Physical Sciences and Mathematics Commons^™

An Experiment To Determine Mineral-Associated Organic Matter Turnover In A Sandy Clay Loam, Samantha Abel

All Master's Theses

Soil is an important terrestrial carbon sink. Through regenerative land management, which includes minimizing soil disturbance, the carbon content of soil can be raised towards preindustrial levels. This feat requires effectively storing carbon in a natural system that is inclined to cyclicity. The most stable form of soil organic matter is mineral-associated organic matter (MAOM). This carbon labelling experiment was designed to identify short-term CO₂ fluxes within the soil-plant-atmosphere system, particularly those related to MAOM turnover in the rhizosphere. Basil (Ocimum basilicum) was planted on a plot at the campus farm at Central Washington University. Another plot …

New Far-Infrared Laser Frequencies Generated By Ch3cn, Cd3cn, 13ch3i, Cd3i, And 13cd3i, Michael Jackson

All Faculty Scholarship for the College of the Sciences

Heterodyne techniques have been used to experimentally determine, for the first time, the frequencies for nineteen laser emissions ranging from 264 to 984 GHz. These laser emissions were generated by optically pumping either CH₃CN, CD₃CN, ¹³CH₃, CD₃I, or ¹³CD₃I with a CO₂ laser. This includes the newly discovered 566.325-μ m laser emission from optically pumped ¹³CD₃I. The fractional uncertainties with which these frequencies were experimentally determined, up to ± 5 × 10^− 7, were of sufficient accuracy to confirm or revise …

Critical Workforce Skills For Bachelor-Level Geoscientists: An Analysis Of Geoscience Job Advertisements, Gregory W. Shafer, K. Viskupic, Anne E. Egger

Geological Sciences Faculty Scholarship

Understanding the skills bachelor-level geoscientists need to enter the workforce is critical to their success. The goal of this study was to identify the workforce skills that are most requested from a broad range of geoscience employers. We collected 3668 job advertisements for bachelor-level geoscientists and used a case-insensitive, code-matching function in Matlab to determine the skills geoscience employers seek. Written communication (67%), field skills (63%), planning (53%), and driving (51%) were most frequently requested. Field skills and data collection were frequently found together in the ads. Written communication skills were common regardless of occupation. Quantitative skills were requested less …

Serendipitous Synthesis Of Cross-Conjugated Dienes By Cascade Deconstructive Esterification Of Thiomorpholinone-Tethered Alkenoic Acids, Abdikani Omar Farah, Jorge Garcia, Claire Borg, Timothy K. Beng

Student Published Works

Functionalized 1,3-dienes are ubiquitous structural motifs in biologically pertinent molecules. They are frequently employed as precursors for a broad range of chemical transformations, including Diels-Alder reactions. The stereoselective construction of highly decorated 1,3-dienes therefore represents an important research objective. Medicinal chemists are becoming increasingly interested in synthetic methodologies that not only achieve expedient construction and peripheral editing of heterocycles, but also seek to modify their core framework in order to achieve skeletal remodeling. In a succinct manifestation of this 'scaffold hopping' concept, we herein describe a cascade reaction, which converts thiomorpholinone-tethered alkenoic acids to 1,1-disubstituted amino-1,3-dienes. This domino process involves …

From Mirrors To Wallpapers: A Virtual Math Circle Module On Symmetry, Nicole A. Sullivant, Christina L. Duron, Douglas T. Pfeffer

Journal of Math Circles

Symmetry is a natural property that children see in their everyday lives; it also has deep mathematical connections to areas like tiling and objects like wallpaper groups. The Tucson Math Circle (TMC) presents a 7-part module on symmetry that starts with reflective symmetry and culminates in the deconstruction of wallpapers into their ‘generating tiles’. This module utilizes a scaffolded, hands-on approach to cover old and new mathematical topics with various interactive activities; all activities are made available through free web-based platforms. In this paper, we provide lesson plans for the various activities used, and discuss their online implementation with Zoom, …

The Impact Of Subjective Risk Analysis On Real Estate Prices In The Nisqually Region Following The 2001 Nisqually Earthquake, Ryan Espedal

All Master's Theses

Earthquakes are an environmental hazard that pose great risks to communities almost every day. With earthquakes, the main cause of concern is physical destruction of property, however, there are also psychological effects that are researched and discussed much less. In 2001, the Nisqually area of western Washington experienced a substantial earthquake that produced minimal physical damage but caused a significant decrease in real estate prices. Studying single-family homes from 1986-2012, this research utilizes hedonic property models to measure the change in consumer’s subjective risk calculations with reference to real estate purchases after the Nisqually earthquake, measure the relationship between earthquake …

