Engineering Science and Materials Commons^™

Syntheses Of Ag@Pd@Pt Nanoparticles With Tunable Shell Thickness For Electrochemical Oxidation Of Formic Acid, Xiao-Dong Lin, Du-Hong Chen, Zhong-Qun Tian

Journal of Electrochemistry

In an effort to lower cost of a catalyst, the silver (Ag) core with palladium (Pd) layer then platinum (Pt) island (Ag@Pd@Pt) nanoparticles were synthesized and the electrocatalytic activity of Ag@Pd@Pt nanoparticles on formic acid was compared with that of Au@Pd@Pt nanoparticles reported previously. The results showed that the existence of a small amount of Pt could significantly improve the activity of the catalyst. When the surface coverage of Pt approached 0.5 monolayers, the activity of Ag@Pd@Pt nanoparticles reached the maximum. Though the onset potential of the electro-oxidation was slightly more positive (about 50 mV), the overall electrocatalytic activity of …

Intrinsic Interfacial Property Between High-Voltage Lini0.5Mn1.5O4 Cathode And Electrolyte, Li Li, Jing-Jing Xu, Shao-Jie Han, Wei Lu, Li-Wei Chen

Journal of Electrochemistry

To obtain high energy density, developing high-voltage cathode materials is an effective approach. The cathode/electrolyte interface stability is the key factor for the cycle performance and safety performance of high-voltage lithium ion batteries. It is, therefore, of significant importance to study the stability of cathode/electrolyte interface. However, many reports have shown that at the cathode/electrolyte interface the cathodes were prepared by coating the mixture of active materials with a conductive additive and a binder on an Al current collector. The introduction of additives will interfere the surface morphology and component analyses, resulting in difficulty to acquire the intrinsic information at …

Lithium-Sulfur (Selenium) Batteries: Interface Issues And Solving Strategies, Nian-Wu Li, Ya-Xia Yin, Yu-Guo Guo

Journal of Electrochemistry

The stable interface is still a challenge for lithium-sulfur (selenium) batteries because of the low conductivity of sulfur (selenium), dissolution of polysulfide (polyselenide), volume expansion of sulfur (selenium), and lithium dendrite growth. This review describers some recent developments in lithium-sulfur (selenium) batteries and highlights our efforts in this field. The possible strategies for building stable interface in the lithium-sulfur (selenium) batteries including nano-restriction effect, chemical bonding, interface adsorption, surface coating, electrolyte optimization, and Lithium anode treatment have been discussed.

Electrochemical Behaviors And Determinations Of Terbutaline Sulfate At Poly Eriochrome Black T Modified Electrode, Yan-Jie Zheng, Hong Yao, Shao-Huang Weng, Hua-Ping Peng, Shi-Wen Gong, Li Huang, Qiang Dai, Xin-Hua Lin

Journal of Electrochemistry

The poly eriochrome black T modified electrode was prepared by electropolymerization. This modified electrode was characterized by scanning electron microscopy(SEM), electrochemical impedance spectroscopy(EIS) and cyclic voltammetry (CV). The electrochemical behaviors of terbutaline sulfate were studied by CV, while the recoveries were measured by differential pulse voltammetry (DPV). The modified electrode shows excellent electrocatalytic characteristics for terbutaline sulfate. In pH 7.0 phosphate buffer solution, the oxidation peak currents obtained by DPV were linear to the terbutaline sulfate concentrations over the range of 1.2x10^-7~2.0x10^-6 mol•L^-1. The detection limit was estimated to be 1.5x10^-8 mol•L^-1 and …

Lithium Plating Identification From Degradation Behaviors Of Lithium-Ion Cells, Jian-Bo Zhang, Lai-Suo Su, Xin-Yu Li, Hao Ge, Ya-Kun Zhang, Zhe Li

Journal of Electrochemistry

Lithium plating has huge impact on the lifetime and safety of lithium-ion cells. It is, therefore, necessary to identify lithium plating. In this study, the accelerated stress tests of lithium-ion cells were conducted under different conditions with multi-stress loads. Based on the different effects of the two major aging mechanisms, namely, SEI (Solid Electrolyte Interface) layer growth and lithium plating, on the degradation behaviors, two lithium plating identification methods of resistance-capacity plot and Arrhenius plot were employed. The experimental results revealed that the two identification methods are highly consistent with each other. Furthermore, the origins of capacity loss were distinguished …

