Graphene Enhanced Linear Low-Density Polyethylene Nanocomposites By Premixing And Melt Compounding,
2021
Chulalongkorn University
Graphene Enhanced Linear Low-Density Polyethylene Nanocomposites By Premixing And Melt Compounding, Wan Nazri Wan Busu, Ruey Shan Chen, Muhammad Jefri Mohd Yusof, Sahrim Ahmad
Journal of Metals, Materials and Minerals
In this study, linear low-density polyethylene/graphene nanoplatelets (LLDPE/GNPs) nanocomposites were prepared from conventional melt-mixing method and our new approach; two-step premix mixing technique. Indirect mixing technique (IDT) was employed to fabricate a premix of LLDPE/ GNPs in the ratio of 80:20 wt%. The effects of GNPs loadings and the processing method of nanocomposites on the mechanical strength, decomposition temperature, crystallinity, electrical impedance and morphology were investigated. Irrespective of processing methods, the prepared nanocomposites exhibited crystalline structure due to the presence of GNPs whilst the degradation temperature was recorded to be increased with GNPs loadings that signified improved thermal stability. The …
Preparation Of Transparent Alumina Thin Films Deposited By Rf Magnetron Sputtering,
2021
Chulalongkorn University
Preparation Of Transparent Alumina Thin Films Deposited By Rf Magnetron Sputtering, Busarin Noikaew Noikaew, Laksana Wangmooklang, Saisamorn Niyomsoan, Siriporn Larpkiattaworn
Journal of Metals, Materials and Minerals
Alumina (Al2O3) thin films were prepared by RF magnetron sputtering technique using Al2O3 ceramic target. Effects of sputtering powers and oxygen gas mixtures were investigated and the optimized coating condition was applied on semi-precious gemstones. RF sputtering powers were varied to optimize the transparency of the films. Besides, the oxygen gas mixtures were also studied at the optimized sputtering power with a constant sputtering pressure. Optical and physical properties of the thin films were investigated using UV-Vis Spectrophotometer, FESEM, XRF, GIXRD, XRR including a microscratch tester. The Al2O3 films were highly transparent in the visible region in form of an …
Extraction Of Cellulose Nanofibers From Empty Palm Fruit Bunches Via Mechanical Defibrillation,
2021
Chulalongkorn University
Extraction Of Cellulose Nanofibers From Empty Palm Fruit Bunches Via Mechanical Defibrillation, Zi-Qian Tan, Takaomi Kobayashi, Duangdao Aht-Ong
Journal of Metals, Materials and Minerals
In recent years, there has been an increasing interest in finding alternative material to replace fossil-oil based product due to the environmental concern. Lignocellulosic biomass has emerged as the promising candidate due to its low-cost and sustainability. The objective of this work was to prepare cellulose nanofibers (CNFs) from empty palm fruit bunches (EPFB), which are the waste originating from palm oil industry. Cellulose fibers were first extracted from EPFB by chemical treatment, followed by mechanical disintegration using high-pressure homogenization. Fiber concentration and defibrillation time during mechanical treatment were studied to investigate their effects on the properties of produced nanofibers. …
The Effect Of Phosphogypsum On Stabilizing Clay Soil And Improving Its Properties For Use As Foundation Soil,
2021
Chulalongkorn University
The Effect Of Phosphogypsum On Stabilizing Clay Soil And Improving Its Properties For Use As Foundation Soil, Mai Yahya Maaitah, Mus'ab Ziad Banat
Journal of Metals, Materials and Minerals
Expansive soil covers large areas in a variety of regions in Jordan which is insufficient to meet the engineering specifications in construction. Phosphogypsum is considered to be the main by-product material which comes from phosphate rock deposits that is available in Jordan. The main purpose of this research is to study the effects of stabilization by phosphogypsum on expansive soil properties. Three Jordanian regions were chosen to represent the expansive soils, Irbid, Madaba, and Abu-Nusire city. Soils were mixed with phosphogypsum at different percentages by dry weight of soil. Some of the representative laboratory tests for swell properties were conducted: …
