Engineering Commons^™

Radiation-Balanced Fiber Lasers And Amplifiers, Esmaeil Mobini Souchelmaei Mr

Optical Science and Engineering ETDs

Over the past decades, high-power fiber lasers and amplifiers have been extensively under research to achieve higher output powers. However, temperature rise in the core of fiber lasers and amplifiers has been a big issue in power-scaling. Radiation-balancing is a viable technique introduced for effective heat mitigation in lasers and amplifiers by S. Bowman in 1995. Radiation-balancing relies on solid-state laser cooling as a self-cooling mechanism to mitigate the generated heat in lasers and amplifiers. To implement the mentioned idea in fiber lasers and amplifiers, a set of issues should be scrutinized; (i) the amenability of silica glass (as the …

A Statistical Analysis Of The Unm Facets Design Identity & Beliefs Survey Data, Clarissa A. Sorensen-Unruh

Mathematics & Statistics ETDs

The NSF-funded FACETS (Formation of Accomplished Chemical Engineers for Transforming Society, NSF Award 1623105) grant aims to transform the undergraduate engineering experience in the Department of Chemical and Biological Engineering at the University of New Mexico to address attrition within engineering majors, especially among underserved populations (Brainard & Carlin, 1998). The UNM FACETS Design Identity & Beliefs survey, an assessment tool used as part of the research of the grant, generated the dataset used in this study. I performed several different statistical analyses on the dataset, including confirmatory factor analysis (CFA), principal component analysis (PCA), and cluster analysis. The …

Target Control Of Networked Systems, Isaac S. Klickstein

Mechanical Engineering ETDs

The control of complex networks is an emerging field yet it has already garnered interest from across the scientific disciplines, from robotics to sociology. It has quickly been noticed that many of the classical techniques from controls engineering, while applicable, are not as illuminating as they were for single systems of relatively small dimension. Instead, properties borrowed from graph theory provide equivalent but more practical conditions to guarantee controllability, reachability, observability, and other typical properties of interest to the controls engineer when dealing with large networked systems. This manuscript covers three topics investigated in detail by the author: (i) the …

Applications Of The Negatively-Charged Silicon Vacancy Color Center In Diamond, Forrest A. Hubert

Optical Science and Engineering ETDs

The spatial resolution and fluorescence signal amplitude in stimulated emission depletion (STED) microscopy is limited by the photostability of available fluorophores. Here, we show that negatively-charged silicon vacancy (SiV) centers in diamond are promising fluorophores for STED microscopy, owing to their photostable, near-infrared emission and favorable photophysical properties. A home-built pulsed STED microscope was used to image shallow implanted SiV centers in bulk diamond at room temperature. We performed STED microscopy on isolated SiV centers and observed a lateral full-width-at-half-maximum spot size of 89 ± 2 nm, limited by the low available STED laser pulse energy (0.4 nJ). For a …

Nonlinear Least Squares 3-D Geolocation Solutions Using Time Differences Of Arrival, Michael V. Bredemann

Mathematics & Statistics ETDs

This thesis uses a geometric approach to derive and solve nonlinear least squares minimization problems to geolocate a signal source in three dimensions using time differences of arrival at multiple sensor locations. There is no restriction on the maximum number of sensors used. Residual errors reach the numerical limits of machine precision. Symmetric sensor orientations are found that prevent closed form solutions of source locations lying within the null space. Maximum uncertainties in relative sensor positions and time difference of arrivals, required to locate a source within a maximum specified error, are found from these results. Examples illustrate potential requirements …

Mid-Ir Optical Refrigeration And Radiation Balanced Lasers, Saeid Rostami

Optical Science and Engineering ETDs

This dissertation reports recent advances in mid-infrared (mid-IR) optical refrigeration and Radiation Balanced Lasers (RBLs). The first demonstration of optical refrigeration in Ho:YLF and Tm:YLF crystals as promising mid-IR laser cooling candidates is reported. Room temperature laser cooling efficiency of Tm- and Ho-doped crystals at different excitation polarization is measured and their external quantum efficiency and background absorption are extracted. Complete characterization of laser cooling samples is obtained via performing detailed low-temperature spectroscopic analysis, and their minimum achievable temperature as well as conditions to achieve laser cooling efficiency enhancement in mid-IR are investigated. By developing a Thulium-doped fiber amplifier, seeded …

Coulombic And Non-Coulombic Effects Of Single And Overlapping Electric Double Layers With Surface Charge Regulation, Raviteja Vangara