Stm Investigation Of Oxygen Reduction Reaction On Solid Interface In Fuel Cell, Zhen-Feng Cai, Bing Sun, Wen-Jie Jiang, Ting Chen, Dong Wang, Li-Jun Wan

Journal of Electrochemistry

An electrocatalyst for oxygen reduction reaction (ORR) is an important component for fuel cells. An investigation at interfacial electrochemical reactions toward ORR at a molecular scale benefits mechanistic understanding as well as rational design of catalysts. Scanning tunneling microscopy (STM) has been proven to be a powerful tool to monitor chemical reactions and to provide in-situ information about the interfacial electrochemical reactions at a molecular level. This review summarizes the recent STM studies in monitoring the interface processes such as morphological changes, molecular changes, reaction intermediates, and oxidation products. The prospects of future development in this field are outlined.

A Study On The Oxidation Of Hydrogen Peroxide At Au(111) And Au(100) Electrodes, Yong-Li Zheng, Jie Wei, Yan-Xia Chen

Journal of Electrochemistry

The oxidation reactions of hydrogen peroxide (H₂O₂) at Au(111) and Au(100) electrodes in 0.1 mol·L^-1 HClO₄ were investigated by using rotating disk electrode system. It was found that H₂O₂ could be readily oxidized to O₂ at both Au(100) and Au(111) surfaces with the onset potential close to its equilibrium potential. In contrast, the onset overpotential for H₂O₂ reduction was above 0.4 V, while the onset overpotential for H₂O₂ oxidation at Au(100) was ca. 0.1 V more negative than that at Au(111), this is probably …

Chitosan/Nonahydrate Gel Derived Fe-N-Doped Porous Carbon Sheet As High-Efficient Orr Electrocatalyst, Fan-Lu Meng, Xin-Bo Zhang, Jun-Min Yan

Journal of Electrochemistry

The chitosan/nonahydrate gel was used as a precursor to realize the uniform mixture of N-polymer and metal salt. After lyophilization treatment, the gel went through heat treatment and acid etch. Accordingly, the Fe-N-doped porous carbon sheet with homogenous composition and microstructure was prepared. Compared with the commercial Pt/C catalyst, the Fe-N-doped porous carbon sheet exhibited more positive onset potential and half-wave potential, higher current density, and especially, excellent durability. The power density of 318 mW·cm^-2 was obtained in alkaline fuel cell with the Fe-N-doped porous carbon sheet as a cathode catalyst, which is higher than 267 mW·cm^-2 with …

Investigation On Laser Induced Deposition Of Cu-Based Materials At [Bmim]Bf4/Pt Electrode Interface, Min-Min Xu, Jin-Hua Mei, Jian-Lin Yao, Ren-Ao Gu

Journal of Electrochemistry

By controlling the negative potential, Cu-based materials were deposited at the [BMIm]BF₄/Pt electrode interface under the laser irradiation. The effects of laser power and irradiation time on the yield of deposition products were studied by using different laser powers and different irradiation time. The product yield could be directly determined by the size of deposition point through the observation from the optical microscope. Further mechanism study combined with the formula deduced that the thermal effect of the laser could make the electrode surface temperature rise 110 degrees, which can promote the occurrence of electrodeposition. By SEM characterization, the …

Synthesis Of Ultrathin Co3O4 Nanoflakes Film Material For Electrochemical Sensing, Hui-Juan Wang

Journal of Electrochemistry

Ultrathin cobalt oxide (Co₃O₄ ) nanoflakes film material was synthesized by using an electro-deposited cobalt layer as a raw material through a simple oxidation method and followed by a heat treatment at 350 ^oC. The physical characterizations of the Co₃O₄ nanoflakes film were performed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and transmission electron microscopy (TEM) technologies, and the electrochemical activity was measured by cyclic voltammetry (CV). As a promising material for electrochemical sensing, the as-synthesized ultrathin Co₃O₄ nanoflakes film material exhibited excellent electrochemical activity for H₂O …

The Effect Of A Powered Ankle Foot Orthosis On Walking In A Stroke Subject: A Case Study, Ali Pourghasem, Ismail Ebrahimi Takamjani, Mohammad Taghi Karimi, Mohammad Kamali, Mohammad Jannesari, Iman Salafian

Department of Mechanical and Materials Engineering: Faculty Publications

[Purpose] Standing and walking are impaired in stroke patients. Therefore, assisted devices are required to restore their walking abilities. The ankle foot orthosis with an external powered source is a new type of orthosis. The aim of this study was to evaluate the performance of a powered ankle foot orthosis compared with unpowered orthoses in a stroke patient.

