Chemical Engineering Commons^™

Comparative Investigations On Microextraction And Conventional Air Sampling Techniques: Challenges And Future Directions, Firoz Ahmed, Mehedi Hasan Roni, Ashiqur Rahman, Sayed M A Salam

Al-Bahir Journal for Engineering and Pure Sciences

Microextraction technique (e.g., solid phase microextraction, thin film microextraction, in-tube extraction) brings a revolutionary change in air sampling techniques over the recent few years. This advanced technique exhibits a high pollutant extraction rate, a low retention time, and a lower error margin compared to conventional air sampling techniques. The accuracy range of microextraction technique (MET) was recorded ~90-95% to isolate the volatile organic components, oxygenated and halogenated carbon particles from the air. However, the efficiency of MET increases additional >3-5% when employed by coupled with gas chromatography or gas chromatography-mass spectrometry. The conventional sampling techniques (e.g., bag sampling, grab sampling) …

Quantification Of Geodetic Strain Rate Uncertainties And Implications For Seismic Hazard Estimates, Jeremy Maurer, Kathryn Materna

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Geodetic velocity data provide first-order constraints on crustal surface strain rates, which in turn are linked to seismic hazard. Estimating the 2-D surface strain tensor everywhere requires knowledge of the surface velocity field everywhere, while geodetic data such as Global Navigation Satellite System (GNSS) only have spatially scattered measurements on the surface of the Earth. To use these data to estimate strain rates, some type of interpolation is required. In this study, we review methodologies for strain rate estimation and compare a suite of methods, including a new implementation based on the geostatistical method of kriging, to compare variation between …

Experimental Data Supporting Co2 Enhanced Oil Recovery And Storage Potential In The Bakken Petroleum System (Bps), University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet on CO₂ enhanced oil recovery (EOR) in the Bakken petroleum system. Highlights experimental data concerning CO₂’s role in oil recovery in the region.

Treating High Salinity Produced Water Using Hybrid Membrane Processes: Electrocoagulation-Microfiltration/Ultrafiltration-Membrane Distillation-Crystallization, Mahmood Gheni Jebur

Graduate Theses and Dissertations

Produced water (PW) is considered the largest industrial wastewater stream in the world. PW generated from oil and gas operations generally contains a range of contaminants including high total dissolved solids, high total suspended solids, polar and nonpolar organic compounds, and low surface tension dissolved species. Treating PW is very challenging and applying only membrane-based technologies is not sufficient due to membrane fouling, which affects their long-term performance. Hence, integrated membrane processes are required to treat PW effectively. Hybrid membrane processes, which may result from combining a conventional process with a membrane separation, could be used to address the issues …

Results Of The Study Of The Pumpkin Drying Process, Jasur Esirgapovich Safarov, Shahnoza Abduvakhitovna Sultanova, Andrey Svyatoslavovich Ponasenko, Gani Toshkhujaevich Dadaev

Chemical Technology, Control and Management

The article presents the results of the study of the pumpkin drying process, comparisons with different drying models are carried out. A mathematical model for numerical analysis has been developed. Pumpkin drying rates are calculated and various drying models are investigated. 5 different drying models were used to verify the accuracy of experimental data and search for the most suitable model. The experimental data obtained for the drying air temperature of 45 °C, 55 °C and 65 °C were applied to various drying models.

Use Of Neural Networks In Intelligent Measurement Tools, N.R Yusupbekov, Y.Sh. Avazov, Umidjon Ruziev Phd

Chemical Technology, Control and Management

The paper presents algorithms for processing the measurement signal with the possibilities of adaptation, learning and decision making. A comparative analysis of the methods of intellectual processing of measurement data is carried out. A model of a measuring instrument for determining the structure of a neural network has been developed. The problem of error reduction due to measurement noise filtering with the use of neural networks is considered. The structure of the neural network has been developed for intelligent processing of the measurement signal and ensuring the implementation of the functions of reconfiguration, calibration, self-diagnosis and self-control. A neural network …

Mathematical Model Of An Industrial Robot Built On The Basis Of Linear Motion Mechatron Modules, Matyokubov Nurbek Rustamovich, Rakhimov Temurbek Omonboyevich

