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Articles 4171 - 4200 of 5701

Full-Text Articles in Engineering

The Electrochemical Behavior Of Daunorubicin Hydrochloride On Galactic Disk Electrode And Its Reaction With Bsa, Hong-Fen Cheng, Yong Zhang, Jie Liu, Yan-Mei Liu Aug 2009

The Electrochemical Behavior Of Daunorubicin Hydrochloride On Galactic Disk Electrode And Its Reaction With Bsa, Hong-Fen Cheng, Yong Zhang, Jie Liu, Yan-Mei Liu

Journal of Electrochemistry

This article used the linear sweep voltammetry and the circulation voltammetry to study the electrochemical behavior of daunorubicin hydrochloride on galactic disk electrode and its electrode reaction with BSA.Also it studied the interaction of daunorubicin hydrochloride with BSA.The results showed that daunorubicin hydrochloride has a sensitive reduction peak at -0.64 V(vs. SCE) in pH 6.50 Britton-Robinson buffer.The valus of reductions peak current reduced by the addition of BSA to the above mentioned solution.A new electrochemical determination method of bovine serum albumin was developed based on the interaction of daunorubicin hydrochloride with BSA.Furthermore,under the optimized condition,the decrease of the reduction peak …

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Redox State Of Polyaniline Nanodot And Its Coulomb Staircase Effect, Jian-Zhang Zhou, Shao-Huang Weng, Zhong-Hua Lin Aug 2009

Redox State Of Polyaniline Nanodot And Its Coulomb Staircase Effect, Jian-Zhang Zhou, Shao-Huang Weng, Zhong-Hua Lin

Journal of Electrochemistry

Polyaniline nanodot array had been fabricated in AAO template with potentiostatic method and the I~V characteristics of nanodots with different redox states were measured by conducting atomic force microscope (C-AFM) in atmosphere at room temperature. We found that only nanodots in partial oxidation state exhibit coulomb staircase in the I~V curves,while those in the full oxidation state and reduced state do not. The above phenomena were discussed preliminarily.

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Electrochemical Reduction Of Nitrobenzene In Different Ionic Liquids, Jun-Li Fan, Wei-Lin Ye, Rong Wang, Li-Qun Xu, Xia-Qin Wu Aug 2009

Electrochemical Reduction Of Nitrobenzene In Different Ionic Liquids, Jun-Li Fan, Wei-Lin Ye, Rong Wang, Li-Qun Xu, Xia-Qin Wu

Journal of Electrochemistry

Electrochemical reduction of nitrobenzene at glassy carbon electrode in different ionic liquids,such as N-methylimidazolium-p-toluene sulfonic acid ([Mim][PhSO3]) and ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim][PF6]) have been investigated by cyclic voltammetry. Experimental results showed that only a cathodic current peak was observed in [Mim][PhSO3],which is a diffusional controlled irreversible reaction. And two pairs of current peaks were obtained in [Bmim][PF6] in the same potential range,indicating showed that the reduction products of nitrobenzene were different in different ionic liquids.

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Electrochemical Studies On The Ionic Charge Transfer Properties Of The Oxygen Vacancy Defects In The Oxide Films Formed On Titanium, De-Sheng Kong, Hai-Yan Liu, Wen-Juan Fan, Wen-Hua Lv, Zhang-Yu Yu, Yuan-Yuan Feng Aug 2009

Electrochemical Studies On The Ionic Charge Transfer Properties Of The Oxygen Vacancy Defects In The Oxide Films Formed On Titanium, De-Sheng Kong, Hai-Yan Liu, Wen-Juan Fan, Wen-Hua Lv, Zhang-Yu Yu, Yuan-Yuan Feng

Journal of Electrochemistry

The ionic charge transfer properties of the oxygen vacancy point defects in TiO2 films formed on titanium were studied in 1.0 mol·L-1 HClO4 solution with cyclic voltammetry,potentiostatic polarization,galvanostatic reduction and capacitance measurements. The measured capacitance data were analyzed based on the Mott-Schottky equation and Einstein equation. Based on the different response times to the changes of the applied electric field between the ionic and the electronic charge transfers,the diffusion coefficient of the point defects in the anodic oxide film on titanium was estimated. It was shown that the passive potential region for titanium in 1.0 mol·L-1 …

