Engineering Commons^™

A One-Dimensional Analysis Of A Microbial Fuel Cell For Efficient Acetate Removal And Power Density Output, David Rouhani

UNLV Theses, Dissertations, Professional Papers, and Capstones

Microbial fuel cells (MFCs) are electrochemical devices that utilize microorganisms to convert organic matter into electrical energy. MFCs have been discussed to have potential application for sustainable wastewater treatment due to their ability to generate electricity while simultaneously treating contaminated water. To optimize MFC performance, numerical models can be used to understand the complex electrochemical and biological processes occurring in the system. In this study, a numerical model was developed to simulate the performance of MFCs under varying operating conditions and to investigate the performance of a MFC for treating wastewater fuel. More specifically, the MFC was modeled to oxidize …

Metastability And Degradation In Cu(In,Ga)Se2 Thin-Film Solar Cells, Mohsen Jahandardoost

UNLV Theses, Dissertations, Professional Papers, and Capstones

Cu(In,Ga)(S,Se)2 or CIGS is a thin-film semiconductor that has shown a device efficiency of 23.35% and 24.2% for single-junction and perovskite/CIGS tandem solar cells, respectively. CIGS offers promising properties such as tunable bandgap and ease of processing making them great candidates for thin-film tandem devices. However, knowledge of the effect of material defects, buffer materials, and post-deposition treatment (PDT) on degradation and metastability behavior in these devices is not well understood.In this dissertation, metastability and long-term degradation of CIGS thin-film solar cells have been investigated under combinatorial stress factors of heat, light, and voltage bias to systematically understand the effect …

Investigating Haloacetonitrile (Han) Formation Potential From Nitrogenous Antibiotics And Agrochemicals, Kazi Shafayet Haider

UNLV Theses, Dissertations, Professional Papers, and Capstones

Disinfection can promote safe drinking water. Chlorine and chloramines are the two most used disinfectants. While these disinfectants are effective in inactivating disease-causing pathogens, they also produce hazardous byproducts when they react with organic compounds (precursors). Nitrogenous disinfection byproducts (N-DBPs) are more toxic than their counterparts. The increased use of nitrogen-based agrochemicals and antibitics has led to their detection in different water sources. The presence of secondary amine and aniline in these compounds can act as a source of reactive nitrogen to form N-DBPs. In addition, the increased concentration of bromide in water systems due to anthropogenic activities can enhance …

Effects Of Distributed Energy Resources On The Bulk Electric System, Stryder Loveday

UNLV Theses, Dissertations, Professional Papers, and Capstones

The traditional power grid was designed with a centralized resource distribution in mind, with a relatively small number of large power generation facilities supplying the vast majority of load. With recent efforts to further diversify the power grid as well as an increased interest in renewable energy sources, there has been an unprecedented amount of new DistributedEnergy Resources (DERs) added to the grid within the last decade. This often heavily influences the local demand where these resources are installed, often causing power to flow in ways not anticipated by the original design of the grid. This thesis reviews the potential …

Dynamic Analysis Of A Microgrid Powered With An Inverter And Machine-Based Distributed Resources, Brandon William Blackstone

UNLV Theses, Dissertations, Professional Papers, and Capstones

The proliferation of renewable distributed energy resources, particularly photovoltaic (PV) power systems, and the increasing need for a reliable power supply has led to the concept of microgrids, a mini-grid that consists of locally connected power generation units and needs, able to operate connected or disconnected from the utility grid, using controlled and coordinated methods to provide for the users of the microgrid the best possible conditions for their needs. The main technical issues facing microgrids include some of the following, seamless transition from stand-alone to utility grid connected operation, how to preserve frequency and voltage stability, and provide the …

Degradation Of Antibiotics In Aqueous Phase Using Pms Catalytic Decomposition With Zero-Valent Iron Nanoparticles Immobilized In Sba-15, Ahdee Bluma Zeidman

UNLV Theses, Dissertations, Professional Papers, and Capstones

Zero-valent iron nanoparticles (nZVI) have been studied as an option for soil remediation and water treatment for many years. The capability of nZVI to produce oxidation/reduction processes, depending on the reaction conditions, has attracted great interest with their major drawback being reactivity loss through agglomeration. The loss in nZVI surface area has been reported to be prevented through immobilization onto a porous media (e.g., SBA-15, MCM-41, or zeolites). In this work, a mesoporous silica structure (SBA-15) is used as an nZVI supporting material to enhance its reactivity and promote peroxymonosulfate (PMS) catalytic decomposition for the degradation of antibiotics in aqueous …

