Open Access. Powered by Scholars. Published by Universities.®

Engineering Science and Materials Commons

Open Access. Powered by Scholars. Published by Universities.®

5,450 Full-Text Articles 12,417 Authors 3,033,212 Downloads 138 Institutions

All Articles in Engineering Science and Materials

Faceted Search

5,450 full-text articles. Page 2 of 194.

Preparation And Performance Study Of In-Situ Self-Assembled Biphasic Smmn2O5-Nimn2O4 Composite Cathode, Neng-Chu Xia, Yu Zhou, Qin Wang, Jia-You Zhang, Chun Yu, Yang Zhang, Wan-Bing Guan, Jian-Xin Wang 2026 School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, P.R. China; Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang, 315201, P.R. China

Preparation And Performance Study Of In-Situ Self-Assembled Biphasic Smmn2O5-Nimn2O4 Composite Cathode, Neng-Chu Xia, Yu Zhou, Qin Wang, Jia-You Zhang, Chun Yu, Yang Zhang, Wan-Bing Guan, Jian-Xin Wang

Journal of Electrochemistry

Mullite-structured oxides exhibit excellent oxygen reduction reaction activity, possess a low thermal expansion coefficient due to their unique crystal structure, and can eliminate the need for a barrier layer and simplify the preparation process as they contain no alkaline earth elements. Thus, they hold great promise as novel cathode materials for solid oxide fuel cells. In this work, a mullite-spinel-structured SmMn2O5-NiMn2O4 (SMO-NMO) composite cathode was one-step synthesized via a solid-liquid composite route, and its in-situ self-assembly enabled good compatibility with the electrolyte without any barrier layer. Characterization results showed that the SMO:NMO = …


In-Situ Stm Visualization Of Molecular Structural Evolution During Electrochemical Oxidation Coupling Of Para-Aminothiophenol On Au(111), Zi-Wei Ma, Tai-Rui Wu, An-Ni Zheng, Lai-Ke Chen, Yuan-Hui Xiao, Zhao-Bin Chen, Qing-Na Zheng, Jian-Zhang Zhou, Jia-Wei Yan, De-Yin Wu 2026 State Key Laboratory of Physical Chemistry of Solid Surface, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, PR China

In-Situ Stm Visualization Of Molecular Structural Evolution During Electrochemical Oxidation Coupling Of Para-Aminothiophenol On Au(111), Zi-Wei Ma, Tai-Rui Wu, An-Ni Zheng, Lai-Ke Chen, Yuan-Hui Xiao, Zhao-Bin Chen, Qing-Na Zheng, Jian-Zhang Zhou, Jia-Wei Yan, De-Yin Wu

Journal of Electrochemistry

Para-aminothiophenol (PATP) is not only a widely-used probe molecule in the field of surface-enhanced Raman spectroscopy (SERS), but also an important model molecule for interfacial reactions, exhibiting distinct photo- and electro-oxidation pathways, so that PATP is selectively activated under different external fields. The evolution of products and intermediates during electrochemical oxidative coupling remains unknown. In this study, we have investigated the dynamic electrochemical oxidation process of PATP on the Au(111) surface using cyclic voltammetry, electrochemical (EC)-SERS, and in situ electrochemical scanning tunneling microscopy (EC-STM). The results showed that PATP forms an unsaturated adsorption coverage on Au(111) in an acidic solution. …


Analysis Of Electronic Control Unit Optimization On The Performance Of A 150 Cc Motorcycle Engine Using Ethanol-Blended Fuel, Agus Achmad Syaiful, Annisa Bhikuning, Muhammad Rizal Baihaqi, Muhammad Aulia Rafli 2026 Universitas Trisakti, Jakarta, Indonesia

Analysis Of Electronic Control Unit Optimization On The Performance Of A 150 Cc Motorcycle Engine Using Ethanol-Blended Fuel, Agus Achmad Syaiful, Annisa Bhikuning, Muhammad Rizal Baihaqi, Muhammad Aulia Rafli

Journal of Mechanical Engineering Science and Technology (JMEST)

The use of ethanol-blended fuel in a standard vehicle can reduce combustion quality, which has an impact on decreasing vehicle performance. At the above 20% blend level, it affects vehicle performance and requires adjustments to engine settings or the Electronic Control Unit (ECU) before use on conventional engines. This study investigates the effect of aftermarket ECU settings on the performance of a 150 cc motorcycle operating on a gasoline-ethanol blend. Four fuel variations were tested: Pertalite (P100), revvo 90 (R100), and 30% ethanol blends (PE30 and RE30). This study analyzes the effects of optimizing injection duration and ignition timing settings …


