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Full-Text Articles in Physical Sciences and Mathematics

A Kinetic Study Pertaining To The Enzymatic Reduction Of Pyruvate By Lactate Dehydrogenase, Ronald Floyd Tienhaara Dec 1971

A Kinetic Study Pertaining To The Enzymatic Reduction Of Pyruvate By Lactate Dehydrogenase, Ronald Floyd Tienhaara

All Master's Theses

The reduction of pyruvate as catalyzed by lactate dehydrogenase has been studied by monitoring the oxidation of DPNH (diphosphopyridine nucleotide) at 340 nm. The kinetic investigation was carried out in phosphate buffer at 25° C. Since pyruvate exists in equilibrium with the enolized and hydrated forms, a kinetic analysis was devised to determine the nature of the true substrate for the enzymatic process. Also, a comparative study was made involving two isozymes of lactate dehydrogenase. The catalytic effectiveness of these isozymes was studied as a function of pH and substrate concentration.


A New Test For Normality, Richard Leroy Roller Dec 1971

A New Test For Normality, Richard Leroy Roller

All Master's Theses

This paper presents a new test for normality which is based on a complete characterization of the normal distribution. Motivation for the test is given in terms of a proof of this characterization. The test is derived and evaluated by computer-simulated sampling from alternative distributions. The empirical powers of the test generated from such samplings are tabled and compared to nine commonly used tests. Evaluation of the proposed test is discussed and further avenues of investigation are suggested.


A Kinetic Analysis Of The Iodination Of Pyruvic Acid And Pyruvate Esters, Mohamed M. Fahmi Hegazi Aug 1971

A Kinetic Analysis Of The Iodination Of Pyruvic Acid And Pyruvate Esters, Mohamed M. Fahmi Hegazi

All Master's Theses

In the present work the relative rates of iodination of pyruvic acid and ethyl and methyl pyruvate have been compared at 25.0° C. These studies allow the determination of the respective free energies of activation for these processes. Measurements have also been carried out at various temperatures to determine the enthalpies and entropies of activation for the spontaneous and base catalysed iodinations of these pyruvate systems. The present thesis also includes a comparison of the solvent deuterium isotope effects associated with the spontaneous rate of iodination of pyruvic acid and the alkyl pyruvates. Also, the catalytic rate coefficients associated with …


A Comparative Investigation Of The Effects Of Frequent Testing Upon Achievement In Secondary Advanced Algebra, John Thomas Fullerton Aug 1971

A Comparative Investigation Of The Effects Of Frequent Testing Upon Achievement In Secondary Advanced Algebra, John Thomas Fullerton

All Master's Theses

Relatively speaking, few studies have concerned themselves with the problem of frequent testing, and as Keys pointed out, empirical evidence, uncomplicated by differences in the amount of testing material employed, on the effects of frequent testing is, at best, scarce (14:427). Also many studies used tests and test results for direct instruction, thus introducing additional variables. Furthermore, the choice of subjects and disciplines has been limited, the better part being taken from college psychology and sociology classes or high school science classes. This investigation was not an attempt to modify previous experiments, nor was it an attempt to identify which …


Orthogonality In Normed Spaces, Martin R. Mccarthy Aug 1971

Orthogonality In Normed Spaces, Martin R. Mccarthy

All Master's Theses

This paper presents three definitions of orthogonality in normed spaces. Each definition is shown equivalent to the inner product being zero when restricted to an inner product space. The definitions arise from such properties in two space as the diagonals of a rectangle being equal and the Pythagorean Theorem. The third definition shows that the idea of an inner product can be generalized under certain conditions.


Synthesis And Characterization Of Some Dioxane Complexes, James Donald Satterlee Aug 1971

Synthesis And Characterization Of Some Dioxane Complexes, James Donald Satterlee

All Master's Theses

The boron trifluoride, tin (IV) fluoride and titanium (IV) fluoride complexes with 1,4-dioxane have been prepared and studied using infrared techniques. The compositions of the complexes have been determined and correspond to the 1:1 adducts in the case of the tin and titanium compounds. The boron trifluoride adduct is a 2:1 (acid:base) adduct. Infrared spectra in the region 1300 cm.-1 to 550 cm.-1 are given and the effects of coordination upon the ligand vibrations are described.


Relationships Between Reversible And Connected Automata, Robert Michael Johnson Jul 1971

Relationships Between Reversible And Connected Automata, Robert Michael Johnson

All Master's Theses

The present investigation explores some of the relationships among special classes of automata defined by Bavel and Muller (1:231-240), Trauth (6:170-175), and Cutlip (2).


A New Confidence Interval For The Mean Of A Normal Distribution, David Lee Wallace Jun 1971

A New Confidence Interval For The Mean Of A Normal Distribution, David Lee Wallace

All Master's Theses

A typical problem in statistical inference is the following: An experimenter is confronted with a density function f(x; ϴ) which describes the underlying population of measurements. The form of f may or may not be known, and ϴ is a parameter (possibly vector-valued) which describes the population. The statistician's job is to estimate or to test hypotheses about the unknown parameter ϴ. In this paper, we shall consider interval estimation of the mean of the normal density function.