The Effect Of Artificial Defects On The Fatigue Characteristics Of Aisi 4340 Steel,
2021
Chulalongkorn University
The Effect Of Artificial Defects On The Fatigue Characteristics Of Aisi 4340 Steel, Yakov B. Unigovski, Dmitry Fishman, Liat Fishman, Liron Shichman, Ofir Moshe, Roni Shneck, Emmanuel Gutman
Journal of Metals, Materials and Minerals
This study examined the fatigue life (Nf) and fatigue limit (FL) of AISI 4340 steel in relation to surface roughness, artificial defects and shot peening. Artificial surface defects on fatigue specimens were obtained by electrical discharge machining (EDM) or by pre-corrosion in 3.5% NaCl and perchloric acid solutions, followed by a fatigue test. The presence of artificial defects of various sizes, taken into account by the area parameter, led to a significant decrease in fatigue characteristics, while shot peening contributed to their noticeable improvement. Defects resulting from electrochemical corrosion had a much greater negative effect on fatigue …
The Enhancement Of Ethanol Gas Sensors Response Based On Calcium And Zinc Co-Doped Lafeo3/Fe2o3 Thick Film Ceramics Utilizing Yarosite Minerals Extraction As Fe2o3 Precursor,
2021
Chulalongkorn University
The Enhancement Of Ethanol Gas Sensors Response Based On Calcium And Zinc Co-Doped Lafeo3/Fe2o3 Thick Film Ceramics Utilizing Yarosite Minerals Extraction As Fe2o3 Precursor, Endi Suhendi, Zeany Luckyta Amanda, Muhamad Taufik Ulhakim, Andhy Setiawan, Dani Gustaman Syarif
Journal of Metals, Materials and Minerals
A gas sensor is a renewed interest of research which has been developed to make a device that can be detected the harmful gases and applied in the several fields of industries. In this paper, we report the modified of gas sensor based thick film ceramic LaFeO3/Fe2O3 by added calcium and zinc co-doping prepared by screen-printed technique. In this work, yarosite mineral was utilized as Fe2O3 precursor. It aims to take the advantages of abundance natural resources in Indonesia to save a cost in gas sensor fabrication. Then, x-ray diffraction (XRD), scanning electron microscopy (SEM) and electrical properties characterization were …
Wollastonite And Talc Reinforced Polypropylene Hybrid Composites: Mechanical, Morphological And Thermal Properties,
2021
Chulalongkorn University
Wollastonite And Talc Reinforced Polypropylene Hybrid Composites: Mechanical, Morphological And Thermal Properties, Naruedee Putfak, Amnouy Larpkasemsuk
Journal of Metals, Materials and Minerals
This study focused on evaluating the mechanical, thermal, and morphological properties of polypropylene (PP) hybrid composites containing two different inorganic mineral fillers, namely wollastonite (WO) and talc. The composites were prepared by melt mixing process using a twin screw extruder and an injection molding machine. All composites contained a constant filler loading at 20 wt% with varying WO/talc weight ratios (20/0, 15/5, 10/10, 5/15, and 0/20). Melt flow index (MFI), mechanical properties (impact strength and tensile properties), heat distortion temperature (HDT) fractured surface morphology, and thermal behaviors of the resulting composites were investigated. The results revealed an enhancement in the …
Effect Of Nitrocarburizing And Argon Admixing On Low Carbon Steel For Component Facility In Radiometallurgical Installation,
2021
Chulalongkorn University
Effect Of Nitrocarburizing And Argon Admixing On Low Carbon Steel For Component Facility In Radiometallurgical Installation, Erwan Hermawan, Suprapto Suprapto, Usman Sudjadi, Siti Shaleha, Maman Kartaman Ajiriyanto
Journal of Metals, Materials and Minerals
Steel is an important component in the industrialized world with rising growth in world consumption. Steel has wide applications due to its high strength, durability, and cost-effectiveness. This has applications in the nuclear power plant. In Indonesian nuclear industry, low carbon steel is used not only for the fabrication of reactor components but also for the radiometallurgical facilities. However, to avoid the risk of premature failure and enhance the longevity of the components in the service condition, surface modification for the improvement of hardness has been realized. Amongst several methods, surface hardening by following nitrocarburizing has been found to be …
