Microstructure And Properties Of Zirconia-Alumina Composites Fabricated Via Powder Injection Molding,
2021
Chulalongkorn University
Microstructure And Properties Of Zirconia-Alumina Composites Fabricated Via Powder Injection Molding, Nalattaporn Saelee, Nutthita Chuankrerkkul, Panitarn Wanakamol
Journal of Metals, Materials and Minerals
This study aimed to fabricate zirconia-alumina composites via powder injection molding and investigated the effects of alumina addition on microstructure as well as physical properties of the composites. Zirconia-alumina composites were prepared using polyethylene glycol (PEG) and polyvinyl butyral (PVB) as binders. The powder loading was fixed at 38 vol%, and PEG: PVB binder weight ratio was fixed at 80:20. Alumina content within ceramic component was varied at 0, 10, 20, 30, 40 and 50 vol% to observe the effect of alumina on the composite structures and properties. The injection molding was done at 190℃ followed by water debinding of …
Enhancing Stability And Antioxidant Efficacy Of Fisetin By Encapsulating As Β-Cyclodextrin Inclusion Complex With Porous Polylactic Acid Film From Breath Figure,
2021
Chulalongkorn University
Enhancing Stability And Antioxidant Efficacy Of Fisetin By Encapsulating As Β-Cyclodextrin Inclusion Complex With Porous Polylactic Acid Film From Breath Figure, Charasphat Preuksarattanawut, Warinyupa Mangmee, Munchumas Prousoontorn, Ekasit Nisarattanaporn, Krisana Siraleartmukul
Journal of Metals, Materials and Minerals
This research aims to investigate the scope of fisetin (FIT)/β-cyclodextrin (β-CD) inclusion complexes with the ratios of 1:2 and 2:1 mole by means of freeze-drying, kneading and physical mixing methods (controlled process). Moreover, the complex compounds are analyzed by Fourier-Transform Infrared Spectroscopy (FTIR) and Differential Scanning Calorimetry (DSC). The results show that the most suitable preparation method of fisetin (FIT)/β-CD complex is the freeze-drying method with the fisetin (FIT) to β-CD ratio at 1:2. The emission of FIT/β-CD was investigated and it is found that the emission rate of freeze-dried FIT/β-CD in 1:2 ratio by freeze-drying method is lower than …
Study Of Mechanical Properties And Characteristics Of Eco-Fibres For Sustainable Children's Clothing,
2021
Chulalongkorn University
Study Of Mechanical Properties And Characteristics Of Eco-Fibres For Sustainable Children's Clothing, Siti Shukhaila Shaharuddin, Marzie Hatef Jalil, Kaveh Moghadasi
Journal of Metals, Materials and Minerals
The aim of this paper is to study the application of eco-fibres as a new approach to achieve the multifunctional design for children’s clothing toward sustainability in the clothing industry. In this regard, this study focuses on the evaluation of the fabrics’ mechanical properties including tensile strength and microstructural details as critical points for multifunctional children's clothing purposes. The eco-fibre fabrics studied are organic cotton twill and recycled polyester. Studies have proven that frequent laundering and dry-cleaning result in increased pilling. Furthermore, high quality of colour fastness properties was found in 100% organic woven cotton fabric and recycled polyester fabric …
Effect Of Micro Graphite Particles On The Microstructure And Mechanical Behavior Of Aluminium 6061 (Al-Mg-Si) Alloy Composites Developed By Novel Two Step Casting Technique,
2021
Chulalongkorn University
Effect Of Micro Graphite Particles On The Microstructure And Mechanical Behavior Of Aluminium 6061 (Al-Mg-Si) Alloy Composites Developed By Novel Two Step Casting Technique, Madeva Nagaral, Raghavendra Pai K., V. Auradi, Bharath V., Shanawaz Patil, Mahantesh S. Tattimani
Journal of Metals, Materials and Minerals
In the present research, the effect of micron sized graphite addition on the microstructure and tensile failure of Al6061 alloy has been studied. The Al6061 alloy metal matrix composites reinforced with 6, 9 and 12 varying weight percentages of graphite particles were fabricated by novel two step stir cast route which helps in improving the wettability of Al6061 alloy matrix with graphite particles. The synthesized composites were subjected to microstructural studies, density, hardness and tensile properties testing. Microstructural characterizations of obtained samples were carried out by SEM microscopy, EDS and XRD patterns. The occurrence of graphite particles were confirmed by …