Abiotic, Biotic, And Bio-Enhanced Reduction Of Hexavalent Chromium, Chloroform And Co-Contaminants Using Nano-Scale Zero Valent Iron In Highly Contaminated Groundwater, Eduardo Robleto Martinez

UNLV Theses, Dissertations, Professional Papers, and Capstones

Investigations of groundwater in a former industrial perchlorate manufacturing site have shown high contamination with perchlorate, chlorate, nitrate, hexavalent chromium (Cr (VI)), and chloroform (CF) with levels greater than 3,000, 30,000, 300, 100, and 4 mg/L, respectively. Remediation efforts using biological reduction to desired contaminant levels at this site has been challenging due to high contaminant concentrations, and high total dissolved solids (TDS). Furthermore, removal of Cr(VI) and CF in the presence of nitrate, chlorate, and perchlorate has not been examined at the contaminated site. Nano-scale Zero-Valent-Iron (NZVI) has been effective at reducing groundwater contamination both with and without bacterial …

Carbon Management And Volatile Fatty Acid Production In Primary Clarifiers At A Wastewater Treatment Plant, Brittany Nicole Radke

UNLV Theses, Dissertations, Professional Papers, and Capstones

An increasing number of treatment plants are required to remove nutrients from domestic wastewater to lessen the impact of nutrient loading to water bodies. Enhanced Biological Phosphorus Removal (EBPR) is one of the processes commonly used to remove phosphorus from domestic wastewater. The presence of an adequate quantity of volatile fatty acids (VFA) in the wastewater influent to EBPR is important for process efficiency and stability. The objective of this research was to investigate the production of VFAs through fermentation of sludge in primary clarifiers as it related to improving nutrient removal, primarily targeting phosphorus.

The research tested, in full-scale, …

Application Of Data-Driven And Process-Based Modeling Approaches For Water Quality Simulation In Lakes And Freshwater Reservoirs, Ali Saber Sichani

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lakes and freshwater reservoirs often serve as the primary drinking and irrigation water sources for surrounding communities. They provide recreational and tourism opportunities, thereby promoting the prosperity of neighboring communities. Reliable estimates of water quality in lakes and reservoirs can improve management practices to protect water resources.

Seasonal water temperature and solar shortwave radiation variations, and their subsequent interactions with water column aquatic life, combined with seasonal variations of mixing intensity throughout the water column, result in variations of water quality constituents with depth during the annual cycle. The complexity of these variations entails the use of advanced water quality …

Utility Of Bench Scale Sand Tank Experiments At Assessing Permeable Reactive Barrier Design, Brandon Meier

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of this work was to evaluate the utility of bench scale sand tank experiments at assessing permeable reactive barrier (PRB) design. Our criteria for meeting this goal was that differences between PRB designs could be identified solely by measuring concentration in outflow from the sand tank models. For our PRB designs (funnel-and-gate, staggered wells, and parallel bars), numerical simulations clearly showed that PRB design had a quantifiable effect on outflow concentration, provided that the solute reacted with the PRB materials. Conversely, use of a conservative (non-reactive) solute did not allow us to discern between PRB design alternatives. Employing …

Utilization Of Remote Sensing Data For Estimation Of The Groundwater Storage Variation, Gaurang Mistry

UNLV Theses, Dissertations, Professional Papers, and Capstones

Groundwater is the most extracted raw material, with an average withdrawal rate of 982 km3 per year, where 70 percent of the total groundwater withdrawn is used for agriculture globally (Margat & van der Gun, 2013). With climate change and increased water demands in recent years, monitoring the changes in the groundwater storage is of the utmost importance. This thesis presents an analysis that determines the rates, trends, and directions where groundwater storage is going in Pakistan. It also correlates fluctuations in groundwater storage with variations in precipitation and agricultural productivity in the country. The overall objectives of this thesis …

Design And Preliminary Evaluation Of A Supercritical Carbon Dioxide Brayton Cycle For Solar Dish Concentrator Clean Energy Production, Danielle Nobles-Lookingbill

