitation laser energy densities was studied. The excitation laser reduces the epitaxial growth temperature …

Steel Angle Section Members Under Combined Axial Load And Unsymmetric Bending, Maheshchandra Rajasekharan Phanibhushan

Civil & Environmental Engineering Theses & Dissertations

This thesis presents the outcome of an investigation into the experimental and theoretical behavior of steel angle section members under combined axial load and unsymmetric bending. Tests are conducted on a series of six angle section members provided with biaxial pinned-end boundaries about the cross-sectional non-principal axes. The end bending moments and axial load are applied in a quasi-static manner until the member load-carrying capacity is reached. The experimental load-deflection and load-strain curves are recorded. The theoretical analysis is based on a system of both elastic as well as materially nonlinear differential equations. The equations were solved using an iterative …

Improving The Efficiency Of Organic Solar Cells By Varying The Material Concentration In The Photoactive Layer, Kevin Anthony Latimer

Electrical & Computer Engineering Theses & Dissertations

Polymer-fullerene bulk heterojunction solar cells have been a rapidly improving technology over the past decade. To further improve the relatively low energy conversion efficiencies of these solar cells, several modifications need to be made to the overall device structure. Emerging technologies include cells that are fabricated with interfacial layers to facilitate charge transport, and tandem structures are being introduced to harness the absorption spectrum of polymers with varying bandgap energies.

When new structures are implemented, each layer of the cell must be optimized in order for the entire device to function efficiently. The most volatile layer of these devices is …

Ultrafast Electron Diffraction Study Of The Dynamics Of Antimony Thin Films And Nanoparticles, Mahmoud Abdel-Fattah

Electrical & Computer Engineering Theses & Dissertations

The ultrafast fast phenomena that take place following the application of a 120 fs laser pulse on 20 nm antimony thin films and 40 nm nanoparticles were studied using time-resolved electron diffraction. Samples are prepared by thermal evaporation, at small thickness (< 10 nm) antimony nanoparticles form while at larger thicknesses we get continuous thin films.

The samples are annealed and studied by static heating to determine their Debye temperatures, which were considerably less than the standard value. The thermal expansion under static heating also yielded the expansion coefficient of the sample material. Nanoparticle samples gave a very accurate thermal expansion coefficient (11 × 10^-6 K^-1).

Ultrafast time resolved electron diffraction …

The Montana Mule: A Case Study In Interdisciplinary Capstone Design, Brock J. Lameres, Ahsan Mian, Hunter Lloyd, Robb Larson

Mechanical and Materials Engineering Faculty Publications

The Montana MULE: A Case Study in Interdisciplinary Capstone Design In May of 2010, NASA held the 1st annual Lunabotics Mining Competition at theKennedy Space Center in Florida. In this competition, 22 teams from across the nationbuilt remote-controlled, robotic excavators to mine lunar regolith simulant. The winnerof the competition was the team who could successfully deposit the most regolith into acollector in 15 minutes. The goal of this competition was to encourage multidisciplinarycapstone design projects. Of the 22 teams that participated in the competition, the“Montana MULE” from Montana State University (MSU) was the only robot tosuccessfully mine the qualifying weight …

Behavior Of Na+-Polystyrene Sulfonate At The Interface With Single-Walled Carbon Nanotubes (Swnts) And Its Implication To Swnt Suspension Stability, Tabbetha A. Dobbins, Richard Chevious, Yuri Lvov

College of Science & Mathematics Departmental Research

The assembly of sodium polystyrene sulfonate (Na+-PSS) at the surface of single-walled carbon nanotubes (SWNTs) in pH 3 aqueous solution is described. Rather than forming linear or sheet-like chain morphologies over SWNT surfaces, Na+-PSS adopts a spherically collapsed conformation believed to be the result of cation (either Na+ or H+) condensation onto the ionized polymer chain. It is well reported that cations (and also anions) adsorb preferentially onto single-walled and multi-walled carbon nanotube surfaces leading to an increased ion concentration in the near surface regions relative to the bulk solution. This work provides experimental evidence for preferentially absorbed cation condensation …

