Engineering Commons^™

Evaluation And Enhancement Of Clean Energy Systems: Analytical, Computational And Experimental Study Of Solar And Nuclear Cycles, Nima Fathi

Mechanical Engineering ETDs

Clean (and specifically renewable) energy is steadily improving its global share. However, finite availability of fossil fuels and the growing effects of climate change make it an urgent priority to convince the industry and governments to incentivize investment in the renewable energy field and to make it more attractive by decreasing the capital cost. Until recently, uncertainties in funding limited renewable energy development, especially in the US. That limitation has been one of the barriers to progress. Another limitation of many renewable energy systems is the variability in their output, which makes them unsuitable for baseline power production. Therefore, fossil …

Ion Size Effects On The Properties Of Charge Regulating Electric Double Layers, Divya Jyoti Prakash

Nanoscience and Microsystems ETDs

The behavior of charged interfaces formed in various systems like colloidal solution, fuel cells, battery, electro-deposition, catalysis is governed by the properties of electrical double layer(EDL). Civilized model with charge regulation boundary condition determined by thermodynamic equilibrium at the interface has been used to model electrical double layer and shows that size of the solvent plays a critical role in characterizing the properties of EDL using classical density functional theory.This thesis investigates the impact of ion size in electrolyte solutions on the electrical double layer formed at the interface using a similar model. It is found that ion size greatly …

Distributed Knowledge Discovery For Diverse Data, Hossein Hamooni

Computer Science ETDs

In the era of new technologies, computer scientists deal with massive data of size hundreds of terabytes. Smart cities, social networks, health care systems, large sensor networks, etc. are constantly generating new data. It is non-trivial to extract knowledge from big datasets because traditional data mining algorithms run impractically on such big datasets. However, distributed systems have come to aid this problem while introducing new challenges in designing scalable algorithms. The transition from traditional algorithms to the ones that can be run on a distributed platform should be done carefully. Researchers should design the modern distributed algorithms based on the …

Microdischarges Utilized In Portable Gas Sensing And Their Atmospheric Contaminants, Colin H. Sillerud

Chemical and Biological Engineering ETDs

Portable applications of microdischarges such as the chemical detection, remediation of gaseous wastes, or the destruction of volatile organic compounds will mandate operation in the presence of contaminant species. This work examines the temporal evolution of microdischarge optical and ultraviolet emissions during pulsed operation by experimental methods. By varying the pulse length of a microdischarge initiated in a 4-hole silicon microcavity array operating in a 655 Torr ambient primarily composed of Ne, we were able to measure the emission growth rates for different contaminant species native to the discharge environment as a function of pulse length. It was found that …

High Precision Refractive Index Measurement Techniques Applied To The Analysis Of Neutron Damage And Effects In Caf2 Crystals, Joseph P. Morris Ph.D.

Nuclear Engineering ETDs

Neutron irradiation damages material by atomic displacements. The majority of these damage regions are microscopic and difficult to study, though they can cause a change in density and thus a change in refractive index in transparent materials. This work utilized CaF₂ crystals to track refractive index change based on neutron radiation dose. High precision refractive index measurements were performed utilizing a nested-cavity mode-locked laser where the CaF₂ crystal acted as a Fabry-Pérot Etalon (FPE). By comparing the repetition rate of the cavity and the repetition rate of the FPE, refractive index change was determined. Following several irradiation experiments, …

Comprehensive Silica Removal With Ferric Compounds For Industrial Wastewater Reuse, Ehren D. Baca

Civil Engineering ETDs

Cooling towers, integrated circuit (IC) manufacture and reverse osmosis (RO) generate copious amounts of wastewater high in colloidal and reactive silica inhibiting on-site or synergistic reuse. Silica present in cooling water can reach solubility limits via evaporation and form impervious scale on heat transfer surfaces that decreases efficiency. When water is treated by RO operating at high rejection, silica forms difficult-to-remove scale on the membrane feed side in the form of glassy patches and communities of aggregate particles, inhibiting aspirations for zero liquid discharge. Current methods for silica scale mitigation include abundant dosing with chemical antiscalents or complex operating schemes. …

Multidataset Independent Subspace Analysis: A Framework For Analysis Of Multimodal, Multi-Subject Brain Imaging Data, Rogers F. Silva

Electrical and Computer Engineering ETDs

Mental illnesses are serious disorders of the brain that have devastating effects on individuals and society. In addition to their disabling and impairing effects, mental illnesses have deep social and economical implications, accounting for an estimated loss of 12 billion working days and a care cost surge to $6 trillion a year by 2030. For diseases such as depression and anxiety, enhancing preventive programs and treatment accessibility, in combination with accurate early diagnosis and personalized treatments, are projected to result in a four-fold return on every dollar invested, a strategy that can drastically help curtail those losses. Notably, within the …

The Mathematical Theory Of Deformation Arrest In Large-Strain Dynamic Plasticity, Brendan A. Kullback

Mechanical Engineering ETDs

Ductile structural components subjected to explosive loadings exhibit a large range of behaviors. The response of beams, walls, and blast doors is estimated using two methods. The engineering level approaches are highly simplified and neglect much of the relevant physics while the use of finite element or shock-code simulation is expensive and not suited to rapid problem solving and parameter studies. In this dissertation, a medium fidelity reduced order modeling approach has been derived to capture the most relevant physics governing rupture of ductile bodies dynamically deforming in tension.

