Physics Commons^™

Use Of Zwitterionic Molecules For Forming A Hole Or Electron Transport Layer, Bernard Doudin, Pierre Braunstein, Lucie Routaboul, Guillaume Dalmas, Zhengzheng Zhang, Peter Dowben

Peter Dowben Publications

The invention relates to the use of zwitterionic molecules for forming a hole or electron transport layer. The preferred zwitterionic molecules of the invention are derivatives of p-benzoquinonemonoimines. The invention is useful in the field of electronic devices in particular.

Adherent Cells Avoid Polarization Gradients On Periodically Poled Litao3 Ferroelectrics, Christof Christophis, Elisabetta Ada Cavalcanti-Adam, Maximilian Hanke, Kenji Kitamura, Alexei Gruverman, Michael Grunze, Peter A. Dowben, Axel Rosenhahn

Peter Dowben Publications

The response of fibroblast cells to periodically poled LiTaO₃ ferroelectric crystals has been studied. While fibroblast cells do not show morphological differences on the two polarization directions, they show a tendency to avoid the field gradients that occur between polarization domains of the ferroelectric. The response to the field gradients is fully established after one hour, a time at which fibroblasts form their first focal contacts. If suspension cells, with a lower tendency to establish strong surface contacts are used, no influence of the field gradients is observed.

Exafs And Epr Analysis Of The Local Structure Of Mn-Doped Li2B4O7, T D. Kelly, L Kong, D A. Buchanan, A T. Brant, J. C. Petrosky, J W. Mcclory, V T. Adamiv, Y V. Burak, Peter A. Dowben

Peter Dowben Publications

The local structure of Mn-doped Li₂B₄O₇(001) was investigated using extended X-ray absorption fine structure (EXAFS) at the Mn K edge and electron paramagnetic resonance (EPR). The location of the Mn dopant in a lithium tetraborate crystal is consistent with occupation of a site with strong oxygen coordination. The Mn–O bond lengths are similar to those observed with Mn doping of the icosahedral based boron carbide whereMnis in a substitutional dopant in one of the cage sites. From EXAFS, the manganese does not appear to greatly alter the overall tetragonal form of lithium tetraborate, with …

Adsorption Of Tcnqh-Functionalized Quinonoid Zwitterions On Gold And Graphene: Evidence For Dominant Intermolecular Interactions+, Lingmei Kong, Lucie Routaboul, Pierre Braunstein, Hong-Gi Park, Jaewu Choi, John P. Colon Cordova, E Vega, Luis G. Rosa, Bernard Doudin, Peter A. Dowben

Peter Dowben Publications

We experimentally investigate the electronic structure of the strongly dipolar, quinonoid-type molecule obtained by TCNQH-functionalization (TCNQH = (NC)₂CC₆H₄CH(CN)₂) of (6Z)-4-(butylamino)-6-(butyliminio)- 3-oxocyclohexa-1,4-dien-1-olate C₆H₂(...NHR)₂(...O)₂ (where R = n-C₄H₉) to be very similar after deposition from solution on either graphene or gold substrates. These zwitterion adsorbate thin films form structures that are distinct from those formed by related quinonoid molecules previously studied. We argue that adsorbate–adsorbate interactions dominate and lead to a Stranski–Krastanov ‘island growth’ mechanism.

The Debye Temperature For Hydrothermally Grown Tho2 Single Crystals, Tony D. Kelly, James C. Petrosky, John W. Mcclory, Timothy Zens, David Turner, J Matthew Mann, Joseph W. Kolis, Juan A. Colon Santana, Peter A. Dowben

Peter Dowben Publications

The electronic properties of ThO₂ single crystals were studied using x-ray photoemission spectroscopy (XPS). The XPS results show that the Th 4f core level is in an oxidation state that is consistent with that expected for Th in ThO₂. The effective Debye temperature is estimated from the temperature dependent photoemission intensities of the Th 4f core level over the temperature range of 290 to 360 K. A Debye temperature of 468±32 K has been determined.

