Polymer and Organic Materials Commons^™

Deformation And Adhesion Of Soft Composite Systems For Bio-Inspired Adhesives And Wrinkled Surface Fabrication, Michael Imburgia

Doctoral Dissertations

The study of soft material deformation and adhesion has broad applicability to industries ranging from automobile tires to medical prosthetics and implants. When a mechanical load is imposed on a soft material system, a variety of issues can arise, including non-linear deformations at interfaces between soft and rigid components. The work presented in this dissertation embraces the occurrence of these non-linear deformations, leading to the design of functional systems that incorporate a soft elastomer layer with application to bio-inspired adhesives and wrinkled surface fabrication. Understanding the deformation of a soft elastomer layer and how the system loading and geometry influence …

Negahban Group Report: Saw-Tooth Shear Response Of Aged Poly(Methyl Methacrylate) (Pmma), Mehrdad Negahban

Department of Mechanical and Materials Engineering: Faculty Publications

Results for isothermal saw-tooth shear loading experiments conducted on annealed and oven-cooled poly(methyl methacrylate) (PMMA) at temperatures between 50^oC and 140^oC. The experiments were conducted 1996.

Development Of Lignin Carbon Fiber And Reinforced Composites, Nathan Kieran Meek

Masters Theses

The aim of this work is to develop lignin carbon fiber for composite applications. This included mechanical testing of single lignin carbon fiber (LCF), interfacial shear strength determination for LCF-resin systems using single fiber fragmentation, x-ray diffraction for the evaluation of microstructural parameters, and finally composite manufacturing and testing. Through these focused areas of analysis, the carbon fiber is thoroughly characterized and composite performance is evaluated. This effort was a collaboration with the Center for Renewable Carbon (CRC) and the Civil and Environmental Engineering Department. LCF produced by the CRC resulted in fibers having tensile strength of 250-800 MPa and …

Structure-Property Relationships Of Polyisobutylene-Block-Polyamide Thermoplastic Elastomers, Morgan Dunn Heskett

Master's Theses

Thermoplastic elastomers (TPEs) are a class of polymer fit for a wide variety of applications due to their customizability. In the synthesis of these types of materials, an elastically-performing polymer, deemed the “soft block,” is combined with a stiffer “hard block” polymer, each of which can be selected based on their own specific properties in order to achieve desired material behavior in the final copolymer. Recently, the use of polyisobutylene as a soft block in combination with a polyamide hard block has been investigated for use in TPE synthesis. While the material showed some promising behavior, many properties were still …

Spray Printing Of Organic Semiconducting Single Crystals, Grigorios-Panagiotis Rigas, Marcia M. Payne, John E. Anthony, Peter N. Horton, Fernando A. Castro, Maxim Shkunov

Chemistry Faculty Publications

Single-crystal semiconductors have been at the forefront of scientific interest for more than 70 years, serving as the backbone of electronic devices. Inorganic single crystals are typically grown from a melt using time-consuming and energy-intensive processes. Organic semiconductor single crystals, however, can be grown using solution-based methods at room temperature in air, opening up the possibility of large-scale production of inexpensive electronics targeting applications ranging from field-effect transistors and light-emitting diodes to medical X-ray detectors. Here we demonstrate a low-cost, scalable spray-printing process to fabricate high-quality organic single crystals, based on various semiconducting small molecules on virtually any substrate by …

Cold Gas Dynamic Spray – Characterization Of Polymeric Deposition, Trenton Bush

Masters Theses

When a solid, ductile particle impacts a substrate at sufficient velocity, the resulting heat, pressure, and plastic deformation can produce bonding at the interface. The use of a supersonic gas flow to accelerate such particles is known as Cold Spray deposition. The Cold Spray process has been commercialized for some metallic materials, but further research is required to unlock the exciting material properties possible with polymeric compounds. In this work, a combined computational and experimental study a) simulated and optimized the nozzle flow conditions necessary to produce bonding in a polyethylene particle, b) developed and fabricated an experimental device, and …