Chemical Composition Stability Of Cu–Sn And Cu–Zn Journal Bechemical Composition Stability Of Cu–Sn And Cu–Zn Alloys Fabricated By Sand And Permanent Mold Casting With Nickel Alloying, Erwin Erwin, Didik Sugiyanto, Juan Pratama, Trisna Ardi Wiradinata, Abdul Rachmadhan, Muhammad Fikri Andika 2026 Darma Persada University, Jakarta Timur, Indonesia

Chemical Composition Stability Of Cu–Sn And Cu–Zn Journal Bechemical Composition Stability Of Cu–Sn And Cu–Zn Alloys Fabricated By Sand And Permanent Mold Casting With Nickel Alloying, Erwin Erwin, Didik Sugiyanto, Juan Pratama, Trisna Ardi Wiradinata, Abdul Rachmadhan, Muhammad Fikri Andika

Journal of Mechanical Engineering Science and Technology (JMEST)

The processes of moulding and reinforcing chemical elements have a big impact on the balance of chemical composition in copper-based bearing alloys. This has a direct impact on how well the material works. This study examines Cu–Sn alloys produced via sand casting and Cu–Zn alloys fabricated through permanent mould casting, with the incorporation of nickel, which remains uncommon. The objective was to examine the variations in the equilibrium of the chemical composition and the performance potential of the bearing alloy metal when subjected to different casting techniques and nickel concentrations ranging from 0% to 4%. Some of the methods used …


Effect Of Concentration And Temperature Of Tio2-Al2o3 Hybrid Nanofluid On The Corrosion Rate Of Aluminum Radiator, Ratna Monasari, Rizky Maulana Ramadhan, Nike Nur Farida, Ahmad Hanif Firdaus, Supa Kusuma Aji, Yuniarto Agus Winoko, Rizkyansyah Alif Hidayatullah 2026 Politeknik Negeri Malang, Malang, East Java, Indonesia

Effect Of Concentration And Temperature Of Tio2-Al2o3 Hybrid Nanofluid On The Corrosion Rate Of Aluminum Radiator, Ratna Monasari, Rizky Maulana Ramadhan, Nike Nur Farida, Ahmad Hanif Firdaus, Supa Kusuma Aji, Yuniarto Agus Winoko, Rizkyansyah Alif Hidayatullah

Journal of Mechanical Engineering Science and Technology (JMEST)

Corrosion of aluminum radiators can reduce cooling system reliability and shorten service life in automotive applications. This study examines the effect of TiO2-Al2O3 hybrid nanofluid concentration and temperature on the corrosion rate of commercially available aluminum radiator material. Hybrid nanoparticles with a TiO2-Al2O3 mass ratio of 50:50 were dispersed in distilled water at concentrations of 0.6 wt.%, 0.8 wt.%, and 1.0 wt.%. Corrosion behavior was evaluated using a 14-day accelerated immersion test at 60°C and 80°C, and the corrosion rate was determined using the gravimetric mass loss method. The results …


Straw As A Potential Vegetable Fibre Insulative Infill In Framed Constructions - Material Testing\Tnotereftnote1, Patrick Daly 2026 Principal Investigator Circular Reno Ireland – KORE AND School of Architecture Building and Environment, Technological University of Dublin, Ireland

Straw As A Potential Vegetable Fibre Insulative Infill In Framed Constructions - Material Testing\Tnotereftnote1, Patrick Daly

Journal of Sustainable Construction Materials and Technologies

The construction sector faces increasing pressure to reduce embodied carbon and adopt circular material strategies, with bio-based materials offering a promising pathway. Straw-based insulation, particularly in loose-fill form, has gained traction in Europe, where several products have achieved certification under EAD 040138-01-1201. This study investigates the potential of Irish-processed straw chip as a bio-based insulative infill for framed construction by evaluating its material properties and thermal conductivity–density performance relative to European ETA-certified reference products. A programme of laboratory testing was undertaken on commercially available Irish straw samples, including material characterisation (moisture content, particle morphology, and dust content) and thermal conductivity …