Changing Molecular Band Offsets In Polymer Blends Of (P3ht/P(Vdf–Trfe)) Poly(3-Hexylthiophene) And Poly(Vinylidene Fluoride With Trifluoroethylene) Due To Ferroelectric Poling, Freddy Wong, Godohaldo Perez, Manuel Bonilla, Juan A. Colon-Santana, Xin Zhang, Pankaj Sharma, Alexei Gruverman, Peter A. Dowben, Luis G. Rosa

Peter Dowben Publications

Photoelectron emission and inverse photoemission spectroscopy studies of polymer blends of poly(vinylidene fluoride (70%) – trifluoroethylene (30%)) P(VDF–TrFE 70 : 30) and regio-regular poly(3- hexylthiophene) (P3HT) provide evidence of changes in the molecular band offsets as a result of changes in the ferroelectric polarization in P(VDF–TrFE). Investigation of the blends with higher concentrations of the semiconducting P3HT component revealed that the organic semiconductor component of the blend dominates the electronic structure in the vicinity of the chemical potential. Specifically, the states of P3HT at the conduction band minimum and valence band maximum fall within the HOMO–LUMO gap of the dielectric …

Induced Magneto-Electric Coupling In Ferroelectric/Ferromagnetic Heterostructures, Jeffery Carvell, Ruihua Cheng, Peter A. Dowben, Q Yang

Peter Dowben Publications

Using an external magnetic field, we have demonstrated room temperature control of the electric polarization of a ferroelectric polymer, polyvinylidene fluoride (PVDF), in an artificial multiferroic structure. For ferroelectric PVDF polymer thin films in an iron-PVDF-iron heterostructure, both the ferroelectric coercivity and polarization display a hysteresis dependence on the external magnetic field. We also find that the thickness of the PVDF layer has an effect on the magnetoelectric coupling in our samples. We observe a giant magnetoelectric coupling with values as large as 3700 V/cm Oe to 41700 V/cm Oe.

Magnetoelectric Coupling At The Euo/Batio3 Interface, Shi Cao, P Liu, Jinke Tang, Haidong Lu, C W. Bark, Sangjin Ryu, Chang-Beom Eom, Alexei Gruverman, Peter A. Dowben

Peter Dowben Publications

Magnetization modulation by ferroelectric polarization switching is reported for the ferromagnetic-ferroelectric EuO/BaTiO₃heterostructure. The value of the magnetization critical exponent β is consistent with the expected Heisenberg-like ferromagnetism of EuO and reported Curie temperature. The critical exponent is seen to decrease with increased magnetic coupling. The results are discussed in the context of data obtained earlier for epitaxial La_0.67Sr_0.33MnO₃/BaTiO₃ heterostructures, where magnetization increases and critical exponent b also declines with ferroelectric polarization pointing away from ferromagnetic layer. The observed similarity between two systems illustrates an importance of charge doping in magnetoelectric coupling, …

Reversible Mn Segregation At The Polar Surface Of Lithium Tetraborate, Christina Dugan, Robert L. Hengehold, Steve R. Mchale, Juan A. Colon Santana, John W. Mcclory, V T. Adamiv, Ya V. Burak, Yaroslav B. Losovyj, Peter A. Dowben

Peter Dowben Publications

We find Mn surface segregation for single crystals of Mn doped Li₂B₄O₇, nominally Li_1.95Mn_0.05 B₄O₇(001), but as the temperature increases, evidence of this Mn surface segregation diminishes significantly. At room temperature, the surface photovoltaic charging is significant for this pyroelectric material but is quenched at a temperature well below that seen for the undoped Li₂B₄O₇ samples. The suppression of surface charging in the region of 120°C that accompanies the temperature of Mn dissolution in the bulk of Li₂B₄O …

Grand Challenges In Condensed Matter Physics: From Knowledge To Innovation, Evgeny Y. Tsymbal, Peter A. Dowben

Peter Dowben Publications

Condensed Matter Physics (CMP) explores the fundamental properties of matter and their origins resulting from the interactions of a large number of atoms and electrons. The intricate nature of these interactions results in properties and associated phenomena that often hint at a rich vein of underlying physics. Although the perspective is changing constantly with new discoveries, the basic challenges in CMP are to predict and observe new phenomena and elucidate novel properties of materials often pushing at the frontiers of quantum mechanics [1].