Characterization Of Suspension Polymerized Polyacrylamide And Poly(Sodium Acrylate-Acrylamide) Copolymer And Their Size Influence On The Properties Of Concrete, Cole R. Davis, Kendra A. Erk, Stacey L. Kelly

The Summer Undergraduate Research Fellowship (SURF) Symposium

Shrinkage leading to cracking and mechanical instability is a major problem for concrete due to the loss of water during the curing process. However, through the addition of Superabsorbent Polymer (SAP) hydrogels, shrinkage can be prevented, increasing the strength of concrete. Characterization of suspension polymerized polyacrylamide (PAM) poly(sodium acrylate-polyacrylamide) (PANa-PAM) copolymer microsphere sizes, morphology and swelling behavior was conducted before adding them to concrete. Size was determined using microscopy paired with ImageJ analysis. Coulter Counter size characterization was also used to determine the particle size distribution. Swelling behavior was determined using the tea bag method as well as size analysis …

First-Principles Studies Of Structure-Property Relationships: Enabling Design Of Functional Materials, Qunfei Zhou

Theses and Dissertations--Chemical and Materials Engineering

First-principles calculations based on quantum mechanics have been proved to be powerful for accurately regenerating experimental results, uncovering underlying myths of experimental phenomena, and accelerating the design of innovative materials. This work has been motivated by the demand to design next-generation thermionic emitting cathodes and techniques to allow for synthesis of photo-responsive polymers on complex surfaces with controlled thickness and patterns. For Os-coated tungsten thermionic dispenser cathodes, we used first-principles methods to explore the bulk and surface properties of W-Os alloys in order to explain the previously observed experimental phenomena that thermionic emission varies significantly with W-Os alloy composition. Meanwhile, …

Process Development For Compression Molding Of Hybrid Continuous And Chopped Carbon Fiber Prepreg For Production Of Functionally Graded Composite Structures, Corinne Marie Warnock

Master's Theses

Composite materials offer a high strength-to-weight ratio and directional load bearing capabilities. Compression molding of composite materials yields a superior surface finish and good dimensional stability between component lots with faster processing compared to traditional manufacturing methods. This experimental compression molding capability was developed for the ME composites lab using unidirectional carbon fiber prepreg composites. A direct comparison was drawn between autoclave and compression molding methods to validate compression molding as an alternative manufacturing method in that lab. A method of manufacturing chopped fiber from existing unidirectional prepreg materials was developed and evaluated using destructive testing methods. The results from …

Effect Of Processing History And Material Properties On The Growth Of Wrinkle Amplitude, Yu-Cheng Chen

Doctoral Dissertations

Wrinkling has been employed by many organisms to form unique topography, such as fingerprints, gut villi, and surface of flower petal cells. The wavy wrinkle structure provides friction enhancement, surface area increase, optical, and wetting properties improvement. Inspired by Nature, scientists have created wrinkles synthetically and proposed numerous uses for them. However, wrinkling surfaces encounters limitations on achieving massive area and high amplitude-to-wavelength ratio (aspect ratio). The three phase contact line wrinkling technique creates well-defined wrinkles in a continuous fashion, and has great potential to scale-up for massive production. In addition to the velocity dependent adhesion force, we find the …

Mimicking The Arterial Microenvironment With Peg-Pc To Investigate The Roles Of Physicochemical Stimuli In Smc Phenotype And Behavior, William G. Herrick

Doctoral Dissertations

The goal of this dissertation was to parse the roles of physical, mechanical and chemical cues in the phenotype plasticity of smooth muscle cells (SMCs) in atherosclerosis. We first developed and characterized a novel synthetic hydrogel with desirable traits for studying mechanotransduction in vitro. This hydrogel, PEG-PC, is a co-polymer of poly(ethylene glycol) and phosphorylcholine with an incredible range of Young’s moduli (~1 kPa - 9 MPa) that enables reproduction of nearly any tissue stiffness, exceptional optical and anti-fouling properties, and support for covalent attachment of extracellular matrix (ECM) proteins. To our knowledge, this combination of mechanical range, low …