Chemical and Biological Engineering ETDs

The physical origin of charged interfaces involving electrolyte solutions is in the thermodynamic equilibrium between the surface reactive groups and certain dissolved ionic species in the bulk. This equilibrium is very strongly dependent on the precise local density of these species, also known as potential determining ions in the solution. The latter, however, is determined by the overall solution structure, which is dominated by the large number of solvent molecules relative to all solutes. Hence, the solvent contribution to the molecular structure is a crucial factor that determines the properties of electric double layers. Models that explicitly account for the …

Integrated Chirped-Grating Spectrometer-On-A-Chip, Shima Nezhadbadeh

Optical Science and Engineering ETDs

In this dissertation we demonstrate a new structure based on waveguide coupling atop a silicon wafer using a chirped grating to provide the dispersion that leads to a high-resolution, compact, fully integrable and CMOS-compatible spectrometer. Light is both analyzed and detected in a single, completely monolithic component which enables realizing a high-resolution portable spectrometer with an extremely compact footprint. The structure is comprised of a SiO₂/Si₃N₄/SiO₂ waveguide on top of a silicon wafer. Grating regions are fabricated on the top cladding of the waveguide. The input light is incident on a chirped grating …

Near-Field And Far-Field Microscopic And Spectroscopic Characterizations Of Coupled Plasmonic, Excitonic And Polymeric Materials, Chih-Feng Wang

Optical Science and Engineering ETDs

The properties of localized surface plasmons (LSP) have been broadly utilized for chemical sensing, surface enhanced Raman spectroscopy, biomedical imaging and photothermal treatments. By exploiting well-established plasmonic effects, the spectroscopic investigation of intriguing quantum phenomena, such as excitonic interband and intersubband (ISB) transitions in semiconductor heterostructures, was examined and extended in both far- and near-field optical measurements. For far-field characterization, we used colloidal plasmonic Au nanorods (AuNRs) to increase the quantum efficiency of InGaAs/GaAs single quantum well. By analyzing the temperature-dependent photoluminescence enhancement as a function of GaAs capping layer thickness, we attributed the mechanism of the LSP enhancement to …

Experimental Testing Of A 3d-Printed Metamaterial Slow Wave Structure For High Power Microwave Generation, Antonio B. De Alleluia

Electrical and Computer Engineering ETDs

A metamaterial (MTM) high power microwave (HPM) vacuum electron device (VED) was developed using 3D printing technology. The specific geometric pattern of the source can produce both negative permittivity and permeability to interact with a relativistic electron beam. The electron beam is generated using a pulsed electron accelerator with a maximum energy of 700 keV and lasting approximately 16 ns. The design of this novel VED consists of a circular waveguide loaded with complementary split-ring resonators in a linear periodic arrangement in which the relativistic beam travels guided by a magnetic field. The electrons interact with the MTM producing electromagnetic …

Organic/Inorganic Interfacial Interactions Affecting Metal Reactivity: Water Treatment And Sensor Applications, Mohamed Nabil Shaikh

Civil Engineering ETDs

The aim of this dissertation was to investigate the interactions occurring at the organic – inorganic interface between solid media and aqueous contaminants for water treatment and sensor applications. The gaps in current literature on these interfacial organic-inorganic interactions must be bridged in order to develop advanced water treatment and monitoring technologies for improving water quality and thus, restore and protect the contaminated water resources. As a part of this dissertation, manganese oxides-based composites and electrospun polymer mats were developed and investigated for gaining mechanistic insights of organic (bisphenol A and acetaminophen) and inorganic (uranium) contaminants removal, respectively. These reactions …

Tailored Frequency Comb Structures And Their Sensing Applications, James Hendrie

Optical Science and Engineering ETDs

The focus of this dissertation is the development and investigation of nested cavity mode-locked lasers and their resultant tailored frequency combs. A nested cavity is made up of two cavities, known as parents. One parent is a larger, active, 100MHz Ti:Saph oscillator and the other is a smaller, passive, 7GHz Fabry-Perot Etalon (FPE). Unlike standard frequency combs that are continuous, a tailored comb’s teeth are distributed in equally spaced groups where the center of each group corresponds to the resonance of the FPE and the side bands are determined by the resonances of the Ti:Saph. This unique coupling of the …

Computational Investigation Of The Interactions Between Bioactive Compounds And Biological Assemblies, Tye D. Martin