Chemical Technology, Control and Management

The use of Industry 4.0 technologies in modern production serves to increase production efficiency. Robots and robotic complexes with innovative intelligent control are widely used in industrial production. However, studying their mechanical part, linear motion mechatronic modules and control system is a complex object. The variety and complexity of control methods and operating modes negatively affects the operator's working time and production productivity. In such cases, it is necessary to improve control methods and develop technologies used in industry, including robots and robotic manipulators, which allow to perform short movements with high accuracy and speed. In the article, the mathematical …

Systematic Analysis Of Methods Of Control Of Dynamic Objects In Conditions Of Non-Measurable Disturbances, Mamirov Farkhodovich Uktam, Buronov Mamurjon Ugli Bunyod

Chemical Technology, Control and Management

The article presents a systematic analysis of control methods of dynamic objects under non-measurable disturbances. It is important to study all the factors affecting the control object in order to increase the efficiency of the control system. Due to the immeasurable nature of disturbances affecting control objects, it is shown that they cause negative effects and increase the complexity of control systems in this case. In the control of dynamic objects of this type, the possibilities of control by indirect measurement of disturbances or by estimation of object position and disturbances have been explored. The use cases, shortcomings and achievements …

Computer Training Systems For Training Engineering Personnel For Control Industrial Enterprises, Yusuf Shodiyevich Avazov, Kamola Rustamovna Abdullaeva

Chemical Technology, Control and Management

A principle has been proposed for constructing computer simulators for improving the qualifications of process control operators at industrial enterprises and for training students of higher educational institutions. The capabilities of a computer simulator that can be used as a digital assistant are revealed. Their architecture for building digital simulators is proposed. From the architecture it is clear that the computer simulator consists of two systems. The training process management system and the server of the computerized simulator are combined into a digital simulator. Simulators in this category provide student operators with the opportunity to develop skills in self-control of …

Bacterial Motion And Spread In Porous Environments, Yasser Almoteri

Dissertations

Micro-swimmers are ubiquitous in nature from soil and water to mammalian bodies and even many technological processes. Common known examples are microbes such as bacteria, micro-algae and micro-plankton, cells such as spermatozoa and organisms such as nematodes. These swimmers live and have evolved in multiplex environments and complex flows in the presence of other swimmers and types, inert particles and fibers, interfaces and non-trivial confinements and more. Understanding the locomotion and interactions of these individual micro-swimmers in such impure viscous fluids is crucial to understanding the emergent dynamics of such complex systems, and to further enabling us to control and …

Challenges In Optimization For The Performance On Sustainability Dimensions In Reverse Logistics Social Responsibility, Sumarsono Sudarto, Katsuhiko Takahashi, Mochammad Dewo

Makara Journal of Technology

Reverse logistics social responsibility is preferred as the most acceptable solution for addressing the challenges in stakeholders’ debate regarding social responsibility in supply chains because it involves as many actors as possible in the supply chain to perform social responsibility to achieve sustainability. This paper explores the challenges in achieving optimal policies in sustainability dimensions for collection and recycling facilities in reverse logistics. Sustainability dimensions include economic, environmental, and social aspects. The reverse logistics is modeled on System Dynamics, and a simplified statistical analysis using a contour chart is employed in numerical experiments. Results show a narrow area of optimal …

Algorithms For Synthesis Of Adaptive Control Systems Based On The Neural Network Approach, Jasur Sevinov, Oxunjon Boborayimov, Sh.M. Abdishukurov

Chemical Technology, Control and Management

Here are algorithms for the synthesis of adaptive control systems based on the neural network approach presented. The issues of choice of architectures of neural networks that produce parametric identification of the object regulation. Adaptative neural networks that reproduce the optimal parameters of implemented controllers, methods of forming training samples for their training are considered. The other question of using the theory of artificial neural networks for approximating the functional of the controller's tuning parameters are determined. Structures of synthesized neural networks of parametric identification of objects with self-alignment in an open loop ACS are proposed. Algorithms made it possible …

Obtaining Sweet Molasses By The Method Of Hydromechanical And Enzymatic Processing Of Grain, Sadritdin Maxamatdinovich Turabdjanov, Kamoliddin Ahmadjonovich Mahmudov, Bexzod Alisherovich Kasimov, Kasun Dissanayake Kumara

Chemical Technology, Control and Management

Methods of hydrolysis of grains to starch under the influence of hydrodynamic and enzymatic processes are logically based. Polysaccharides derived from starchy grains are known and popular in the food industry for their thickening and stabilizing properties. To date, studies that allow for a deeper understanding of the mechanism of interaction of polysaccharide-containing products with their main components, the effect on the set of rheological, organoleptic, physico-chemical properties of food products that determine their functions are relevant.

