Engineering Commons^™

The Accelerated Test Of Simulated Atmospheric Corrosion And The Rust Evolution Of Low Carbon Steel, Jun-Hua Dong, Wei Ke

Journal of Electrochemistry

It has been set up an accelerated method of simulating to atmospheric corrosion by using wet/dry alternate test.The rust evolution rule of mass change vs time(in logarithmic coordinate) of low carbon steel under this test shows two linear sections with different slopes,in which the rust evolution transition in weight change corresponds to the compactness transition and crystallization transition during the rust layer growth.It has found that the rust evolution rule of low carbon steel in Wanning exposure site correlates to the rust evolution rule obtained by simulating the coastal atmospheric corrosion test,and the rust evolution rule of low carbon steel …

Investigation Of Electrochemical Noise In The Crevice Corrosion Of Q235 Carbon Cteel, Qian Hu, Yu-Bing Qiu, Xing-Peng Guo

Journal of Electrochemistry

The crevice corrosion behavior of Q235 carbon steels in a NaHCO₃+NaCl solution was investigated by electrochemical noise(EN) and electrochemical impedance spectroscopy(EIS).Three stages of crevice corrosion including the induction,the rapid transform and the stable development could be clearly distinguished.The characteristics of the electrochemical noise and the noise resistance Rn showed remarkable differences at each stage.The electrode area ratio(r) of outside to inside the crevice had a significant influence in the development of crevice corrosion.The time of the induction stage increased with increasing r.However,under the stable development stage of the crevice corrosion,the surface outside the crevice was at an active …

Effect Of Naphthalene Water Reducer On Corrosion Behavior Of Reinforcing Steel In Concrete, Yu-Ming Tang, Jie Zhang, Yu Zuo

Journal of Electrochemistry

The influence of naphthalene water reducer on corrosion behavior of reinforcing steel in concrete was studied by the methods of corrosion potential measurement,linear polarization and EIS test.The values of concrete resistance(Rc) and polarization resistance(Rp) of the samples with naphthalene water reducer were higher than those without naphthalene water reducer,especially in the concrete with 0.2 percent naphthalene water reducer.A suitable amount of water reducer can improve the pore structures of concrete,increase the concrete compactness and impermeability,and decrease corrosion rate of rebars in concrete.

Effect Of Electrochemical Property Of Uns J91450 Stainless Steel On Stress Corrosion Cracking In Hydrogen Sulfide Solutions, Zhi-Yong Liu, Chao-Fang Dong, Xiao-Gang Li, Li-Xian Wang

Journal of Electrochemistry

Effect of electrochemical behaviours on stress corrosion cracking(SCC) of UNS J91450 stainless steel in hydrogen sulfide environment was investigated using slow-strain-rate test(SSRT) and electchemial techniques.Results show that UNS J91540 stainless steel was susceptible to SCC in varying H₂S solutions,and the SCC susceptibility reduced with the increase of pH value.The electrochemical property plays an important role in the SCC occurrence,as a combined effect of hydrogen embritlement and anodic dissolution at SCC cracktip at open circuit potential.In the solution with a lower pH the hydrogen revolution was intensive and the cracktip anodic dissolution was weaker,however,in the higher pH solution the …

Developments Of Scanning Electrochemical Probes And Their Applications In Studying Of Localized Corrosions, Chang-Jian Lin, Yan Li, Bin Lin, Rong-Gang Hu, Min Zhang, Xiang-Dong Zhuo, Rong-Gui Du

Journal of Electrochemistry

The electrochemical inhomogeneities always exist at the interface of metal/solution,and play an important and often controlling role in localized corrosion of metals in a given environment.It is necessary to develop in situ imaging techniques for further studying the electrochemical and environmental inhomogeneities at the interface of metal/solution for the localized corrosion system.In this paper,various techniques with spatial resolution,such as scanning micro reference electrode(SMET),scanning electrochemical microscope(SECM),atomic force microscope(AFM),and scanning Kelvin probe(SKP),and their applications in corrosion studies were briefly reviewed.The chemical probes and array electrode have been developed.It was concentrated to describe our newly developed techniques of the scanning electrochemical probes,including SMET …

Preparation And Electrochemical Properties Of Layered Manganese Oxide(Li-Birnessite Type), Xing-Kang Huang, Hai-Tao Chang, Jian-Long Gan, Qing-Shun Zhang, Hong-Jun Yue, Dong-Ping Lv, Yong Yang

Journal of Electrochemistry

Layered Li-birnessite was prepared by means of oxidizing Mn²⁺ with O₂ gas in alkaline media.The as-prepared sample was characterized by scanning electron microscopy(SEM), X-ray diffraction(XRD), BET and thermogravimetric/diffenential thermal analysis(TG/DTA) techniques. The electrochemical properties of the material were also investigated. The results show that such a Li-birnessite consists of well-crystallized spherical particles with an interlayer distance of 0.70 nm. The Li-birnessite delivered a high discharge capacity of 203 mAh/g at a rate of 0.2 C(40 mA/g), and had good rate capability as well.