Structural, Magnetic And Transport Properties Of Ca And Sr Doped Lanthanum Manganites,
2021
Chulalongkorn University
Structural, Magnetic And Transport Properties Of Ca And Sr Doped Lanthanum Manganites, Sunita Keshri, Shailendra Rajput, Sonali Biswas, Leena Joshi, Wojciech Suski, Piotr Wiśniewski
Journal of Metals, Materials and Minerals
This article presents a comparative study for the effect of average A-site cation size on the structural, transport and magnetic properties of Lanthanum manganites. Three polycrystalline colossal magneto-resistive compounds were synthesized using standard solid state reaction method. The electrical resistivity data were analyzed employing standard two-phase model to understand the conduction mechanism. The resistance of polycrystalline ceramic depends on the intragrain resistance (intrinsic resistance) and the intergrain or grain-boundary resistance (extrinsic resistance). The substitution of Sr ions at La-site provides higher magnetic and metal-insulator transitions as compared to Ca ions. The combined substitution of Ca and Sr ions at La-site …
Formation Of Nano-Crystalline Chromium-Zirconium Nitride (Cr-Zr-N) Film Coating By Dc Unbalanced Magnetron Sputtering,
2021
Chulalongkorn University
Formation Of Nano-Crystalline Chromium-Zirconium Nitride (Cr-Zr-N) Film Coating By Dc Unbalanced Magnetron Sputtering, Kumpon Leelaruedee, Kattareeya Taweesup, Patama Visuttipitukul
Journal of Metals, Materials and Minerals
This research aimed to improve the properties of chromium nitride (CrN) film coatings by addition of zirconium (Zr) as the third element to form Cr-Zr-N ternary nitride. DC unbalanced magnetron sputtering method was used to form Cr-Zr-N film with various Zr/Zr + Cr atomic ratios. Mechanical properties, surface morphology and crystal structure of the film were investigated. In the research, Cr-Zr-N film were categorised into 3 types with different Zr amount: low zirconium, (Zr/Zr + Cr = 0.29), medium zirconium (Zr/Zr + Cr = 0.44), and high zirconium (Zr/Zr + Cr = 0.74). All Cr-Zr-N films exhibited nano-crystalline structures with …
Controlled Plasma Tuning Of Mos2 Based Photodetector: From Visible To Ultraviolet Photo Response,
2021
Chulalongkorn University
Controlled Plasma Tuning Of Mos2 Based Photodetector: From Visible To Ultraviolet Photo Response, Huda Musa Mutlaq, Ali Jabbar Fraih
Journal of Metals, Materials and Minerals
Among diverse family of two-dimensional materials, molybdenum disulfide (MoS2) is one of the most promising materials for optical applications thanks to its tunable optical energy bandgap. In this work, a MoS2 based photodetector is fabricated and its optical properties is investigated. With the help of controlled oxygen plasma bombardment, its photoresponse is tuned from visible to ultraviolet region. The photodetector was subjected to three bombardment times of 60 s, 120 s, and 180 s, and it was observed that 180 s irradiation resulted in a change in the optical response range of the photodetector from visible to ultraviolet. In fact, …
Retaining The High-Temperature Phases Of Rb3h(So4)2 And Rb5h3(So4)4 At Room Temperature,
2021
Chulalongkorn University
Retaining The High-Temperature Phases Of Rb3h(So4)2 And Rb5h3(So4)4 At Room Temperature, Chatr Panithipongwut Kowalski
Journal of Metals, Materials and Minerals
The attempts to maintain the higher-temperature phases of Rb3H(SO4)2 and Rb5H3(SO4)4 were demonstrated in this work for the first time. The goal was to explore the possibility to utilize solid acids at lower temperatures while keeping the high-temperature phases which connects to the desirable conductivities. Enabling to do so will allow the ease of handling and thermal cycling, and the energy saving in fuel cell applications, and will allow researchers to study the high-temperature properties of solid acids at lower temperatures without the expenses for the in-situ measurements and the accessibility limitations. The four relatively simple methods, which were the …
