Mechanics of Materials Commons^™

Ligand Assisted Growth Of Perovskite Single Crystals With Low Defect Density, Ye Liu, Xiaopeng Zheng, Yanjun Fang, Ying Zhou, Zhenyi Ni, Xun Xiao, Shangshang Chen, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

A low defect density in metal halide perovskite single crystals is critical to achieve high performance optoelectronic devices. Here we show the reduction of defect density in per[1]ovskite single crystals grown by a ligand-assisted solution process with 3‐(decyldimethy[1]lammonio)‐propane‐sulfonate inner salt (DPSI) as an additive. DPSI ligands anchoring with lead ions on perovskite crystal surfaces not only suppress nucleation in solution, but also regulate the addition of proper ions to the growing surface, which greatly enhances the crystal quality. The grown CH₃NH₃PbI₃ crystals show better crystallinity and a 23-fold smaller trap density of 7 × 10 …

Social Connectedness And Negative Affect Uniquely Explain Individual Differences In Response To Emotional Ambiguity, Maital Neta, Rebecca L. Brock

Department of Mechanical and Materials Engineering: Faculty Publications

Negativity bias is not only central to mood and anxiety disorders, but can powerfully impact our decision-making across domains (e.g., financial, medical, social). This project builds on previous work examining negativity bias using dual-valence ambiguity. Specifically, although some facial expressions have a relatively clear negative (angry) or positive valence (happy), surprised expressions are interpreted negatively by some and positively by others, providing insight into one’s valence bias. Here, we examine putative sources of variability that distinguish individuals with a more negative versus positive valence bias using structural equation modeling. Our model reveals that one’s propensity toward negativity (operationalized as temperamental …

Bio-Binder—Innovative Asphalt Technology, Amir Tabakovic

Articles

The global road network spans 16.3 million km [1], of which 5 million km is in the EU. These road networks fulfil major economic and social goals by facilitating the movement of goods and people throughout the EU, and are therefore of the utmost importance to the economic and social life of the EU [2]. National governments invest heavily in their road networks, e.g., in 2014, EUR 53.33 billion was invested in the development and maintenance of the EU road network [3]. Each year, the world produces 1.6 trillion tonnes of asphalt [4], of which 218 million tonnes is produced …

Enhancement Of Regeneration Ratio And Thermal Durability For Regenerated Fiber Bragg Grating Based On Pre-Annealing Treatment And Multimaterial Fibers, Nurul Asha Mohd Nazal

Student Works (2020-2029)

Regenerated fiber Bragg grating (RFBG) or also known as regenerated grating (RG) is the creation of the temperature resistant grating through thermal erasure of seed grating (SG) followed by a rebirth of new grating in a annealing process. RG has shown to be a promising fiber Bragg grating component for operation under very high ambient temperature condition. Nonetheless, further investigation and improvement are required to better understand its formation mechanism and to enhance its performance. This study aims to enhance the regeneration ratio and thermal durability of the RG based on pre-annealing treatment and multimaterial fiber. In this work, the …

Adhesion And Deformation Mechanisms Of Polydopamine And Polytetrafluoroethylene: A Multiscale Computational Study, Matthew Brownell

Graduate Theses and Dissertations

Polydopamine (PDA) has been shown to bond via covalent bonding, van der Waals forces, and hydrogen bonding and is known to adhere strongly to almost any material. The application of PDA between a substrate and a PTFE surface coating has resulted in low friction and a greatly reduced wear rate. Previous research probing the capabilities and limitations of PDA/PTFE films have studied the wear and mechanical properties of the film, but the overall adhesive and deformation mechanisms remain unclear.

In this research, we investigate the tribological properties of PDA and PTFE molecules and composites from the atomic to the microscale …

Leveraging Biomimicry And Additive Manufacturing To Improve Load Transfer In Brittle Materials, Ana Paula Bernardo

Graduate Theses and Dissertations

With the emergence of Additive Manufacturing (i.e., 3D printing) in construction, new strategically designed shapes can be created to improve load transfer through structural members and foundations. Cross-sections can be optimized to carry load using less material, or even using weaker constituent materials, like soils, which are cheap and abundant. The goal of this research is to investigate the benefits of using cellular patterns which leverage biomimicry in civil engineering applications, since nature has perfectly engineered materials and patterns which carry loads with the least amount of material possible. Most of the periodic cellular work to date has focused on …

Comparison Of Additively Manufactured And Wrought 17-4 Ph Stainless Steels In Ultra Low Cycle Fatigue, Timothy Strasser

Graduate Theses and Dissertations

Additive manufacturing (AM) processes allow for creation of complex geometries that are otherwise impractical to fabricate with traditional subtractive methods. AM technology has potential to improve the optimization of seismic lateral force resisting components which dissipate seismic energy through large plastic strains; however, the ultra low-cycle fatigue performance of AM metals are not yet well understood. Void formation during the AM fabrication process has potential to affect performance. This study compares the performance of heat-treated and non-heat-treated AM and wrought 17-4PH stainless steel in Ultra Low Cycle Fatigue. To understand ULCF performance differences between the AM and wrought specimens, post …

