Engineering Science and Materials Commons^™

In Situ/Operando Visualization Of Electrode Processes In Lithium-Sulfur Batteries: A Review, Shuang-Yan Lang, Xin-Cheng Hu, Rui Wen, Li-Jun Wan

Journal of Electrochemistry

Lithium-sulfur (Li-S) batteries have been regarded as one of the most promising candidates for the next-generation energy storage devices. Fundamental understanding of the structure and evolution processes at electrode-electrolyte interfaces is essential to the further development. In this review, we summarize recent advances in the interfacial observations by means of various in situ/operando visualization techniques, including scanning probe microscopy (SPM), electron microscopy (EM), X-ray microscopy (XRM) and optical microscopy (OM). The real-time investigation provides important evidence for the morphology and component changes including S/Li₂S transformation, polysulfide dissolution on cathodes and Li/solid electrolyte interphase (SEI) evolution on anodes, which …

Sensitive Photoelectrochemical Assay Of Nucleic Acids Based On Catalytic Hairpin Assembly And Ru(Nh3)63+, Ya-Min Fu, Xiao-Xia Yan, Xiao-Hua Zhang, Jin-Hua Chen

Journal of Electrochemistry

A simple “signal-on” photoelectrochemical (PEC) sensing platform for sensitive assay of nucleic acids was developed by coupling catalytic hairpin assembly (CHA) signal amplification strategy with Ru(NH₃)₆³⁺. Herein, cadmium sulfide (CdS) was deposited on the TiO₂/indium tin oxide (ITO) electrode by a method of successive ionic layer adsorption and reaction (SILAR), serving as one kind of photoelectric material to broaden absorption range of TiO₂ and to improve the photoelectric conversion efficiency. Thereafter, the capture DNA (C-DNA) was immobilized on the CdS/TiO₂/ITO electrode. Simultaneously, Au-hairpin DNA probe 1 (Au-HP1) and hairpin DNA …

A Facile Strategy For Two-Step Fabrication Of Gold Nanoelectrode For In Vivo Dopamine Detection, Li-Hao Guan, Chao Wang, Wang Zhang, Yu-Lu Cai, Kai Li, Yu-Qing Lin

Journal of Electrochemistry

In vivo monitoring neurochemicals with microelectrode is invasive and the damage to brain tissue may inevitably cause disturbance signals physiologically to the measurement. It is of great importance to reduce the electrode size and to decrease the damage. This study demonstrates a novel nanoelectrode preparation methodology for in vivo monitoring dopamine (DA) fluctuation in the living brain of rats with high dependability. The fabrication process of the gold nanoelectrode involving a few minutes consists of only two steps: 1) growing gold nanoseeds on surface of tip of glassy capillary by ion sputtering; 2) wet depositing a continuous conductive gold film …

Preparation And Electrocatalytic Oxygen Reduction Performance Of Self-Doped Sludge-Derived Carbon, Ya-Li Ye, Wei-Ming Feng, Ge Li, Zhen-Chao Lei, Chun-Hua Feng

Journal of Electrochemistry

The development of low-cost, high-performance cathode catalysts is critical for practical application of fuel cells. Here, the N, P-doped porous graphene-like carbon with outstanding oxygen reduction reaction (ORR) performance was synthesized by pyrolysis of surplus sludge, which functioned as a self-doped, self-activated, and self-templated precursor by acclimation with continuous feedings of phenol. The results show that the amounts of microorganisms were enriched after acclimation, with increasing contents of N, P, Fe, as well as C atoms. The increasing pyrolysis temperature resulted in the formation of an ordered graphitic structure, however, the excessively high temperature induced the drop in the amounts …

Influence Of Metal Additives On Microstructure And Properties Of Amorphous Metal–Sioc Composites, Kaisheng Ming, Qing Su, Chao Gu, Dongyue Xie, Yongqiang Wang, Michael Nastasi, Jian Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Strong, ductile, and irradiation-tolerant structural materials are in urgent demand for improving the safety and efficiency of advanced nuclear reactors. Amorphous ceramics could be promising candidates for high irradiation tolerance due to thermal stability and lack of crystal defects. However, they are very brittle due to plastic flow instability. Here, we realized enhanced plasticity of amorphous ceramics through compositional and microstructural engineering. Two metal–amorphous ceramic composites, Fe-SiOC and Cu-SiOC, were fabricated by magnetron sputtering. Iron atoms are preferred to form uniformly distributed nano-sized Fe-rich amorphous clusters, while copper atoms grow non-uniformly distributed nano-crystalline Cu particles. The Fe-SiOC composite exhibits high …

Equivalent Numerical Algorithm For The Strip-Rolling Process Of A Continuous Variable Crown Mill Using The Coupled Rigid-Plastic Finite Element Method, Tao Wang, Zhong-Kai Ren, Dong-Ping He