CMP is also a field which stimulates technological innovation that revolutionizes modern society. For more than five …

Gamma And X-Ray Sensitivity Of Gd2O3 Heterojunctions, Juan A. Colon Santana, C M. Young, J W. Mcclory, J C. Petrosky, X Wang, P Liu, Jinke Tang, V T. Adamiv, Ya V. Burak, Keisuke Fukutani, Peter A. Dowben

Peter Dowben Publications

We find that Gd₂O₃ thin films strongly favor a (-402) texture growth on a variety of substrates and will form heterojunction diodes with silicon, especially when doped with oxygen vacancies. Even in the thin film limit, these heterojunction diodes appear to be sensitive to gamma radiation, likely from the X-rays created by scattering events, adding to the numerous hurdles that must be overcome if Gd based semiconductor devices are to be used for solid state neutron detection applications.

Effect Of Gadolinium Doping On The Electronic Band Structure Of Europium Oxide, Juan Colon Santana, Joonhee Michael An, Ning Wu, Kirill D. Belashchenko, Xianjie Wang, Pan Liu, Jinke Tang, Yaroslav B. Losovyj, I. N. Yakovkin, Peter A. Dowben

Peter Dowben Publications

High quality films of EuO and Eu_0.96Gd_0.04O were grown on p-type Si(100) via pulsed laser deposition. X-raydiffraction results show that the addition of Gd changes the growth texture from [001] to [111]. Angular-resolved photoemission spectroscopy reveals electron pockets around the X points in Gd-doped EuO, indicating that the band gap in EuO is indirect. Combined photoemission and inverse photoemission measurements showan apparent transition from n-type to p-type behavior, which is likely due to band bending near the polar (111) surface.

Electron And Hole Traps In Ag-Doped Lithium Tetraborate (Li2b4o7) Crystals, A. T. Brant, B. E. Kananan, M. K. Murari, J. Mcclory, J. C. Petrosky, V. T. Adamiv, Ya. V. Burak, Peter A. Dowben, L. E. Halliburton

Peter Dowben Publications

Electron paramagnetic resonance (EPR), electron-nuclear double resonance (ENDOR), and thermoluminescence (TL) are used to characterize the primary electron and hole trapping centers in a lithium tetraborate (Li₂B₄O₇) crystal doped with Ag⁺. Three defects, two holelike and one electronlike, are observed after exposure at room temperature to 60 kV x-rays. The as-grown crystal contains both interstitial Ag⁺ ions and Ag⁺ ions substituting for Liþ ions. During the irradiation, substitutional Ag⁺ ions (4d¹⁰) trap holes and two distinct Ag²⁺ centers (4d⁹) are formed. These Ag^{2+ …}

Resonant Photoemission Of Rare Earth Doped Gan Thin Films, S. R. Mchale, J. W. Mcclory, J. C. Petrosky, J. Wu, R. Palai, Yaroslav B. Losovyj, Peter A. Dowben

Peter Dowben Publications

The 4d → 4f Fano resonances for various rare earth doped GaN thin films (RE = Gd, Er, Yb) were investigated using synchrotron photoemission spectroscopy. The resonant photoemission Fano profiles show that the major Gd and Er rare earth 4f weight is at about 5–6 eV below the valence band maximum, similar to the 4f weights in the valence band of many other rare earth doped semiconductors. For Yb, there is very little resonant enhancement of the valence band of Yb doped GaN, consistent with a largely 4f¹⁴ occupancy.

Schottky Barrier Formation At The Au To Rare Earth Doped Gan Thin Film Interface, S. R. Mchale, J. W. Mcclory, J. C. Petrosky, J. Wu, R. Palai, Yaroslav B. Losovyj, Peter A. Dowben

Peter Dowben Publications

The Schottky barriers formed at the interface between gold and various rare earth doped GaN thin films (RE = Yb, Er, Gd) were investigated in situ using synchrotron photoemission spectroscopy. The resultant Schottky barrier heights were measured as 1.68 ± 0.1 eV (Yb:GaN), 1.64 ± 0.1 eV (Er:GaN), and 1.33 ± 0.1 eV (Gd:GaN). We find compelling evidence that thin layers of gold do not wet and uniformly cover the GaN surface, even with rare earth doping of the GaN. Furthermore, the trend of the Schottky barrier heights follows the trend of the rare earth metal work function.