Using Modflow To Assess Groundwater Storage Enhancement Via A Floodplain Infiltration Basin, Lindsay Henning

All Master's Theses

Delaying groundwater discharge into rivers until it is critically needed during baseflow conditions provides promise for lowering elevated stream temperatures and improving habitat for aquatic species. Increasing groundwater storage may accomplish this in locations where excess spring runoff can be captured and allowed to infiltrate into the subsurface for later beneficial use, a process known as Managed Aquifer Recharge (MAR). Here, MAR via an infiltration basin is considered at a site along the Teanaway River in central Washington State. The effects of simulated ephemeral ponds of sizes varying from 554 m³ to 2430 m³ (0.449 acre-feet to 1.97 …

Estimating Evapotranspiration And Analyzing Soil Moisture And Heat Flux Parameters At Taneum Creek, Central Washington, Edward Vlasenko

All Master's Theses

In the past two decades, stream restoration work, primarily in the form of wood emplacement, has been undertaken in the Taneum Creek watershed, resulting in increased channel-floodplain connectivity. One of the goals of stream restoration was to boost dry season groundwater storage in the shallow floodplain aquifer. However, any gains in groundwater due to increased connectivity may be nullified by increased evapotranspiration (ET) losses because of denser floodplain vegetation. Within the floodplain aquifer budget, ET is a major flow of water out of the system and is not well quantified.

In order to quantify ET, a monitoring site was established …

Floodplain Aquifer Storage Capacity In Upper Yakima River Tributaries, Kittitas County, Wa, Emily Polizzi

All Master's Theses

Large wood (LW) restoration projects were recently implemented in the Upper Yakima Basin following the destructive logging practices of the early 20^th Century, which stripped Upper Yakima River tributaries of LW. The removal of natural LW increased incision, isolating channels from floodplain aquifers, and degrading resident and anadromous fish habitat. Returning streams to their natural state through instream LW installations is believed to increase floodplain groundwater storage by decreasing channel incision, increasing floodplain-channel connectivity, and raising the water table elevation. Additional storage in floodplain aquifers can help combat the adverse effects of climate change, namely decreasing snowpack and earlier …

Windblown Snow Bedforms And Their Effects On Snow Water Content Wenatchee Range, Washington, Ryan Hampton

All Master's Theses

ABSTRACT

WINDBLOWN SNOW BEDFORMS AND THEIR

EFFECTS ON SNOW WATER CONTENT

WENATCHEE RANGE, WASHINGTON

by

Ryan C. Hampton

June 2023

Windblown snow bedforms (WBSBF) are formations of distinct sizes, shapes, and patterns, resulting from the interaction of wind and snow particles. Due to the extreme nature of the formation of WBSBF, which occur in remote high elevation mountain environments during severe weather events, it makes it difficult to not only study these dramatic formations in real time but also predict their occurrence with any regularity. The purpose of this research was to 1) establish a method to actively monitor WBSBF …

Nasa Student Launch - Payload, Eli Kirk

All Undergraduate Projects

A team of mechanical engineering, physics, and computer science students from Central Washington University have constructed a fully functional subscale model rocket to be flown at the NASA Student Launch competition. The rocket’s payload was designed to open the nose cone and take a photo of the rocket’s surroundings after descending from the launch. Smaller parts were constructed through machining and 3D printing that will be added to the purchased major component, the linear actuator, in order to perform the required tasks. These tasks are signaled by an attached electronics board, which will receive an RF command remotely, execute code, …

A Conceptual Framework For Managed Aquifer Recharge In The Columbia River Basalts Of The Lower Yakima River Basin, Bethany Kharrazi

All Master's Theses

In the Yakima River Basin in south-central Washington, increasing demands for water, overallocation of surface water, and a changing climate are leading to a loss of water storage and increasing water deficits in drought years. A warming climate has reduced snowpack in the Cascade Range, a vital reservoir for the irrigated agricultural industry which supports the basin’s economy. Managed aquifer recharge (MAR) is a sustainable and cost-effective approach for securing water supply by storing water underground for recovery during drought. Diminishing groundwater levels in regional basalt aquifers over the last several decades suggest there is significant storage available for intentional …