Journal of Marine Science and Technology–Taiwan

For the accurate simulation of the rolling process of a wide strip and plates, highly sophisticated algorithms must be developed to couple material flow behavior with the elastic deformation of rolls. A coupling simulation system based on a three-dimensional rigid-plastic finite element method (RPFEM), elastic-plastic finite element method, and influential function method was developed in this study. Calculation of the continuous variable crown (CVC) mill was more complex than that of the normal 4-high rolling mill. According to the point symmetry of the roll gap profile, the CVC curves of work rolls at various shifting positions were equal to various …

Mechanical And Tribological Behaviour Of Treated And Untreated Moringa Oleifera Pods Fiber Reinforced Epoxy Polymer Composite For Packaging Applications, Prakash Sampath, Senthil Kumar V.S Dr

Journal of Applied Packaging Research

Researchers now focus on the use of natural fiber polymer composites materials for packing applications. This attention is due to their low cost and renewable characteristics. Fabrication of composites with the use of renewable resources has many benefits of alternating from an appropriate management and reduction in industrial wastages, ecofriendly behaviour to cost effectiveness. The artificial fibers in packing industries can be replaced by natural fibers in the areas where stiffness and high strength are not the primary requirement. In the last decade the use of Natural fibers in the place of artificial fibers for reinforcements in epoxy resin matrix …

Biomechanical Foot Guidance Linkage, Carl Nelson, Cale J. Stolle, Judith M. Burnfield

Department of Mechanical and Materials Engineering: Faculty Publications

A gait replication apparatus can include a scalable mechanical mechanism configured to replicate different gaits . The scalable mechanical mechanism can include , for example , a four - bar linkage , a pantograph , a cam / Scotch - yoke mechanism , and so forth . In some embodiments , the mechanical mechanism includes a beam rotating about an axis passing proximate to its center , with a foot pedal slidably coupled with the beam , and a timing chain / belt or cable pulley - pair coupled with the foot pedal and looped about the beam . A …

A Discrete Curvature Estimation Based Low-Distortion Adaptive Savitzky-Golay Filter For Ecg Denoising, Hui Huang, Shiyan Hu, Ye Sun

Department of Mechanical and Aerospace Engineering Publications

Electrocardiogram (ECG) sensing is an important application for the diagnosis of cardiovascular diseases. Recently, driven by the emerging technology of wearable electronics, massive wearable ECG sensors are developed, which however brings additional sources of noise contamination on ECG signals from these wearable ECG sensors. In this paper, we propose a new low-distortion adaptive Savitzky-Golay (LDASG) filtering method for ECG denoising based on discrete curvature estimation, which demonstrates better performance than the state of the art of ECG denoising. The standard Savitzky-Golay (SG) filter has a remarkable performance of data smoothing. However, it lacks adaptability to signal variations and thus often …

Mechanism For Disodium Carboxymethyl Trithiocarbonate (Orfom® D8) Depression In Chalcopyrite-Molybdenite Flotation Systems, Simon Timbillah

Graduate Theses & Non-Theses

The chalcopyrite-molybdenite (Cu-Mo) flotation industry is increasingly turning to organic depressants as suitable replacements for inorganic reagents such as NaHS due to environmental and safety concerns as well as high consumption rates of the inorganic reagents. An opportunity arises for improving, designing and synthesizing new alternative reagents. Disodium Carboxymethyl Trithiocarbonate (Orfom^® D8) depressant is an organic depressant with a carboxylate group on one end and a trithiocarbonate group at the other end. Fundamental results are shown regarding the interaction of the Orfom^® D8 depressant in the bulk flotation of a Cu-Mo concentrate from an operating North American mine. …

Investigation Of Multiple Torch Paw-Based Additive Manufacturing, Nathan Huft

Graduate Theses & Non-Theses

PAW Print 3D (PP3D), a wire and arc additive manufacturing (AM) system was developed. PP3D comprises three plasma arc welding torches arranged radially around a central wire feed. Using three torches was hypothesized to eliminate sensitivity to travel direction. Two deposition modes were developed – continuous, which deposited continuous beads, and dabber, which deposited discreet “dabs” of material. Dabber was hypothesized to provide favorable solidification conditions that would refine the as-deposited grain structure. Three sets of process parameters for each deposition mode were developed. Ineffective workpiece melting was observed and investigated during process development. Using COMSOL Multiphysics software and experimental …

A Novel Correlation Model For Horizontal Axis Wind Turbines Operating At High-Interference Flow Regimes, Anurag Rajan, Fernando L. Ponta

Department of Mechanical and Aerospace Engineering Publications

Driven by economics-of-scale factors, wind-turbine rotor sizes have increased formidably in recent years. Larger rotors with lighter blades of increased flexibility will experiment substantially higher levels of deformation. Future turbines will also incorporate advanced control strategies to widen the range of wind velocities over which energy is captured. These factors will extend turbine operational regimes, including flow states with high interference factors. In this paper we derive a new empirical relation to both improve and extend the range of Blade Element Momentum (BEM) models, when applied to high interference-factor regimes. In most BEM models, these flow regimes are modeled using …

Computational Aerothermodynamic Analysis Of Satellite Trans-Atmospheric Skip Entry Survivability, John J. Runco