Electrochemical Behavior Of Mg-Li Electrodes In Nacl Solution, Lin Wu, Yan-Zhuo Lv, Xue Cao, Gui-Ling Wang, Dian-Xue Cao

Journal of Electrochemistry

The Mg-Li electrodes containing 8.5% and 14% Li were prepared using an induction melting method. Their electrochemical behavior in NaCl solution was investigated by means of potentiodynamic polarization, potentiostatic oxidation,electrochemical impedance technique and mass-loss measurements. The morphology of the electrodes after discharge was examined using scanning electron microscopy. The Mg-14Li electrode showed more negative open circuit potential and higher discharge current density than Mg-8.5Li electrode. The oxidation products of Mg-14Li loosely attached on the electrode surface and peeled off easily. The Mg-8.5Li exhibited higher utilization efficiency. Both electrodes gave higher utilization efficiencies when discharged at lower anodic potential.

Electrochemical Performance Of The Exfoliated Graphite Containing Sulfur Cathode Material For Lithium Sulfur Battery, Ke-Guo Yuan, Wei-Kun Wang, Zhong-Bao Yu, An-Bang Wang

Journal of Electrochemistry

The exfoliated graphite containing sulfur cathode material was prepared by the high temperature sulfur gas diffusion adsorption method.This cathode material could obtain an initial discharge specific capacity 972 mAh·g^-1,capacity retention ratio 78% and cycling efficiency above 80%,respectively.The exfoliated graphite containing sulfur cathode could decrease the reaction interphase charge transfer impedance,and restrain the sulfur or polysulfide shuttle phenomenon during the charge-discharge process through improving the diffusion impedance.

Effects Of Kscn On Kinetic Characters Of The Positive Couple And Performance For Vanadium Redox Flow Battery, Jian-Guo Liu, Dong Shi, Yue Men, Chuan-Wei Yan

Journal of Electrochemistry

In order to improve the reaction activity of VO²⁺/VO²⁺ and the battery performance of Vanadium redox flow battery,different concentration of potassium sulfocyanates KSCN were added into 0.1mol/L VOSO₄/ H₂SO₄ solution,and the kinetic characters of electrochemical reaction of VO²⁺/VO²⁺ was studied by CV and EIS.The results showed that the addition of KSCN could improve the oxidative peak current value of positive couple VO²⁺/VO²⁺ reaction,but had little influence in the reductive peak.The addition of KSCN decreased the impedance at 1.0 V.And the value of standard rate constant k0 …

Effect Of Impurity Cu(2+) On Oxygen Electrode In Pemfc, Xiao Jie, Jun-Bo Hou, Zhi-Gang Shao, Bao-Lian Yi

Journal of Electrochemistry

Rotating disk electrode was adopted in this paper to simulate the cathode in PEMFC.In the Cu²⁺ electrolyte,the influence of impurity Cu²⁺ on Carbon-Supported Pt Catalysts was investigated by using electrochemical measurements such as chronocoulometry,cyclic voltammetry and linear sweep.Experimental results showed that,after constant voltage at 0.49 V,the ECA of Pt/C decreased dramatically,it's perhaps under potential deposition of Cu might occur on the substrate.Meanwhile the change of ORR Tafel scope reaction is very large.It might be because oxygen adsorption sites are occupied by Cu atoms after they under potential deposit on surface of Pt/C catalyst,and the adsorption of oxygen on …

Electro-Oxidation Of Methanol On Fe-Doped Pt-Zro2/C Catalyst, Mao-Cai Lin, Dong-Dong Liu, Qing-Chun Yu, Ming-Ruo Hu, Heng-Yong Tu