The Effects Of Damage Arrestment Devices In Composite Plate Sandwiches With Fastener Holes, Mark Anderson, Nancy Hung Choy, Lacey Jones, Rita Kourskaya

Aerospace Engineering

Composite materials such as a carbon fiber are used in a variety of new technologies including aircraft, spacecraft, and motor vehicles. Carbon fiber has a high strength to weight ratio, a key advantage over other material options. This report discusses the use of composite damage arrestment devices (DADs) in composite sandwich panels with a foam core. There are three different curing cycles tested for the DADs: pressure only, vacuum only, and vacuum with 1000 lbs of pressure. Using a Tetrahedron Heat Press to cure the composite specimen and an Instron Machine to perform tensile testing, data was collected for each …

A Comparison Of Two Headless Compression Screws For Operative Treatment Of Scaphoid Fractures, Ruby Grewal, Joseph Assini, David Sauder, Louis Ferreira, Jim Johnson, Kenneth Faber

Surgery Publications

PURPOSE: The purpose of this study was to compare the interfragmentary compression force across a simulated scaphoid fracture by two commonly used compression screw systems; the Acutrak 2 Standard and the 3.0 mm Synthes headless compression screw.

METHODS: Sixteen (8 pairs; 6 female, 2 male) cadaver scaphoids were randomly assigned to receive either the Acutrak 2 or Synthes screw with the contralateral scaphoid designated to receive the opposite. Guide wires were inserted under fluoroscopic control. Following transverse osteotomy, the distal and proximal fragments were placed on either side of a custom load cell, to measure interfragmentary compression. Screws were placed …

The Effects Of Cure Schedule On Properties Of Glass-Fiber Reinforced Epoxy Matrix Composites, Trevor J. Lee

Materials Engineering

Two different two-component resin systems were cured, via Differential Scanning Calorimetry, for the times recommended by their respective manufacturers. The resin cure schedules were designed to simulate typical and attainable processing conditions; they were cured at 120°F, 140°F, and 160°F, and in-mold post-cured at 200°F, 230°F, and 260°F. The resulting scans were then compared to a baseline cure for each resin system, consisting of two heating-cooling cycles at a constant rate of temperature change. These baseline cures were then used to determine the percent cure of each sample and the shift in glass transition temperature between the baseline cure and …

Final Design Review: Design Of An Integrated Solar Cell Array To Power A Solar Ear Hearing Aid Battery Recharger, Christina (Chrissa) Blattner, Scott Carey, Jared Myren, Faye Siao

Materials Engineering

As the energy of fossil fuel supplies are fast depleting due to high consumptions of energy by human beings, the need for other sources of energy, such as solar energy, has become a viable option. By creating solar cell arrays the desired voltage can be generated. The overall goal of the Solar Ear project is to create an array of photovoltaic cells connected with aluminum tracings to recharge batteries that are specifically used for hearing aids. The goal embodies two main areas: the design of a processing method to connect the cells during a micro-fabrication process and the creation of …

Process Refinement Through Design Of Experiments (Taguchi) To Reduce Porosity Levels Of Thin Flame Spray Nicrbsi Coatings On Cast Aluminium Alloys, David Culliton, David Kennedy, Tony Betts

Conference Papers

Thin(16matrix of key deposition parameters was constructed to develop the optimum spray parameters. The effects of parameter variations on the porosity levels of these coatings were assessed. Key parameter interactions were reported. Quantifiable interactions between the selected parameters were noted for the LM24 substrate. However, on the LM25 substrate these interactions were much less defined. Corrosion performance of the optimised coatings, based on electrochemical impedance spectroscopy, was reported. The presence of through-pores in the coatings were shown to reduce the corrosion resistance of the coated systems by a factor of 10, in dilute NaCl solutions, compared to bulk 316L stainless …

Dissimilar Metal Weld Variability Due To Lot Differences In Nitinol/ Stainless Steel Interface, Matthew R. Rudow

Materials Engineering

Abstract

An experiment was conducted to determine and reduce the causes of variation between a 304 Stainless Steel and super elastic Nickel Titanium dissimilar metal weld. Six factors were established to understand the cause of variation: perpendicularity, final grind, surface finish, weld force, weld pulse duration, and alignment. Using a rotational test with an air piston break pressures were established and charted in Minitab to identify trends. It was shown that weld force and weld pulse duration were the two factors that had the most influence on break strength. This data also showed that higher strength groups had less variability. …