Ab Initio Calculations And Ellipsometry Measurements Of The Optical Properties Of The Layered Semiconductor In4Se3, L. Makinistian, E. A. Albanesi, N. V. Gonzalez Lemus, A. G. Petukhov, D. Schmidt, Eva Schubert, M. Schubert, Yaroslav B. Losovyj, P. Galiy, Peter A. Dowben

Peter Dowben Publications

In this work, we present a thorough study of the optical properties of the layered orthorhombic compound In₄Se₃. The dielectric function—real and imaginary parts, the complex refraction index, the reflectivity, the absorption coefficient, and the conductivity of In₄Se₃ were calculated with the inclusion of the spin-orbit interaction, using an ab initio FP-LAPW method based on DFT. Also, generalized ellipsometry was employed for more precise measurement of the anisotropic dielectric functions for polarization along crystal a, b, and c axes of orthorhombic absorbing In₄Se₃ single crystals cut approximately parallel to …

The Electron–Phonon Coupling At The Mo(112) Surface, Ning Wu, Keisuke Fukutani, Peter A. Dowben

Peter Dowben Publications

We investigated the electron–phonon coupling (EPC), in the vicinity of the Fermi level, for the surface-weighted states of Mo(112) from high resolution angle-resolved photoemission data taken parallel to the surface corrugation (i.e. (111)). The surface-weighted bandwidth may be discussed in terms of electron–electron interactions, electron impurity scattering and electron–phonon coupling and exhibits a mass enhancement factor λ = 0.42, within the Debye model, determined from the experimentally derived self-energy. Gold overlayers suppress the mass enhancement of the Mo(112) surface-weighted band crossing the Fermi level at 0.54 Å^-1.

The Local Structure Of Transition Metal Doped Semiconducting Boron Carbides, Jing Liu, Guangfu Luo, Wai-Ning Mei, Orhan Kizilkaya, Eric D. Shepherd, Jennifer I. Brand, Peter A. Dowben

Peter Dowben Publications

Transition metal doped boron carbides produced by plasma enhanced chemical vapour deposition of orthocarborane (closo-1,2-C₂B₁₀H₁₂) and 3d metal metallocenes were investigated by performing K-edge extended x-ray absorption fine structure and x-ray absorption near edge structure measurements. The 3d transition metal atom occupies one of the icosahedral boron or carbon atomic sites within the icosahedral cage. Good agreement was obtained between experiment and models for Mn, Fe and Co doping, based on the model structures of two adjoined vertex sharing carborane cages, each containing a transition metal. The local spin configurations of all …

Isomeric Effects With Di-Iodobenzene (C6H4I2) On Adsorption On Graphite, Keisuke Fukutani, Ning Wu, Peter A. Dowben

Peter Dowben Publications

Differences are seen in the adsorption of 1,2-di-iodobenzene, 1,3-di-iodobenzene, and 1,4-di-iodobenzene on graphite, as a function of exposure, using core level photoemission. The isomer 1,3-di-iodobenzene exhibits significant differences from 1,2-di-iodobenzene, and 1,4-di-iodobenzene in apparent sticking coefficients and core level binding energies. 1,3-Di-iodobenzene adsorb on graphite at 110 K in a strongly Stranski–Krastanov or Volmer–Weber (island) growth mode. The implication is that, even for small molecules adsorption, the adsorbate dipole in the plane of surface and the choice of isomer may matter.

Adsorbate/Absorbate Interactions With Organic Ferroelectric Polymers, Peter A. Dowben, Luis G. Rosa, Carolina C. Ilie, Jie Xiao

Peter Dowben Publications

We discuss the interactions of adsorbates with the organic ferroelectric copolymer poly(vinylidene fluoride (PVDF)–trifluoroethylene (TrFE)). Range of molecular adsorbates is discussed from the smaller polar molecules like water, which is small enough to both adsorb and absorb, to the larger macrocyclic metal–organic metal phthalocyanines. The changes in local dipole orientation may affect the strength of the coupling between adsorbate or absorbate and the copolymer poly(vinylidene fluoride–trifluoroethylene). The interface dipole interactions may also affect device properties. The dipole interactions are implicated at the interface between copper phthalocyanine and poly(vinylidene fluoride with trifluoroethylene) affecting the band offsets and the diode properties.