Journal of Electrochemistry

The Fe-doped ZrO₂ powders were prepared by so-gel method.After that,Pt-Zr_1-xFe_xO₂/C catalysts were made by reducing platinum salts with ethylene glycol.The physical property of the catalyst was characterized by XRD and TEM.It was found that the distribution of the catalyst was narrow,the particle sizes of Pt and ZrO₂ particles were 2~4 nm and 3~7 nm,respectively.The Cyclic Voltammetry and Chronoamperometry testing indicated that the electro-catalytic activity for methanol electro-oxidation on Pt-ZrO₂/C catalyst increased when ZrO₂ was doped with Fe.And Pt-Zr_0.95Fe_0.05O₂/C catalyst showed the highest activity …

Performance Analysis Of Coal-Fired Boiler And Natural Gas Fired Boiler At Morehead State University, Devender Banne

Morehead State Theses and Dissertations

A thesis presented to the faculty of the College of Science & Technology at Morehead State University in partial fulfillment of the requirements for the Degree of Master of Science by Devender Banne on May 4, 2009.

A Study In The Information Content, Consistency, And Expressive Power Of Function Structures In Mechanical Design, Chiradeep Sen

All Theses

In engineering design research, function structures are used to represent the intended functionality of technical artifacts. Function structures are graph-based representations where the nodes are functions, or actions, and the edges are flows, or objects of those actions. For the consistent description of artifact functionality, multiple controlled vocabularies have been developed in previous research. The Functional Basis is one such vocabulary that provides for a set of verbs and a set of nouns, organized in the three-level hierarchy. This vocabulary is extensively studied in design research. Two major application of this vocabulary are the Design Repository, which is a web-base …

Development Of A Falling Sphere Instrument For High-Resolution Neutral Wind Measurements In The Mesosphere And Lower Thermosphere, Arpan Shah

All Theses

Passive falling spheres launched from small rockets have been used extensively in the past to measure the winds and densities in the mesosphere. In principle, the same technique can be extended to higher altitudes that cover the lower thermosphere, in addition to the mesosphere. The main difficulties are that accelerations decrease rapidly with height due to the decreasing atmospheric density and rigid spheres are required at higher altitudes, which implies larger mass and smaller accelerations. Accelerometers with broad dynamic range and high sensitivity are required for the measurements, but such devices are not readily available. We describe an instrumented falling …

A Priori Analysis Of Subgrid Scalar Phenomena And Mass Diffusion Vectors In Turbulent Hydrogen-Oxygen Flames, Justin Foster

All Theses

Direct Numerical Simulations (DNS) of high pressure, turbulent H₂/O₂ non-premixed flames employing real gas effects, detailed chemistry, multicomponent, differential, and cross diffusion are conducted. The results of these simulations are analyzed to provide important subgrid information relevant to Large Eddy Simulation (LES) of turbulent combustion. Subgrid filtered scalar dissipation and scalar variances, species concentrations, reaction rates, and flame temperature are presented as a function of mixture fraction. The analysis also includes a detailed comparison of the actual filtered mass flux vectors with their corresponding forms evaluated with the filtered primitive variables. The results show a reasonable correlation …

Droplet Assisted Self-Assembly Of Semiconductor Nanostructures, Kimberly Annosha Sablon

Graduate Theses and Dissertations

There is increasing interest in quantum dot (QD) structures for a plethora of applications, including optoelectronic devices, quantum computing and energy harvesting. While strain driven surface diffusion via stranski-krastanow (SK) method has been commonly used to fabricate these structures, a more recent technique, droplet epitaxy (DE) does not require mismatch strain and is therefore much more flexible in the combination of materials utilized for the formation of QDs.

As reported in this work, a hybrid approach that combines DE and SK techniques for realizing lateral ordering of QDs was explored. First, the droplet formation of various materials was discussed and …

Development Of A Nonlinear Ride Quality Model To Aid In Tweelå© Parameter Selection, Marc Paradiso

All Theses

The ride comfort of a vehicle is very important to both automotive and tire manufacturers. Unfortunately the ride comfort provided by the tire has an inverse relationship with the handling ability of the vehicle. Michelin has sought to decouple ride comfort and handling capability by developing a non-pneumatic tire they have dubbed the TWEEL©. To better understand what effects fitting a TWEEL with specific characteristics would have on the ride comfort of a vehicle a computer simulation was developed to study the effects of TWEEL stiffness and deflection on ride comfort.
The vehicle model used in the simulation is a …