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Crystallization And Electrochemical Corrosion Behaviors Of Amorphous And Nanocrystalline Fe-Based Alloys, Xiang Li, Biao Yan, Peng Dong Aug 2009

Crystallization And Electrochemical Corrosion Behaviors Of Amorphous And Nanocrystalline Fe-Based Alloys, Xiang Li, Biao Yan, Peng Dong

Journal of Electrochemistry

In this study,amorphous Fe78Si13B9 and Fe73.5Si13.5B9Nb3Cu1 ribbons were prepared by the chill block melt-spinning process and nanocrystalline Fe73.5Si13.5B9Nb3Cu1 ribbons were obtained by annealing. The amorphous ribbons and their crystallization processes were identified by differential scanning calorimeter (DSC) and X-ray diffraction (XRD). A comparative study of the electrochemical corrosion behaviors of  Fe78Si13B9 and Fe73.5Si13.5B9Nb3Cu1 amorphous and nanocrystallized alloys was performed by linear polarization method …

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Synthesis And Characterization Of Sulfur-Carbonnanotubes As Cathode Of Lithium/Sulfur Rechargeable Battery, Rui Du, Zhong-Zhi Yuan Aug 2009

Synthesis And Characterization Of Sulfur-Carbonnanotubes As Cathode Of Lithium/Sulfur Rechargeable Battery, Rui Du, Zhong-Zhi Yuan

Journal of Electrochemistry

A carbon-containing composite was synthesized by heating element sulfur and carbon nanotubes. The sulfur-carbonnanotube composites were characterized by X-ray diffraction, SEM, Brunauer-Emmett-Teller. The electrochemical property was characterized by cyclic voltammetry,constant current charge and discharge. It was revealed that the sulfur-carbonnanotube cathode 2016-type coin cells exhibited a good electrochemical property with the initial dicharge specific capacity up to 680 mAh/g and a stable capacity approximately 500 mAh/g after 30 cycle numbers.

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Capacitor Property Of Pani/Mwcnt Electrode In Li2So4 Solution, Wen-Bo Cong, Xiao-Shu He Aug 2009

Capacitor Property Of Pani/Mwcnt Electrode In Li2So4 Solution, Wen-Bo Cong, Xiao-Shu He

Journal of Electrochemistry

Polyaniline/multi-walled carbon nanotubes (PANI/MWCNT) composites synthesized by chemical oxidation method were characterized by scanning electron microscopy (SEM),X-ray diffraction (XRD) and IR techniques. In 1mol/L Li2SO4 neutral solution,the electrochemical performance of the composites electrode was investigated by cyclic voltammetry,galvanostatic charge-discharge tests and ac impedance spectroscopy. The results showed that the composites electrode performed well in 1mol/L Li2SO4 solution,the specific capacitance reached 412F/g at 5 mA/cm2. The composites electrode possessed better capability of high current than that of PANI electrode,the specific capacitance kept at 318 F/g at 50mA/cm2 and was 77.2% of that …

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Tungstate/Pertungstate System Cathodic Indirect Oxidation To Synthesis Hydrophobic Monascus Yellow Colorant, Wen-Jian Chen, Xue-Hong Huang, Zhen Chen, Sheng-Bo Ke, You-Zhen Lin Aug 2009

Tungstate/Pertungstate System Cathodic Indirect Oxidation To Synthesis Hydrophobic Monascus Yellow Colorant, Wen-Jian Chen, Xue-Hong Huang, Zhen Chen, Sheng-Bo Ke, You-Zhen Lin

Journal of Electrochemistry

Using SBS-g-(AA/StSO3Na)/SBS-g-DMAEMA Bipolar Membrane as a separator between the cathode and anode chambers in the electrolysis cell,the optimum conditions of deoxidization of oxygen in cathode were obtained through orthogonal experiment. Then using tungstate/pertungstate as media to indirect electrooxidate hydrophobic monascus red colorant to prepare hydrophobic monascus yellow colorant in cathode. The experiment results show the average current efficiency of cathode was up to 72.39% under the following conditions:that graphite as electrode,10% sulfuric acid as anode electrolyte,0.5 g·L-1 hydrophobic monascus red colorant solution as cathode electrolyte,tungstate concentration:15 mmol/L,pH=3,flow rate of oxygen:65 cm3/min,electrolyze 2 h under the …

