Engineering Commons^™

Proposal For No-Cost Extension And Re-Scope For Unlv Trp Project: Neutron Multiplicity Measurements For The Afci Program (Advanced Fuel Cycle Initiative), Denis Beller

Transmutation Sciences Physics (TRP)

The U.S. Advanced Fuel Cycle Initiative (AFCI) is a program to develop economic and environmental methods to reduce the impact of waste from commercial nuclear fuel cycles. One concept for near-complete destruction of waste isotopes from used nuclear fuel is accelerator-driven transmutation. High-power accelerators would be used to produce high-energy charged particles, which then collide with heavy metal targets to create a cascade of neutrons. These neutrons then cause a nuclear chain reaction in subcritical systems. Fission neutrons then transmute fissile waste isotopes as well as other problematic isotopes such as technetium-99 and iodine-129. To design these systems, complex reactor …

Land For Maine's Future Program: Increasing The Return On A Sound Public Investment, Richard Barringer, Hugh Coxe, Jack Kartez, Catherine Reilly, Jonathan Rubin

Economics and Finance

Maine is nowhere a more special place than in the quality of its landscape and the traditions of its land use. Among the mo st privately-owned of all the states, Maine’s natural diversity and beauty combine with its traditions of resource stewardship, open access, and appreciation of nature to distinguish it in the public mind and national imagination. In recent decades, however, these traditions have come under assault from the forces of economic and social change; and the people of Maine have responded. In 1986, Governor Joseph Brennan’s Special Commission on Outdoor Recreation recognized the growing threats to Maine’s natur …

Optimisation Of Heat Transfer And Fluid Flow In The Cooling Of Building Integrated Photovoltaic Facades., Eoin Patrick Hodge

Theses

The aim of this research was to explore the effects of mature and developing technologies from aeronautical industries such as impingement and film cooling, and electronic cooling techniques, in the setting up of different laminar and turbulent flow regimes on PV cooling duct heat transfer rates, with air flow as that brought about with natural buoyancy effects in a vertical building facade. The problem of efficiency losses in PV panels, due to overheating, is one of the factors restricting the development and use of this renewable power source. PV panels can experience very high temperatures, due to the heat input …

Hydrologic Variations Within Created And Natural Wetlands In Southeastern Virginia, Aaron Dyer Despres

OES Theses and Dissertations

The hydrology of wetlands, particularly how wetland soils collect, store, and redistribute water strongly affects how wetland systems function. In created wetlands, construction processes and materials influence the hydrology and consequently, the potential for successful reestablishment of target vegetation communities. During 2002–2004, the Virginia Department of Transportation constructed large mitigation wetlands on two different Quaternary aged surfaces with very similar hydrogeomorphic conditions. The Sandy Bottom Nature Park site (SBNP) located in Hampton, VA and rests on the sandy loam Tabb Formation while the Charles City Wetland site (CCW) lies on the older and clay-rich Shirley Formation. This study documents and …

Fundamental And Applied Experimental Investigations Of Corrosion Of Steel By Lbe Under Controlled Conditions: Kinetics, Chemistry, Morphology, And Surface Preparation: Quarterly Report, Allen L. Johnson, John Farley, Dale L. Perry

Transmutation Sciences Materials (TRP)

This project has four components:

(1) the fabrication of a materials test apparatus with unique capabilities,

(2) comparative studies of steel corrosion under gas phase conditions comparable to the Lead Bismuth Eutectic (LBE) oxygen control conditions,

(3) isotope labeling studies, and

(4) collaborative efforts with other workers in the field.

Estimating Energy Savings In Compressed Air Systems, Chris Schmidt, J. Kelly Kissock

Mechanical and Aerospace Engineering Faculty Publications

Compressed air is typically one of the most expensive utilities in an industrial facility. As a result, potential savings opportunities are aggressively sought out and identified. Once identified, projected energy savings must be calculated in order to justify the cost of implementing the savings opportunity. It is important to calculate projected energy and cost savings as accurately as possible. Unfortunately, savings are frequently overestimated because the methods used to estimate savings neglect to consider important factors such as compressor control and type, storage, and multiple compressor operation.