Experimental And Computational Analysis Of Progressive Failure In Bolted Hybrid Composite Joints, John S. Brewer

Theses and Dissertations

Composite materials are strong, lightweight, and stiff making them desirable in aerospace applications. However, a practical issue arises with composites in that they behave unpredictably in bolted joints, where damage and cracks are often initiated. This research investigated a solution to correcting the problem with composite bolted joints. A novel hybrid composite material was developed, where thin stainless steel foils were placed between and in place of preimpregnated composite plies during the cure cycle to reinforce stress concentrations in bolted joints. This novel composite was compared to control samples experimentally in quasi-static monotonic loading in double shear configuration in 9-ply …

Sustainable Drug Release From Polycaprolactone Coated Chitin‑Lignin Gel Fibrous Scaffolds, Turdimuhammad Abdullah, Kalamegam Gauthaman, Azadeh Mostafavi, Ahmed Alshahrie, Numan Salah, Pierfrancesco Morganti, Angelo Chianese, Ali Tamayol, Adnan Memic

Department of Mechanical and Materials Engineering: Faculty Publications

Non-healing wounds have placed an enormous stress on both patients and healthcare systems worldwide. Severe complications induced by these wounds can lead to limb amputation or even death and urgently require more effective treatments. Electrospun scaffolds have great potential for improving wound healing treatments by providing controlled drug delivery. Previously, we developed fibrous scaffolds from complex carbohydrate polymers [i.e. chitin-lignin (CL) gels]. However, their application was limited by solubility and undesirable burst drug release. Here, a coaxial electrospinning is applied to encapsulate the CL gels with polycaprolactone (PCL). Presence of a PCL shell layer thus provides longer shelf-life for the …

Effective Hair Styling Compositions And Processes, Yiqi Yang, Helan Xu, Kaili Song

Department of Textiles, Merchandising and Fashion Design: Faculty Publications

This disclosure relates to hair styling compositions and processes , and more particularly to compositions for disentangling or crosslinking hair that are useful in hair styling processes.

Advances In The Application Of Biomimetic Surface Engineering In The Oil And Gas Industry, Yanbao Guo, Zheng Zhang, Siwei Zhang

Friction

Friction is widespread in almost every field in the oil and gas industry, and it is accompanied by huge energy losses and potential safety hazards. To deal with a series of questions in this regard, biomimetic surfaces have been developed over the past decades to significantly reduce economic losses. Presently, biomimetic surface engineering on different scales has been successfully introduced into related fields of the oil and gas industry, such as drill bits and the inner surfaces of pipes. In this review, we focused on the most recent and promising efforts reported toward the application of a biomimetic surface in …

Rubber Plunger Surface Texturing For Friction Reduction In Medical Syringes, Haytam Kasem, Harel Shriki, Lihi Ganon, Michael Mizrahi, Kareem Abd-Rbo, Abraham J. Domb

Friction

Friction is a genuine issue in the use of many medical devices involving rubbery materials such as plungers in medical syringes. This paper presents a new direction for the reduction of friction in medical syringes based on surface texturing of the rubber plunger. The specimens were prepared by casting poly(vinylsiloxane) (PVS) rubber into a pre-fabricated negative template obtained by 3D printing. Friction tests were performed on a home-made test-rig. It was clearly shown that friction resistance can be considerably manipulated when using textured plungers.

Erosive Wear Properties Of Za-27 Alloy-Based Nanocomposites: Influence Of Type, Amount, And Size Of Nanoparticle Reinforcements, Aleksandar Vencl, Ilija Bobić, Biljana Bobić, Kristina Jakimovska, Petr Svoboda, Mara Kandeva

Friction

Metal matrix nanocomposites (MMnCs) comprise a metal matrix filled with nanosized reinforcements with physical and mechanical properties that are very different from those of the matrix. In ZA-27 alloy-based nanocomposites, the metal matrix provides ductility and toughness, while usually used ceramic reinforcements give high strength and hardness. Tested ZA-27 alloy-based nanocomposites, reinforced with different types (SiC and Al2O3), amounts (0.2 wt.%, 0.3 wt.%, and 0.5 wt.%) and sizes (25 nm, 50 nm, and 100 nm) of nanoparticles were produced through the compocasting process with mechanical alloying pre-processing (ball milling). It was previously shown that the presence of nanoparticles in ZA-27 …

Friction And Wear Behaviors Of Mos2-Multi-Walled-Carbon-Nanotube Hybrid Reinforced Polyurethane Composite Coating, Zhaozhu Zhang, Mingming Yang, Junya Yuan, Fang Guo, Xuehu Men