Poly(Vinyl)Alcohol Film Composited With Carbon Dots From Water Hyacinth Stalks Based On Gamma Irradiation For The Uv Blocking Film,
2021
Chulalongkorn University
Poly(Vinyl)Alcohol Film Composited With Carbon Dots From Water Hyacinth Stalks Based On Gamma Irradiation For The Uv Blocking Film, Tanagorn Kwamman, Threeraphat Chutimasakul, Panida Sangangam, Nattamon Puengposop, Kanokorn Wechakorn
Journal of Metals, Materials and Minerals
UV-radiation in the range of 200 nm to 400 nm from sunlight can inhibit the photosynthesis process in plants, while visible light in the range of 400 nm to 700 nm promotes photosynthesis and plant growth. In this work, poly(vinyl)alcohol-carbon dots composite film (PVA-CDs film) was developed as a UV-blocking film due to the excellent optical properties of carbon dots and the film-forming properties of PVA. For the synthesis of carbon dots using gamma irradiation, water hyacinth stalk, an invasive aquatic plant, was used as a carbon source. The result showed that PVA-CDs composite film exhibited excellent UV absorption (200 …
Luminescent Properties Of Polyaniline Capped Mn Doped Zns Quantum Dots,
2021
Chulalongkorn University
Luminescent Properties Of Polyaniline Capped Mn Doped Zns Quantum Dots, Anju Bala, Rajeev Sehrawat, Anil Kumar Sharma, Pardeep Soni
Journal of Metals, Materials and Minerals
Synthesis of polyaniline capped and Mn doped quantum dots are performed with co-precipitation tech. while structural, optical and morphological properties have been carried out by using Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD) study, photoluminescent (PL), absorption spectroscopy and High-Resolution Transmission Electron Microscopy (HR-TEM). Particles size is nearly 2 nm calculated using XRD analysis and nearly 2.5 nm as estimated from HR-TEM study. FTIR spectra confirm that ZnS and polyaniline interact through S-H vibrations. The absorption spectra analysis reflects the occurrence of blue shift at the peak of absorption along with the enhanced band gap of polyaniline capped ZnS(Mn) …
Corrosion Behavior And Characteristics Of Passive Films Of Laser Powder Bed Fusion Produced Ti-6al-4v In Dynamic Hank’S Solution,
2021
Edith Cowan University
Corrosion Behavior And Characteristics Of Passive Films Of Laser Powder Bed Fusion Produced Ti-6al-4v In Dynamic Hank’S Solution, Liang-Yu Chen, Hong-Yue Zhang, Chuanbo Zheng, Hong-Yu Yang, Peng Qin, Cuihua Zhao, Sheng Lu, Shun-Xing Liang, Linjiang Chai, Lai-Chang Zhang
Research outputs 2014 to 2021
The corrosion behavior of laser powder bed fusion produced (L-PBF-produced) titanium alloys involving flowing body fluid is still unclear. Therefore, this work investigates in vitro corrosion behavior and the characteristics of passive films formed on L-PBF-produced Ti–6Al–4V in both static and dynamic Hank’s solutions. Electrochemical measurements, immersion tests, X-ray photoelectron spectroscopy and scanning electron microscopy were conducted. In comparison to the L-PBF-produced Ti–6Al–4V in static Hank’s solution, the samples showed lower charge transfer resistance and higher passivation current density (anodic current density as well) in dynamic Hank’s solution. Meanwhile, a more apparent deposition of apatite and hydroxyapatite is found on …
Relationship Between Pressure And Output Parameters In Belt Grinding Of Steels And Nickel Alloy,
2021
Edith Cowan University
Relationship Between Pressure And Output Parameters In Belt Grinding Of Steels And Nickel Alloy, Nelli V. Syreyshchikova, Danil Y. Pimenov, Munish K. Gupta, Krzysztof Nadolny, Khaled Giasin, Muhammad Aamir, Shubham Sharma
Research outputs 2014 to 2021