In this paper, a methodology is presented for modeling air compressor performance and …

Neutron Multiplicity Measurements Of Target/Blanket Materials, Denis Beller

Transmutation Sciences Physics (TRP)

To optimize the performance of accelerator-driven transmutation subcritical systems (ADS), engineers will need to design the system to operate with a neutron multiplication factor just below that of a critical, or self-sustaining, system. This design criterion requires particle transport codes that instill the highest level of confidence with minimal uncertainty, because larger uncertainties in the codes require larger safety margins in the design and result in a lower efficiency of the ADS transmuter. For current design efforts in the U.S., a Monte Carlo particle transport code MCNPX is used to model neutron production and transport for spallation neutron systems.

While …

Corrosion Of Steel By Lead Bismuth Eutectic, John Farley, Allen L. Johnson, Dale L. Perry

Transmutation Sciences Materials (TRP)

There is an active international interest in lead-bismuth eutectic and similar liquid lead systems because of the relevance to the transmutation of nuclear waste, fast reactors, and spallation neutron sources. A successful program in nuclear waste processing that includes transmutation in accelerator-driven systems and fast reactors, would significantly decrease the space requirements for geological repositories.

Materials in these systems must be able to tolerate high neutron fluxes, high temperatures, and chemical corrosion. For lead bismuth eutectic (LBE) systems, there is an additional challenge because the corrosive behaviors of materials in LBE are not well understood. Most of the available information …

Environment-Induced Degradation And Crack-Growth Studies Of Candidate Target Materials, Ajit K. Roy

Transmutation Sciences Materials (TRP)

The primary objective of this task is to evaluate the effect of environmental and mechanical parameters on environment induced degradations of candidate target structural materials for applications in spallation-neutron-target systems, such as accelerator-driven systems for the transmutation of waste. The materials selected for evaluation and characterization are martensitic stainless steels including Alloys HT-9, EP-823 and Type 422 stainless steel (SS).

More recently, this experimental program has been expanded to evaluate the effect of molten lead-bismuth eutectic (LBE) on the corrosion behavior of target structural materials in the presence of oxygen. Since the Materials Performance Laboratory (MPL) at UNLV currently cannot …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The corrosion of structural materials is a major concern for the use of lead-bismuth eutectic (LBE) systems for nuclear applications such as in transmuter targets or fast reactors. Corrosion in liquid metal systems can occur through various processes, including, for example, dissolution, formation of inter-metallic compounds at the interface, and penetration of liquid metal along grain boundaries. Predicting the rate of these processes depends on numerous system operational factors: temperature, system geometry, thermal gradients, solid and liquid compositions, and velocity of the liquid metal, to name a few. Corrosion, along with mechanical and/or hydraulic factors, often contributes to component failure. …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The focus of this work is to determine the effect of elevated temperatures on the tensile properties of Alloy EP-823 and other martensitic alloys having similar compositions. The information obtained through this work describing the mechanism of elevated-temperature deformation will assist in developing suitable target structural materials possessing enhanced LBE corrosion resistance at process temperatures, allowing the continued development and eventual deployment of these technologies.

Developing A Sensing System For The Measurement Of Oxygen Concentration In Liquid Pb-Bi Eutectic, Yingtao Jiang, Bingmei Fu, Woosoon Yim

Transmutation Sciences Materials (TRP)

Lead-bismuth eutectic (LBE) is a candidate as a spallation target in sub-critical transmutation systems and as a coolant in nuclear programs. One of the primary concerns with LBE systems is the corrosion of stainless steel, the primary structural material used in nuclear systems. To mitigate this problem, trace levels of oxygen can be introduced into the system, causing the formation of a protective oxide layer at the interface between the LBE and steel. To protect the steel components, this oxide layer must be properly maintained. However, too much oxygen will produce unwanted oxide precipitation within the coolant and elsewhere in …

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements, Ajit K. Roy

Transmutation Sciences Materials (TRP)

Metals and alloys, when subjected to tensile loading beyond a limiting value, can undergo plastic deformation resulting in lattice defects such as voids and dislocations. These imperfections may interact with the crystal lattice, producing a higher state of internal stresses characterized by reduced ductility. Residual stresses can also be generated in welded structures due to rapid rate of solidification, and dissimilar metallurgical microstructures between the weld and the base metals. Premature failures can be experienced in engineering metals and alloys due to the presence of these residual stresses. Specific thermal treatments commonly known as stress relief operations can relieve these …

Development Of Nanostructure Based Corrosion-Barrier Coatings On Steel For Transmutation Applications: Quaterly Report, Biswajit Das

Transmutation Sciences Materials (TRP)

During the past quarter, this project employed one graduate student and two undergraduate student researchers and made the following accomplishments :

• Acquisition of steel samples for experiments

• Design and fabrication of specialized anodization apparatus to accommodate steel samples