Fission Processes Following Core Level Excitation In Closo-1,2-Orthocarborane, E. Rühl, A. P. Hitchcock, J. D. Bozek, T. Tyliszczak, A. L. D. Kilcoyne, D. N. Mcilroy, A. Knop-Gericke, Peter A. Dowben

Peter Dowben Publications

Time-of-flight mass analysis with multi-stop coincidence detection was used to study the multi-cation ionic fragmentation of the closo carborane cage molecule closo-1,2-orthocarborane (C₂B₁₀H₁₂) following inner-shell excitation in or above the B 1s regime. Electron ion coincidence spectra reveal the cationic products which are formed after core level excitation. Distinct changes in fragmentation pattern are observed as a function of excitation energy. Photoelectron–photoion– photoion coincidence (PEPIPICO) spectroscopy was used to study the dominant fission routes in the core level excitation regime. Series of ion pairs are identified, where asymmetric fission dominates, leading to ion pairs …

Selective Nanoshaving Of Self-Assembled Monolayers Of 2-(4-Pyridylethyl)Triethoxysilane, Luis G. Rosa, Jinyue Jiang, Ocelio V. Lima, Jie Xiao, Emmanuel Utreras, Peter A. Dowben, Li Tan

Peter Dowben Publications

Single molecular layers of 2-(4-pyridylethyl)triethoxysilane have been deposited on native oxide surfaces of silicon, with the triethoxysilylethyl groups towards the silicon oxide interface and pyridine at the surface. It is possible to “shave” or mechanically break the molecular bonds at the alkoxy-silane (Si–C) bond using scanning atomic force microscope, leaving large swaths of surface area cut to a depth of 0.64 ± 0.06 nm, exposing the silicon of the alkoxy-silane ligand. Mechanical cleavage of the pyridine ligand alone is also possible, but more difficult to control selectively.

Changes In The Adsorbate Dipole Layer With Changing D-Filling Of The Metal (Ii) (Co, Ni, Cu) Phthalocyanines On Au(111), Jie Xiao, Peter A. Dowben

Peter Dowben Publications

In combined photoemission and inverse photoemission spectroscopy studies, we observe changes in the metal phthalocyanine molecular orbital offsets with respect to the conducting gold substrate Fermi level, with the changing d-electron filling of the metal (II) (Co, Ni, Cu) phthalocyanines. The implication is that the interfacial dipole layer depends upon the choice of metal (Co, Ni, Cu) centers within the metal (II) phthalocyanines adsorbed on Au(111).

Haloform Adsorption On Crystalline Copolymer Films Of Vinylidene Fluoride With Trifluoroethylene, Jie Xiao, Carolina C. Ilie, Ning Wu, Keisuke Fukutani, Peter A. Dowben

Peter Dowben Publications

Reversible bromoform adsorption on crystalline polyvinylidene fluoride with 30% of trifluoroethylene, P(VDF–TrFE 70:30) was examined by photoemission and inverse photoemission spectroscopies. The adsorption of bromoform on this polymer surface is associative and reversible. Molecular bromoform adsorption appears to be an activated process at 120 K with enhanced adsorption following the initial adsorption of bromoform. Strong intermolecular interactions are also implicated in the presence of a weak shake off or screened photoemission final state, whose intensity scales with the unscreened photoemission final state.

3d Transition Metal Doping Of Semiconducting Boron Carbides, Peter A. Dowben, Orhan Kizilkaya, Jing Liu, B. Montag, K. Nelson, Ildar F. Sabiryanov, Jennifer I. Brand

Peter Dowben Publications

The introduction metallocenes, in particular ferrocene (Fe(η⁵-C₅H₅)₂), cobaltocene (Co(η⁵-C₅H₅)₂), and nickelocene (Ni(η⁵-C₅H₅)₂), together with the carborane source molecule closo-1,2-dicarbadodecaborane, during plasma enhanced chemical vapor deposition, will result in the transition metal doping of semiconducting boron carbides. Here we report using ferrocene to introduce Fe dop¬ants, and a semiconducting boron-carbide homojunction has been fabricated. The diode characteristics are very similar to those fabricated with Co and Ni doping.

The Surface Core Level Shift For Lithium At The Surface Of Lithium Borate, David Wooten, Ihor Ketsman, Jie Xiao, Yaroslav B. Losovyj, J. C. Petrosky, J. Mcclory, Ya. V. Burak, V. T. Adamiv, Peter A. Dowben

Peter Dowben Publications

The shallow Li 1s core level exhibits a surface-to-bulk core level shift for the stoichiometric Li₂B₄O₇ (1 1 0) surface. Angle-resolved photoemission spectroscopy was used to identify Li1s bulk and surface core level components at binding energies –56.5 ± 0.4 and –53.7 ± 0.5 eV, respectively. We find photoemission evidence for surface states of Li₂B₄O₇ (1 1 0) that exist in the gap of the projected bulk density of states. The existence of surface states is consistent with the large surface-to-bulk core level shift for the Li 1s core.