Flexi-Focus Lens: Pdms Variable Focal Length Lens, Patrick Angulo, Alex Doyle, Dylan Mcdaniel, Michael Olivarez

Industrial and Manufacturing Engineering

The design of a variable focal length, or flexi-focus, polydimethylsiloxane (PDMS) lens incorporating a light emitting diode (LED) source is intended for future use on board commercial aircraft. Specifically, the design is intended for the Boeing 787 Dreamliner aircraft, serving as a personal reading light for the passengers seated in the cabin. Most current reading lights on board aircraft are rigid, incandescent, and have very limited freedom in terms of adjusting the emitted light. Incandescent lamps are also inefficient with respect to energy consumption and light output as well as a high heat output. In an economy of increasing demand …

Determining A Method For Rendering Low Cost Cdse(Zns) Core(Shell) Quantum Dots Aqueous Soluble Via Amphiphilic Polymer Wrapping, Patrick Mcbride

Materials Engineering

Herein is described the procedure of two amphiphilic polymer wrapping techniques that may be employed for obtaining aqueous soluble quantum dots (QDs) for use in biological fluorescent imaging applications. The advent of QDs has led to new nanoscale fluorescent materials that exhibit unparalleled quantum yields (QYs), high resistance to photobleaching, tunable emissions, and
absorption over a large optical range. However, the QD synthesis employed here at Cal Poly to obtain bright, photostable CdSe(ZnS) core(shell) QDs involves the use of organic solvents and surfactants, leading to hydrophobic QDs. Since all of biology relies on aqueous solubility, this hydrophobicity creates a major …

Artificial Muscle Project: Process Development Of Polydimethyl Siloxane Thin Films For Use In Dielectric Electroactive Polymer Artificial Muscle Actuators, Vincent J. Gayotin, Richard W. Morrison, Paul A. Preisser

Materials Engineering

An artificial muscle design was created founded on the principles of a dielectric electroactive polymer (DEAP), which is fundamentally similar to a capacitor. A polydimethyl siloxane (PDMS)-based elastomer, Sylgard 184 from Dow Corning, was chosen for the design and spun coat onto polystyrene (PS) Petri dishes at varying speeds to create a thin film, using speeds of 2000 rpm, 3000 rpm, 4000 rpm, 5000 rpm, and 6000 rpm. The film thicknesses were measured optically through use of a microscope with coupled computer imaging software to generate a characteristic curve of film thickness to spin speed, achieving a minimum film thickness …

Design And Characterization Of A Process For Bulk Synthesis Of Cadmium Selenide Quantum Dots, Susan Harada

Materials Engineering

The objective of the process is to synthesize quantum dots that will fluoresce over the visible spectrum of 450 to 650nm; then to mix the quantum dots together in a polymer matrix so that when illuminated with a blue LED the mixture yields “white” light. The current quantum dot synthesis is a chemical process that involves adding a room temperature Se-TOP precursor to a 225°C Cd precursor solution to cause nucleation and growth of nanoparticles. This method, however, only yields quantum dots that fluoresce in the 520 to 600nm range. In order to create the “white” light phosphor replacement, red …

Materials Characterization Of Bamboo And Analysis Of Bonding Strength And Internal Strength As A Structural Member In Reinforced Concrete, Nithi Plangsriskul, Nicholas Dorsano

Materials Engineering

This study evaluates the potential to utilize bamboo as reinforcement in concrete structural members.  In this project, the mechanical properties of bamboo were tested, specifically force required to embed a 0.5” diameter ball 0.016” into the bamboo samples and its bonding strength with concrete.  One type of bamboo, Bambusa Oldhamii, was cut into eight sections, approximately 2.54 cm wide, along the length of the culm.  The compression test recorded the bamboo’s strength at eight points along the length of the internode and at three points along the transverse direction of each specimen.  Bambusa Oldhamii’s specimen base 1 data for inner, …