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Electrocatalytic Oxidation Of Glucose On Cnt/Nanocrystlline Tio2-Pt Complex Film Electrode In Ionic Liquids, Dao-Bao Chu, Long-Wu Zha, Shu-Xi Wang, Jian Wang, Ying Xiao, Yuan-Yuan Hou, Jian-Guo He, Xue-Jiao Zhang Aug 2009

Electrocatalytic Oxidation Of Glucose On Cnt/Nanocrystlline Tio2-Pt Complex Film Electrode In Ionic Liquids, Dao-Bao Chu, Long-Wu Zha, Shu-Xi Wang, Jian Wang, Ying Xiao, Yuan-Yuan Hou, Jian-Guo He, Xue-Jiao Zhang

Journal of Electrochemistry

Using ionic liquid [EMI]BF4 as the electrolyte,the electrocatalytic oxidation of glucose on carbon nanotubes/nanocrystlline TiO2 film loaded on Pt (CNT/nanoTiO2-Pt) complex film electrode was investigated by cyclic voltammetry. The results found that the CNT/nanoTiO2-Pt complex electrode had high catalytic activity to the electrochemical oxidation of glucose in ionic liquids and the oxidation potential was -0.46 V. The best effect of glucose oxidation was obtained with the volume ratio of ionic liquid to water being 3:1. The process of electrodic reaction process was concentration polarization controlled.

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Electrochemical Properties Of Ru-P/Mwcnts-Dhp/Gc Electrode, Miao-Jing Chen, Bao-Yi Lu, Wen-Jie Mei, Hong Li Aug 2009

Electrochemical Properties Of Ru-P/Mwcnts-Dhp/Gc Electrode, Miao-Jing Chen, Bao-Yi Lu, Wen-Jie Mei, Hong Li

Journal of Electrochemistry

Electrochemical properties of a novel monoruthenated porphyrin [Ru(phen)2(MPyTMPP)Cl]+ (where phen =1,10-phenanthroline,MPyTMPP =5-(3-pyridyl)-10,15,20-tris-(4-methylphenyl) porphyrin) on a multi-walled carbon nanotubes (MWCNTs) modified glassy carbon (GC) electrode with the participation of dihexadecyl phosphate (DHP) have been investigated by using cyclic voltammetry,differential pulse voltammetry,UV-Visible spectroscopy and fluorescence spectroscopy. It is found that [Ru(phen)2(MPyTMPP)Cl]+ has the ability to adsorb strongly onto the MWCNTs-DHP modified GC electrode and exhibits a pair of redox waves controlled by surface electrochemical process. DHP dispersed on the MWCNTs/GC electrode can facilitate the ruthenium complex to adsorb onto the MWCNTs-DHP surface. A new complex is generated by the …

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Ellipsometric Study On Colored Electroplating Of Cuprous Oxide On Ni Substrate, Xue-Song Feng, Jing-Lei Lei, Ai-Xiang Chen, Wan-Shan Yin, Ling-Jie Li, Sha Zheng, Hui Zhao, Shao-Yan Pan Aug 2009

Ellipsometric Study On Colored Electroplating Of Cuprous Oxide On Ni Substrate, Xue-Song Feng, Jing-Lei Lei, Ai-Xiang Chen, Wan-Shan Yin, Ling-Jie Li, Sha Zheng, Hui Zhao, Shao-Yan Pan

Journal of Electrochemistry

The colored Cu2O coating was electroplated on Ni substrate to meet the decorative requirements. Results of X-ray photoelectron spectroscopy (XPS) indicate the coating consisting of Cu2O. Images of scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) show that the Cu2O coating is smooth and uniform,and covers the Ni substrate wholly. Ellipsomtric measurements for Cu2O coatings with various electroplating time were carried out. Using a 4-layer model of "Air-Cu2O layer-interphase-Ni" ,the interphase was modeled with the graded effective medium approximation (EMA),the ellipsomtric data were deconvoluted and the Cu2O …

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Doppler Broadening Analysis Of Steel Specimens Using Accelerator Based In Situ Pair Production, V. Makarashvili, Douglas P. Wells, Ajit K. Roy Aug 2009