Development And Characterization Of Mycelium-Based Biocomposites From Ganoderma Lucidum Using Spent Yerba Mate And Residual Sunflower Oil For Sustainable Insulation In Construction, Paula V. Alfieri, Guadalupe Canosa 2026 Laboratorio de Biomateriales, Biorremediación y Biodeterioro, Universidad Tecnológica Nacional (UTN), Facultad Regional La Plata, Argentina

Development And Characterization Of Mycelium-Based Biocomposites From Ganoderma Lucidum Using Spent Yerba Mate And Residual Sunflower Oil For Sustainable Insulation In Construction, Paula V. Alfieri, Guadalupe Canosa

Journal of Sustainable Construction Materials and Technologies

The construction industry urgently requires sustainable alternatives to petroleum-based insulation materials such as expanded polystyrene (EPS) and mineral wool. Mycelium-based biocomposites offer a promising solution by valorizing agricultural waste while delivering competitive thermal and acoustic performance. In this study, developed and characterized biocomposites using Ganoderma lucidum mycelium combined with spent yerba mate and residual sunflower oil (70 g/30 mL), both commonly generated as waste in Argentine institutions. Two formulations were evaluated: high density (HD: 280 ± 5 kg/m³) and low density (LD: 185 ± 5 kg/m³). Samples were cultivated for 90 days at 28 °C and 65% relative humidity and …


Comparative Life Cycle Assessment Of Hemp Walls In Residential Construction In Morocco, Hicham Kaddouri, Rachida Elbarghmi, Firyal Latrache, Marwane Hammouti, Abderrahim Abidouche, Ismael Driouch 2026 Abdelmalek Essaadi University, National School of Applied Sciences, Al-Hoceima, Morocco

Comparative Life Cycle Assessment Of Hemp Walls In Residential Construction In Morocco, Hicham Kaddouri, Rachida Elbarghmi, Firyal Latrache, Marwane Hammouti, Abderrahim Abidouche, Ismael Driouch

Journal of Sustainable Construction Materials and Technologies

This study analyzes the energy and environmental performance of hemp-based wall solutions applied to Moroccan residential buildings by combining dynamic thermal simulation and life cycle assessment (LCA). A reference building is assessed under four representative Moroccan climates (Al Hoceima, Oujda, Marrakech, and Ouarzazate), comparing a conventional wall retrofitted with hemp plaster and a wall incorporating hemp concrete. The results show that hemp concrete significantly reduces annual heating and cooling energy demands by 20–24% depending on the climate, with heating needs decreasing by up to 40% and cooling needs by approximately 15%, particularly in hot and arid regions. The LCA reveals …


Dual-Waste Integration For Geotechnical Improvement: Silica Fume And Eggshell Ash In Kaolin Soil Stabilization, Ng Jun Shen, Muzamir Hasan, Siti Sarah Eliyun, Md. Ikramul Hoque, Mohamad Afiq Jazrin Mohamad Sidek 2026 Department of Civil Engineering, Faculty of Civil Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuhraya Tun Razak 26300 Kuantan, Pahang Darul Makmur, Malaysia

Dual-Waste Integration For Geotechnical Improvement: Silica Fume And Eggshell Ash In Kaolin Soil Stabilization, Ng Jun Shen, Muzamir Hasan, Siti Sarah Eliyun, Md. Ikramul Hoque, Mohamad Afiq Jazrin Mohamad Sidek

Journal of Sustainable Construction Materials and Technologies

This study reveals the potential substitution of silica fume and eggshell ash in the technique of soil stabilization, varying across distinct proportions in the modification of geotechnical parameters. The untreated kaolinitic soil which has low soil bearing capacity in nature is frequently reflected in its mechanical instability, for instance, soil settlement and extreme compressibility. By associating the industrial and agricultural material, it is potentially to resolve the above-mentioned issues with explicit designs. A number of laboratory approaches have been implemented in the assessment of basic geotechnical properties, including grain size distribution, Atterberg limits, specific gravity, proctor properties, and shear strength …


Numerical Simulation Of Centrifugal Pump Performance Under Impeller Blade And Suction Diameter Variations, Gunawan Budi Santoso, Susanto -, Akhmad Nuriyanis, Anang Budhi Nugroho, Rizka Noor Miftakhul Ulum, Suyono - 2026 Politeknik Maritim Negeri Indonesia, Kabupaten Semarang, Central Java, Indonesia