Molecular Dynamics Investigation Of The Arabinan-Cellulose Interface For Cellulose Nanocomposite Applications, Luke Thornley

Materials Engineering

Atom level computer simulations of the arabinan and cellulose interface were performed to better understand the mechanisms that give arabinan-cellulose composites (ArCCs) their strength with the goal to improve man-made ArCCs. The molecular dynamics (MD) software LAMMPS was used in conjunction with the ReaxFF/c force field to model the bond between cellulose and arabinan. A cellulose nanocrystal with dimensions 51 x 32 x 8 Å was minimized with various weight percent of water, 0%, 3%, 5%, 8%, 10%, and 12%. After the system was equilibrated for at least 100,000 femtoseconds, an arabinan molecule composed of 8 arabinose rings was added …

Effect Of Time Delay Between Etching And Adhesive Bonding (“Outlife” Time) On Lap-Shear Strength Of Aluminum Alloys Using Environmentally-Friendly P2 Etch, Josh Barkhimer, Matthew Erich, Gokul Nair

Materials Engineering

Raytheon Company currently uses a Forest Products Laboratory (FPL) paste etchant for preparing aluminum surfaces for adhesive bonding, and FPL is a source of hazardous hexavalent chromium. The goal of this study was to evaluate a less-toxic P2 paste etchant as a possible replacement. Coupons of 2024-T3, 6061-T6, and 7075-T6 grades of aluminum alloy were solvent-degreased, abrasively cleaned, and etched at room temperature using P2 paste following a strict protocol adopted from Raytheon. Coupons were then left exposed to air for assigned time intervals (or “outlife” times) of 0, 1, 4, 8, 16, and 63 or 72 hours. The aluminum …

Predictive Modeling Of Oxygen Transmission Through Micro-Perforations For Packaging Applications, Ayman Abdellatief, Bruce A. Welt, Jason Butler, Eric Mclamore, Arthur Teixeira, Sanjay Shukla

Journal of Applied Packaging Research

Methods for creating precise perforations in respiring produce packaging are being increasingly adopted. Knowledge of oxygen transfer through perforated packaging and oxygen distribution in packages is necessary for successful packaging design of fresh produce. An approach to modeling perforated packaging performance was developed using a cylindrical chamber with precision perforations using Fick’s second law. The model was simulated using two techniques including Finite Element Method (FEM) using commercially available software and Finite Volume Method (FVM) through programming. Perforations were approximated as a source term in the second method. Both simulation techniques showed trends similar to experimental data.

Studies On The Wrinkling Of Thin Polymer Films Floating On Liquid, Kamil B. Toga

Doctoral Dissertations

This dissertation aims to broaden our understanding on wrinkling instabilities occurring on floating polymeric sheets, and tries to establish innovative methods that exploit these patterns in studies on material behavior and interfacial phenomena. We will address three major topics in this thesis including, i) characterization of the conditions required to buckle an annular disc, ii) characterization of wrinkles occurring around a droplet/bubble placed on a membrane that is kept taut at the liquid-air interface, and iii) using wrinkling patterns as a probe to understand the interfacial behavior and dynamics of ultrathin films. The first project in this thesis is about …

Radiation-Induced Radicals In Polyurea-Crosslinked Silica Aerogel, Benjamin Michael Walters

Masters Theses

Free radicals are atoms or molecules with an odd number of electrons in an outer shell. Since electrons typically occur in pairs, this leaves one electron that is unpaired. In seek of another electron to pair with, free radicals react with and steal electrons from neighboring molecules, which then become free radicals themselves. This can start a chain reaction, cascading into large scale damage.

