Engineering Science and Materials Commons^™

Electric Current Induced Flow And Electrocapillary Deformation Of Liquid Wood Alloy In Naoh Aqueous Solution, Guo-Di Zhang, Qiao-Li Lin, Jian-Hong Cheng, Rui Cao

Journal of Electrochemistry

The phenomena of the electric current induced flow and electrocapillary deformation for a liquid Wood alloy in a NaOH electrolyte were studied. Electrocapillary behaviors for the liquid Wood alloy in NaOH electrolytes by applying external low voltages were investigated. The electrode reaction (redox reaction) induced the formation or removing removal of an oxide film, and further caused the drop deformation by decreasing or increasing an interfacial tension. The same polar charge in the electric double layer would also decrease the interfacial tension. In order to maintain the stability of system, the contact area of the interface would be expanded, and …

A New Type Carbon Composited Molybdenum Doped Vanadium Oxide Nanowires As A Cathode Material For Sodium Ion Batteries, Guang-Rui Zhang, Li-Qiang Hu, Bao-Zhu Zhang

Journal of Electrochemistry

In recent years, the development of lithium ion batteries (LIBs) has been limited due to the insufficient lithium resource and increasing cost. As a promising candidate, sodium ion batteries (SIBs) with the similar electrochemical mechanism and lower cost than LIBs are developing rapidly. However, as a result of the larger radius of Na⁺ compared with Li⁺, the crystalline structures of the most electrode materials are damaged severely during the intercalation of Na⁺, which limits the electrochemical properties of SIBs. Thus, developing new types of electrode materials for SIBs is particularly important. Among the cathode materials, …

Influence Of Typical Anions In Seawater Environments On Corrosion Behaviors Of 5083 Aluminum Alloy, Yang-Fan Tu, Li-Ming Feng, Zhi-Gang Fang, Hai-Tao Liu, Ming-Hua Jing, Yong Guan

Journal of Electrochemistry

The interaction effects of typical anions, namely, Cl^-, HCO₃^- and SO₄^2-, presented in seawater environments on corrosion resistance behaviors of AA5083 aluminum alloy have been studied. The corrosion resistances of the 5083 aluminum alloy in different simulated seawater environments were tested by factorial analysis method. The polarization curves, the corrosion potentials, corrosion current densities and the breakdown potentials were examined in different concentrations of Cl^-, HCO₃^- and SO₄^2-.The corrosion behavior was analyzed by electrochemical impedance spectroscopy (EIS). The results showed that both Cl^-,  and …

Effects Of Temperature On The Nucleation And Growth Mechanism Of Pbo2 Electrodeposition, Lei Wang, Juan-Qin Xue, Li-Hua Yu, Chang-Bin Tang, Qiang Bi

Journal of Electrochemistry

In order to investigate the effects of temperature on the nucleation and growth of lead dioxide (PbO₂), the in situ electrochemical depositions of PbO₂ were carried out on the glassy carbon electrode at different temperatures, namely, 25℃,35℃, 45℃, 55℃, and 65℃.The cyclic voltammetric curves, the time-current and the time-potential curves,SEM images and XRD patterns of the PbO₂ coatings deposited at different temperatures were obtained. The results showed that the PbO₂ underwent nucleation and grew at different temperatures. The 3D continuous nucleation mode of PbO₂ electrodeposition remained unchanged with the increase of temperature. However, the …

Tetrabutylammonium Hexafluorophosphate As Flame Retardant Additive For Lithium Ion Batteries, Qing Zhao, Qian Zhang, Jing-Min Fan, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

Safety issues have been attracted more and more attentions due to the wide applications of lithium ion batteries. Introducing flame retardant additives are one of the effective strategies to improve the safety of lithium-ion batteries. In this paper, the tetrabutylammonium hexafluorophosphate (TBAPF₆) as a flame retardant additive was added to the electrolyte as a flame retardant additive to enhance the safety of lithium ion batteries. The self-extinguishing time (SET) and ionic conductivities of the electrolytes with different TBAPF₆ contents were investigated. It is found that TBAPF6 dramatically reduced the flammability of the electrolyte while slightly decreasing ionic …

Electrochemical Performance Of Sodium Difluoro(Oxalato)Borate As The Additive Of Non-Aqueous Electrolytes For Sodium-Ion Batteries, Ding Zhang, Qin Zhu, Ying Wang, Cheng-Long Zhao, Shi-Bin Liu, Shou-Dong Xu

Journal of Electrochemistry

Sodium ion battery has attracted worldwide and intensive attention recently, while the adoption of electrolyte additives has been considered as one effective strategy to promote the cell performance. Within this work sodium difluoro(oxalato)borate (NaDFOB) was prepared and adopted as an additive for the general non-aqueous electrolyte formula of 1 mol·L-1 NaClO4/EC/PC (Vol: Vol=1:1), and the effects of the additive concentration on ionic conductivity and oxidization decomposition voltage were investigated in detail. In addition, the cell performance evaluated by NaNi0.5Mn0.5O2 as the cathode was also studied. It reveals that the addition of NaDFOB into the NaClO4/EC/PC electrolyte resulted in the significantly …

An Investigation Of The Synergistic Effect Between (1,3-Dioxolan-2-Ylmethyl)Triphenylphosphonium Bromide And Iodide Ion For The Corrosion Inhibition Of Zinc In Citric Acid, Saadawy M.