Numerical Simulation Of Centrifugal Pump Performance Under Impeller Blade And Suction Diameter Variations, Gunawan Budi Santoso, Susanto -, Akhmad Nuriyanis, Anang Budhi Nugroho, Rizka Noor Miftakhul Ulum, Suyono -

Journal of Mechanical Engineering Science and Technology (JMEST)

The objective of this study is to model variations in pump geometry to obtain optimal performance under the effects of cavitation. The resulting geometric variation models were then simulated using ANSYS Fluent software. The first geometric variation model used a standard 5-blade impeller with suction pipe diameter variations of 2, 2 ½, 2 ¾, 3, 3 ¼, 3 ½, and 4 inches. The second geometric variation model for simulation used a standard 3-inch suction pipe with impeller blade variations of 3, 4, 5, 6, 7, 8, and 9. The simulation results indicated that the number of blades without changes in …


Chemistry Of Co2 Capture And Storage: From Molecular Interactions To Advanced Functional Materials, Nany Hairunisa, Hazim F. Abbas, Amamer M. Redwan 2026 Department of Occupational Medicine, Faculty of Medicine, Universitas Trisakti, Jakarta,11440, INDONESIA

Chemistry Of Co2 Capture And Storage: From Molecular Interactions To Advanced Functional Materials, Nany Hairunisa, Hazim F. Abbas, Amamer M. Redwan

Al-Mustaqbal Journal of Sustainability in Engineering Sciences

In light of the industrial development taking place, the burning of fossil fuels for transportation and electricity generation, and the accompanying carbon dioxide emissions, there is an urgent and continuing need to innovate methods of capture and storage, as well as competitive materials to address increasing carbon emissions. This review describes the importance of this procedure and the technologies that help solve this problem, some of which have been adopted by many countries and industrial institutions and differ in their efficiency, cost, and applicability.


Influence Of Altitude On The Energy Payback Time Of Grid-Connected Photovoltaic Systems: A District-Level Analysis In Himachal Pradesh, India, Aniket Sharma, Mohinder Singh 2026 Research Scholar, HPKVBS, SCMS, Central University of Himachal Pradesh, India - 176215

Influence Of Altitude On The Energy Payback Time Of Grid-Connected Photovoltaic Systems: A District-Level Analysis In Himachal Pradesh, India, Aniket Sharma, Mohinder Singh

Al-Mustaqbal Journal of Sustainability in Engineering Sciences

This study presents a district-level assessment of the influence of altitude on the Energy Payback Time (EPBT) of grid-connected photovoltaic (PV) systems in the Western Himalayan region of Himachal Pradesh, India. Although several studies have examined photovoltaic performance under different climatic conditions, systematic evaluation of altitude-sensitive EPBT using a standardized PV configuration remains limited for mountainous regions. A uniform 14.82 kWp polycrystalline PV system was simulated for twelve district headquarters representing elevations from 360 m to 3025 m above sea level using PVsyst software and Meteonorm meteorological data. Annual energy output and EPBT were evaluated under identical system configuration and …


Energy And Exergy Analysis Of Combined Cycle Power Plants: A Comprehensive Evaluation, Mohammad Ibrahim Hussein Hussein 2026 Islamic Azad University, South Tehran Branch, Faculty of Technology and Engineering

Energy And Exergy Analysis Of Combined Cycle Power Plants: A Comprehensive Evaluation, Mohammad Ibrahim Hussein Hussein

Al-Mustaqbal Journal of Sustainability in Engineering Sciences

Evaluating the thermodynamic performance of combined cycle power plants (CCPPs) requires a comprehensive understanding of both energy quantity and energy quality across highly integrated components, including the gas turbine, heat recovery steam generator (HRSG), steam turbine, and condenser. This study presents a structured critical review of recent developments in energy and exergy analysis of CCPPs, covering studies published between 2001 and 2025. Unlike previous descriptive summaries, this work introduces a comparative synthesis framework that critically evaluates component-level losses, thermodynamic irreversibilities, and system optimization strategies across conventional and advanced CCPP configurations. The review shows that the condenser is the dominant source …


Mitigating The Effects Of Poor Power Quality Conditions Using Adaptive Model Predictive Current Control, B. O. Akinloye, B. G. Ologunwa, A. A. Okubanjo 2026 Department of Electrical and Electronics Engineering, Federal University of Petroleum Resources, Effurun, Nigeria

Mitigating The Effects Of Poor Power Quality Conditions Using Adaptive Model Predictive Current Control, B. O. Akinloye, B. G. Ologunwa, A. A. Okubanjo