Theses and Dissertations

Computational aerothermodynamic analysis is presented for a spacecraft in low Earth orbit performing an atmospheric skip entry maneuver. Typically, atmospheric reentry is a terminal operation signaling mission end-of-life and, in some instances, executed for spacecraft disposal. A variation on reentry – skip entry – is an aeroassisted trans-atmospheric maneuver in which a spacecraft utilizes the effects of aerodynamic drag in order to reduce energy prior to a terminal entry, pinpoint a targeted entry, or change orbital elements such as inclination. Spacecraft performing a skip entry enable new modes of maneuver to enhance operations in nominal or possibly contested mission environments. …

Tracking Shock Movement On The Surface Of An Oscillating, Straked Semispan Delta Wing, Justin A. Pung

Theses and Dissertations

A recent research effort, sponsored by the Air Force Office of Scientific Research, numerically investigated the unsteady aerodynamic flow field around an oscillating, straked, delta wing. The study was centered on determining the importance of the unsteady aerodynamic forces acting as a driver for a nonlinear motion known as limit cycle oscillations. The current effort focused on creating a computational model to compare to the results of previous tests and modeling efforts and discover new information regarding the onset of LCO. The computational model was constructed using the Cartesian overset capabilities of the CREATE-AV™ fixed wing fluid dynamics solver Kestrel. …

Ballistic Evaluation Of Carbon Nanotube Sheet Material In Multifunctional Applications, Casey M. Keilbarth

Theses and Dissertations

Significant development of carbon nanotubes has occurred since they were first studied in the 1990's. Attempts to capture the phenomenal molecular properties in practical applications are gaining ground as new methods of producing CNTs have been developed. This thesis sought to determine if the addition of commercially produced CNT sheets to thin carbon fiber panels improved the ballistic properties of the panel. The difference between 0 and 4 CNT sheets was studied. The hypothesis was that inte- grating CNT sheets into the laminate would increase the projectile energy absorbed by the panel and reduce the damage to the panel incurred …

Analytical Models And Control Design Approaches For A 6 Dof Motion Test Apparatus, Kyra L. Schmidt

Theses and Dissertations

Wind tunnels play an indispensable role in the process of aircraft design, providing a test bed to produce valuable, accurate data that can be extrapolated to actual flight conditions. Historically, time-averaged data has made up the bulk of wind tunnel research, but modern flight design necessitates the use of dynamic wind tunnel testing to provide time-accurate data for high frequency motion. This research explores the use of a 6 degree of freedom (DOF) motion test apparatus (MTA) in the form of a robotic arm to allow models inside a subsonic wind tunnel to track prescribed trajectories to obtain time-accurate force …

Influence Of Leading Edge Oscillatory Blowing On Time-Accurate Dynamic Store Separation, Ryan G. Saunders

Theses and Dissertations

The primary objective of this research is to support the static and dynamic characterization and the time-accurate dynamic load data acquisition of store separation from a cavity with leading edge oscillatory blowing. Developing an understanding of, and potentially controlling, pitch bifurcation of a store release is a motivation for this research. The apparatus and data acquisition system was used in a two-part experiment to collect both static and dynamic testing data in the AFIT low speed wind tunnel in speeds of 60, 100, and 120 mph, from Reynolds numbers varying from 5.5x10⁴ to 4.6x10⁵, depending on reference …

Manufacture Of Fused Deposition Modeling Joints Using Ultem 9085, Zane A. Willburn

Theses and Dissertations

The manufacture of joints between a base structure and a structure manufactured via Fused Deposition Modeling (FDM) will be investigated. ULTEM 9085, a high temperature plastic with potential aerospace applications, will be the material used. The specific application this research is focused on is a robotic and mobile FDM printer capable of building structures onto other structures in space. A joint will be formed by fusing the base layer of the printed structure and the top of the base structure together. Tensile testing will be performed to determine the strength of the bond between parts. Tensile specimens will be manufactured …

Application Of Computational Tools To Spaghetti-Based Truss Bridge Design, Jin Xu, Jiliang Li, Nuri Zeytinoglu, Jinyuan Zhai

ASEE IL-IN Section Conference

Application of Computational Tools to Spaghetti-Based Truss Design

Statics and Strength of Materials are two foundational courses for Mechanical/Civil Engineering. In order to assist students in better understanding and applying concepts to a meaningful design task, SolidWorks and theoretical calculation were used for a spaghetti-bridge design contest with the constraints of given maximum weight and allowable support-material weight. As the first step of this iterative designing process, both extrude feature and structural member were introduced to model planar bridge trusses. Then SolidWorks’ Statics module was used to run FEA analysis of the structural performance in efforts to optimize the …

Problem Of A Particle Solid Particles With A Ground Surface Airflow Formed Due To High-Speed Train Movement, Sh.S. Fayzibayev, R.Sh. Isanov, M.Sh. Valiyev

Journal of Tashkent Institute of Railway Engineers

The paper deals with the problem of entrainment of particles by air flow with increasing speed of a high-speed train. We have obtained solutions to the problem in the case when the particles in the section have the shape of a trapezoid. If the speed of a high-speed train increases at the end of the train, a whirlwind may occur, which we will study