Crosshair Optimizer, Jason Torrence

All Master's Theses

Metaheuristic optimization algorithms are heuristics that are capable of creating a "good enough'' solution to a computationally complex problem. Algorithms in this area of study are focused on the process of exploration and exploitation: exploration of the solution space and exploitation of the results that have been found during that exploration, with most resources going toward the former half of the process. The novel Crosshair optimizer developed in this thesis seeks to take advantage of the latter, exploiting the best possible result as much as possible by directly searching the area around that best result with a stochastic approach. This …

Constraining Rock Type Controls On Geophysical Properties: Implications For Earthquake Hazard Assessment Near Ellensburg, Washington, Zachary Stevens

All Master's Theses

High precision geophysical modeling can constrain the geometry of structures in the upper to middle crust beyond what is possible with surface data alone, which allows for a better understanding of seismic hazards. This modeling requires values of both the magnetic susceptibility and density relevant to rocks at depth; this study presents a combination of field and laboratory measurements of basement units to determine these properties. The basement rock of the Kittitas Valley is made up of a complex series of metamorphic and igneous bodies, so it was important to gather a representative suite of samples of the most volumetrically …

Paleoseismic Investigation Of Rupture On The Dead Coyote Fault In The Kittitas Valley, Washington, Garet Huddleston

All Master's Theses

Recently discovered fault scarps along the Dead Coyote Fault (DCF) in the northern Kittitas Valley (KV) of central Washington suggests active faulting in the late Quaternary, but constraints on the timing and potential magnitude of earthquakes along the fault zone are limited. The KV lies at the northwestern edge of the Yakima Fold and Thrust Belt (YFTB), a low-strain region where individual structures are capable of producing M~7 earthquakes.

This investigation uses surficial geologic mapping and topographic analysis of the DCF scarps, ground penetrating radar transects, and paleoseismic trenching to determine the rupture history of the DCF. The trench was …

Hydrologic And Geomorphic Investigations Of Two Engineered Stream Crossings Under Interstate 90 In Washington State, Catherine Mast

All Master's Theses

The importance of stream restoration in providing a healthy ecosystem is widely recognized. The Washington State Department of Transportation (WSDOT) has implemented environmental changes to facilitate habitat restoration and wildlife passage along the Interstate 90 Highway (I-90) corridor where it passes over the Cascade Mountains. Prior to the I-90 corridor expansion, Price and Noble Creeks passed under the highway though culverts, limiting passage of aquatic species or wildlife below the highway. In 2019 the stream channel crossings were expanded, and the size/shape of these creeks were engineered to mirror what would be seen in a natural environment. Since construction, erosion …

An Evolution Of Gold Of The Swauk Mining District, Liberty Washington, Timothy Miller

All Master's Theses

The Swauk Mining District in Central Washington state is a historic mining community with active small scale mining dating back to the 1870’s. Gold has been mined from both lode and placer deposits. The placer deposits of Liberty area are unique due to the variety of gold textures, most notably are the nuggets of tangled masses of dendritic crystals and wire gold.

This research aims to determine the paragenic sequence that led to the formation of the lode and placer gold deposits using a combination of field work and laboratory analyses. Field work consisted of small-scale detailed mapping, recording of …

Historical Tsunami Observability For Izu–Bonin–Mariana Sources, Walter Szeliga, Rachelle Reisinger, Breanyn T. Macinnes

Geological Sciences Faculty Scholarship

The Izu–Bonin–Mariana Subduction System (IBM) is one of the longest subduction zones in the world with no instrumental history of shallow focus, great earthquakes (Mw > 8). Over the last 50 years, researchers have speculated on the reason for the absence of large magnitude, shallow seismicity on this plate interface, exploring factors from plate age to convergence rate. We approach the question from a different point of view: what if the IBM has hosted great earthquakes and no documentable evidence was left? To address the question of observability, we model expected tsunami wave heights from nine great earthquake scenarios on the …

Contra-Thermodynamic Halolactonization Of Lactam-Tethered 5-Aryl-4(E)-Pentenoic Acids For The Flexible And Stereocontrolled Synthesis Of Fused Lactam-Halolactones, Timothy K. Beng, Claire Borg, Morgan J. Rodriguez

All Faculty Scholarship for the College of the Sciences

Halolactonization of alkenoic acids enables the construction of oxygen-heterocycles via intramolecular halonium-induced nucleophilic addition. Although the literature is currently inundated with halolactonizations of 5-aryl-4(E)-pentenoic acids that predictably afford the 6-endo cyclization adducts, methods that reliably alter the innate regioselectivity bias to instead deliver the thermodynamically less favored 5-exo cyclization products are relatively rare. Here, we attempt to bridge this gap and have found mild conditions for contra-thermodynamic halolactonization of lactam-tethered 5-aryl-4(E)-pentenoic acids that lead to the formation of trans-fused lactam-γ-lactones. The natural proclivity for these 5-aryl-4(E)-pentenoic acids to undergo 6-endo cyclization is overridden and 5-exo-trig cyclization predominates. The success of …