Doppler Broadening Analysis Of Steel Specimens Using Accelerator Based In Situ Pair Production, V. Makarashvili, Douglas P. Wells, Ajit K. Roy

Mechanical Engineering Faculty Research

Positron Annihilation Spectroscopy (PAS) techniques can be utilized as a sensitive probe of defects in materials. Studying these microscopic defects is very important for a number of industries in order to predict material failure or structural integrity. We have been developing gamma‐induced pair‐production techniques to produce positrons in thick samples ( ∼4–40 g/cm2, or ∼0.5–5 cm in steel). These techniques are called ‘Accelerator‐based Gamma‐induced Positron Annihilation Spectroscopy’ (AG‐PAS). We have begun testing the capabilities of this technique for imaging of defect densities in thick structural materials. As a first step, a linear accelerator (LINAC) was employed to produce photon beams …

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Characterization And Enhancement Of Sensing Properties Of Piezoelectric Materials With Applications To Vibration Suppression, Siddharth Aphale Aug 2009

Characterization And Enhancement Of Sensing Properties Of Piezoelectric Materials With Applications To Vibration Suppression, Siddharth Aphale

All Theses

This thesis undertakes the study of piezoelectric properties of polymer-based fabric and film sensors. An enhancement in piezoelectric properties of such sensors, as noted through earlier work, is observed with increasing weight ratios of nanomaterials dispersed in the polymer matrix. A comprehensive mathematical model using cantilever beams is developed to analyze this enhancement both qualitatively and quantitatively. An experimental setup is also developed to implement the proposed real time signal processing necessary to collect required data towards the characterization. In order to distinguish piezoelectric materials from other materials, study of the frequency response of developed fabric sensors to periodic chirp …

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On The Modeling Of Energy Harvesters And Analysis Of Their Response Under Time-Varying Frequency Excitations, Thiago Seuaciuc-Osorio Aug 2009

On The Modeling Of Energy Harvesters And Analysis Of Their Response Under Time-Varying Frequency Excitations, Thiago Seuaciuc-Osorio

All Theses

Energy harvesting is a process by which otherwise wasted ambient energy can be captured and transformed into a useful form. Historical examples of this concept include windmills, sailing ships, and waterwheels. Modern technologies and current energy needs have brought this same concept to a smaller scale wherein small wireless devices with minute energy consumption can be operated autonomously. Today, many critical electronic devices, such as health-monitoring sensors, pace makers, spinal stimulators, electric pain relievers, etc. require minimal amounts of power to function, which permits utilizing energy from their environment to power them. By exploiting the ability of active materials and …

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Use Of Orthogonal Arrays For Efficient Evaluation Of Geometric Designs For Reducing Vibration Of A Non-Pneumatic Wheel During High-Speed Rolling, William Rutherford Aug 2009

Use Of Orthogonal Arrays For Efficient Evaluation Of Geometric Designs For Reducing Vibration Of A Non-Pneumatic Wheel During High-Speed Rolling, William Rutherford

All Theses

During high speed rolling of a non-pneumatic wheel, vibration may be produced by the interaction of collapsible spokes with a shear deformable ring as they enter the contact region, buckle and then snap back into a state of tension. In the present work, a 2D planar finite element model with geometric nonlinearity and explicit time-stepping is used to simulate rolling of the non-pneumatic wheel. Vibration characteristics are measured from the FFT frequency spectrum of the time-signals of perpendicular distance of marker nodes from the virtual plane of the spoke, thickness change in the ring between spokes, and ground reaction forces. …

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Development Of A Rigid Ring Tire Model And Comparison Among Various Tire Models For Ride Comfort Simulations, Norm Frey Aug 2009

Development Of A Rigid Ring Tire Model And Comparison Among Various Tire Models For Ride Comfort Simulations, Norm Frey

All Theses

One vehicle subassembly that is of great importance to automobile manufacturers for tuning final vehicle performance is the pneumatic tire. Pneumatic tires present themselves as unique tuning tools as they 1) are the sole link between the roadway surface and the integrated vehicle suspension, chassis and steering systems, and 2) provide a wide range of tunability over many vehicle performances, including handling (steering feel as well as chassis dynamics), traction (braking, driving, and cornering), and ride comfort (roadway isolation). Therefore the vehicle manufacturing industry continues to research and refine various aspects of tire modeling to improve up-front integrated tire/vehicle CAE/CAD …