Magnetism Of Cr-Doped Diamond-Like Carbon, J. A. Colón Santana, Ralph Skomski, V. R. Singh, V. Palshin, A. Petukhov, Yaroslav B. Losovyj, Andrei Sokolov, Peter A. Dowben, Ihor Ketsman

Peter Dowben Publications

Chromium-doped hydrogenated diamond-like carbon (Cr-DLC) and chromium carbide hydrogenated DLC alloys were synthesized by plasma-assisted vapor deposition and investigated by x-ray absorption near edge structure spectroscopy, extended x-ray absorption fine structure, and superconducting quantum interference device (SQUID) magnetometry. Structural and magnetic properties of the doped and alloy materials were investigated as a function of the Cr concentration (0.1–20 at. %). Toward the upper end of the concentration range, Cr precipitates in the form of chromium carbide (Cr₃C₂) nanoclusters. For low Cr concentrations, the systems are ferromagnetic at very low temperatures, whereas the chromium carbide clusters appear …

Comparison Of N-Type Gd2O3 And Gd-Doped Hfo2, Yaroslav B. Losovyj, David Wooten, Juan Colon Santana, Joonhee Michael An, Kirill D. Belashchenko, N. Lozova, J. C. Petrosky, Andrei Sokolov, Jinke Tang, Wendong Wang, Navamoney Arulsamy, Peter A. Dowben

Peter Dowben Publications

Gd₂O₃ and Gd-doped HfO₂ films were deposited on p-type silicon substrates in a reducing atmosphere. Gd 4f photoexcitation peaks at roughly 7 and 5 eV below the valence band maximum have been identified using the resonant photoemission of Gd₂O₂ and Gd-doped HfO₂ films, respectively. In the case of Gd₂O₃, strong hybridization with the O 2p band is demonstrated, and there is evidence that the Gd 4f weighted band exhibits dispersion in the bulk band structure. The rectifying (diode-like) properties of Gd-doped HfO₂–silicon and Gd₂O …

Radiation-Induced Decomposition Of The Metal-Organic Molecule Bis(4-Cyano-2,2,6,6-Tetramethyl-3,5-Heptanedionato)Copper(Ii), David Wisbey, Ning Wu, Yaroslav B. Losovyj, Ihor Ketsman, A. N. Caruso, Danqin Feng, John Belot, Elio Vescovo, Peter A. Dowben

Peter Dowben Publications

The effects of vacuum ultraviolet radiation on the adsorbed copper center molecule bis(4-cyano-2,2,6,6- tetramethyl-3,5-heptanedionato)copper(II) (or Cu(CNdpm)₂), (C₂₄H₃₆N₂O₄Cu, Cu(II)) was studied by photoemission spectroscopy. Changes in the ultraviolet photoemission spectra (UPS) of Cu(CNdpm)₂, adsorbed on Co(1 1 1), indicate that the ultraviolet radiation leads to decomposition of Cu(CNdpm)₂ and this decomposition is initially dominated by loss of peripheral hydrogen.

Induced Spin Polarization Of Copper Spin 1/2 Molecular Layers, David Wisbey, Ning Wu, Danqin Feng, A. N. Caruso, J. Belot, Yaroslav B. Losovyj, Elio Vescovo, Peter A. Dowben

Peter Dowben Publications

Thin films of the metal organic molecule bis(4-cyano-2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II) (or Cu(CNdpm)₂), (C₂₄H₃₆N₂O₄Cu, Cu(II)), deposited on ferromagnetic Co(111) at 40 K, exhibit a finite electron spin polarization. The spin polarization magnitude and sign for Cu(CNdpm)₂ deposited on Co(111) is coverage dependent, but deviates from the mean field expectations for a simple paramagnet on a ferromagnetic substrate. The spin asymmetry is seen to favor select molecular orbitals, consistent with the predicted single molecule density of states. The overlayer polarization observed indicates a strong influence of the ferromagnetic Co(111) substrate and some extra-molecular …