Development Of The Computer Model Of The Waste Water Treatment Process Using Ion-Exchange Resins In The Matlab Program, Jaloliddin Abdurazzakovich Eshbobaev, Bakhodir Tajiddinovich Khamidov, Adham Tilovovich Norkobilov, Orifjon Sharipovich Kodirov

Chemical Technology, Control and Management

In this work, a mathematical model of industrial wastewater treatment technology was formed. First, wastewater treatment technologies were analyzed and the technology of ion-exchange resin treatment was selected. A water purification device using ion-exchange resins was made, and tested on the Kungrad soda plant and the results were obtained. According to these results, it was determined that the cleaning coefficient of the device is up to 98-99%. In this article, a mathematical model of a wastewater treatment device using ion-exchange resins was developed using the stoichiometric matrix method. After the mathematical model of the process was found, a graph of …

The Morphology Analysis Of Soil In Remote Sensing Image Processing, Mirzayan Mirzaaxmedovich Kamilov, Mirzaakbar Xakkulmirzayevich Hudayberdiev, Bobomurod Mamitjonovich Tojiboev

Chemical Technology, Control and Management

This article analyzed various techniques used in satellite image processing to analyze soil morphology. Analysis of soil morphology using satellite imagery plays a crucial role in soil science research, Land Management, and environmental monitoring. It provides an economical and efficient means of studying large-scale soil variability, providing information on land sustainable use, resource management and soil conservation decisions.

Application Of Evolutionary Algorithms For Optimization Of Operation Modes Of Regional Electric Power Systems, Isamiddin Khakimovich Siddikov, Oksana Vitalevna Porubay

Chemical Technology, Control and Management

The paper presents the possibilities of using evolutionary algorithms to solve the problem of optimizing the operation modes of electric power facilities in the presence of constraints in the form of inequalities and equalities. The limits of constraints have a variable character, depending on the generated and consumed energy. Existing methods used for the optimization of modes are based on general principles and approaches to optimization, which usually adapt to the specifics of the problem. In electric power facilities, optimization problems have some peculiarities, among which is the presence of multiple constraints applied to both independent and dependent variables. Many …

Investigating The Rheological Behavior Of A Simple Yield Stress Fluid Under Shear Flows, Francesco Accetta

Theses

Many soft materials display unique and complex rheological behavior characterized by a transition from a solid-like to a fluid-like state upon the application of a force that exceeds the threshold to flow, known as the yield stress. Yield stress fluids are found in a wide range of commonly encountered materials including microgels, emulsions, and foams, and have been widely studied by rheologists over the last several decades. Carbopol is a popular polymeric microgel system as it displays simple, non-thixotropic rheological behavior and is typically seen as an ideal yield stress fluid. Previous research has demonstrated the reproducible behavior of shear …

Optimization Of A Bioreactor, Ali Alshami

AI Assignment Library

The primary objective of this assignimentis to learn to work effectively as a team, and to design an experiment where optimization is essential.

Synthesis And Evaluation Of Organic Additives For Copper Electroplating Of Interconnects, Yue-Hui Zhai, Yi-Xiao Peng, Yan Hong, Yuan-Ming Chen, Guo-Yun Zhou, Wei He, Peng-Ju Wang, Xian-Ming Chen, Chong Wang

Journal of Electrochemistry

Copper interconnects are essential to the functionality, performance, power efficiency, reliability, and fabrication yield of electronic devices. They are widely found in chips, packaging substrates and printed circuit boards, and are often produced by copper electroplating in an acidic aqueous solution. Organic additives play a decisive role in regulating copper deposition to fill microgrooves, and micro-vias to form fine lines and interlayer interconnects. Generally, an additive package consists of three components (brightener, suppressor, and leveler), which have a synergistic effect of super-filling on electroplating copper when the concentration ratio is appropriate. Many works of literature have discussed the mechanism of …

Conversion Of Biomass Derived Tar In A Catalytic Post-Gasification Process, Floria Rojas Chaves