Biomedical Engineering ETDs

Small, biologically active molecules with unique properties and applications are potential solutions to a wide range of threats to global health including infectious agents and neurodegenerative disease. Experimental studies on a class of oligomeric p-phenylene ethynylenes (OPEs) have shown potential both as bioactive antimicrobials and fluorescent sensing agents for tracking amyloid-β (Aβ) aggregates found in Alzheimer’s Disease (AD). A second type of small molecule with potential applications in AD therapy, curcumin, has been found to interfere with Aβ fibril growth. Curcumin also attenuates Aβ-membrane interactions and Aβ toxicity. Our goal has been to use computational techniques to better understand the …

Characterization Of Single- And Multi-Phase Shock-Accelerated Flows, Patrick John Wayne

Mechanical Engineering ETDs

Experiments conducted in the Shock Tube Facility at the University of New Mexico are focused on characterization of shock-accelerated flows. Single-phase (gaseous) initial conditions consist of a heavy gas column of sulfur hexafluoride seeded with approximately 11% acetone gas by mass. Visualization of the image plane for gaseous initial conditions is accomplished via planar laser-induced fluorescence (PLIF) with a high-powered Nd:YAG ultraviolet laser and an Apogee Alta U-42 monochrome CCD camera, with a quantum efficiency > 90%. Multi-phase (gas-solid) initial conditions consist of glass micro-beads deposited on small 1-cm diameter discs of specific surface chemistry, mounted flush with the bottom wall …

Symmetry And Dopant Diffusion In Inverted Nanopyramid Arrays For Thin Crystalline Silicon Solar Cells, Seok Jun Han

Chemical and Biological Engineering ETDs

In this dissertation, we enhance the efficiency of thin flexible monocrystalline silicon solar cells by breaking symmetry in light trapping nanostructures and improving homogeneity in dopant concentration profile. These thin cells are potentially less expensive than conventional thick silicon cells by using less silicon material and making the cells more convenient to be handled when supported on polymer films. Moreover, these cells are widely applicable due to their flexibility and lightweight. However, for high efficiencies, these cells require effective light trapping and charge collection. We achieve these in cells based on 14-mm-thick free-standing silicon films with light-trapping arrays of nanopyramidal …

Multifunctional Properties Of Gan Nws Applied To Nanometrology, Nanophotonics, And Scanning Probe Microscopy/Lithography, Mahmoud Behzadirad

Optical Science and Engineering ETDs

GaN nanowires are promising for optical and optoelectronic applications because of their waveguiding properties and large optical bandgap. Recent researches have shown superior mechanical properties of GaN nanowires which promises their use in new research areas e.g. nanometrology. In this work, we develop a scalable two-step top-down approach using interferometric lithography as well a bottom-up growth of NWs using MOCVD, to manufacture highly-ordered arrays of nanowires with atomic surface roughness and desired aspect-ratios to be used in nanophotonics and atomic precision metrology and lithography. Using this method, uniform nanowire arrays were achieved over large-areas (~1 mm²) with aspect-ratio …

Fluid Transport In Porous Media For Engineering Applications, Eric M. Benner

Chemical and Biological Engineering ETDs

This doctoral dissertation presents three topics in modeling fluid transport through porous media used in engineering applications. The results provide insights into the design of fuel cell components, catalyst and drug delivery particles, and aluminum- based materials. Analytical and computational methods are utilized for the modeling of the systems of interest. Theoretical analysis of capillary-driven transport in porous media show that both geometric and evaporation effects significantly change the time dependent behavior of liquid imbibition and give a steady state flux into the medium. The evaporation–capillary number is significant in determining the time-dependent behavior of capillary flows in porous media. …

Generation And Use Of Femtosecond, Gigawatt, Near Infrared Laser Pulses From An Amplified, Mode-Locked, Ti:Sapphire Laser, David Anthony Valdés

Optical Science and Engineering ETDs

This work modeled the early to middle successes achieved in the field of ultrafast, high peak power optics, beginning with the work of Nobel Prize winners Donna Strickland and Gérard Mourou in 1985. In our work, 100 fs light pulses of around 800 nm were generated by a Ti:Sapphire oscillator, then amplified to approximately 30 GW peak power using a chirped pulse amplification system that included regenerative and multi-pass amplifiers. As a verification of our pulses having high peak powers and ultrashort durations, they were then used to strike water, glass, and a Kerr Cell. Supercontinuum generation was observed as …