[Subjects and Methods] A single stroke subject participated in this study. The subject was fitted with three types of ankle foot orthosis (powered, posterior leg spring, and carbon ankle foot orthoses). He was asked to walk with and without the three types …

Lucidpipe™ Power System, Purdue Ect Team

ECT Fact Sheets

In most gravity fed water transmission pipelines, it is desired to reduce excess pressure head to prevent undue strain on a pipeline and lower the incidence of leaks. Normally this is done with pressure reducing valves that essentially burn off this excess pressure as heat. The LucidPipe™ system converts it to low cost electricity thereby removing unwanted pressure and generating energy at the same time - energy that can be put used behind the grid or put back on the grid. The LucidPipe™ system extracts a small percentage of pressure head providing nearly invisible operation allowing water operators to fulfill …

Microstructure Control And Correlation To Creep Properties In Grade 91 Steel Weldment After Thermo-Mechanical Treatments And An Fe-30cr-3al Alloy Strengthened By Fe2nb Laves Phase, Benjamin Allen Shassere

Doctoral Dissertations

Type IV cracking in weldments of steel pipes after creep deformation is a concern in modern fossil-fueled power plants. Two possible methods for minimizing or eliminating Type IV cracking will be discussed. The first method alters the initial microstructure of typical Grade 91 steel base metal before welding, while the second provides baseline microstructure characteristics and creep performance of a new alloy that is strengthened by the intermetallic Fe2Nb Laves phase. The initial microstructure of the Grade 91 steel can be controlled by Thermo-Mechanical Treatments, which aids in precipitation of fine (5-10 nm) MX particles in austenite before transformation to …

Mechanics Of Soft Polymers, Trisha Sain

TechTalks

Understanding the mechanics and physics of soft polymers are essential due to their widespread applications across disciplines. (e.g.-composite materials, bio mechanics, soft robotics etc.) The soft polymers in general inherent lightweight, high stretchability, extreme viscous damping and stimuli responsive behavior. Development of computational modeling strategy to predict their constitutive response, stimuli responsive behavior is indeed helpful for designing novel multifunctional soft composites, artificial mussels/tissues. In this talk I will briefly emphasize how we are developing multiscale-multiphysics based modeling methods for soft polymers to understand their macroscopic deformation mechanism, failure and other mechanical properties. The long term goal is to develop …

Aps Labs (Advanced Power Systems Research Center), Jeffrey D. Naber

TechTalks

Our mission is to promote & facilitate education and research in clean, efficient, and sustainable power and powertrain systems. The center was established in 2007 and in 2014 the 55,000 sq ft APSRC building located near the airport was denoted as a MTU core facility. Our new research contracts in FY2016 were over $2.5M. Our partners include automotive OEMs: GM, Ford, FCA, Toyota, Honda; Commercial OEMs: Cummins, Deere, Detroit, Isuzu, MHI; Suppliers: Delphi, Denso, Borg Warner, Hitachi; and DOE Labs: ANL, ORNL, PNNL, SNL, & INL. We have seven staff to assist in educational and R&D programs and facilities to …

Microstructural Analysis Of Thermoelastic Response, Nonlinear Creep, And Pervasive Cracking In Heterogeneous Materials, Alden C. Cook

Electronic Theses and Dissertations

This dissertation is concerned with the development of robust numerical solution procedures for the generalized micromechanical analysis of linear and nonlinear constitutive behavior in heterogeneous materials. Although the methods developed are applicable in many engineering, geological, and materials science fields, three main areas are explored in this work. First, a numerical methodology is presented for the thermomechanical analysis of heterogeneous materials with a special focus on real polycrystalline microstructures obtained using electron backscatter diffraction techniques. Asymptotic expansion homogenization and finite element analysis are employed for micromechanical analysis of polycrystalline materials. Effective thermoelastic properties of polycrystalline materials are determined and compared …

Me-Em Enewsbrief, December 2016, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University

Department of Mechanical Engineering-Engineering Mechanics eNewsBrief

No abstract provided.