Friction

MoS2-multi-walled-carbon-nanotube (MWCNT) hybrids containing two-dimensional MoS2 and one-dimensional MWCNTs were synthesized through a one-step hydrothermal reaction. X-ray-diffraction and transmission-electron-microscopy results demonstrated that MoS2 nanosheets were successfully synthesized, and uniformly anchored on the MWCNTs' surfaces. Furthermore, the effects of the MoS2-MWCNT hybrids on the tribological performances of polyurethane composite coatings were investigated using a UMT-2MT tribo-tester. Friction and wear test results revealed that the friction coefficient and wear rate of a 3 wt% MoS2-MWCNT-1 filled polyurethane composite coating were reduced by 25.6% and 65.5%, respectively. The outstanding tribological performance of the MoS2-MWCNT-1 reinforced polyurethane composite coating was attributed to the excellent …

Sliding Friction Of Shale Rock On Dry Quartz Sand Particles, Huijie Zhang, Shuhai Liu, Huaping Xiao

Friction

The sliding friction of rock, involving all kinds of particles at the contact surface, is relevant to many problems, ranging from those in artificial engineering to earthquake dynamics. In this work, the frictional performance of the shale rock-dry quartz sand contact was investigated using a self-developed testing device. The study showed that the coefficient of friction of the contact increases with nominal stress and that the corresponding friction force increases approximately linearly with nominal stress, which is directly related to the contact stress between each single sand particle and rock shale. An overall dynamic coefficient, γ, reflecting the response of …

Friction Predication On Pin-To-Plate Interface Of Ptfe Material And Steel, Zhuming Bi, Donald W. Mueller

Friction

In this paper, the friction behavior at a pin-to-plate interface is investigated. The pin and plate are made of Polytetrafluoroethylene (PTFE) and steel, respectively, and there is a reciprocating motion at the interface. Governing mathematical models for the relations of design variables and frictions are investigated, and a general procedure is proposed to solve the developed models and predict the friction forces at the interface subjected to given test conditions. Novel models have been developed to represent intrigued friction behaviors affected by various factors such as pin geometrics and finishes, lubrication conditions, and reciprocating speed. The test data from experiments …

Significant Friction Reduction Of High-Intensity Pulsed Ion Beam Irradiated Wc-Ni Against Graphite Under Water Lubrication, Gaolong Zhang, Yuechang Wang, Ying Liu, Xiangfeng Liu, Yuming Wang

Friction

Two types of commercial WC-Ni samples were irradiated with the High-intensity pulsed ion beam (HIPIB). Both the surface characteristics and tribo-characteristics of the non-irradiated and irradiated WC-Ni samples, sliding against graphite under water lubrication, were compared. Quite low steady friction coefficients (approximately of 0.02) of the irradiated WC-Ni were observed. The surface topographies and components were investigated. The quite low friction of the irradiated WC-Ni samples was ascribed to the higher fluid retention capability of the latter and the tribofilm formed during sliding.

Metal-Containing Nanomaterials As Lubricant Additives: State-Of-The-Art And Future Development, Igor E. Uflyand, Vladimir A. Zhinzhilo, Victoria E. Burlakova

Friction

This review focuses on the effect of metal-containing nanomaterials on tribological performance in oil lubrication. The basic data on nanolubricants based on nanoparticles of metals, metal oxides, metal sulfides, nanocomposities, and rare-earth compounds are generalized. The influence of nanoparticle size, morphology, surface functionalization, and concentration on friction and wear is analyzed. The lubrication mechanisms of nanolubricants are discussed. The problems and prospects for the development of metal-containing nanomaterials as lubricant additives are considered. The bibliography includes articles published during the last five years.

Experimental Study On The Tribo-Chemical Smoothening Process Between Self-Mated Silicon Carbide In A Water-Lubricated Surface-Contact Reciprocating Test, Le Jin, Herbert Scheerer, Georg Andersohn, Matthias Oechsner, Dieter Hellmann

Friction

Silicon carbide (SiC) can be tribo-chemically smoothened during a self-mated sliding procedure in the aqueous environment. As well reported in the point-contact tests, this smoothening process works well due to the abundant water as oxidant. After this smoothening process, the tribo-surface is well polished, a closely mated tribo-gap naturally forms, and an ultra-low friction state is built. However, water in the tribo-gap could be insufficient in industrial applications, e.g., the seal gap in mechanical seals. In this study, the tribo-chemical smoothening behavior in such environment was researched. A surface-contact reciprocating test was used to simulate the aqueous environment where water …

Water-Based Superlubricity In Vacuum, Chen Xiao, Jinjin Li, Lei Chen, Chenhui Zhang, Ningning Zhou, Tao Qing, Linmao Qian, Jiyang Zhang, Jianbin Luo

Friction

This study achieved water-based superlubricity with the lubrication of H3PO4 solution in vacuum (highest vacuum degree <10-4 torr) for the first time by performing a pre-running process in air before running in vacuum. The stable water-based superlubricity was sustainable in vacuum (0.02 torr) for 14 h until the test was stopped by the user for non-experimental factor. A further analysis suggested that the superlubricity may be attributed to the phosphoric acid-water network formed in air, which can efficiently lock water molecules in the liquid lubricating film even in vacuum owing to the strong hydrogen bond interaction. Such capability to lock water is strongly affected by the strength of hydrogen bond and environmental conditions. The realization of water-based superlubricity with H3PO4 solution in vacuum can lead to its application in space environment.