Belt grinding of flat surfaces of typical parts made of steel and alloys, such as grooves, shoulders, ends, and long workpieces, is a good alternative to milling. Several factors can influence the belt grinding process of flat surfaces of metals, such as cutting speed and pressure. In this work, the importance of pressure in the belt grinding was investigated in terms of technological and experimental aspects. The grinding experiments were performed on structural alloy steel 30KhGSN2/30KhGSNA, structural carbon steel AISI 1045, corrosion-resistant and heat-resistant stainless steel AISI 321, and heat-resistant nickel alloy KHN77TYuR. The performance of the grinding belt was …
Review On Machining Of Additively Manufactured Nickel And Titanium Alloys,
2021
Edith Cowan University
Review On Machining Of Additively Manufactured Nickel And Titanium Alloys, Navneet Khanna, Kishan Zadafiya, Tej Patel, Yusuf Kaynak, Rizwan Abdul, Rahman Rashid, Ana Vafadar
Research outputs 2014 to 2021
The machining of nickel and titanium-based superalloy components is very expensive and involves unusually high lead times compared with other engineering metals such as steels and aluminum. This has led to the development of most suitable additive manufacturing (AM) processes to fabricate these difficult-to-machine metals into near-net shape parts, thereby reducing the lead time and material waste, and significantly increasing productivity. Nonetheless, finish machining is still required on the AMed metal components to meet the dimensional and surface requirements of the application. Several research studies have investigated the machinability of AMed nickel and titanium alloy workpieces and have compared the …
Quality Assurance Of Lightweight Structures Via Phase-Based Motion Estimation,
2021
Georgia Southern University
Quality Assurance Of Lightweight Structures Via Phase-Based Motion Estimation, Ikenna E. Ifekaonwu
College of Graduate Studies: Theses & Dissertations
In recent years, lightweight structures have become mature and adopted in various applications. The importance of quality assurance cannot be overemphasized hence extensive research has been conducted to assess the quality of lightweight structures. This study investigates a novel process that exploits motion magnification to investigate the damage characteristics of lightweight mission-critical parts. The goal is to assure the structural integrity of 3D printed structures and composite structures by determining the inherent defects present in the part by exploiting their vibration characteristics. The minuscule vibration of the structure was recorded with the aid of a high-speed digital camera, and the …
Impact Of Blended Salt Anti-Icers/Deicers On Properties Of Asphalt Binders,
2021
Geogia Southern University
Impact Of Blended Salt Anti-Icers/Deicers On Properties Of Asphalt Binders, Nurudeen A. Abidoye
College of Graduate Studies: Theses & Dissertations
Anyone who has ever attempted to remove a layer of ice from a roadway or sidewalk by plowing or shoveling knows it is no easy task when the ice is firmly bonded to the asphalt/concrete surface. Winter anti-icing/deicing operations are moral choices that mankind has made to combat winter storms. This research is aimed at evaluating the macro and nano structural impacts of (anti-icing/de-icing) salt on aged and unaged asphalt binders. The macro structural impacts focused on the rheological and creep properties, and the nano structural impacts focused on the surface topography, adhesion force, and modulus of asphalt binders. Rheological …
Determination Of Hydrogel Degradation By Passive Mechanical Testing,
2021
Bucknell University
Determination Of Hydrogel Degradation By Passive Mechanical Testing, Avery Rosh-Gorsky
Honors Theses
This paper details a new technique to measure the mechanical properties of ETTMP PEGDA hydrogels using Hertz Contact Theory and simultaneously analyze both the model drug release and gel erosion in situ. This method involves curing a drug loaded hydrogel in a standard cuvette and placing a glass bead and phosphate buffer solution (PBS). Over time, the cross-linked network of the hydrogel breaks down, and, as a result, the ball sinks into the hydrogel. This method provides a macroscopic and inexpensive way to continuously and passively measure properties of the hydrogel as the hydrogel degrades. By plotting both the …