Modeling Multiphase Flow And Substrate Deformation In Nanoimprint Manufacturing Systems, Andrew Cochrane

Nanoscience and Microsystems ETDs

Nanopatterns found in nature demonstrate that macroscopic properties of a surface are tied to its nano-scale structure. Tailoring the nanostructure allows those macroscopic surface properties to be engineered. However, a capability-gap in manufacturing technology inhibits mass-production of nanotechnologies based on simple, nanometer-scale surface patterns. This gap represents an opportunity for research and development of nanoimprint lithography (NIL) processes. NIL is a process for replicating patterns by imprinting a fluid layer with a solid, nano-patterned template, after which ultraviolet cure solidifies the fluid resulting in a nano-patterned surface. Although NIL has been demonstrated to replicate pattern features as small as 4 …

An Experimental And Numerical Investigation Of Flow Accelerated Flibe Corrosion, David B. Weitzel

Nuclear Engineering ETDs

Renewed interest in molten salt reactor technology has brought to light the need for a better understanding of FLiBe corrosion. To this end a flowing FLiBe corrosion test loop was designed to test the flow effects of FLiBe corrosion. The loop consists of a pump, melt tank, and stainless-steel tubing assembly that heats the molten salt to high temperatures and circulates it over test specimens. The experiment has been constructed and has completed initial shakedown testing.

To support the flowing FLiBe experiment, a numerical corrosion model that couples FLiBe electrochemistry, solid metal diffusion, and mass transport was implemented. The model …

Transverse Anderson Localization In Optical Fibers: High-Quality Wave Transmission And Novel Lasing Applications, Behnam Abaie

Optical Science and Engineering ETDs

In this dissertation, transverse Anderson localization (TAL) of light mediated by disordered optical fibers is exploited for high-quality optical wave transmission and novel random lasing applications. En route, we first establish a powerful numerical platform for detailed investigation of TAL optical fibers (TALOF). Our approach is based on a modal perspective as opposed to beam propagation method (BPM) which was primarily used in the previous studies of TAL in disordered optical fibers. The versatile numerical tools developed in our simulations result in a potent methodology for simulation of TALOFs; the result is a fast and effective algorithm which can be …

Criticality Assessments For Improving Algorithmic Robustness, Thomas B. Jones

Computer Science ETDs

Though computational models typically assume all program steps execute flawlessly, that does not imply all steps are equally important if a failure should occur. In the "Constrained Reliability Allocation" problem, sufficient resources are guaranteed for operations that prompt eventual program termination on failure, but those operations that only cause output errors are given a limited budget of some vital resource, insufficient to ensure correct operation for each of them.

In this dissertation, I present a novel representation of failures based on a combination of their timing and location combined with criticality assessments---a method used to predict the behavior of systems …

High-Performance Testbed For Vision-Aided Autonomous Navigation For Quadrotor Uavs In Cluttered Environments, Shakeeb Ahmad

Electrical and Computer Engineering ETDs

This thesis presents the development of an aerial robotic testbed based on Robot Operating System (ROS). The purpose of this high-performance testbed is to develop a system capable of performing robust navigation tasks using vision tools such as a stereo camera. While ensuring the computation of robot odometery, the system is also capable of sensing the environment using the same stereo camera. Hence, all the navigation tasks are performed using a stereo camera and an inertial measurement unit (IMU) as the main sensor suite. ROS is used as a framework for software integration due to its capabilities to provide efficient …

Novel Compact Narrow-Linewidth Mid-Infrared Lasers For Sensing Applications, Behsan Behzadi

Optical Science and Engineering ETDs

The mid-infrared (2-14 μm) spectral region contains the strong absorption lines of many important molecular species, which make this region crucial for several well-know applications such as spectroscopy, chemical and biochemical sensing, security, and industrial monitoring. To fully exploit this region through absorption spectroscopic techniques, compact and low-cost narrow-linewidth (NLW) mid-infrared (MIR) laser sources are of primary importance.

This thesis is focused on three novel compact NLW MIR lasers: demonstration and characterization of a new glass-based spherical microlaser, investigation of the performance of a novel fiber laser, and the design of a monolithic laser on a silicon chip. Starting with …

From Flasks To Applications: Design And Optimization Of Giant Quantum Dots Using Traditional And Automated Synthetic Methods, Christina J. Hanson

Nanoscience and Microsystems ETDs

Semiconducting nanocrystals, also known as quantum dots (QDs), that emit light with near-unity quantum yield and are extremely photostable are attractive options as down-conversion and direct electricity-to-light materials for a variety of applications including solid-state lighting, display technologies, bio-imaging and optical tracking. Standard QDs with a core/thin shell structure display fluorescence intermittency (blinking) and photobleaching when exposed to prolonged room temperature excitation for single dot measurements, as well as significant reabsorption and energy transfer when densely packed into polymers or at high solution concentrations.