Electronic Thesis and Dissertation Repository

The present MESc thesis reports the performance of a fluidizable CeO₂ promoted Ni/γ-Al₂O₃ catalyst to be used in a post-gasification process for tar removal. The catalysts developed were prepared using the incipient wetness technique and characterized chemically and physically, using the following techniques: N₂ Adsorption-Desorption, XRD, NH₃ and CO₂ TPD, Pyridine-FTIR, H₂-TPR, and H₂-Pulse Chemisorption. The catalysts were tested in a fluidized CREC Riser Simulator, in the 500°C-550°C temperature range, within 5 s-10 s reaction times, using both steam and steam-H₂/CO₂ atmospheres.A 2-methoxy-4-methlyphenol (2M4MP) compound was …

Retracted: Fabrication And Characterization Of Wood Fiber Reinforced Polymer Composites, Firoz Ahmed, Omar Faroque, Saif Hasan, Khan Rajib Hossain, Rezaul Karim Sheikh

Al-Bahir Journal for Engineering and Pure Sciences

Wood-polymer composites (WPCs) combine the properties of wood and polymers. Creating composites involves adding plant or wood fibers as fillers to a polymer matrix. This study used mahogany and mango wood sawdust as reinforcement materials, while high-density polyethylene (HDPE) and polyvinyl chloride (PVC) were used as matrices. The investigated data in this study comprises four different (10, 20, 30, and 40) weight percentages (wt%) of mahogany and mango sawdust paired with corresponding wt% (90, 80, 70, and60) of HDPE and PVC matrices. The extrusion method produced composites with different amounts of sawdust and polymer matrices. Wood polymer composites were characterized …

Ph Gradients In Spatially Non-Uniform Ac Electric Fields Around The Charging Frequency; A Study Of Two Different Geometries And Electrode Passivation, Azade Tahmasebi, Sanaz Habibi, Jeana Collins, Ran An, Esmaeil Dehdashti, Adrienne Minerick

Michigan Tech Publications, Part 2

Dielectrophoresis (DEP), a precision nonlinear electrokinetic tool utilized within microfluidic devices, can induce bioparticle polarization that manifests as motion in the electric field; this phenomenon has been leveraged for phenotypic cellular and biomolecular detection, making DEP invaluable for diagnostic applications. As device operation times lengthen, reproducibility and precision decrease, which has been postulated to be caused by ion gradients within the supporting electrolyte medium. This research focuses on characterizing pH gradients above, at, and below the electrode charging frequency (0.2–1.4 times charging frequency) in an aqueous electrolyte solution in order to extend the parameter space for which microdevice-imposed artifacts on …

Engineering Multifunctional Adhesive Hydrogel Patches For Biomedical Applications, Aishik Chakraborty, Shana Alexander, Wei Luo, Narisse Al-Salam, Mia Van Oirschot, Sudhir H. Ranganath, Subrata Chakrabarti, Arghya Paul

Chemical and Biochemical Engineering Publications

Traditional patches, such as sticking plaster or acrylic adhesives used for over a hundred years, lack functionality. To address this issue of poor functionality, adhesive hydrogel patches have emerged as an efficient bioactive multifunctional alternative. Hydrogels are three-dimensional, water-swellable, and polymeric materials closely resembling the native tissue architecture. The physicochemical properties of hydrogels can be modified easily, allowing them to be suitable for various biomedical applications. Moreover, adhesive properties can be imparted to hydrogels through physicochemical manipulations, making them ideal candidates for supplementing or replacing traditional sticking plaster. As a result, sticky hydrogel patches are widely used for transdermal drug …

Measuring Of Thermal Conductivity And Heat Capacity Of Different Papers And Heat-Sealing Process Of Papers With A Polymer Layer, Amenah Khalaf

Electronic Theses and Dissertations

Packaging is an important and safe way to protect our food and other things through transportation, but the use of plastic based packaging is causing issues with plastic pollution. To replace plastic packaging with a paper-based option that has a barrier coating, good heat sealing will be needed to be a drop-in replacement. While much as been studied on the heat sealing of polymer layers, little has been reported around the heat sealing of paper that has a polymeric barrier coating.