Al-Mustaqbal Journal of Sustainability in Engineering Sciences

Permanent Magnet Synchronous Motors (PMSMs) are susceptible to performance degradation in applications with poor power quality, such as those found in regions with unstable electrical grids. Conventional control strategies often fail to maintain stability and efficiency under simultaneous voltage sags and harmonic distortions. This paper presents an adaptive Model Predictive Current Control (MPCC) framework designed to enhance the resilience of PMSM drives under such composite disturbances. The proposed strategy integrates three key mechanisms: a real-time voltage sag compensation module that adjusts current references and employs flux-weakening, a multivector-based harmonic mitigation technique embedded within the predictive cost function, and a thermal …


Effect Of Naoh Concentration On The Structural, Morphological, And Tensile Properties Of Pineapple Stem Fibers, Ahmad Norca Kurnia Zen, Heru Suryanto, Aminnudin Aminnudin, Fajar Nusantara, Joseph Selvi Binoj 2026 Master Program of Mechanical Engineering, Faculty of Engineering, State University of Malang, Indonesia

Effect Of Naoh Concentration On The Structural, Morphological, And Tensile Properties Of Pineapple Stem Fibers, Ahmad Norca Kurnia Zen, Heru Suryanto, Aminnudin Aminnudin, Fajar Nusantara, Joseph Selvi Binoj

Journal of Mechanical Engineering Science and Technology (JMEST)

Natural fiber reinforced composites are increasingly being developed due to their environmentally friendly nature, low production costs, and safety for human health. However, the presence of lignin and hemicellulose reduces adhesion properties between fiber and composite matrix. Alkalization treatment is an effective way to remove lignin and hemicellulose attached to cellulose. This study aims to determine the optimum concentration of NaOH used during alkalization process of pineapple stem fiber. The methods included the retting process of fibers from pineapple stems. The obtained fibers were soaked in variations of 2%, 4%, 6%, and 8% NaOH for 4 hours,  then dried and …


Performance Evaluation And Sustainable Benefits Of Using Metakaolin And Recycled Steel Fibers In Concrete, Lova Raju Surla, Ramprasad Naik Desavathu, Raja Murugadoss Jeyaraju 2026 Ph.D. Candidate, Department of Civil Engineering, GIET University, Gunupur, Odisha, India

Performance Evaluation And Sustainable Benefits Of Using Metakaolin And Recycled Steel Fibers In Concrete, Lova Raju Surla, Ramprasad Naik Desavathu, Raja Murugadoss Jeyaraju

Journal of Sustainable Construction Materials and Technologies

The rapid accumulation of waste vehicle tires and the increasing demand for cement pose significant environmental challenges through land pollution and CO2 emissions. The combined use of recycled steel fibers (RSFs) recovered from waste tires and supplementary cementitious materials (SCMs) offers a sustainable solution to these issues. This study investigates concrete incorporating 20% fly ash (FA), varying metakaolin (MK) contents (4–16%), and RSF dosages of 0.5–1.5%. Mechanical properties (compressive, split tensile, and flexural strengths) and durability characteristics (sorptivity, water absorption, chloride permeability, and homogeneity) were evaluated at 7, 28, and 90 days. Results showed that the mixture containing 20% FA …


Climate-Responsive Design For Sustainable Construction: Passive Strategies In Domestic Architecture Supporting Sustainability, Nahed Chakouf 2026 Department of College of Arts and Creative Enterprise, Zayed University, Dubai, United Arab Emirates

Climate-Responsive Design For Sustainable Construction: Passive Strategies In Domestic Architecture Supporting Sustainability, Nahed Chakouf

Journal of Sustainable Construction Materials and Technologies

This study explores climate-responsive design in domestic architecture, focusing on the application and effectiveness of passive strategies across various climatic regions, including the UK, hot-arid, tropical, and cold climates. A qualitative comparative case study method was used to explore different passive design strategies, integration of sustainability, procurement, the coordination of stakeholders, and compliance with regulations in residential architectural projects under varying climate conditions. Drawing from a combination of historical case studies and original architectural projects, the research evaluates how spatial configuration, material selection, solar orientation, shading, ventilation, and insulation are optimized to achieve thermal comfort and energy efficiency. In temperate …


