Other Engineering Science and Materials Commons^™

Use Of Energy Consumption During Milling To Fill A Measurement Gap In Hybrid Additive Manufacturing, K. L. M. Avegnon, P. Noll, M. R. Uddin, G. Madireddy, R. Williams, A. Achuthan, M. P. Sealy

Department of Mechanical and Materials Engineering: Faculty Publications

Coupling additive manufacturing (AM) with interlayer peening introduces bulk anisotropic properties within a build across several centimeters. Current methods to map high resolution anisotropy and heterogeneity are either destructive or have a limited penetration depth using a nondestructive method. An alternative pseudo-nondestructive method to map high-resolution anisotropy and heterogeneity is through energy consumption during milling. Previous research has shown energy consumption during milling correlates with surface integrity. Since surface milling of additively manufactured parts is often required for post-processing to improve dimensional accuracy, an opportunity is available to use surface milling as an alternative method to measure mechanical properties and …

Electrostatic Flocking Of Salt-Treated Microfibers And Nanofiber Yarns For Regenerative Engineering, Alec Mccarthy, Kossi Loic M. Avegnon, Phil A. Holubeck, Demi Brown, Anik Karan, Navatha Shree Sharma, Johnson V. John, Shelbie Weihs, Jazmin Ley, Jingwei Xie

Department of Mechanical and Materials Engineering: Faculty Publications

Electrostatic flocking is a textile technology that employs a Coulombic driving force to launch short fibers from a charging source towards an adhesive-covered substrate, resulting in a dense array of aligned fibers perpendicular to the substrate. However, electrostatic flocking of insulative polymeric fibers remains a challenge due to their insufficient charge accumulation. We report a facile method to flock electrostatically insulative poly(ε-caprolactone) (PCL) microfibers (MFs) and electrospun PCL nanofiber yarns (NFYs) by incorporating NaCl during preflock processing. Both MF and NFY were evaluated for flock functionality, mechanical properties, and biological responses. To demonstrate this platform's diverse applications, standalone flocked NFY …

A Method Of Identifying Allographs In Undeciphered Scripts And Its Application To The Indus Valley Script, Shruti Daggumati, Peter Revesz

Department of Mechanical and Materials Engineering: Faculty Publications

This work describes a general method of testing for redundancies in the sign lists of ancient scripts by data mining the positions of the signs within the inscriptions. The redundant signs are allographs of the same grapheme. The method is applied to the undeciphered Indus Valley Script, which stands out from other ancient scripts by having a large proposed sign list that contains dozens of asymmetric signs that have mirrored pairs. By a statistical analysis of mirrored asymmetric signs, this paper shows that the Indus Valley Script was multi-directional and the mirroring of signs often denotes only the direction of …

Metallic Surface Doping Of Metal Halide Perovskites, Yuze Lin, Yuchuan Shao, Jun Dai, Tao Li, Yi Liu, Xuezeng Dai, Xun Xiao, Yehao Deng, Alexei Gruverman, Xiao Cheng Zeng, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

Intentional doping is the core of semiconductor technologies to tune electrical and optical properties of semiconductors for electronic devices, however, it has shown to be a grand challenge for halide perovskites. Here, we show that some metal ions, such as silver, strontium, cerium ions, which exist in the precursors of halide perovskites as impurities, can n-dope the surface of perovskites from being intrinsic to metallic. The low solubility of these ions in halide perovskite crystals excludes the metal impurities to perovskite surfaces, leaving the interior of perovskite crystals intrinsic. Computation shows these metal ions introduce many electronic states close to …

Recurrence Network Analysis Of Design-Quality Interactions In Additive Manufacturing, Ruimin Chen, Prahalada K. Rao, Yan Lu, Edward W. Reutzel, Hui Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Powder bed fusion (PBF) additive manufacturing (AM) provides a great level of flexibility in the design-driven build of metal products. However, the more complex the design, the more difficult it becomes to control the quality of AM builds. The quality challenge persistently hampers the widespread application of AM technology. Advanced imaging (e.g., X-ray computed tomography scans and high-resolution optical images) has been increasingly explored to enhance the visibility of information and improve the AM quality control. Realizing the full potential of imaging data depends on the advent of information processing methodologies for the analysis of design-quality interactions. This paper presents …

Valorization Of Xylan In Agroforestry Waste Streams, Harrison Appiah

Graduate Theses, Dissertations, and Problem Reports (ETD)

Valorization of Xylan in Agroforestry Waste Streams.