Journal of Electrochemistry

The effect of (1,3-Dioxolan-2-ylmethyl)-triphenylphosphonium bromide (DTPB) on the zinc corrosion in 0.5 mol·L^-1 citric acid solution was investigated at 30 ^oC using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. An ecofriendly bath was used for acid cleaning of zinc, which has not been widely used in literatures. The results showed that DTPB could serve as an effective inhibitor for the zinc corrosion in a citric acid solution with the inhibition efficiency of 98.9% at the DTPB concentration of 3×10^-3 mol·L^-1. A synergistic effect between DTPB and potassium iodide (KI) enhanced the inhibition …

Effects Of Surface Modification Modes On Proton-Over-Vanadium Ion Selectivity Of Nafion®Membrane For Application In Vanadium Redox Flow Battery, Qing-Long Tan, Hai-Ning Wang, Shan-Fu Lu, Da-Wei Liang, Chun-Xiao Wu, Yan Xiang

Journal of Electrochemistry

The effect of surface modification modes on proton-over-vanadium ion selectivity was studied by spin-coating chitosan-Phosphotungstic Acid (PWA) as a single or double layer on Nafion membrane surface. To suppress the vanadium ions permeation through the Nafion? membrane in a vanadium redox flow battery (VRFB), the single surface-modified Nafion membrane (Nafion/chitosan-PWA)S and double surface-modified Nafion membrane (Nafion/chitosan-PWA)D demonstrated a 89.9% and 92.7% reduction of vanadium ion permeability in comparison with pristine Nafion, respectively. The (Nafion/chitosan-PWA)D exhibited betterhigher selectivity between proton and vanadium ions than the (Nafion/chitosan-PWA)S at the same layer thickness. Furthermore, the columbic efficiency for the VRFB single cell based …

Rice Hull Bioreactor For Recirculating Aquaculture, Marlon A. Greensword

LSU Doctoral Dissertations

The engineering of floating media biofilters has been optimized over the years. The backwashing process has made them more energy and water efficient. Likewise, moving bed bioreactors (MBBR) are gaining interest and popularity because they are relatively affordable to build. Yet, developing countries’ aquaculture production remains largely excluded from the advances made in recirculating aquaculture systems (RAS). This discrepancy is partially driven by the high costs of media such plastic beads and Kaldnes (KMT) media, commonly used in MBBR.

This dissertation evaluates the usability and profitability of rice hulls (RH), an abundant by-product in many developing nations, as a sinking …

Energy Absorbing Guardrail System, John R. Rohde, John D. Reid, King K. Mak, Dean L. Sicking

Department of Mechanical and Materials Engineering: Faculty Publications

A highway crash attenuation system having W - beam rail elements attached to a plurality of vertical posts . An impact terminal with a feeder chute guides one or more of the W - beam rail elements through the impact terminal . The feeder chute has an impact shield extending along a traffic facing side of the chute from an upstream - most end to a downstream - most end of the chute closing the traffic - facing side of the chute . The system also has an anchor cable release mechanism for releasing the cable downstream of the first …

Photodynamic Therapy: Agents And Mechanisms, Rebecca Claire Gilson

McKelvey School of Engineering Graduate Student Theses & Dissertations

Despite enormous efforts, cancer remains a leading cause of morbidity and mortality world-wide. The main challenges currently facing cancer therapy include lack of adequate tumor targeting, failure to treat hypoxic tumor cells, and induction therapy resistant tumors. A solution to these limitations can be found in photodynamic therapy (PDT) which combines light and light activatable compounds, photosensitizers (PSs), to produce cytotoxic reactive oxygen species (ROS) to damage tumor tissue. This creates a spatiotemporal therapeutic effect, where cell damage only occurs at the intersection of the PS and light. PDT can treat tumors through unique mechanisms which reduce induction of tumor …

Hollow And Porous Plasmonic Nanostructures For Highly Efficient Chemical And Biological Sensing, Keng-Ku Liu

McKelvey School of Engineering Graduate Student Theses & Dissertations

Localized surface plasmon resonance (LSPR) involves the collective and coherent oscillation of dielectrically confined conduction electrons. The LSPR wavelength of noble metal nanoparticles (such as gold, silver and copper), which falls into the visible and near infrared range of the electromagnetic spectrum, is sensitive to the composition, size, shape, dielectric properties of the surrounding medium, and proximity to other nanostructures (plasmon coupling). Based on the sensitivity of the surface plasmon resonance to the changes in the dielectric properties of the surrounding medium and the enhancement of the electromagnetic (EM) field in proximity of metal nanostructures, two important classes of plasmonic …

Shape-Adaptive Mechanism For Robotic Grasping, Carl A. Nelson

Department of Mechanical and Materials Engineering: Faculty Publications

A grapser can include a first pantograph cell and a second pantograph cell coupled with the first pantogrpah cell. The first and second pantograph cells can be coupled together at a first pivot and a second pivot. The grasper can also include a finger extendable in a direction extending between the first pivot and the second pivot. The grasper can include a support base, where one or more links of the first pantograph cell can be slidably coupled with the support base for extending the grasper. In some embodiment, the grasper can be configured to extend along a curved path. …