Ionizing radiation can tear through molecules, just as bullets can tear through things that we see. If free radicals can be detected, and seen to increase in a material upon radiation exposure, this can indicate molecular …

Nanolayer Polymeric Coatings To Enhance The Performance And Service Life Of Inorganic Membranes For High Temperature-High Pressure Biomass Pretreatment And Other Applications, Vincent C. Kandagor

Doctoral Dissertations

Membrane technology has become increasingly attractive in several applications including water filtration, food industry, oil and gas, and biomedical applications. Most recently the quest for renewable, bioenergy has called for use of membranes in biomass pretreatment and other stages of producing biofuel. The success and advancement of the membrane technology for these various applications has, however, been impeded by the fouling of membranes, which causes the pores in the microporous structure to block, resulting in reduced efficiency, and in some cases, total failure of the membranes system. This challenge leads to a tremendous increase in the cost of using membranes …

Self-Assembly Of Block Copolymers By Solvent Vapor Annealing, Mechanism And Lithographic Applications, Xiaodan Gu

Doctoral Dissertations

Block copolymers (BCP) are a unique class of polymers, which can self-assemble into ordered microdomains with sizes from 3 nm to about 50 nm making BCPs an appealing meso-scale material. In thin films, arrays of BCP microdomains with longrange lateral order can serve as ideal templates or scaffolds for patterning nano-scale functional materials and synthesizing nanostructured materials with size scales that exceed the reach of photolithography. Among many annealing methods, solvent vapor annealing (SVA) is a low-cost, highly efficient way to annihilate defects in BCP thin films and facilitates the formation of highly ordered microdomains within minutes. Directing the self-assembly …

Electrospinning Applications Air Filtration And Superhydrophobic Materials, Negar Ghochaghi, Adetoun Taiwo

Graduate Research Posters

Electrospinning is a widely applicable technique that generates non-woven fibers in the micro and nano range. In this project two of its applications are highlighted namely filtration media and enhancement of wettability. The first project demonstrates that electrospinning can be used to produce new fiber filtration media with controlled microstructure. The bimodal and unimodal orthogonal and random filters were made and characterized against their filtration efficiency and pressure drop. Figure of Merit (FOM) was also calculated and discussed. It is shown that the FOM increases when the electrospun fibers are arranged into alternating layers of aligned course and fine fibers. …

Kolsky Bar Experiment For High-Rate Large Deformations Of Polycarbonate, Jason Gerald Vogeler

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Polycarbonate (PC) is a tough, transparent engineering thermoplastic. Its impact strength and ability undergo large plastic deformations without shatter make PC an ideal protective material for impact-resilient eyewear, aircraft windows and transparent armor. A good understanding of the response of this material to large deformations at high strain rates is critical for its utilization in these applications. To this end, a striker-less Kolsky bar device is employed in this work for the needed material characterization. The apparatus allow impulsive torsion and/or compression loadings with pulse durations sufficiently long for the plastic flow behavior to develop fully. Three new testing techniques …

Kolsky Bar Experiment For High-Rate Large Deformations Of Polycarbonate, Jason G. Vogeler

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Polycarbonate (PC) is a tough, transparent engineering thermoplastic. Its impact strength and ability undergo large plastic deformations without shatter make PC an ideal protective material for impact-resilient eyewear, aircraft windows and transparent armor. A good understanding of the response of this material to large deformations at high strain rates is critical for its utilization in these applications. To this end, a striker-less Kolsky bar device is employed in this work for the needed material characterization. The apparatus allow impulsive torsion and/or compression loadings with pulse durations sufficiently long for the plastic flow behavior to develop fully. Three new testing techniques …

Structure And Morphology Of Sulfonated Polysulfone And Perfluorosulfonic Acid Ionomers, Chen Wang

Doctoral Dissertations

The limitations of conventional perfluorosulfonic acid (PFSA) based membrane materials have provoked the search for alternative materials which can function as the electrolyte in PEM fuel cells operated at higher temperatures (> 100 °C) and without humidification. A novel class of sulfonated poly(phenylene) sulfone (sPSO2) ionomers have shown much higher proton conductivity than typical PFSA membranes at elevated temperatures. In this dissertation, both computational and experimental methods were used to investigate proton transfer, morphological and structural properties of sPSO2 and PFSA ionomers. We have undertaken ab initio electronic structure calculations to understand the primary hydration and the transfer of protons …