Sustainable Valorization Of Sugarcane Leaves For Succinic Acid And Biochar Production,
2021
Chulalongkorn University
Sustainable Valorization Of Sugarcane Leaves For Succinic Acid And Biochar Production, Nuttaporn Chokesawatanakit, Pasakorn Jutakridsada, Khanita Kamwilaisak
Journal of Metals, Materials and Minerals
The leaves of sugarcane (Saccharum officinarum) are agricultural waste that is burnt before harvesting. This project aims to find an alternative way to increase the value of sugarcane leaves and decrease air pollution by using the leaves as raw material to produce succinic acid and biochar. Reducing sugars were extracted from the leaves by H2SO4 hydrolysis. The sugars were then fermented by Yarrowia lipolytica TBRC 4417 to produce succinic acid. The solid residue was used as the raw material for biochar production by pyrolysis. The effects of pyrolysis temperature (350, 400, and 450℃) and nitrogen gas flow rate (5, 10, …
Assessment Of Hydrothermal Parameters On Alkaline Activation Of Fly Ashes Using A Central Composite Design,
2021
Chulalongkorn University
Assessment Of Hydrothermal Parameters On Alkaline Activation Of Fly Ashes Using A Central Composite Design, Ivan Supelano García, César Armando Ortíz Otálora, Carlos Arturo Parra Vargas, Julieth Alexandr Mejía Gómez
Journal of Metals, Materials and Minerals
Coal fly ash (CFA) is a powder generated during combustion of coal; its improper disposal constitutes an environmental issue. To minimize this problem, one of the uses of CFA is as feedstock for production of zeolite. Different studies have shown that zeolites may be easily obtained from CFA by relatively cheap and fast conversion processes. Most of these studies have been focused on the study of the zeolite synthesis using classical methods through changing one factor per time and fixing the other factors, where it illustrates the impact of each variable individually via a huge number of experiments, however it …
Debinding Behaviour And Sintering Temperature-Dependent Features Of Coloured Zirconia Fabricated By Ceramic Injection Moulding,
2021
Chulalongkorn University
Debinding Behaviour And Sintering Temperature-Dependent Features Of Coloured Zirconia Fabricated By Ceramic Injection Moulding, Wantanee Buggakupta, Thanakorn Wasanapiarnpong, Nutthita Chuankrerkkul
Journal of Metals, Materials and Minerals
Zirconia (ZrO2) is one of ceramic materials that has very good mechanical and chemical properties suitable for biomedical applications as well as other industrial applications. ZrO2 ceramics, in fact, has been used in orthodontic dentistry. Nowadays, ZrO2 has been played its role in decorative and jewelry purposes, such as watchcases and artificial stones. Ceramic injection moulding (CIM), a near-net shape manufacturing process that can produce small, complex-shaped components and is suitable for large volume production, is one of the best powder fabrication methods. In this work, CIM was carried out in order to form the coloured-ZrO2 specimens. Binders used in …
Effects Of Annealing Treatment On Microstructure And Hardness In The 28 Wt% Cr Cast Iron With Mo/W Addition,
2021
Chulalongkorn University
Effects Of Annealing Treatment On Microstructure And Hardness In The 28 Wt% Cr Cast Iron With Mo/W Addition, Kittikhun Ruangchai, Ruangdaj Tongsri, John Thomas Harry Pearce, Torranin Chairuangsri, Amporn Wiengmoon
Journal of Metals, Materials and Minerals
In this study, the effects of annealing on the hardness and microstructure of 28 wt% Cr-2.6 wt% C iron with 1.4 wt% Mo/1 wt% W addition have been investigated. The as-cast samples were heated to 800℃ and held for 4 h followed by slow cooled with a cooling rate of 20℃h-1 to 500℃. Microstructures were characterized by X-ray diffractometry, optical microscopy, scanning electron microscopy and energy-dispersive X-ray spectroscopy. Vickers macro-hardness and micro-hardness were measured. It was found that the as-cast microstructure in the hypoeutectic 28 wt% Cr iron without Mo or W addition consisted of primary austenite dendrite, eutectic M7C3 …
Mechanical Properties And Ionic Conductivity Of Biodegradable Materials In Solid Polymer Electrolyte,
2021
Chulalongkorn University
Mechanical Properties And Ionic Conductivity Of Biodegradable Materials In Solid Polymer Electrolyte, Fatin Arhana Awang, Mohd Faiz Hassan, Khadijah Hilmun Kamarudin
Journal of Metals, Materials and Minerals
No abstract provided.