UNLV Theses, Dissertations, Professional Papers, and Capstones

As we move toward energy independence and more ambitious clean energy goals, solar energy research must push the efficiency limits of traditional energy generation systems. Increases in efficiency can be achieved by increasing the hot temperature of the power cycle. Recent research demonstrates the potential for increased efficiency and a vastly smaller component size when supercritical carbon dioxide Brayton power cycles are used. Concentrated solar and nuclear heat sources are capable of achieving the high working fluid temperatures needed for significant efficiency gains. This NSF EPSCoR funded, experimental research system is designed to exploit the uniquely immense solar irradiance of …

Static And Dynamic Quantitative Microbial Risk Assessment Of Potable Reuse Paradigms, Erfaneh Amoueyan

UNLV Theses, Dissertations, Professional Papers, and Capstones

In recent years, potable reuse applications have become more common due to population growth and increased water demand, especially in communities with limited or variable water resources. However, there are concerns about potential exposure to pathogens and chemical compounds in treated wastewater. Therefore, advanced wastewater treatment processes are of paramount importance in any potable reuse system. The overall aim of this study was to develop and implement static and dynamic QMRAs to compare public health risk in various potable reuse scenarios. Cryptosporidium, norovirus, adenovirus, and Salmonella were chosen as the target pathogens. The research evaluated the performance of full advanced …

Investigation Of Setting Time And Compressive Strength Of Ready-Mixed Concrete Blended With Returned Fresh Concrete, Negasi Niguse Gebremichael

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Center for Sustainable Transportation Infrastructure (CSTI), in its 2012 study, estimated that out of all the concrete leaving the plant, between 2% and 7% of concrete returns to the plant unused as a returned fresh concrete (RFC). Disposal of both the truck wash water and RFC is a growing concern for the industry. Most industry personnel contacted during the investigation, agree that reusing is superior to recycling of this substantial RFC economically and environmentally. This study will determine if the reuse of RFC in subsequent batches compromises the quality of newly blended concrete.

The effect of RFC on fresh …

Remote Sensing Of The Environmental Impacts Of Utility-Scale Solar Energy Plants, Mohammad Masih Edalat

UNLV Theses, Dissertations, Professional Papers, and Capstones

Solar energy has many environmental benefits compared with fossil fuels but solar farming can have environmental impacts especially during construction and development. Thus, in order to enhance environmental sustainability, it is imperative to understand the environmental impacts of utility-scale solar energy (USSE) plants. During recent decades, remote sensing techniques and geographic information systems have become standard techniques in environmental applications. In this study, the environmental impacts of USSE plants are investigated by analyzing changes to land surface characteristics using remote sensing. The surface characteristics studied include land cover, land surface temperature, and hydrological response whereas changes are mapped by comparing …

Stationary Nonimaging Concentrators – A Comprehensive Study And Design Improvements, Srikanth Madala

UNLV Theses, Dissertations, Professional Papers, and Capstones

Most places on our planet receive an annual average radiation between 800-1000 W/m2. In the man-made world, this radiation is largely incident on stationary structures such as buildings, roads, monuments, bridges etc. Moreover, in the natural world also, there are large tracts of barren land which can be put to good use given their solar energy potential. The vision of the current research is to concentrate all this available solar energy to a more readily usable form. Therefore, stationary nonimaging solar concentrator technologies are sought after. This dissertation work is an exhaustive research on the nonimaging concentrating mechanisms with stationary …

Development Of Solar Experiments With Remote Laboratory Capability For Engineering Education Of The Future, Otto Kyle Neidert

UNLV Theses, Dissertations, Professional Papers, and Capstones

Educating future engineers will be handled differently as this modern society has various methods of doing so and a plethora of knowledge to pursue. The availability of computers and internet has changed many things. A subject that is relevant in today’s world but not common to most people and some engineers is solar energy. As part of a grant from the National Science Foundation that was awarded to Louisiana State University (LSU), Florida State University (FSU), and the University of Nevada, Las Vegas (UNLV), the UNLV Center for Energy Research partnered with them to create solar application based learning modules. …

Chemical And Electronic Structure Of Surfaces And Interfaces In Cadmium Telluride Based Photovoltaic Devices, Douglas Arthur Duncan

UNLV Theses, Dissertations, Professional Papers, and Capstones

The surface and interface properties are of the upmost importance in the understanding, optimization, and application for photovoltaic devices. Often the chemical, electronic, and morphological properties of the films are empirically optimized, however when progress slows, a fundamental understanding of these properties can lead to breakthroughs. In this work, surfaces and interfaces of solar cell-relevant films are probed with a repertoire of X-ray analytical and microanalysis techniques including X-ray photoelectron (XPS), X-ray excited Auger electron (XAES), X-ray emission (XES) spectroscopies, and atomic force (AFM) and scanning electron (SEM) microscopies.