Taxonomy Of Physical Prototypes: Structure And Validation, Ashwin Michaelraj

All Theses

This thesis introduces a taxonomy of physical prototypes, and validates the proposed taxonomy by five different approaches. The proposed taxonomy is validated by, (i) checking the orthogonality of individual elements of the taxonomy, (ii) benchmarking the taxonomy with existing classifications of prototypes, (iii) demonstrating its utility by applying it to classify different prototypes, (iv) building a prototype database containing 35 different prototypes, and (v) consistency evaluation of the prototype database using a description logic based software called ProtŽgŽ.
The results indicate that the proposed taxonomy is capable of distinguishing prototypes with greater accuracy when compared to existing classifications. The orthogonality …

An Evaluation Of Function-Based Representations And Information Archival In Engineering Design, Benjamin Caldwell

All Theses

Recent research in function-based design includes the development of a vocabulary of functions, the Functional Basis, and a repository of products and their functions. Many design tools are being developed around this vocabulary and repository to support conceptual design. The usefulness of these tools, however, is dependent on the quality of the vocabulary and the information contained in the repository. In this research, both the vocabulary and the repository are empirically evaluated to understand their strengths and limitations. A statistical analysis is performed on function models in the repository to determine the frequency of usage of Functional Basis terms. It …

Development, Parameterization And Validation Of Dynamic Material Models For Soil And Transparent Armor Glass, Bhaskar Pandurangan

All Dissertations

Despite the signing of several mine ban treaties in the 1990's, it is widely recognized that there is a landmine crisis. The following are some of the main aspects of this crisis: (a) Millions of unexploded landmines remain deployed all over the world; (b) Thousands of civilians are killed or maimed every year by unintended detonations of the mines; (c) The cost of medical treatment of landmine injuries runs into the millions; (d) the ability of the international community to provide the humanitarian relief in terms of medical services, safe drinking water and food, etc., is greatly hampered by landmine …

Foundations Of Design Method Development, Sudhakar Teegavarapu

All Dissertations

A systematic procedure for developing design methods, tools, and/or processes, referred to as meta-method, is proposed. It is hypothesized that design methods developed without following a systematic procedure are not effective and thus are not widely accepted by industry and academia likewise. The systematic framework provided by the meta-method will ensure 1) faster development of design methods, 2) enable tracking of requirements throughout the development process, 3) facilitate efficient exploration and selection of alternatives, 4) document the development process for future reuse, 5) help in testing and validation of design methods, and 6) bridge gap between multiple disciplines by forming …

Microcantilever-Based Force Sensing, Control And Imaging, Reza Saeidpourazar

All Dissertations

This dissertation presents a distributed-parameters base modeling framework for microcantilever (MC)-based force sensing and control with applications to nanomanipulation and imaging. Due to the widespread applications of MCs in nanoscale force sensing or atomic force microscopy with nano-Newton to pico-Newton force measurement requirements, precise modeling of the involved MCs is essential. Along this line, a distributed-parameters modeling framework is proposed which is followed by a modified robust controller with perturbation estimation to target the problem of delay in nanoscale imaging and manipulation. It is shown that the proposed nonlinear model-based controller can stabilize such nanomanipulation process in a very short …

Multiscale Modeling Of Impact On Heterogeneous Viscoelastic Solids With Evolving Microcracks, Flavio V. Souza

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Multiscale computational techniques play a major role in solving problems related to viscoelastic composite materials due to the complexities inherent to these materials. In the present work, a numerical procedure for multiscale modeling of impact on heterogeneous viscoelastic solids containing evolving microcracks is proposed in which the (global scale) homogenized viscoelastic incremental constitutive equations have the same form as the local scale viscoelastic incremental constitutive equations, but the homogenized tangent constitutive tensor and the homogenized incremental history dependent stress tensor depend on the amount of damage accumulated at the local scale. Furthermore, the developed technique allows the computation of the …

Effect Of Steam Environment On Creep Behavior Of Nextel720/Alumina-Mullite Ceramic Matrix Composite At Elevated Temperature, Tolga Kutsal

Theses and Dissertations

The tensile creep behavior of an oxide-oxide ceramic matrix composite (CMC) was investigated at 1000 and 1100° C in laboratory air and steam. The oxide-oxide CMC studied in this research was Nextel™ 720/alumina-mullite (N720/AM). The composite consists of N720/fibers with 0°/90° fiber orientation and a porous alumina-mullite matrix. Tensile-strain behavior was investigated and tensile properties measured at 900, 1000 and 1100° C. The effect of loading rate on tensile properties of N720/AM ceramic matrix composite at 1100° C in steam was also examined. Creep-rupture tests were performed at 1100° C in laboratory air and steam, and at 1000° C only …

A Finite Element Evaluation Of An Experiment Related To Coating Damping Properties, Armando Deleon