We have developed thick shell “giant” QDs (gQDs), ultra-stable photon sources both at the ensemble and …

An Exploration Of The Optical Detection Of Ionizing Radiation Utilizing Modern Optics Technology, Sean D. Fournier, Adam Hecht, Cassiano De Oliveira, Jeffrey B. Martin, Richard K. Harrison, Charles Potter

Nuclear Engineering ETDs

Modern ultraviolet (UV) cameras, when combined with UV-transmitting lenses/filter arrangements, can be used to detect radiation dose in air. Ionizing radiation excites nitrogen molecules in ambient air, the resulting decay includes weak emission of ultraviolet photons. Previous work has proven this phenomenon is detectable using highly-sensitive electronically cooled cameras traditionally used in astronomy for low-background imaging. While the ability to detect the presence of radiation (i.e. qualitative measurement) has been demonstrated at Sandia National Laboratories, there are several challenges in correlating images to known dose-fields (quantitative measurement). These challenges include: a low signal to background ratio, interferences due to electronic …

Hydrogeochemical Investigation Of Recharge Pathways To Intermediate And Regional Groundwater In Cañon De Valle And Technical Area 16, Los Alamos National Laboratory, Brendan W. Brady

Civil Engineering ETDs

In aquifers consisting of fractured or porous igneous rocks, as well as conglomerate and sandstone products of volcanic formations, silicate minerals actively dissolve and precipitate (Eby, 2004; Eriksson, 1985; Drever, 1982). Dissolution of hydrated volcanic glass is also known to influence the character of groundwater to which it is exposed (White et al., 1980). Hydrochemical evolution, within saturated zones of volcanic formations, is modeled here as a means to resolve the sources feeding a perched groundwater zone. By observation of solute mass balances in groundwater, together with rock chemistry, this study characterizes the chemical weathering processes active along recharge pathways …

Investigating Scalable Manufacturing Of High-Conductivity Wires And Coatings From Ultra-Long Carbon Nanotubes, Pouria Khanbolouki

Mechanical Engineering ETDs

Carbon nanotubes (CNTs) are a promising candidate for next generation of electrical wirings and electromagnetic interference (EMI) shielding materials due to their exceptional mechanical and electrical properties. Wires and coatings from ultralong nanotubes that are highly crystalline, well-aligned and densely packed can achieve this goal. High-performance CNT conductors will be relatively lightweight and resistant to harsh conditions and therefore can potentially replace current conductors in many industries including aerospace, automotive, gas and oil.

This thesis investigates a new manufacturing approach, based on conventional solution coating and wire drawing methods, to fabricate high conductivity wires and coatings from ultra-long carbon nanotubes. …

Improving Hpc Communication Library Performance On Modern Architectures, Matthew G. F. Dosanjh

Computer Science ETDs

As high-performance computing (HPC) systems advance towards exascale (10^18 operations per second), they must leverage increasing levels of parallelism to achieve their performance goals. In addition to increased parallelism, machines of that scale will have strict power limitations placed on them. One direction currently being explored to alleviate those issues are many-core processors such as Intel’s Xeon Phi line. Many-core processors sacrifice clock speed and core complexity, such as out of order pipelining, to increase the number of cores on a die. While this increases floating point throughput, it can reduce the performance of serialized, synchronized, and latency sensitive code …

Nanowire-Based Light-Emitting Diodes: A New Path Towards High-Speed Visible Light Communication, Mohsen Nami

Physics & Astronomy ETDs

Nano-scale optoelectronic devices have gained significant attention in recent years. Among these devices are semiconductor nanowires, whose dimeters range from 100 to 200 nm. Semiconductor nanowires can be utilized in many different applications including light-emitting diodes and laser diodes. Higher surface to volume ratio makes nanowire-based structures potential candidates for the next generation of photodetectors, sensors, and solar cells. Core-shell light-emitting diodes based on selective-area growth of gallium nitride (GaN) nanowires provide a wide range of advantages. Among these advantages are access to non-polar m-plane sidewalls, higher active region area compared to conventional planar structures, and reduction of threading …