Magnetic Field-Induced Transformation In Polycrystalline Ni2mnal Heusler Type Magnetic Shape Memory Alloy, Choji J. Daches, Joseph W. Newkirk, Mario Buchely, Laura N. Bartlett 2026 Missouri University of Science and Technology

Magnetic Field-Induced Transformation In Polycrystalline Ni2mnal Heusler Type Magnetic Shape Memory Alloy, Choji J. Daches, Joseph W. Newkirk, Mario Buchely, Laura N. Bartlett

Materials Science and Engineering Faculty Research & Creative Works

The martensitic and magnetic transformations, as well as the mechanical properties, of Ni₂MnAl alloys in as-cast (AC) and heat-treated (HT) conditions were investigated. Magnetic-field-induced strain was evaluated via magnetostriction, with reversible strains of 0.14% and 0.2% achieved in the martensitic phase at 2 K for the AC and HT alloys, respectively. Transformation temperatures and Curie temperatures were determined under constant applied magnetic field, revealing that γ-phase inclusions in the AC microstructure suppress antiferromagnetic domain response, yielding a lower magnetization (∼8.4 emu g⁻¹) compared to the HT alloy (∼13.4 emu g⁻¹). Both alloys exhibited hysteretic behavior in the martensitic state and …


Li+/Na+ Hybrid Ion Conduction Mechanism In The Superionic Conductor Li3–XNaXZr2Si2Po12, Yi-Hong Wu, Xia Xie, Lei Zhu, Mu-Ran Yu, Guo-Tai Zhang, Jun-Chao Chen, Shu-Ying Sun, You-Wei Wang, Wei-Ping Tang 2026 School of Resources and Environmental Engineering, East China University of Science and Technology, Shanghai, 200237, China

Li+/Na+ Hybrid Ion Conduction Mechanism In The Superionic Conductor Li3–XNaXZr2Si2Po12, Yi-Hong Wu, Xia Xie, Lei Zhu, Mu-Ran Yu, Guo-Tai Zhang, Jun-Chao Chen, Shu-Ying Sun, You-Wei Wang, Wei-Ping Tang

Journal of Electrochemistry

Hybrid ion conductors that transport multiple ionic conductive species provide a useful platform for understanding how mixed-ion transport governs ionic conductivity within a single phase. However, the controlled introduction of multiple mobile ions into solid-state electrolytes and a mechanistic understanding of their migration within the framework remain challenging. Herein, a skeleton-retained Li+↔Na+ cationic exchange was used to simultaneously induce Li+ and Na+ cations into the NASICON-type framework of Li3–xNaxZr2Si2PO12 (0 < x < 3). We show that the interpenetration of NaO6 and NaO8 coordination polyhedra significantly influences the ionic conductivity of hybrid ion conductors. Computational …


Distinct Co2 Electroreduction Behaviors Over Planar And Non-Planar Cobalt Molecular Catalysts, Ru Jia, Cheng-Biao Zhu, Zi-Mo Zhang, Tuo Wang, Kai-Cong Yang, Guang-Zhe Wang, Yang Hu, Ting-Ting Zhang, Zhen-Wei Wei, Li Xiao, Gong-Wei Wang, Lin Zhuang 2026 College of Chemistry and Molecular Sciences, Hubei Key Lab of Electrochemical Power Sources, Wuhan University, Wuhan 430072, China

Distinct Co2 Electroreduction Behaviors Over Planar And Non-Planar Cobalt Molecular Catalysts, Ru Jia, Cheng-Biao Zhu, Zi-Mo Zhang, Tuo Wang, Kai-Cong Yang, Guang-Zhe Wang, Yang Hu, Ting-Ting Zhang, Zhen-Wei Wei, Li Xiao, Gong-Wei Wang, Lin Zhuang

Journal of Electrochemistry

Molecular catalysts serve as ideal platforms for studying electrocatalytic reaction mechanisms. While current research mainly focuses on modulating central metals or surrounding ligands, the influence of molecular spatial configuration remains largely unexplored. Herein, we synthesized two cobalt complexes with similar ligand environments but distinct spatial geometries, a planar cobalt hexaazamacrocyclic complex (CoHAM) and a non-planar acyclic Co(phen)2Cl2, and evaluated their performance in CO2 reduction reaction (CO2RR). The planar CoHAM exhibited dramatically superior CO2RR performance compared to the non-planar Co(phen)2Cl2. Through a series of combined analyses using in-situ …


Digital Commons powered by bepress