Sea Level Rise Estimation On The Pacific Coast From Southern California To Vancouver Island, Xiaoxing He, Jean-Philippe Montillet, Rui Fernandes, Timothy I. Melbourne, Weiping Jiang, Zhengkai Huang

Geological Sciences Faculty Scholarship

Previous studies have estimated the sea level rise (SLR) at various locations on the west coast of the USA and Vancouver Island in Canada. Here, we construct an entire SLR profile from Vancouver Island in the Pacific Northwest to San Diego in Southern California. First, we process global navigation satellite system (GNSS) measurements at 405 stations blanketing the whole coast to generate a profile of vertical land motion (VLM) known to bias century-long tide gauge (TG) measurements recording relative SLR (RSLR). We are then able to estimate the absolute SLR (ASLR) by correcting the SLR with the VLM. Our study …

Developing Research Data Management Services In A Regional Comprehensive University: The Case Of Central Washington University, Ping Fu, Maurice Blackson, Maura Valentino

Library Scholarship

This study aims to analyze the needs of researchers in a regional comprehensive university for research data management services; discuss the options for developing a research data management program at the university; and then propose a phased three-year implementation plan for the university libraries. The method was to design a survey to collect information from researchers and assess and evaluate their needs for research data management services. The results show that researchers’ needs in a regional comprehensive university could be quite different from those of researchers in a research-intensive university. Also, the results verify the hypothesis that researchers in the …

Weighted Incremental–Decremental Support Vector Machines For Concept Drift With Shifting Window, Honorius Gâlmeanu, Răzvan Andonie

Computer Science Faculty Scholarship

We study the problem of learning the data samples’ distribution as it changes in time. This change, known as concept drift, complicates the task of training a model, as the predictions become less and less accurate. It is known that Support Vector Machines (SVMs) can learn weighted input instances and that they can also be trained online (incremental–decremental learning). Combining these two SVM properties, the open problem is to define an online SVM concept drift model with shifting weighted window. The classic SVM model should be retrained from scratch after each window shift. We introduce the Weighted Incremental–Decremental SVM (WIDSVM), …

Magpies: Math & Girls + Inspiration = Success: Creating And Implementing A Virtual Math Circle For Girls, Lauren L. Rose, Amanda Landi, Jazmin Zamora Flores, Cathy Zhang, Shea Roccaforte, Julia Crager

Journal of Math Circles

During the academic year 2020-2021, we ran a virtual math outreach program for upper elementary and middle school girls, MAGPIES: Math & Girls + Inspiration = Success. Monthly sessions were held over Zoom, beginning with a short introduction by a guest presenter, followed by breakout rooms led by undergraduates paired with more experienced facilitators (upper division and graduated math majors and volunteer math educators). The online community was created purposefully to be an inclusive and collaborative environment for the attending girls, and the lessons were designed to provide a learning experience for all levels of participants. Examples of sessions include …

Monitoring Whitebark Pine Stand Health In The Central Washington Cascades, Nancy H. Parra, Teresa J. Lorenz, Taza D. Schaming, Alison Scoville

Student Published Works

Whitebark pine (Pinus albicaulis) plays a vital role in colonizing newly disturbed areas, providing shade for other tree species to germinate, and supplying food for a variety of birds and mammals, such as Clark’s Nutcrackers (Nucifraga columbiana) and grizzly bears (Ursus arctos horribilis). Decline of whitebark pine populations has been attributed to several factors, including white pine blister rust (Cronartium ribicola), mountain pine beetle (Dendroctonus ponderosae) outbreaks, and fire exclusion. In 2009, the U.S. Forest Service began to install permanent plots in whitebark pine stands in Washington and Oregon as …

Nitrogen Fixation Rates In Forested Mountain Streams: Are Sediment Microbes More Important Than Previously Thought?, Erica A. H. Bakker, Carmella Vizza, Clay Arango, Sarah S. Roley

Biology Faculty Scholarship

1. Biological nitrogen (N) fixation, the microbial conversion of N₂ gas to ammonia, makes N available to food webs. Low-N streams often have a high relative abundance of N-fixing taxa, suggesting that N fixation is an important N source in these systems. Despite this potential, stream N fixation has not been well-characterised, particularly compared to lakes and marine environments. One unknown is the relative contributions of various N-fixing organisms, particularly heterotrophic microbes.
2. In low-N streams in the Cascade Mountains (Washington, USA), three groups of N-fixers predominate: cyanobacteria (Nostoc paramelioides) colonies that house a midge symbiont (Cricotopus spp.), …