Theses and Dissertations

Typically turbine engine blades gain protection from thermal damage by the use of hard coatings, such as magnesium aluminate spinel. Known as Thermal Barrier Coatings (TBC's), they have material properties that include several nonlinearities. These TBC's create damping primarily due to their nonlinear dissipation of energy. In order to effectively represent their damping properties, it is necessary to create a method which combines experimentation and analysis. Previous work has shown the need for a beam bounded and loaded in such a fashion that external support energy dissipation functions i.e. boundary conditions and aerodynamics are eliminated. Thus, a new experimental apparatus …

Effects Of Prior Aging At 316°C In Argon On Inelastic Deformation Behavior Of Pmr-15 Polymer At 316°C: Experiment And Modeling, Ozgur Ozmen

Theses and Dissertations

The inelastic deformation behavior of PMR-15 neat resin, a high-temperature polymer, was investigated at 316 deg C. The experimental program was designed to explore the influence of strain rate on tensile loading, unloading, and strain recovery behaviors. In addition, the effect of the prior strain rate on the relaxation response of the material, as well as on the creep behavior following strain controlled loading were examined. The material exhibits positive, nonlinear strain rate sensitivity in monotonic loading and unloading. Early failures occur in the inelastic regime. The recovery of strain at zero stress and creep response are strongly affected by …

Thermomechanical Properties Of Center-Reinforced Aluminum, Geofrey S. Cox

Theses and Dissertations

The rule of mixture approach was shown to produce an accurate theoretical prediction of the room temperature elastic modulus values when compared to the experimental results. The laminate's modulus value remained relatively constant over the -55C to 80C temperature range, indicating stable behavior despite temperature changes. Blunt notch tests also revealed that the laminate's strength was not significantly reduced due to the presence of small holes. Finally, fatigue testing demonstrated that the laminate retains its stiffness properties throughout its fatigue life, until failure.

The Effect Of Silicon Content On Impact Toughness Of T91 Grade Steels, Ajit K. Roy, Pankaj Kumar, Debajyoti Maitra

Mechanical Engineering Faculty Research

The impact resistance of silicon (Si)-containing modified 9Cr-1Mo steels has been investigated within a temperature regime of -40 to 440°C using the Charpy method. The results indicate that the energies absorbed in fracturing the tested specimens were substantially lower at temperatures of -40, 25, and 75°C compared to those at elevated temperatures. Lower impact energies and higher ductile-to-brittle-transition-temperatures (DBTTs) were observed with the steels containing 1.5 and 1.9 wt.% Si. The steels containing higher Si levels exhibited both ductile and brittle failures at elevated temperatures. However, at lower temperatures, brittle failures characterized by cleavage and intergranular cracking were observed for …

Preparation And Performance Of Co And La Co-Doped Li-Rich Lithium Manganate, Da-Qiao Zhou

Journal of Electrochemistry

The cathode material of Li_1.1Co_0.02La_0.01Mn₂O₄ was successfully synthesized by the method of co-precipitation followed by a solid state reaction.In the sintering temperature range of 700～850 ℃,X-ray diffraction(XRD) results showed a single phase of each material and the increase of crystallization degree,and scanning electron microscopic(SEM) images indicated that the particle size increased and the specific surface area decreased,respectively,with increasing the sintering temperature.Due to its lower polarization resistance,the Co and La co-doped lithium-rich lithium manganate(sintered at 800 ℃) positive electrodes showed the most promising electrochemical performance.The capacity retention after 50 cycles reached 98.5%.

Electrochemical Properties Of Functionalized Carbon Nanotubes And Their Applications In Analysis Of 6-Mercaptopurine, Bao-Yi Lu, Yan-Yan Lai, Hong Li

Journal of Electrochemistry

The electrochemical behaviors and adsorption properties of single-walled carbon nanotubes such as SWNT,SWNT-COOH,and SWNT-OH and multi-walled carbon nanotubes including MWNT,MWNT-COOH,and MWNT-OH modified at a graphite electrode have been investigated by using [Fe(CN)₆]^3-anion and [Co(phen)₃]³⁺ cation.It was shown that shows good redox reversibility of [Fe(CN)₆]^3-/4-reactions on the existed carbon nanotubes(CNT) modified electrode.Based on the strong adsorptive property of [Co(phen)₃]³⁺ on the CNT surface,the [Co(phen)₃]³⁺/CNT modified graphite electrode can be obtained by progressive potential sweeping and developed to monitor quantitatively 6-mercaptopurine(6-MP).The adsorption capacity of …