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Survey Of Concurrent Engineering Environments And The Application Of Best Practices Towards The Development Of A Multiple Industry, Multiple Domain Environment, Jonathan Osborn Aug 2009

Survey Of Concurrent Engineering Environments And The Application Of Best Practices Towards The Development Of A Multiple Industry, Multiple Domain Environment, Jonathan Osborn

All Theses

This thesis investigates the best practices of fifteen existing Concurrent Engineering Environments (CEE). A CEE is defined as any environment, from physical to virtual, designed to facilitate concurrent engineering with multiple domain experts real time. All existing environments surveyed have been focused on the aerospace industry showing significant reductions in design time and cost. I have identified hardware, software, and peopleware as three major classifications as well as sixteen subcategories with which to compare the different CEEs. The success in reducing time and cost of designs seen in the aerospace industry with the introduction of CEEs can and should be …

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Dynamic Finite Element Simulation Of Ultrasonic Consolidation, Daniel Mccullough Aug 2009

Dynamic Finite Element Simulation Of Ultrasonic Consolidation, Daniel Mccullough

All Theses

Ultrasonic Consolidation (UC) is a promising solid state rapid manufacturing process that provides the ability to create functional, multilayered, and often geometrically complex parts. This thesis seeks to address one of the primary obstacles faced when using the process, namely the apparent build height limit encountered when using UC to construct high aspect ratio specimens. A fully transient, three dimensional Finite Element model is created to study the dynamic behavior of an ultrasonically consolidated part during the UC process. The model is used to find the cause of bond failure at the build height limit and a potential way to …

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Predictive Energy Management In Smart Vehicles: Exploiting Traffic And Traffic Signal Preview For Fuel Saving, Behrang Asadi Aug 2009

Predictive Energy Management In Smart Vehicles: Exploiting Traffic And Traffic Signal Preview For Fuel Saving, Behrang Asadi

All Theses

This master thesis proposes methods for improving fuel economy and emissions of vehicles via use of future information of state of traffic lights, traffic flow, and deterministic traffic flow models.
The first part of this thesis proposes use of upcoming traffic signal information
within the vehicle's adaptive cruise control system to reduce idle time at stop lights and lower fuel use. To achieve this goal an optimization-based control algorithm is formulated for each equipped vehicle that uses short range radar and traffic signal information predictively to schedule an optimum velocity trajectory for the vehicle. The objectives are timely arrival at …

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Development And Integration Of Geometric And Optimization Algorithms For Packing And Layout Design, Santosh Tiwari Aug 2009

Development And Integration Of Geometric And Optimization Algorithms For Packing And Layout Design, Santosh Tiwari

All Dissertations

The research work presented in this dissertation focuses on the development and application of optimization and geometric algorithms to packing and layout optimization problems. As part of this research work, a compact packing algorithm, a physically-based shape morphing algorithm, and a general purpose constrained multi-objective optimization algorithm are proposed. The compact packing algorithm is designed to pack three-dimensional free-form objects with full rotational freedom inside an arbitrary enclosure such that the packing efficiency is maximized. The proposed compact packing algorithm can handle objects with holes or cavities and its performance does not degrade significantly with the increase in the complexity …

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The Effects Of Combined Compression And Aging On The Properties Of Glassy Polycarbonate, Kyle W. Strabala Aug 2009

The Effects Of Combined Compression And Aging On The Properties Of Glassy Polycarbonate, Kyle W. Strabala

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Physical aging and plastic flow are known to cause changes in the properties of glassy polycarbonate (PC). Although the individual effects of physical aging and plastic flow have been studied, the combined mechanical and thermal effects have yet to be evaluated for PC at large plastic strains. This work is the first characterization of the combined effects in PC of large plastic flow followed by thermal (physical) aging. To conduct this study, samples were prepared with different extents of plastic compressive strain, up to approximately 50% engineering strain, followed by thermal aging up to 135 °C, with various …

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Multiscale Modeling Of Glass Fiber Reinforced Viscoelastic Polymers Subjected To Impact Loads, Victor Ferreira Teixeira Jun 2009