Experiments were conducted to characterize the thermal conductivity and heat capacity of paper as a function of press pressure …

Use Of Photo Isomers To Enhance The Removal Of Lignin From Woody Biomass Hydrolysate, Dipesh J. Karki

Electronic Theses and Dissertations

In this investigation we propose a novel method to enable precipitation of desired solutes using photo-isomers in the extraction solvent. This photo-switchable solvent would enable dissolution or precipitation of desired components using alternating UV or visible light to modify the solubility of the compounds of interest. Three photo-isomers namely native azobenzene, diethoxy azobenzene and diethylamino azobenzene were studied in three different organic solvents: medium chain length alcohol, ethanol and acetone. It was found that among the different combinations of solvent and photo-isomer, acetone and the 4,4’-diethoxy azobenzene solution was most efficient at precipitating dissolved lignin in response to UV light …

Application Of Crystal Engineering In Multicomponent Pharmaceutical Crystals: A Study Of Theory And Practice, Soroush Ahmadi Nasrabadi

Electronic Thesis and Dissertation Repository

Multicomponent crystallization, a prominent strategy in crystal engineering, offers the ability to modify the physicochemical properties of crystals by introducing a secondary component to their lattice structure. Such multicomponent crystals have found widespread application in the pharmaceutical industry. This thesis explores the experimental screening, characterization, application, and theoretical prediction of multicomponent crystals of Active Pharmaceutical Ingredients (APIs).

The first case study investigates a new solvate of Dasatinib which exhibits high instability at room temperature and transforms into a different polymorph upon desolvation. The crystal structure of this compound is obtained, revealing insights into its transient nature and the potential application …

Elucidating Self-Assembly Of Semiconducting Polymers In The Presence Of A Low Molecular Weight Gelator, Madhubhashini Lakdusinghe

Theses and Dissertations

Semiconducting polymers with a conjugated backbone are important for energy storage, conversion, and biomedical field applications. The self-assembly process of these polymers in solutions depends on the polymer concentration and quality of the solvent. The electrical properties of thin films obtained from the solution phase depend on the self-assembled process. Thin films of conjugated polymer gels with percolating networks of self-assembled structures display improved electrical conductivities. In this dissertation, we studied the impact of the secondary gel matrix formed by a low molecular weight gelator, on the self-assembly of conjugated polymers, the preservation of assembled structures in dried gel films …

Designing Bioinspired Materials With Tunable Structures And Properties From Natural And Synthetic Polymers, Anandavalli Varadarajan

Theses and Dissertations

Biological systems are composed of complex materials which are responsible for performing various functions, such as providing structural support, mobility, functional adaptation to the environment, damage repair, and self-healing. These complex materials display excellent mechanical properties and can rapidly adapt to external stimuli. Thus, nature inspires in terms of source materials, functions, and designs to develop new-generation structural and functional materials. Polymers (natural or synthetic) are excellent sources of developing materials to mimic the functions of soft segments in biological systems. This dissertation focuses on synthesizing and characterizing two different materials with tunable structures and properties: complexes from natural polysaccharides …

Discovering The Kinetic Behaviors Of Zeolites Of Mordenite, Ferrierite, Faujasite, Beta, Weixuan Huang

Theses - ALL

Fossil fuels have played a significant role in the development of nations. However, they have also given rise to various societal problems. In this context, Gamma-Valerolactone (GVL) emerges as a potential solution as a fuel additive and feedstock for the production of gasoline, jet fuel, and other products. GVL can undergo decarboxylation reactions facilitated by zeolite catalysts. Surprisingly, it has been observed that reactions taking place on different zeolites, despite having similar Brønsted acid site densities, exhibit distinct simulated initial rates. This research aims to compare the initial rate trends of mordenite and its poisoned derivatives with those of the …

Discovering The Kinetic Behaviors Of Zeolites Of Mordenite, Ferrierite, Faujasite, Beta, Weixuan Huang

Theses - ALL

Fossil fuels have played a significant role in the development of nations. However, they have also given rise to various societal problems. In this context, Gamma-Valerolactone (GVL) emerges as a potential solution as a fuel additive and feedstock for the production of gasoline, jet fuel, and other products. GVL can undergo decarboxylation reactions facilitated by zeolite catalysts. Surprisingly, it has been observed that reactions taking place on different zeolites, despite having similar Brønsted acid site densities, exhibit distinct simulated initial rates. This research aims to compare the initial rate trends of mordenite and its poisoned derivatives with those of the …