Development Of Lignin Carbon Fiber And Reinforced Composites, Nathan Kieran Meek

Masters Theses

The aim of this work is to develop lignin carbon fiber for composite applications. This included mechanical testing of single lignin carbon fiber (LCF), interfacial shear strength determination for LCF-resin systems using single fiber fragmentation, x-ray diffraction for the evaluation of microstructural parameters, and finally composite manufacturing and testing. Through these focused areas of analysis, the carbon fiber is thoroughly characterized and composite performance is evaluated. This effort was a collaboration with the Center for Renewable Carbon (CRC) and the Civil and Environmental Engineering Department. LCF produced by the CRC resulted in fibers having tensile strength of 250-800 MPa and …

Self-Patterning Gd Nano-Fibers In Mg-Gd Alloys, Yangxin Li, Jian Wang, Kaiguo Chen, Meiyue Shao, Yao Shen, Li Jin, Guo-Zhen Zhu

Department of Mechanical and Materials Engineering: Faculty Publications

Manipulating the shape and distribution of strengthening units, e.g. particles, fibers, and precipitates, in a bulk metal, has been a widely applied strategy of tailoring their mechanical properties. Here, we report self-assembled patterns of Gd nano-fibers in Mg-Gd alloys for the purpose of improving their strength and deformability. 1-nm Gd nano-fibers, with a 〈c〉-rod shape, are formed and hexagonally patterned in association with Gd segregations along dislocations that nucleated during hot extrusion. Such Gd-fiber patterns are able to regulate the relative activities of slips and twinning, as a result, overcome the inherent limitations in strength and ductility of Mg alloys. …

Structure-Property Relationships Of Polyisobutylene-Block-Polyamide Thermoplastic Elastomers, Morgan Dunn Heskett

Master's Theses

Thermoplastic elastomers (TPEs) are a class of polymer fit for a wide variety of applications due to their customizability. In the synthesis of these types of materials, an elastically-performing polymer, deemed the “soft block,” is combined with a stiffer “hard block” polymer, each of which can be selected based on their own specific properties in order to achieve desired material behavior in the final copolymer. Recently, the use of polyisobutylene as a soft block in combination with a polyamide hard block has been investigated for use in TPE synthesis. While the material showed some promising behavior, many properties were still …

Sulfate Resistance Of Nanosilica Contained Portland Cement Mortars, Iani Batilov Batilov

UNLV Theses, Dissertations, Professional Papers, and Capstones

Soils, sea water and ground water high in sulfates are commonly encountered hostile environments that can attack the structure of concrete via chemical and physical mechanisms which can lead to costly repairs or replacement. Sulfate attack is a slow acting deteriorative phenomenon that can result in cracking, spalling, expansion, increased permeability, paste-to-aggregate bond loss, paste softening, strength loss, and ultimately, progressive failure of concrete. In the presented research study, Portland cement (PC) mortars containing 1.5% to 6.0% nanosilica (nS) cement replacement by weight were tested for sulfate resistance through full submersion in sodium sulfate to simulate external sulfate attack. Mortars …

Alkali-Activated Natural Pozzolan/Slag Binder For Sustainable Concrete, Meysam Najimi

UNLV Theses, Dissertations, Professional Papers, and Capstones

This study aimed to fully replace Portland cement (PC) with environmentally friendly binders capable of improving longevity of concrete. The new binders consisted of different proportions of natural Pozzolan and slag which were alkaline-activated with various combinations of sodium hydroxide and sodium silicate. A step-by-step research program was designed to (1) develop alkali-activated natural Pozzolan/slag pastes with adequate fresh and strength properties, (2) produce alkali-activated natural Pozzolan/slag mortars to assess the effects of dominant variables on their plastic and hardened properties, and (3) finally produce and assess fresh, mechanical, dimensional, transport and durability properties of alkali-activated natural Pozzolan/slag concretes. The …

Spray Printing Of Organic Semiconducting Single Crystals, Grigorios-Panagiotis Rigas, Marcia M. Payne, John E. Anthony, Peter N. Horton, Fernando A. Castro, Maxim Shkunov

Chemistry Faculty Publications

Single-crystal semiconductors have been at the forefront of scientific interest for more than 70 years, serving as the backbone of electronic devices. Inorganic single crystals are typically grown from a melt using time-consuming and energy-intensive processes. Organic semiconductor single crystals, however, can be grown using solution-based methods at room temperature in air, opening up the possibility of large-scale production of inexpensive electronics targeting applications ranging from field-effect transistors and light-emitting diodes to medical X-ray detectors. Here we demonstrate a low-cost, scalable spray-printing process to fabricate high-quality organic single crystals, based on various semiconducting small molecules on virtually any substrate by …

Single Site Robotc Device And Related Systems And Methods, Jack Mondry, Shane M. Farritor, Eric Markvicka, Thomas Frederick, Joseph Bartels

Department of Mechanical and Materials Engineering: Faculty Publications

The embodiments disclosed herein relate to various medical device components, including components that can be incor porated into robotic and/or in vivo medical devices. Certain embodiments include various medical devices for in vivo medical procedures.