Electrochromic Property Of Tungsten Trioxide Films Prepared By Dc Magnetron Sputtering With Oblique Angle Deposition And Thermal Oxidation,
2021
Chulalongkorn University
Electrochromic Property Of Tungsten Trioxide Films Prepared By Dc Magnetron Sputtering With Oblique Angle Deposition And Thermal Oxidation, Chantana Aiempanakit, Areeya Chanachai, Nattaya Kanchai, Montri Aiempanaki, Kamon Aiempanakit
Journal of Metals, Materials and Minerals
In this work, WO3 thin films were prepared in two steps: First, tungsten (W) films with thickness of 100-300 nm were deposited by DC magnetron sputtering with oblique angle deposition (OAD) technique at 0 and 85. Second, sputtered W films were annealed under air atmosphere at a temperature of 500℃ and different oxidation times for 1-3 h. The structure of WO3 thin films were examined by X-ray diffraction and field emission scanning electron microscope. In addition, the optical and electrochromic properties of the WO3 thin films were measured by a spectrophotometer before and after testing in potassium hydroxide electrolytes. The …
Improvement Of Alkali Resistance Of Glass Fiber From Basalt And Lignite Bottom Ash Mixture By Addition Of Zro2 Content,
2021
Chulalongkorn University
Improvement Of Alkali Resistance Of Glass Fiber From Basalt And Lignite Bottom Ash Mixture By Addition Of Zro2 Content, Apirat Theerapapvisetpong, Phraethong Kwanpanngam, Thanapat Tamrongwongwi
Journal of Metals, Materials and Minerals
No abstract provided.
New Views On The Ingenious Applications Of Ag Nanoparticles As A Sensor For Antibiotic Detection And As A Potent Antimicrobial Agent,
2021
Chulalongkorn University
New Views On The Ingenious Applications Of Ag Nanoparticles As A Sensor For Antibiotic Detection And As A Potent Antimicrobial Agent, Keyur Bhatt, Anita Kongor, Mohd Atharb, Vinod Jain
Journal of Metals, Materials and Minerals
Nanotechnology uses exceptional approaches for the control of bacterial infections which uncovers the potential function of bio-systems at nano-scale level. Compared to silver ions, silver nanoparticles possess enhanced physicochemical stability and low bio-toxicity properties. The intrinsic chemical framework of silver nanoparticles is prone to exhibit a significant chemistry when used as sensor and as therapeutic. Nowadays, silver is used in (nano-) medicine, in the form of nanoparticles to optimize its therapeutic property for controlling infections caused by multidrug-resistant bacteria. Exclusive use of antibiotics as medicines and its discharge from the body of the infected person or animals into the sewage …
Investigations On Phase Coexistence And Functional Properties Of Bczt Lead-Free Piezoceramic,
2021
Chulalongkorn University
Investigations On Phase Coexistence And Functional Properties Of Bczt Lead-Free Piezoceramic, Jirapa Tangsritrakul, Thiyanee Sonkami, Chumpon Wichittanakom, Chotiros Dokkhan, Panithi Wiroonpochit
Journal of Metals, Materials and Minerals
Large piezoelectric properties was observed in (1-x)BZT-(x)BCT where x=0.5 or Ba0.85Ca0.15Ti0.9Zr0.1O3 (denoted as BCZT), leading to a promising candidate for lead-free piezoelectric materials. However, phase formation of the BCZT is controversial and still unclear since various phase coexistences were identified in the literatures, for instances, the mixed phases of rhombohedral-tetragonal (R-T), ortho-rhombic-tetragonal (O-T) or rhombohedral-orthorhombic-tetragonal (R-O-T). Additionally, it is well known that the crystal structure plays a crucial role on the occurrence of polarization in the piezoceramics. Therefore, this work aims to investigate the coexistence of phase formation at room temperature for the BCZT powder and ceramic. Moreover, the electrical …