Pan Nanofibers And Nanofiber Reinforced Composites, Cheng Ren

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Nanomaterials play an important role in the development of nanotechnology. They possess unique mechanical, physical, and chemical properties coupled with small size and ultrahigh surface area that can provide critical advantages for applications. Continuous nanofibers attract special interest due to their dual nano-macro nature and ability to bridge scales. Nanofibers are being considered for a broad range of applications spanning advanced filters, separation membranes, ultrasensitive sensors, micro/nano actuators, nanoprobes, tissue engineering scaffolds, protective and smart closing, and multifunctional composites. Most of these applications require certain mechanical properties and robustness. However, the literature on the mechanical behavior of nanofibers and their …

Development Of A Novel Handheld Device For Active Compensation Of Physiological Tremor, Abhijit Saxena

Abhijit Saxena

In microsurgery, the human hand imposes certain limitations in accurately positioning the tip of a device such as scalpel. Any errors in the motion of the hand make microsurgical procedures difficult and involuntary motions such as hand tremors can make some procedures significantly difficult to perform. This is particularly true in the case of vitreoretinal microsurgery. The most familiar source of involuntary motion is physiological tremor. Real-time compensation of tremor is, therefore, necessary to assist surgeons to precisely position and manipulate the tool-tip to accurately perform a microsurgery. In this thesis, a novel handheld device (AID) is described for compensation …

Influence Of Van Der Waals Forces On Increasing The Strength And Toughness In Dynamic Fracture Of Nanofibre Networks: A Peridynamic Approach, Florin Bobaru Ph.D.

Florin Bobaru Ph.D.

The peridynamic method is used here to analyse the effect of van der Waals forces on the mechanical behaviour and strength and toughness properties of three-dimensional nanofibre networks under imposed stretch deformation. The peridynamic formulation allows for a natural inclusion of long-range forces (such as van der Waals forces) by considering all interactions as ‘long-range’. We use van der Waals interactions only between different fibres and do not need to model individual atoms. Fracture is introduced at the microstructural (peridynamic bond) level for the microelastic type bonds, while van der Waals bonds can reform at any time. We conduct statistical …

Complementarities Of Probabilistic And Evidence Approaches: An Uncertainty Assessment For Selection Of Composite Material, Stella B. Bondi, Resit Unal, Patrick T. Hester, Trina M. Chytka

Engineering Technology Faculty Publications

A complimentary probabilistic and evidence theory approach is utilized to enhance uncertainty assessments in the area of critical safety characteristics for conceptual design. This research provides additional exploration into the failure modes necessary to utilize Fiber Reinforced Polymer (FRP) and various composites to their fullest potential and to minimize uncertainty by comparing probability and evidence theories. This combined approach has been applied to a selection of composite material that could provide uncertainty assessment design for a space transportation system. Uncertainty estimates presented are bounded by belief and plausibility functions. The results may provide additional information to the decision makers in …

Materials Education And Research In Art And Design: A New Role For Libraries (Website), Mark Pompelia

Materials Education and Research in Art and Design: A New Role for Libraries

No abstract provided.

Materials Education And Research In Art And Design: A New Role For Libraries (Program Sheet), Mark Pompelia

Materials Education and Research in Art and Design: A New Role for Libraries

No abstract provided.

Materials Education And Research In Art And Design: A New Role For Libraries (Program Booklet), Mark Pompelia

Materials Education and Research in Art and Design: A New Role for Libraries

No abstract provided.

Materials Education And Research In Art And Design: A New Role For Libraries (Survey Stats), Mark Pompelia

Materials Education and Research in Art and Design: A New Role for Libraries

No abstract provided.