Understanding The Effects Of Temperature Extremes On The Tensile And Short Beam Shear Strength Of Epoxy-Based, Glass-Fiber Reinforced Composites, Jonathan Blake Patterson

Materials Engineering

Aptera (Oceanside, CA) has developed two epoxy-based, silica fiber-reinforced composites to be used on their three-wheeled all-electric vehicle called the 2e.  Aptera’s composites were studied at temperature extremes using a dynamic mechanical analysis (DMA) system and by tensile and short beam shear (SBS) testing using an Instron testing system. These tests were conducted to simulate the loading of the composite in the 2e vehicle.  Tensile and short beam shear samples were machined to 150 mm x 25 mm x 2 mm and 40 mm x 13 mm x 6 mm, respectively.  DMA samples were machined to 30 mm x 5 …

The Design And Manufacture Of A Microfluidic Reactor For Synthesis Of Cadmium Selenide Quantum Dots Using Silicon And Glass Substrates, Peter Gonsalves

Materials Engineering

A microfluidic reactor for synthesizing cadmium selenide (CdSe) quantum dots (QDs) was synthesized out of silicon and Pyrex glass. Microfabrication techniques were used to etch the channels into the silicon wafer. Holes were wet-drilled into Pyrex glass using a diamond-tip drill bit. The Pyrex wafer was aligned to the etched silicon wafer and both were anodically bonded to complete the microfluidic reactor. Conditions for anodic bonding were created by exposing the stacked substrates to 300V at ~350^oC under 5.46N of force.  Bulk CdSe solution was mixed at room temperature and treated as a single injection. The syringe containing …

Large Kinetic Asymmetry In The Metal-Insulator Transition Nucleated At Localized And Extended Defects, W. Fan, Jinbo Cao, J. Seidel, Yijia Gu, J. W. Yim, For Full List Of Authors, See Publisher's Website.

Materials Science and Engineering Faculty Research & Creative Works

Superheating and supercooling effects are characteristic kinetic processes in first-order phase transitions, and asymmetry between them is widely observed. In materials where electronic and structural degrees of freedom are coupled, a wide, asymmetric hysteresis may occur in the transition between electronic phases. Structural defects are known to seed heterogeneous nucleation of the phase transition, hence reduce the degree of superheating and supercooling. Here we show that in the metal-insulator transition of single-crystal VO 2, a large kinetic asymmetry arises from the distinct spatial extension and distribution of two basic types of crystal defects: point defects and twin walls. Nanometer-thick twin …

Characterisation, Modelling And Simulation Of Flexible Polyurethane Foam, Conor Briody, Barry Duignan, Stephen Jerrams

Conference Papers

Flexible polyurethane foam is an open-celled polymeric material that exhibits strain rate and temperature effects. It has found various applications in areas including the packaging, medical, sports, aerospace and aeronautical industries. Polyurethane foam is ubiquitous in seating applications and finds particular use in specialised wheelchair seating where customised seating solutions are required which can provide proper comfort and support without the risk of developing pressure ulcers. Proper seating design is critical for users if this problem is to be avoided, but a lack of quantitative knowledge of this material’s behaviour has limited its effectiveness. The objectives of the work presented …

Ir Nonlinear Absorption Leading To Laser-Induced Damage In Ge & Gasb, Torrey J. Wagner, Matthew J. Bohn, Ronald A. Coutu Jr., L. P. Gonzales, J. M. Murray, K. L. Schepler, S. Guha

Faculty Publications

Using a simultaneous fitting technique to extract nonlinear absorption coefficients from data at two pulse widths, we measure two-photon and free-carrier absorption coefficients for Ge and GaSb at 2.05 and 2.5 μm for the first time. Results agreed well with published theory. Single-shot damage thresholds were also measured at 2.5 μm and agreed well with modeled thresholds using experimentally determined parameters including nonlinear absorption coefficients and temperature dependent linear absorption. The damage threshold for a single-layer Al₂O₃ anti-reflective coating on Ge was 55% or 35% lower than the uncoated threshold for ps or ns pulses, respectively. Wavelength-dependant …

The Effects Of Heat Treatment On Area Percent Porosity And Corrosion Behavior Of High-Nickel Thermal Spray Coatings, Travis Crowe, Alec Guraydin