Multiscale Modeling Of Glass Fiber Reinforced Viscoelastic Polymers Subjected To Impact Loads, Victor Ferreira Teixeira

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

New applications for polymer composite materials are occurring at a rapid pace today. These include structural components in the energy, transportation, and biomedical fields.  Many if not all of these new applications will require that part performance is insured with some degree of sustainable damage.  With the growth in the use of composite structures comes the necessity of improved methodologies that can predict more accurately the life and serviceability conditions of composite parts. Damage mechanics in two-phase composite materials is a very complex problem that has challenged researchers for many years. However, most of the available models perform only a …

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Flexible Electronics Using Ion Implantation To Adhere Polymer Substrate To Single Crystal Silicon Substrate, Terry L. Alford, Douglas C. Thompson Jr., Hyunchul Kim, Michael A. Nastasi, James W. Mayer, Daniel Adams Jun 2009

Flexible Electronics Using Ion Implantation To Adhere Polymer Substrate To Single Crystal Silicon Substrate, Terry L. Alford, Douglas C. Thompson Jr., Hyunchul Kim, Michael A. Nastasi, James W. Mayer, Daniel Adams

Department of Mechanical and Materials Engineering: Faculty Publications

An electronic apparatus uses a single crystalline silicon Substrate disposed adjacent to a flexible substrate. The electronic apparatus may be a flexible flat panel display, or a flexible printed circuit board. The flexible substrate can be made from polymer, plastic, paper, flexible glass, and stainless steel. The flexible substrate is bonded to the single crystalline substrate using an ion implantation process. The ion implantation process involves the use of a noble gas Such as hydrogen, helium, Xenon, and krypton. A plurality of semiconductor devices are formed on the single crystalline silicon Substrate. The semi conductor devices may be thin film …

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Me-Em Enewsbrief, June 2009, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University Jun 2009

Me-Em Enewsbrief, June 2009, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University

Department of Mechanical and Aerospace Engineering eNewsBrief

No abstract provided.

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Effect Of Liquid Dispersion On Corrosion Behavior Of Metals In Gas/Liquid/Solid Multiphase Corrosion Systems, Jing Jiang, Jia Wang May 2009

Effect Of Liquid Dispersion On Corrosion Behavior Of Metals In Gas/Liquid/Solid Multiphase Corrosion Systems, Jing Jiang, Jia Wang

Journal of Electrochemistry

Liquid dispersion,described by the parameters of gas/liquid/solid three-phase boundary(TPB) zone of dispersed liquid on a metal surface,is an important property of liquid state influencing corrosion behavior of metals in gas/liquid/solid multiphase corrosion systems.In our paper,the characterisation of cathodic oxygen reduction process in TPB zone was discussed,and a model describing the cathodic process of TPB zone was developed.On this basis,the relationship between the cathodic limiting current and the TPB parameters was studied,and the simulation results were in good agreement with the experimental data.The role of liquid dispersion in atmospheric and sandy soil corrosion systems was also simulated.

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Electrodeposition Of Al On Magnesium Alloy In Ionic Liquid, Wen-Ta Tsai, Shu-You Chen, Mu-Huan Zhuang, Jeng-Kuei Chang, Yi-Wen Sun May 2009

Electrodeposition Of Al On Magnesium Alloy In Ionic Liquid, Wen-Ta Tsai, Shu-You Chen, Mu-Huan Zhuang, Jeng-Kuei Chang, Yi-Wen Sun

Journal of Electrochemistry

Electrodeposition of a metallic aluminum on a magnesium alloy in acidic aluminum chloride-1-ethyl-3-methylimidazolium chloride ionic liquids(AlCl3-EMIC) was investigated.The effects of current density and AlCl3 content in the ionic liquid on the electrodeposition behavior were studied.The results showed that aluminum could be successfully electrodeposited on the AZ91D substrate.At-0.2 V,the ionic liquid containing 60 m/o AlCl3 was optimum for Al electrodeposition.The current efficiency was higher if electrodeposition was performed at a lower applied current density.The existence of Al coating could caused a substantial increase in open circuit potential,reducing the susceptibility of Mg alloy to corrosion.The results of electrochemical …

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Electrochemical Characteristics Of Vitaminb6 At Polybromocresol Green Modified Electrode, Jun Yao, Jiang-Yuan Li, Yang Luo May 2009