• Investigation of adhesiveness of aluminum on steel

• Investigation of effects of anodizing acids on steel to identify most appropriate acid and a suitable barrier material

Stress Corrosion Cracking Of Target Material, Mohammad K. Hossain

Transmutation Sciences Materials (TRP)

The primary objective of this paper is to evaluate the effect of hydrogen on environment assisted cracking of candidate target materials for transmutation applications. Transmutation refers to transformation of long-lived actinides and fission products from spent nuclear fuels (SNF), and occurs when the nucleus of an atom changes because of natural radioactive decay, nuclear fission, nuclear fusion, neutron capture, or other related processes. Martensitic Alloy EP 823 was selected to be the candidate alloy for this investigation. During the initial phase, the stress corrosion cracking (SCC) behavior of this alloy was evaluated in neutral (pH: 6-7) and acidic (pH: 2-3) …

Development Of A Systems Engineering Model Of The Chemical Separations Process, Yitung Chen, Darrell Pepper, Sean Hsieh

Separations Campaign (TRP)

The chemical processing of used nuclear fuel is an integral component of any strategy for the transmutation of nuclear waste. Due to the large volume of material that must be handled in this first step of the transmutation process, the efficiency of the separations process is a key factor in the potential economic viability of the transmutation strategies. The ability to optimize the chemical separation systems is vital to ensure the feasibility of the transmutation program.

Systems analysis, or total systems modeling, is one of the strongest tools available to researchers for understanding and optimizing complex systems such as chemical …

Nuclear Criticality, Shielding, And Thermal Analyses Of Separations Processes For The Transmutation Fuel Cycle, William Culbreth

Separations Campaign (TRP)

The first step in any transmutation strategy is the separation of radionuclides in used nuclear fuel. The current separation strategy supporting the Advanced Fuel Cycle Initiative (AFCI) program is based on the use of a solvent extraction separation process to separate the actinides, fission products, and uranium from used commercial nuclear fuel, and on the use of pyrochemical separation technologies to process used transmuter fuels. To separate the fission products and transuranic elements from the uranium in used fuel, the national program is developing a new solvent extraction process, the Uranium Extraction Plus, or UREX+, process based on the traditional …

Fundamental Chemistry Of U And Pu In The Tbp-Dodecane-Nitric Acid System: Quaterly Report, Kenneth Czerwinski, Byron Bennett

Separations Campaign (TRP)

The speciation of hexavalent U and tetravalent Pu will be examined in the TBP-dodecane- nitric acid systems. This topic is chosen based on data needs for separation modeling identified by the AFCI. Emphasis will be placed on studying the influence of nitrate and acetohydroxamic acid on U and Pu speciation as well as conditions where a third phase forms in the organic phase. The organic phase will be 30 % TBP in dodecane. Equal volumes of aqueous and organic phase will be used. The speciation of the actinides in the aqueous and organic phase will be determined by a number …

Design And Evaluation Of Processes For Fuel Fabrication, Georg F. Mauer

Fuels Campaign (TRP)

The goal of this research project is to provide technical support to process designers working on the development of the fuel cycles for transmutation applications. Detailed process models are developed to better define the impact of fuel choice on the transmuter fuel cycle, including relative process losses, waste generation, and plant capital cost. These process models provide insight regarding required plant size and number of plants needed to mesh with the fuel recycling line. They also determine requirements for automation.

Manufacturing models for large-scale production in a hot cell environment are also developed. Combined, these two models allow the assessment …

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion, Clemens Heske

Fuels Campaign (TRP)

The goal of this project is to elucidate the chemical bonding and interface formation of metal fission products with the coating materials used in state-of-the-art TRISO fuel particles. Particular emphasis is placed on an analysis of intermediate chemical phases at the interface, the intermixing/diffusion behavior, and the electronic interface structure as a function of material choice (metal and coating materials), temperature, and external stress. Furthermore, we intend to assess the chemical state of some of the metal fission products. The findings are expected to give valuable information about failure mechanisms of TRISO particles and fission product transport. Secondly, through simulating …

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion: 3rd Quarter Report, 2004, Clemens Heske

Fuels Campaign (TRP)

The goal of this project, which started in May 2004, is to elucidate the chemical bonding and interface formation of metal fission products with the coating materials used in state-of-the-art TRISO fuel particles. Particular emphasis is placed on an analysis of intermediate chemical phases at the interface, the intermixing/diffusion behavior, and the electronic interface structure as a function of material choice (metal and coating materials), temperature, and external stress.