Harrison Appiah

Microwave-assisted deep eutectic solvent and gamma-valerolactone metallic chloride catalyzed conversion of xylan to furfural were investigated using a 2x3 factorial experimental design at two levels of percent microwave power, reaction time, and catalyst concentration. The levels of each factor studied were (20%, 60% microwave power, 2, 4 minutes, and 10, 20mg) respectively. The effect of three metallic chloride catalysts (LiCl, FeCl3.6H20, CuCl2) on the conversion of xylan to furfural was also investigated. The gamma-valerolactone-ferric chloride sent system exhibited the highest mean yield of furfural (56.50%). The next highest furfural yield of …

Process-Structure Relationship In The Directed Energy Deposition Of Cobalt-Chromium Alloy (Stellite 21) Coatings, Ziyad M. Smoqi, Joshua Toddy, Harold (Scott) Halliday, Jeffrey E. Shield, Prahalada K. Rao

Department of Mechanical and Materials Engineering: Faculty Publications

In this work, we accomplished the crack-free directed energy deposition (DED) of a multi-layer Cobalt- Chromium alloy coating (Stellite 21) on Inconel 718 substrate. Stellite alloys are used as coating materials given their resistance to wear, corrosion, and high temperature. The main challenge in DED of Stellite coatings is the proclivity for crack formation during printing. The objective of this work is to characterize the effect of the input energy density and localized laser-based preheating on the characteristics of the deposited coating, namely, crack formation, microstructural evolution, dilution of the coating composition due to diffusion of iron and nickel from …

Quantifying Shape Of Star-Like Objects Using Shape Curves And A New Compactness Measure, Gopal K. Mulukutla, Emese Hadnagy, Matthew Fearon, Edward Garboczi

All Materials

Shape is an important indicator of the physical and chemical behavior of natural and engineered particulate materials (e.g., sediment, sand, rock, volcanic ash). It directly or indirectly affects numerous microscopic and macroscopic geologic, environmental and engineering processes. Due to the complex, highly irregular shapes found in particulate materials, there is a perennial need for quantitative shape descriptions. We developed a new characterization method (shape curve analysis) and a new quantitative measure (compactness, not the topological mathematical definition) by applying a fundamental principle that the geometric anisotropy of an object is a unique signature of its internal spatial distribution …

Perceived Importance Of Aac Messages To Support Communication In Rehabilitation Settings, Susan Koch Fager, Judith M. Burnfield, Chase M Pfeifer, Tabatha Sorenson

Department of Mechanical and Materials Engineering: Faculty Publications

Purpose: Permanent or temporary speech loss can occur due to a variety of medical conditions and often requires individuals to use augmentative and alternative communication (AAC) strategies and technologies to support communication. The use of AAC in medical and rehabilitation settings is critical to ensure the health, safety and psychological well-being of communicatively vulnerable individuals.

Method: This study surveyed the perceived importance of communication messages within five categories (Basic Needs, Patient-Provider Specific Communication, Social, Feelings, and Messages for Young Children) by individuals with disability who have undergone recent medical care as well as by rehabilitation care providers.

Results: Results indicated …

Feasibility Of Motor-Assisted Elliptical To Improve Walking, Fitness And Balance Following Pediatric Acquired Brain Injury: A Case Series, Judith M. Burnfield, Guilherme Manna Cesar, Thad W. Buster

Department of Mechanical and Materials Engineering: Faculty Publications

Purpose: Walking, fitness, and balance deficits are common following acquired brain injury (ABI). This study assessed feasibility, acceptability, and usefulness of a modified motor-assisted elliptical (ICARE) in addressing walking, fitness, and balance deficits in children with chronic ABIs.

Methods: Three children (> 5 years post-ABI) completed 24 ICARE exercise sessions (exercise time, speed, and time overriding motor-assistance gradually increased) to promote mass repetition of gait-like movements and challenge cardiorespiratory fitness. Parents’ and children’s perceptions of ICARE’s safety, comfort, workout, and usability were assessed. Cardiovascular response, gait and balance outcomes were assessed.