Electrochemical Characteristics Of Vitaminb6 At Polybromocresol Green Modified Electrode, Jun Yao, Jiang-Yuan Li, Yang Luo

Journal of Electrochemistry

Electrochemical characteristics of VB6 were investigated at PBG modified electrode by Cyclic voltammetry and linear sweep voltammetry.The VB6 produced an irreversible oxidation peak at 0.978 V(Vs.SCE) in HAc-NaAc(pH=4.0) buffer solution over the potential range of 0.7 to 1.2 V.The electron number,the proton number,the transfer coefficient were determined to be 1,1 and 0.37,respectively.The oxidation peak currents of VB6 versus its concentration showed a linear relationship in the concentration range of 1×10-3~2×10-5mol/L with the correlation coefficient of 0.9967 and the detection limit of 2×10-6mol/L.The recovery was 100.06%.

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Corrosion Performance Of Epoxy Coatings By Chemical Modification With Silanes, Liang Liu, Wei-Gang Ji, Ji-Ming Hu, Jian-Qing Zhang, Chu-Nan Cao May 2009

Corrosion Performance Of Epoxy Coatings By Chemical Modification With Silanes, Liang Liu, Wei-Gang Ji, Ji-Ming Hu, Jian-Qing Zhang, Chu-Nan Cao

Journal of Electrochemistry

The improvement of corrosion performance of epoxy coatings by modification with "active" and "non-active" silanes is presented."Active" silanes are defined as ones having functional groups that can react with the epoxy groups in the epoxy resin,usually amino-silanes."Non-active" silanes are defined as ones not reacting with the epoxy groups,but can react with the hydroxyl groups in the epoxy backbone by the condensation reactions under the catalysis of organic tin compounds.The FTIR results showed that both the "active" and "non-active" silanes had been successfully grafted onto the epoxy resin.Electrochemical impedance spectroscopy(EIS) and accelerated corrosion test(Machu test) showed that the corrosion performance of …

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Complex Of 3-Amino-1,2,4-Triazole And Na2Wo4 As An Inhibitor For Brass Corrosion, Qun-Jie Xu, Chun-Xiang Li, Yu-Hong Ni, Guo-Ding Zhou May 2009

Complex Of 3-Amino-1,2,4-Triazole And Na2Wo4 As An Inhibitor For Brass Corrosion, Qun-Jie Xu, Chun-Xiang Li, Yu-Hong Ni, Guo-Ding Zhou

Journal of Electrochemistry

AC impedance and polarization methods were used to study the inhibition effect of ATA and the complex of ATA and Na2WO4 for brass corrosion in 3% NaCl solution.The results indicated that ATA had inhibition effect for brass corrosion.ATA showed the best inhibition effect for brass corrosion at the ATA concentration of 7.5 mg·L-1,and the inhibition efficiency was 87.46%.At the ATA concentration of 7.5 mg·L-1 and at the Na2WO4 concentration of 0.15 mg·L-1,the complex showed optimum inhibition effect for brass corrosion,and also showed synergistic effect and the inhibition efficiency reached …

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Electrode Of Metallic Oxides Coated Titanium With Interlayer, Yi Tang, Li-Kun Xu, Yong-Lei Xin, Jun-Tao Wang, Ping Long May 2009

Electrode Of Metallic Oxides Coated Titanium With Interlayer, Yi Tang, Li-Kun Xu, Yong-Lei Xin, Jun-Tao Wang, Ping Long

Journal of Electrochemistry

Various Ti/IrRuSn,Ti/IrTa/IrRuSn and Ti/IrTaSn/IrRuSn oxide electrodes were prepared by sol-gel method.The surface morphology and microstructure were analysed with FESEM and XRD.The electrochemical activity and stability were investigated using electrochemical technologies including chlorine and oxygen evolving potential measurements,cyclic voltammetry,accelerated life test,and alternative electrolysis.The results indicate that the electrodes with interlayers present more cracks on the surface and a little bigger average grain size,with particles of different shapes precipitated in the cracks.The electroactive sites are increased and the selectivity for the chlorine evolving reaction is enhanced,but the current efficiency for the chlorine production is somewhat lowered by the addition of different interlayers.The …

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