Two-Phase Transport In Proton Exchange Membrane Fuel Cells, Kazuya Tajiri

TechTalks

In Multiscale Transport Process Laboratory our research is focused on the experimental and computational analysis of transport phenomena in electrochemical devices and propulsion systems. In this talk our research activity on proton exchange membrane fuel cells (PEMFCs) for automotive application will be explained. Water management is one of the most critical issues in PEMFCs. The water generated in catalyst layer as a product of the electrochemical reaction needs to be removed through porous media by diffusion if it’s vapor, or by capillarity in case of liquid. In flow channels, the liquid water is removed primarily by inertial force of the …

Solid State Sound: A "Hot" Topic, Andrew Barnard

TechTalks

As seen with the latest iPhone 7 release, traditional audio components can now be a limiting factor in technology design. What if we could make a loudspeaker with no moving parts and virtually no weight? Carbon nanotube loudspeakers are such devices. They create sound using heat oscillations, as opposed to a moving diaphragm. They have the thickness of only a handful of carbon atoms, are flexible and stretchable. In this TechTalk I’ll discuss the carbon nanotube loudspeaker and the design challenges in maturing this intriguing technology.

Wearable Electronics, Human-Centered Monitoring, Ye Sarah Sun

TechTalks

Non-contact solution in wearable electronics: A conventional clinical system requires the use of wet electrodes that are in contact with skin using conductive gel to acquire physiological signals. Those systems can acquire high quality signals but may not be feasible for a long-term purpose due to the skin irritation and allergic contact dermatitis. The emerging of human-centered monitoring calls for alternative solutions. Recent technological advances enable capacitive measurement that can acquire signals through cloth or even with an air gap in wearable condition. In this TechTalk I will introduce the non-contact solution in wearable electronics.

Finite Element Simulation Of Pzt-Aided Interrogation Of Composite Laminates Exhibiting Damage, Amany Micheal, Yehia Bahei-El-Din

Centre for Advanced Materials

Piezoelectricity has proved effective in capturing changes in structures caused by various damage mechanisms. In one approach, piezoelectric wafer active sensors (PWAS) are mounted on the surface of the host structure and utilized as both actuators and sensors to interrogate the structure and monitor its health. This is achieved by subjecting the PWAS to a transient electric pulse and reading the resulting voltage. Changes in the stiffness of the substrate due to structural damage affect the response of the PWAS, which could be correlated to integrity of the structure. Applying this technique to fibrous composite laminates encounters particular challenges due …

The Effects Of The Stratosphere On Materials, Ashley C. Greene, Theresa M. Palandro

Posters-at-the-Capitol

Abstract 1:

Making AND Breaking: How reliable are some water pipes?

Ashley C. Greene.

Three different types of pipes were tested to see at what point in time they would break. The pipes, PVC pipe, PEX pipe, and CPVC pipe, were filled with water and attached to a helium filled weather balloon. The ends of the pipes were sealed to trap the water inside. The pipes were secured onto a payload in a Styrofoam box surrounded by cheese cloth. This frame secured the pipes and ensured that they stayed in one place and could not move around the container. The …

Cold Gas Dynamic Spray – Characterization Of Polymeric Deposition, Trenton Bush

Masters Theses

When a solid, ductile particle impacts a substrate at sufficient velocity, the resulting heat, pressure, and plastic deformation can produce bonding at the interface. The use of a supersonic gas flow to accelerate such particles is known as Cold Spray deposition. The Cold Spray process has been commercialized for some metallic materials, but further research is required to unlock the exciting material properties possible with polymeric compounds. In this work, a combined computational and experimental study a) simulated and optimized the nozzle flow conditions necessary to produce bonding in a polyethylene particle, b) developed and fabricated an experimental device, and …