Results: No adverse events occurred. Parent’s …

Ultrasound-Activated Ciliary Bands For Microrobotic Systems Inspired By Starfish, Cornel Dillinger, Nitesh Nama, Daniel Ahmed

Department of Mechanical and Materials Engineering: Faculty Publications

Cilia are short, hair-like appendages ubiquitous in various biological systems, which have evolved to manipulate and gather food in liquids at regimes where viscosity dominates inertia. Inspired by these natural systems, synthetic cilia have been developed and utilized in microfluidics and microrobotics to achieve functionalities such as propulsion, liquid pumping and mixing, and particle manipulation. Here, we demonstrate ultrasound-activated synthetic ciliary bands that mimic the natural arrangements of ciliary bands on the surface of starfish larva. Our system leverages nonlinear acoustics at microscales to drive bulk fluid motion via acoustically actuated small-amplitude oscillations of synthetic cilia. By arranging the planar …

Preperitoneal Insufflation Pressure Of The Abdominal Wall In A Porcine Model, Riley E. Reynolds, Benjamin Wankum, Sean J. Crimmins, Mark A. Carlson, Benjamin S. Terry

Department of Mechanical and Materials Engineering: Faculty Publications

Background Most complications and adverse events during laparoscopic surgery occur during initial entry into the peritoneal cavity. Among them, preperitoneal insufflation occurs when the insufflation needle is incorrectly placed, and the abdominal wall is insufflated. The objective of this study was to find a range for static pressure which is low enough to allow placement of a Veress needle into the peritoneal space without causing preperitoneal insufflation, yet high enough to separate abdominal viscera from the parietal peritoneum.

Methods A pressure test was performed on twelve fresh porcine carcasses to determine the minimum preperitoneal insufflation pressure and the minimum initial …

Advancement Of Full-Vector Variable-Temperature Magnetometry For Rock-Magnetic And Paleointensity Applications, Leonid Surovitskii

Dissertations, Master's Theses and Master's Reports

Data on the variation of the direction and strength of Earth’s ancient magnetic field (absolute paleointensity) provide crucial information into the mechanisms of the geodynamo and the Earth’s thermal history. However, the use of conventional methods and instrumentation for absolute paleointensity determination has been hampered by physicochemical alteration of the samples caused by multiple high-temperature cycles and long experiment durations. The reliability and efficiency of the measurement process can be improved by the measurement of the full remanent magnetization vector simultaneously with the temperature cycling of a sample. Such as approach can also substantially expand the scope of materials available …

Entertainment 721, Mark Hendricks, Noah John, Jadon Vanyo, Chelsea Payne

Williams Honors College, Honors Research Projects

The goal of this project was to design a luxury, aesthetically pleasing entertainment system with a TV lift mechanism that could be remote controlled. The design would also include a cooling cabinet for gaming systems, a remote locking system, and additional storage. Using a morphological chart and weighted decision matrix for each subsystem key features were determined to be included in the design. Several performance benchmarks were determined to accomplish the team’s design. Almost every benchmark was successful in the build of the first prototype. Several heat calculations and FEA analyses were performed on the system to ensure the success …

Application Of Laser Assisted Ultrasonic Nanocrystal Surface Modification On Aluminum And 3d Printed Titanium, Eman Hassan, Thomas Crouse

Williams Honors College, Honors Research Projects

A novel surface treatment, laser assisted ultrasonic nanocrystal surface modification (LA-UNSM), has proved effective in increasing surface hardness, and fatigue life. The objective of this research is to determine the effectiveness of this process on components created with additive manufacturing. To accomplish this, we investigated the effectiveness of LA-UNSM treatment on aluminum, a common 3d printed metal, and the effectiveness of LA-UNSM processing on 3d printed titanium. We first conducted our own literature review to assess the practicality of using this same treatment on aluminum. We then treated traditionally manufactured aluminum at varying levels of laser intensity to determine if …

Surface Strengthening Of Single-Crystal Alumina By High-Temperature Laser Shock Peening, Fei Wang, X. L. Yan, Lei Liu, Michael Nastasi, Yongfeng Lu, Bai Cui