Influence Of Precursor Preparation On The Synthesis Of Boron Carbide From Glutinous Rice Flour,
2021
Chulalongkorn University
Influence Of Precursor Preparation On The Synthesis Of Boron Carbide From Glutinous Rice Flour, Kannigar Dateraksa, Sujarinee Sinchai
Journal of Metals, Materials and Minerals
Boron carbide is a promising candidate for a variety of applications, including blasting nozzles, neutron moderators, and lightweight armor. Using of inexpensive and readily available starting materials which can react with boric acid to form B-O-C bonds, e.g., glutinous rice flour, is one of alternative means to produce high purity boron carbide powder at low temperature. In this study, boric acid and glutinous rice flour, boron and carbon sources, were used for synthesizing B4C powder by the carbothermic reduction. The mole ratios of boric acid to glutinous rice flour ranging from 1:1 to 2.5:1 were formulated and mixed by continuous …
Effect Of Zinc-Hydroxo Species On The Growth Of One-Dimensional Zno Nanostructures,
2021
Chulalongkorn University
Effect Of Zinc-Hydroxo Species On The Growth Of One-Dimensional Zno Nanostructures, Nontakoch Siriphongsapak, Somyod Denchitcharoen
Journal of Metals, Materials and Minerals
One-dimensional ZnO nanostructures were grown on ZnO seed layer by hydrothermal method using zinc nitrate (Zn(NO3)2) and sodium hydroxide (NaOH) as precursors. The concentrations of NaOH and Zn(NO3)2 were varied from 40 mM to 680 mM and kept constant, respectively. Effects of increasing the hydroxide ions on the concentration of zinc-hydroxo species in the solution were studied using thermodynamic simulation software. The simulated results showed that Zn(OH)2 and Zn(OH)3- concentrations tended to decrease but Zn(OH)42- was non-linearly increased when the concentration of NaOH at room temperature was increased. After the growth of ZnO, the samples were characterized by FESEM and …
Experimental And Numerical Characterization Of Fatigue Crack Propagation In High-Speed Railway Wheel Er8 Steel,
2021
Chulalongkorn University
Experimental And Numerical Characterization Of Fatigue Crack Propagation In High-Speed Railway Wheel Er8 Steel, Chaichayo Suetrong, Vitoon Uthaisangsuk
Journal of Metals, Materials and Minerals
In this work, characteristics of fatigue crack growth in the Paris regime of the rail wheel steel grade ER8 were investigated. Experimental crack growth tests under different cyclic loads of a compact tension (CT) specimen and corresponding FE simulations were carried out. The extended FE method (XFEM) coupled with damage evolution based on the strain energy release rate or the Paris law was applied to describe the crack propagation mechanism in the tested CT samples. Hereby, the fatigue fracture model parameters were firstly determined from the experimental data. It was found that the predicted crack growth rates agreed well with …
Effect Of Cladding Of Stellite-6 Filler Wire On The Surface Of Ss316l Alloy Through Cold Metal Arc Transfer Process,
2021
Chulalongkorn University
Effect Of Cladding Of Stellite-6 Filler Wire On The Surface Of Ss316l Alloy Through Cold Metal Arc Transfer Process, Thinesh Babu Thiagarajan, Sengottuvel Ponnusamy
Journal of Metals, Materials and Minerals