Stereocontrolled Access To Δ-Lactone-Fused-Γ-Lactams Bearing Angular Benzylic Quaternary Stereocenters, Timothy K. Beng, Morgan J. Rodriguez, Claire Borg

All Faculty Scholarship for the College of the Sciences

C-fused γ-lactam-lactones are resident in several bioactive molecules, including anticancer agents such as omuralide. In this embodiment, we report mild conditions for the catalytic halolactonization of lactam-tethered 5-aryl-4(E)-pentenoic acids. The use of dichloromethane as the solvent and Ph₃PS as the catalyst led to predominant 6-endo-trig cyclization and furnished the trans-fused-γ-lactam-δ-lactones. The transformation is modular, regioselective, chemoselective, and diastereoselective. The γ-lactam-δ-lactones bear angular quaternary benzylic stereocenters, which is noteworthy since the presence of a quaternary carbon in bioactive small molecules often promotes an element of conformational restriction that imparts potency, selectivity, and metabolic stability. The …

Revisiting Prejudiced Polygons: Adapting A Familiar Activity During A Time Of Unknowns, Anne M. Ho, Jaime J. Mccauley, Tara T. Craig

Journal of Math Circles

This article describes the design process behind various iterations of Prejudiced Polygons, a Math Circles activity about segregation. In particular, we frame our discussion around two guiding principles from User Experience (UX) Design in thinking about the interconnected components of a Math Circles session, which includes all the people, the physical or virtual setting, the technology, and the world context. Additionally, we describe how we think about developing a “low floor" and “high ceiling" for math content, social issues content, as well as technology and access.

Sensitivity Of The West Antarctic Ice Sheet To +2 °C (Swais 2c), Molly O. Patterson, Richard H. Levy, Denise K. Kulhanek, Tina Van De Flierdt, Huw Horgan, Gavin B. Dunbar, Timothy R. Naish, Jeanine Ash, Alex Pyne, Darcy Mandeno, J. Paul Winberry

Geological Sciences Faculty Scholarship

The West Antarctic Ice Sheet (WAIS) presently holds enough ice to raise global sea level by 4.3 m if completely melted. The unknown response of the WAIS to future warming remains a significant challenge for numerical models in quantifying predictions of future sea level rise. Sea level rise is one of the clearest planet-wide signals of human-induced climate change. The Sensitivity of the West Antarctic Ice Sheet to a Warming of 2 ^∘C (SWAIS 2C) Project aims to understand past and current drivers and thresholds of WAIS dynamics to improve projections of the rate and size of ice sheet …

Black Carbon And Organic Carbon Dataset Over The Third Pole, Shichang Kang, Yulan Zhang, Pengfei Chen, Junming Guo, Qianggong Zhang, Zhiyuan Cong, Susan Kaspari, Lekhendra Tripathee, Tanguang Gao, Hewen Niu, Xinyue Zhong, Xintong Chen, Zhaofu Hu, Xiaofei Li, Yang Li, Bigyan Neupane, Fangping Yan, Dipesh Rupakheti, Chaman Gul, Wei Zhang, Guangming Wu, Ling Yang, Zhaoqing Wang, Chaoliu Li

Geological Sciences Faculty Scholarship

The Tibetan Plateau and its surroundings, also known as the Third Pole, play an important role in the global and regional climate and hydrological cycle. Carbonaceous aerosols (CAs), including black carbon (BC) and organic carbon (OC), can directly or indirectly absorb and scatter solar radiation and change the energy balance on the Earth. CAs, along with the other atmospheric pollutants (e.g., mercury), can be frequently transported over long distances into the inland Tibetan Plateau. During the last decades, a coordinated monitoring network and research program named “Atmospheric Pollution and Cryospheric Changes” (APCC) has been gradually set up and continuously operated …

Analysis Of Skills Sought By Employers Of Bachelors-Level Geoscientists, Gregory Shafer, Karen Viskuptic, Anne E. Egger

Geological Sciences Faculty Scholarship

Bachelors-level geoscientists make up the majority of the geoscience workforce, and positions for entry-level geoscientists are expected to grow rapidly over the next decade, with some jobs anticipating upward of 10% growth (National Center for O*NET Development, 2021). Are geoscience departments adequately preparing undergraduate students to succeed in these positions?