Department of Mechanical and Materials Engineering: Faculty Publications

This manuscript reports a novel process of high-temperature laser shock peening (HTLSP) for surface strengthening of single-crystal ceramics such as sapphire and reveals its fundamental mechanisms. HTLSP at 1200°C can induce a high compressive residual stress on the surface of sapphire while minimize the damage of laser-driven shock waves. Transmission electron microscopy characteriza- tions revealed high dislocation densities near the surface, suggesting that plastic deformation at an ultrahigh strain rate was generated by the high shock wave pressure. The HTLSP-induced compres- sive residual stress can significantly improve the hardness and fracture toughness of sapphire, while maintain its outstanding optical transmittance.

Twinning-Assisted Dynamic Adjustment Of Grain Boundary Mobility, Qishan Huang, Qi Zhu, Yingbin Chen, Mingyu Gong, Jixue Li, Ze Zhang, Wei Yang, Jian Wang, Haofei Zhou, Jiangwei Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Grain boundary (GB) plasticity dominates the mechanical behaviours of nanocrystalline materials. Under mechanical loading, GB configuration and its local deformation geometry change dynamically with the deformation; the dynamic variation of GB deformability, however, remains largely elusive, especially regarding its relation with the frequently-observed GB-associated deformation twins in nanocrystalline materials. Attention here is focused on the GB dynamics in metallic nanocrystals, by means of well-designed in situ nanomechanical testing integrated with molecular dynamics simulations. GBs with low mobility are found to dynamically adjust their configurations and local deformation geometries via crystallographic twinning, which instantly changes the GB dynamics and enhances the …

Dry Reforming Of Methane Using Microwave Irradiated Metal Oxide/Coal Char Catalysts, Anthony Carter

Graduate Theses, Dissertations, and Problem Reports (ETD)

This research focuses on the synthesis of both shaped and amorphous powder materials, the combination of these materials with dried Powder River Basin (PRB) coal char, and their reactionary properties with methane and carbon dioxide gasses with conventional and microwave (MW) heating. The first goal of this project was to synthesize shaped micro and nano sized particles with ideal dielectric properties for converting electromagnetic energy into heat and proven capabilities of activating methane. These particles were synthesized via solvothermal, hydrothermal, and co-preceptory treatments alone and onto the surface of dried PRB coal char. PRB is a sub-bituminous, low-ranking coal (LRC) …

Direct Numerical Simulation Of A Pulsatile Flow In A Stenotic Channel Using Immersed Boundary Method, Siamak Mirfendereski, Jae Sung Park

Department of Mechanical and Materials Engineering: Faculty Publications

A three-dimensional direct numerical simulation model coupled with the immersed boundary method has been developed to simulate a pulsatile flow in a planar channel with single and double one-sided semicircular constrictions. For relevance to blood flow in large arteries, simulations have been performed at Reynolds numbers of 750 and 1000. Flow physics and resultant wall shear stress (WSS)-based hemodynamic parameters are presented. The instantaneous vortex dynamics, mean flow characteristics, and turbulent energy spectra are evaluated for flow physics. Subsequently, three WSS-based parameters, namely the time-averaged WSS, oscillatory shear index, and relative residence time, are calculated over the stenotic wall and …

Test-Retest Reliability And Minimal Detectable Change Of The Computerized Dynamic Posturography Proprio For Adults With Chronic Traumatic Brain Injury, Guilherme Manna Cesar, Thad W. Buster, Judith M. Burnfield

Department of Mechanical and Materials Engineering: Faculty Publications

Purpose: Balance deficits after brain injury, including reactive recovery from unexpected perturbations, can persist well after rehabilitation is concluded. While traditional clinical assessments are practical, the anticipatory nature of the tasks may mask perceptible balance control. Computerized dynamic posturography can directly quantify capacity to respond to unexpected, external perturbations. This study examined the reliability of the computerized dynamic posturography assessment with the device PROPRIO® 4000 in adults with traumatic brain injury and created the minimal detectable change for its standardized test.

Methods: Ten adults (ages 21–55 years) with chronic (average 10 ± 6 years post-injury) severe (loss of consciousness 2–75 …