In this work, Cladding was done on SS316L alloy through the CMT process using Stellite-6 filler wire. 31 experiments were done at different welding conditions as per CCD matrix. The cladding specimens were characterized by macro and micro-study, Vickers microhardness evaluation and corrosion resistance analysis. An optical microscope, SEM-EDAX, and XRD were used to predict the structural characterizations, presence and the distributions of the elements. Based on the study higher voltage & welding speed showed appreciable hardness at the interface & cladding regions. The thickness of the interface was noted at a maximum of 190 μm. The EDS spectra showed …
Development And Characterization Of Sic Fiber Reinforced B4c Composite,
2021
Chulalongkorn University
Development And Characterization Of Sic Fiber Reinforced B4c Composite, Jitendra Kumar Sonber, Sanjib Majumdar, Vivekanand Kain
Journal of Metals, Materials and Minerals
This study is conducted to investigate the effects of silicon carbide short fiber (SiCf) reinforcement on processing and properties of boron carbide ceramic. Studies have been carried out on the hot pressing, mechanical property measurement, microstructure evolution and oxidation study of SiCf reinforced B4C composite. B4C-SiCf composites have been prepared by hot pressing at 1950℃ with varying SiCf content in the range of 10 vol% to 30 vol%. All the composites are densified to near theoretical density. It is noticed that hardness of composite is decreased and fracture toughness of composite is increased by addition of SiC fiber. Hardness of …
Facile Purification Of Locally Mined Gypsum And Its Use For Preparing Nano-Hemihydrates,
2021
Chulalongkorn University
Facile Purification Of Locally Mined Gypsum And Its Use For Preparing Nano-Hemihydrates, Luqman Ayodeji Adams, Enobong Essien, Taiwo Aiyeloro, Stella Oseyomon, John Makanjuola
Journal of Metals, Materials and Minerals
Gypsum has a wide range of applications, in interior decorations, building construction, supplements or implants in orthopaedics to mention a few. However, in many developing countries including Nigeria, there is still a large-scale importation despite huge available natural deposits. In this study, a facile method to purify locally-mined gypsum has been explored based on the mineral retrograde solubility in water. The purified gypsum was investigated for its elemental composition in comparison to the crude sample and a commercially obtained medical-grade gypsum using X-ray fluorescence (XRF). The results showed that the purified gypsum contained 94.05% CaSO4 compared with the crude which …
Efficiency Of 2-Dodecylaminopyridine For The Liquid-Liquid Extraction Of Gold(Iii) From Succinic Acid Medium,
2021
Chulalongkorn University
Efficiency Of 2-Dodecylaminopyridine For The Liquid-Liquid Extraction Of Gold(Iii) From Succinic Acid Medium, Umrao Shep, Rucha Pawar, Balasaheb Arbad
Journal of Metals, Materials and Minerals
Extractive recovery of gold(III) from succinic acid solution with high molecular weight amine: 2-dodecylaminopyridine (2-DDAP) as a new extractant in xylene has been investigated. Extraction data indicates that 5 × 10-4 mol⋅L-1 2-DDAP is a very efficient and fast extractant. Gold(III) can be effectively extracted (D = 414.16) with 2-DDAP from 0.04 M succinic acid solution. The equilibrium of gold(III) from aqueous phase of succinic acid with 2-DDAP is achieved within 60 sec. The extraction of gold(III) with 2-DDAP proceed at the interface according to ion pair formation mechanism. The best stripping solution from among the studied ones is the …