Silicon-based devices currently dominate the solar market, which is rather inflexible …

Simulation Of An Air Cooled Single-Effect Solar Absorption Cooling System With Evacuated Tube Collectors, Mohsen Jahandardoost

UNLV Theses, Dissertations, Professional Papers, and Capstones

Consistently increasing CO2 emission and ozone depletion from synthetic refrigerants are serious environmental issues challenging the scientific community. Absorption cooling systems give scope of utilizing low grade energy source for generating cooling effect. Solar energy is one of these low grade energy sources and with considering the fact that cooling demand increases with the intensity of solar radiation, solar refrigeration has been considered as a logical solution.

This thesis consists of two different simulation stages, in the first stage, a single effect lithium bromide absorption cooling system with constant cooling capacity is modeled and the effect of ambient and generator …

Designing, Building And Testing A Solar Thermoelectric Generation, Steg, For Energy Delivery To Remote Residential Areas In Developing Regions, Yacouba Moumouni

UNLV Theses, Dissertations, Professional Papers, and Capstones

New alternatives and inventive renewable energy techniques which encompass both generation and power management solutions are fundamental for meeting remote residential energy supply and demand today, especially if the grid is quasi-inexistent. Solar thermoelectric generators can be a cost-effective alternative to photovoltaics for a remote residential household power supply. A complete solar thermoelectric energy harvesting system is presented for energy delivery to remote residential areas in developing regions. To this end, the entire system was built, modeled, and then validated with LTspice simulator software via thermal-to-electrical analogy schemes. Valuable data in conjunction with two novel LTspice circuits were obtained, showing …

Alkali-~Activated Fly Ash Binders: Feasibility As A Sustainable Alternative To Ordinary Portland Cement For Pre-~Cast Systems, Kimberly Sierra

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fresh, load-dependent, transport, and durability properties of alkali-activated fly ash mortars were studied. The influences of activator concentration, solution-to-binder ratio, curing condition, activator type, and sodium silicate-to-total solution ratio on the properties of the studied alkali-activated mortars were examined. This study was divided in two phases. The first phase dealt with the use of sodium hydroxide as the sole activator. The second phase of the study was divided into two parts, both of which used a combination of sodium hydroxide and sodium silicate as the activator solution. Part I of phase II used elevated temperature curing conditions, whereas part II …

Development Of A Decision Support Framework For The Planning Of Sustainable Transportation Systems, Pankaj Maheshwari

UNLV Theses, Dissertations, Professional Papers, and Capstones

With the rapid increase in economic development throughout the world, there is stress on the resources used to support global economy, including petroleum, coal, silver, and water. Currently, the world is consuming energy at an unprecedented rate never seen before. The finite nature of such non-renewable natural resources as petroleum and coal puts pressure on the environmental system, and ultimately reduces the availability of resources for future generations. Hence, it is critical to develop planning and operational strategies that seek to achieve a sustainable use of existing natural resources.

With this motivation, this dissertation focuses to develop a decision support …

Impacts Of Ozone Dose And Empty Bed Contact Time On Total Organic Carbon Removal Through Ozone-Biological Activated Carbon Treatment, Ashley Selvy

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the face of climate change, pollution, and population growth, water scarcity has become a global threat. Many populations have witnessed their drinking water sources dwindle to an unsustainable level. These severe conditions have sparked interest in potable reuse as an increasingly viable alternative to typical ‘pristine’ drinking water sources. Currently, the California Division of Drinking Water (DDW) provides the most stringent requirements for reuse water quality. The best way to meet these standards is through the use of full advanced treatment (FAT), which consists of reverse osmosis (RO) and an advanced oxidation process (AOP). Alternative treatment trains composed of …

Spectroscopic Investigation Of The Chemical And Electronic Properties Of Chalcogenide Materials For Thin-Film Optoelectronic Devices, Kimberly Horsley

UNLV Theses, Dissertations, Professional Papers, and Capstones

Chalcogen-based materials are at the forefront of technologies for sustainable energy production. This progress has come only from decades of research, and further investigation is needed to continue improvement of these materials.