Solution of the inertially stretching jet is used to reveal the …

Synchronous Generation And Coherent Control Of Extreme Wavelength Radiation And Ultrafast Spectroscopy, Aram Gragossian

Optical Science and Engineering ETDs

Recent progress in ultrafast laser science has made it possible to synthesize and control complex electromagnetic waveforms down to sub-femtosecond timescales. These tailored ultrashort laser pulses can generate coherent bursts of electromagnetic radiation in the extreme ultraviolet (XUV) and terahertz spectral regions with durations reaching the attosecond regime in the XUV region. This is accomplished by coherently controlling electronic motion in gas plasma targets. With these novel radiation sources, ultrafast time-resolved spectroscopy can be performed on a large variety of materials. Knowledge of the spectral phase of an ultrashort pulse is crucial for many applications. There are a variety of …

Scatterometry Of 50 Nm Half Pitch Features, Ruichao Zhu

Optical Science and Engineering ETDs

Metrology technologies are an essential adjunct to Integrated Circuit (I.C.) Semiconductor manufacturing. Scatterometry, an optical metrology, was chosen to measure 50 nm half pitch feature structures. A bread-board scatterometry system has been assembled to provide a non-contact, non-destructive, accurate and flexible measurement. A real-time, on-line scatterometry system has also been demonstrated and proven to provide a high throughput measurement.

Three different types of samples have been measured using the scatterometry setup. The wire-grid polarizer (WGP) sample has been made by Jet and Flash Nanoimprint Lithography with ~100 nm pitch and ~50 nm wide ~200 nm tall Al gratings on fused …

Development Of In Vivo Systems For Detecting And Studying Ribosome Inhibition By Small Molecules, Shijie Huang

Chemistry and Chemical Biology ETDs

The ribosome is the quintessential antibacterial drug target, with many structurally and mechanistically distinct classes of antibacterial agents acting by inhibiting ribosome function. Detecting and quantifying ribosome inhibition by small molecules and investigating their binding modes and mechanisms of action are critical to antibacterial drug discovery and development efforts. To develop a ribosome inhibition assay that is operationally simple, yet provides direct information on the drug target and the mechanism of action, we have developed engineered E. coli strains harboring an orthogonal ribosome controlled green fluorescent protein reporter that produce fluorescent signal when the O-ribosome is inhibited. As a proof …

Searching Neuroimaging Biomarkers In Mental Disorders With Graph And Multimodal Fusion Analysis Of Functional Connectivity, Hao He

Electrical and Computer Engineering ETDs

Mental disorders such as schizophrenia (SZ), bipolar (BD), and major depression disorders (MDD) can cause severe symptoms and life disruption. They share some symptoms, which can pose a major clinical challenge to their differentiation. Objective biomarkers based on neuroimaging may help to improve diagnostic accuracy and facilitate optimal treatment for patients. Over the last decades, non-invasive in-vivo neuroimaging techniques such as magnetic resonance imaging (MRI) have been increasingly applied to measure structure and function in human brains. With functional MRI (fMRI) or structural MRI (sMRI), studies have identified neurophysiological deficits in patients’ brain from different perspective. Functional connectivity (FC) analysis …

Experimental Investigation Of Plasma Dynamics In Jets And Bubbles Using A Compact Coaxial Plasma Gun In A Background Magnetized Plasma, Yue Zhang

Electrical and Computer Engineering ETDs

Numerous solar and astrophysical observations of jet- and bubble-like plasma structures exhibit morphological similarities, suggesting that there may be common plasma physics at work in the formation and evolution processes of these structures at different system scales. The ideal magnetohydrodynamics (MHD) provide the necessary theoretical basis for employing laboratory experiments to investigate key physical processes in nonlinear astrophysical and solar systems, especially when magnetic fields are present.

A coaxial magnetized plasma gun has been designed, installed, and operated in the HelCat linear device at the University of New Mexico. In Region I, a current-driven plasma jet is formed. The plasma …

High Power Optically Pumped Semiconductor Lasers For Sodium Guidestar Applications, Shawn W. Hackett

Optical Science and Engineering ETDs

Optically pumped semiconductor lasers (OPSLs) are shown to provide a much more compact and less expensive source for illumination of the sodium layer of the mesosphere for use as a sodium laser guidestar via single and two photon excitation schemes. This represents a revolution in laser guidestar technology as the cost, size, and power requirements for a laser guidestar system are shown to have been decreased by an order of magnitude with guidestar performance shown to be similar to previous sources. Sodium laser guidestar sources for broadband simultaneous illumination of multiple lines are developed and simulated. Simulations are then compared …

Molecular Tetrapods For Optoelectronic Applications, Jianzhong Yang

Chemistry and Chemical Biology ETDs

In this dissertation, several molecular tetrapods were synthesized for optoelectronic applications. In the first two sections, two tetrapodal breakwater-like small molecules: SO and SFBTD were synthesized and characterized. Absorption, X-ray scattering and differential scanning calorimetry experiments indicate crystalline nature of these compounds but slow crystallization kinetics. Solar cells employing SO or SFBTD and phenyl-C₆₁-butyric acid methyl ester (PCBM) were fabricated and evaluated. Relatively low performance was obtained mainly due to the lack of appropriate phase separation, which was caused by molecularly mixed blends with PCBM. The molecularly mixed blends is the result of slow crystallization …

Transistorized Circuits For Telemetry, Dominick Misciascio Jr.

Physics & Astronomy ETDs

This thesis is concerned with the telemetry of small DC signals from photomultiplier tubes. The circuitry must have a high input impedance so as not to load down the photomultiplier tube and a low output impedance which is capable of controlling the current through a small incandescent bulb. This bulb is used to illuminate a photoresistor. The output of the circuit consists of a variation of the resistance of the photoresistor. This variable resistance is conventionally converted into a variable audio frequency which is transmitted to the receiving station on a radio-frequency carrier. The output resistance must be independent of …