Materials Engineering

Samples of two Thermal Spray Coating (TSC) alloys on a low carbon steel substrate were obtained: alloy C276 and Nicko-Shield 200. Specimens of each alloy were subjected to heat treatments at temperatures at 1100° for 60 minutes and 1200° for 10 minutes, with some specimens left in the as-sprayed condition. Three replicates were prepared for each condition. Thin 1” strips were cut using a diamond wafering blade for porosity measurements and 2” x 1” specimens were cut for corrosion testing using a SiC abrasive saw. The porosity specimens were mounted in acrylic resin, polished, and examined using SEM. From these …

Characterization Of A Pdms Microfluidic Reactor For Synthesizing Quantum Dots, Brian Harley

Materials Engineering

A PDMS microfluidic reactor was made in Cal Poly’s class 1000 clean room for the purpose of synthesizing quantum dots.  The device master mold was made from a silicon substrate and SU-8 features 50μm tall.  The PDMS reactor was cast from that mold.  The flow rates of fluid through the channels, heating of the reactor and pressure in the reactor were measured in order to characterize the potential for synthesizing quantum dots.  Flow rates of 20 mL/hr through 4 mL/hr were tested to characterize the consistency of amount of time the fluid remains in the reactor at a constant flow …

Characterization Of The Oxidation Kinetics Of Fecral Ferritic Stainless Steels At 900°C For Catalytic Converter Applications, Stacy Stamm

Materials Engineering

This study characterized the oxidation kinetics of two types of ferritic stainless steel foils used as substrates for catalytic converters. Catalytic converters rely on an alumina layer on the surface of the foils, which allows the catalyst to attach to the substrate. Because the alumina layer is so important, this study characterized the weight gain, thickness, and composition of the alumina as it grew at 900°C for up to 400 hours. The two foils characterized were an MK foil, used for gasoline engines, and an EMS foil, used for diesel engines. The MK foil showed a percent weight gain of …

Characterization Of The Relationship Between The Microstructure And Tensile Strength Of Annealed Ti-6al-4v, Aldo Corona

Materials Engineering

Tensile coupons of Ti-6Al-4V were heat treated at varying annealing temperatures from 1200°F (648°C) to 1450°F (787°C)  at 50°F  (23°C) increments for 1 hour. The samples were air cooled to room temperature or furnace cooled to 800°F (426°C) followed by air cooling to room temperature. Four tensile coupons were treated at each annealing temperature and cooling rate. Alpha case was observed to form on the surface of the samples post heat treatment with a maximum depth of 25 µm (.001 in). Samples were tensile tested for their ultimate tensile strength, yield strength, and percent elongation.  Samples across all annealing temperatures …

The Effects Of Colorant Oxides And Firing Rate On The Nucleation And Growth Of Zinc Silicate Crystals In Crystalline Glazes, Nicolas Coffey

Materials Engineering

This study looked at the effects of colorant oxides and firing rate on the nucleation and growth of crystals in zinc-based crystalline glazes. One weight percent of iron and copper oxide powders were mixed separately with a zinc-based crystalline glaze. The uncolored glaze along with both colored glazes were applied to test tiles and fired. Two different firing schedules were used with different ramp up firing rates of 165°C/hr (slow) and 205°C/hr (fast). X-ray diffraction (XRD) analysis found both zinc oxide and silica oxide in the raw glaze, which are the main components in the formation of zinc silicate. XRD …

Processing Pdms Gecko Tape Using Isopore Filters And Silicon Wafer Templates, Boris Luu

Materials Engineering

Gecko tape was processed through nanomolding involving two types of templates. One template was a Millapore Isopore polycarbonate membrane filter and the other template was an n-type silicon wafer processed to include four different pore diameters. These pore diameters were 20, 40, 80, and 160 microns. AutoCAD was used to design to a mask to be used later during photolithography. Two n-type wafers were sputtered with aluminum, underwent photolithography, and then etched using reactive ion etching. A template was placed into a Petri dish and Sylgard 184 polydimethylsiloxane (PDMS) was poured on the template. Once the PDMS cured,   the 1 …