In detail, this project is devoted to studying the interface formation of Pd, Ag, and Cs with SiC and pyrolytic carbon. Using the TRISO coating materials and single crystal references as …

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion: 4th Quarter Report, 2004, Clemens Heske

Fuels Campaign (TRP)

The goal of this project, which started in May 2004, is to elucidate the chemical bonding and interface formation of metal fission products with the coating materials used in state-of-the-art TRISO fuel particles. Particular emphasis is placed on an analysis of intermediate chemical phases at the interface, the intermixing/diffusion behavior, and the electronic interface structure as a function of material choice (metal and coating materials), temperature, and external stress. In detail, this project is devoted to studying the interface formation of Pd, Ag, and Cs with SiC and pyrolytic carbon. In order to study the properties of the relevant interfaces, …

Trust, Collaboration, And Financial Return In Conservation/Development Partnerships, New England Environmental Finance Center

Economics and Finance

In early 2002 the New England Environmental Finance Center hosted a series of roundtable discussions among municipal officials, residential developers, land trust representatives, and others about "Innovative Approaches to Land Conservation and Smart Growth". Among our observations was that for many of the over 20 conservation/development partnerships we discussed in the series, creation and maintenance of trust was central to success or failure of various stages of the partnership. This suggested a link between creation of trust and financial return for traditionally opposed project partners.

To further examine this matter, we interviewed 11 round table participants and asked questions about …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics-Task V: Fourth Quarterly Report 09/01/2003-11/30/2003, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the TRP proposed application. Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with only very sparse experimental data. Scientists have noticed that the concentration of oxygen dissolved in the liquid alloy could control the corrosion rate of steels exposed to Pb or Pb-Bi. At high …

Bomb-Pulse Chlorine-36 At The Proposed Yucca Mountain Repository Horizon: An Investigation Of Previous Conflicting Results And Collection Of New Data, Klaus J. Stetzenbach, Fred Phillips, Drew Coleman, Don Baepler, Amy J. Smiecinski

Publications (YM)

Previous studies by scientists at Los Alamos National Laboratory (LANL) and the United States Geological Survey (USGS) quantified ³⁶Cl/Cl to test for the presence of fast pathways at the proposed Yucca Mountain high-level nuclear waste repository. The goal of these studies was to determine whether or not fluids containing bomb-pulse ³⁶Cl/Cl traveled along fast travel pathways and reached the repository horizon, however, the two groups followed somewhat different procedures and produced conflicting results. The objective of this study is to attempt to determine the cause of the conflicting results and to obtain additional data to determine whether or …

Slides: Encana, John Moran

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

Presenter: John Moran, Reservoir Engineer, Encana Oil & Gas

23 slides

Abstract: For companies doing directional drilling, what are the direct and indirect costs and benefits? When is it economical and what factors does industry take into account in making the decision to utilize directional drilling?

Notes From The Directional Drilling Workshop, University Of Colorado Boulder. Natural Resources Law Center

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

20 pages

"These notes were taken by one of our law students attending the workshop. They are not a verbatim transcript and they were not supplied by, and may not have been reviewed by, the speakers. There may be errors or gaps in the notes and for these we apologize in advance. Where the speaker provided an abstract of their talk, these are included and noted as such."

Slides: Directional Drilling: The Promise And The Peril, Alfred W. Eustes Iii

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

Presenter: Dr. Bill Eustes, Ph.D., P.E., Department of Petroleum Engineering, Colorado School of Mines, Golden, CO

63 slides

Abstract: What is it, where can it be done and how does it fit into full field development for oil and gas? This segment will set the foundation and bring everyone up to a basic level of understanding of the technology of directional drilling.

Slides: Untitled [British Petroleum], Rusty Riese

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

Presenter: Dr. Rusty Riese, Consulting Geologist, BP American Production Co.

6 slides

Abstract: For companies doing directional drilling, what are the direct and indirect costs and benefits? When is it economical and what factors does industry take into account in making the decision to utilize directional drilling?

Slides: Untitled [Western Resource Advocates], Mike Chiropolos

Workshop on Directional Drilling in the Rocky Mountain Region (November 13)

Presenter: Mike Chiropolos, Attorney, Western Resource Advocates

10 slides

Abstract: What are the environmental considerations involved with directional drilling? How should the NEPA analysis take this technology into account? When should it be analyzed as an alternative to conventional vertical drilling?