Simulating Dynamic Failure Of Polymer-Bonded Explosives Under Periodic Excitation, Rachel Kohler, Camilo Duarte Cordon, Marisol Koslowski

The Summer Undergraduate Research Fellowship (SURF) Symposium

Accidental mishandling of explosive materials leads to thousands of injuries in the US every year. Understanding the mechanisms behind the detonation process is crucial to prevent such accidents. In polymer-bonded explosives (PBX), high-frequency mechanical excitation generates thermal energy and can lead to an increase in temperature and vapor pressure, and potentially the initiation of the detonation process. However, the mechanisms behind this energy release, such as the effects of dynamic fracture and friction, are not well understood. Experimental data is difficult to collect due to the different time scales of reactions and vibrations, so research is aided by running simulations …

Technology To Manufacture Oriented Pvc (Pvc-O) Pipes, Purdue Ect Team

ECT Fact Sheets Archive

The development of Molecor´s technology, which is based on the application of a Molecular Orientation process, has delivered a significant turning point in the pipelines sector. With this technological development, the company has begun to manufacture TOM® PVC-O pipes, the most eco-friendly pipes on the market. The Molecor technology enabled eradicating many of the existing disadvantages of thermoplastic pipes.

This technology delivers a clear objective; to provide the water industry with a solution for pipes carrying pressurized water in an environmentally friendly, yet cost efficient manner. This also extends a service life compared to pipeline materials currently in use.

The …

Thermodynamics Of Coherent Structures Near Phase Transitions, Julia M. Meyer, Ivan Christov

The Summer Undergraduate Research Fellowship (SURF) Symposium

Phase transitions within large-scale systems may be modeled by nonlinear stochastic partial differential equations in which system dynamics are captured by appropriate potentials. Coherent structures in these systems evolve randomly through time; thus, statistical behavior of these fields is of greater interest than particular system realizations. The ability to simulate and predict phase transition behavior has many applications, from material behaviors (e.g., crystallographic phase transformations and coherent movement of granular materials) to traffic congestion. Past research focused on deriving solutions to the system probability density function (PDF), which is the ground-state wave function squared. Until recently, the extent to which …

A Parametric Study Of The Mechanics Of Different Skin Flap Techniques, Steven J. Meza, Adrián Tepole Buganza

The Summer Undergraduate Research Fellowship (SURF) Symposium

In modern day plastic and reconstructive surgeries numerous skin flap designs have been developed and are used to close open wounds. Skin flaps are developed with the intention of imposing minimal tension in skin closure. Excessive tension can lead to poor blood flow that result in post-surgery complications such as necrosis. Currently there is no standard in choosing a skin flap design and a surgeon's choice is based personal experience. A comparison of the mechanical loading in these various designs has not yet been done. We have developed a parametric study, using finite element analysis, of two advancement skin flaps …

Development Of The End-Effector Of A Cable-Driven Parallel Manipulator For Automated Crop Sensing, Iman Salafian

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

A four cable-driven parallel manipulator (4CDPM), consisting of sophisticated spectrometers and imagers, is under development for use in acquiring phenotypic and environmental data over an acre-sized maize field. This thesis presents the design, controls, and testing of two sub-systems in a 4CDPM: a Center of Mass Balance System (CMBS) and a Drop-Down System (DDS).

One of the factors that influences stability is the center of mass (COM) position of the end effector. An offset in COM can cause a pendulum effect or an undesired tilt angle. A center of mass balancing system is presented in this thesis to minimize the …

Optimum Conditions For Eor Using Nanofluids Subjected To Em Waves, Muhammad Kashif, Poppy Puspitasari

Journal of Mechanical Engineering Science and Technology (JMEST)

Today’s major challenge for oil industry is to improve the oil recovery from the reservoir. Various enhanced oil recovery (EOR) methods have been applied in the field and the steam injection is one of the most favourable methods. The deep reservoir will result in failure of this method due to excessive heat dissipation. In this situation, generating and injecting steam may be uneconomical due to the tremendous reduction of the recovery. Some methods using nanotechnology have been introduced and elaborated. However, we propose the electromagnetic (EM) method as an alternative due to its long range transmission of the transverse waves. …

Analysis Of Strength Of Glass Fibre Composite Leaf Spring Using Finite Element Method, Andoko Andoko, Poppy Puspitasari, Avita Ayu Permanasari

Journal of Mechanical Engineering Science and Technology (JMEST)

Leaf spring, as one of the main components of the suspension system, serves the function of absorbing road shocks and any wheel vibrations, preventing them from being transmitted directly to the vehicle body. Moreover, it can increase the tire traction as well as support the weight of the vehicle and various kinds of external forces. Various studies on the use of composite materials for leaf springs have shown that the strength of composite leaf spring is similar to steel leaf spring with the same load carrying capacity. However, the composite leaf spring has the added advantage of being more lightweight. …