For this dissertation, a number of chalcogenide systems were studied, which have applications in optoelectronic devices, such as LEDs and Photovoltaics. The systems studied include Cu(In,Ga)Se2 (CIGSe) and CuInSe2 (CISe) thin-film absorbers, CdTe-based photovoltaic structures, and CdTe-ZnO nanocomposite materials. For each project, a sample set was prepared through collaboration with outside institutions, and a suite of spectroscopy techniques was employed to answer specific questions about the system. These …

Identification Of Long Term Changes And Evaluation Of The Relationships Among Streamflow Variability And Oceanic-Atmospheric Indices, Soumya Sagarika

UNLV Theses, Dissertations, Professional Papers, and Capstones

To examine the effects of climate variability on streamflow, this thesis presents a comprehensive analysis of the streamflow variability of the continental United States and its association with oceanic-atmospheric indices. First, the presence of trends with consideration of short term and long term persistence followed by shifts over the past years in the continental U.S. streamflow were analyzed by using the non-parametric tests: Mann Kendall and Pettitt. Second, the spatio-temporal relationships between seasonal streamflow variability of continental U.S. and sea surface temperatures (SST) and 500 mbar geopotential height (Z500) of the Pacific and Atlantic were established using the singular valued …

Development Of A Black-Box Transient Thermal Model For Residential Buildings, Andrew Cross

UNLV Theses, Dissertations, Professional Papers, and Capstones

Heavily populated metropolitan areas located in cooling-dominated climates, as are found in the Desert Southwest, pose a challenge to electrical utilities that service these areas. During the late afternoons of the summer months, residents of these metropolitan areas require larger than normal amounts of power to run their homes' air conditioning systems, at significant expense to the utilities. In the study reported here, interior temperature and power consumption data, accumulated over the course of a year and a half from seven houses within a Las Vegas neighborhood, are used to develop a predictive black-box statistical model for residential thermal transience. …

Power Optimization, Diagnostic Monitoring, And Modeling Of Photovoltaic System, Khalid Hurayb

UNLV Theses, Dissertations, Professional Papers, and Capstones

Photovoltaic (PV) solar energy has been sustaining a major growth rate over the last decade in many parts of the world. This steep growth has been driven by concern about climate change, the adoption of renewable portfolio standards, government incentives, and reduction in PV system costs. Recently, however, such large PV penetration into the electrical grid is cause a concern that might curb such a growth; namely, the incontrollable intermittency of power generated on cloudy days. Furthermore, conventional PV system configurations often do not harness the maximum power that is available under partial shading caused by clouds or shadows of …

Study Of Water Transport Phenomena On Cathode Of Pemfcs Using Monte Carlo Simulation, Karn Soontrapa

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation deals with the development of a three-dimensional computational model of water transport phenomena in the cathode catalyst layer (CCL) of PEMFCs. The catalyst layer in the numerical simulation was developed using the optimized sphere packing algorithm. The optimization technique named the adaptive random search technique (ARSET) was employed in this packing algorithm. The ARSET algorithm will generate the initial location of spheres and allow them to move in the random direction with the variable moving distance, randomly selected from the sampling range, based on the Lennard-jones potential of the current and new configuration. The solid fraction values obtained …

Post-Occupancy Energy Efficiency Evaluation Of A Leed Platinum Federal Government Facility, Theresa Tincher

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of this study was to gain a comprehensive understanding of the Leadership in Energy and Environmental Design (LEED®) certification system and its relevance to Federal policies, building codes, and building standards, develop experience with whole building energy modeling, and determine the actual post-occupancy energy usage as compared with developed model and design projections. This thesis hypothesized the U.S. Green Building Council's LEED rating system compared favorably to other policies, codes, and standards in use at the time, and the U.S. Bureau of Reclamations' LEED Platinum Lower Colorado Regional Office Green Building (LCROGB), located in Boulder City, Nevada, operated …

Evaluation Of Alternative Project Delivery Methods In Water And Wastewater Projects, Ruiko Maharjan

UNLV Theses, Dissertations, Professional Papers, and Capstones

The United States (U.S.) is facing significant challenges in addressing aging water infrastructure. Most of the drinking water infrastructure is reaching the end of their useful lives. The American Water Works Association (AWWA) estimated that it will cost about $1 trillion to repair or replace drinking water pipes. Over the next 20 years, it will cost about $298 billion to fix or expand pipes of the nation's wastewater and storm-water systems (AWWA, 2012). Owners, engineers, and contractors are using Alternative Project Delivery (APD) methods - e.g., Design-Build Construction Management-at-Risk Construction Management/General Contractor- to build water and wastewater projects in order …