Engineering Commons^™

Coulombic And Non-Coulombic Effects Of Single And Overlapping Electric Double Layers With Surface Charge Regulation, Raviteja Vangara

Chemical and Biological Engineering ETDs

The physical origin of charged interfaces involving electrolyte solutions is in the thermodynamic equilibrium between the surface reactive groups and certain dissolved ionic species in the bulk. This equilibrium is very strongly dependent on the precise local density of these species, also known as potential determining ions in the solution. The latter, however, is determined by the overall solution structure, which is dominated by the large number of solvent molecules relative to all solutes. Hence, the solvent contribution to the molecular structure is a crucial factor that determines the properties of electric double layers. Models that explicitly account for the …

Integrated Chirped-Grating Spectrometer-On-A-Chip, Shima Nezhadbadeh

Optical Science and Engineering ETDs

In this dissertation we demonstrate a new structure based on waveguide coupling atop a silicon wafer using a chirped grating to provide the dispersion that leads to a high-resolution, compact, fully integrable and CMOS-compatible spectrometer. Light is both analyzed and detected in a single, completely monolithic component which enables realizing a high-resolution portable spectrometer with an extremely compact footprint. The structure is comprised of a SiO₂/Si₃N₄/SiO₂ waveguide on top of a silicon wafer. Grating regions are fabricated on the top cladding of the waveguide. The input light is incident on a chirped grating …

Near-Field And Far-Field Microscopic And Spectroscopic Characterizations Of Coupled Plasmonic, Excitonic And Polymeric Materials, Chih-Feng Wang

Optical Science and Engineering ETDs

The properties of localized surface plasmons (LSP) have been broadly utilized for chemical sensing, surface enhanced Raman spectroscopy, biomedical imaging and photothermal treatments. By exploiting well-established plasmonic effects, the spectroscopic investigation of intriguing quantum phenomena, such as excitonic interband and intersubband (ISB) transitions in semiconductor heterostructures, was examined and extended in both far- and near-field optical measurements. For far-field characterization, we used colloidal plasmonic Au nanorods (AuNRs) to increase the quantum efficiency of InGaAs/GaAs single quantum well. By analyzing the temperature-dependent photoluminescence enhancement as a function of GaAs capping layer thickness, we attributed the mechanism of the LSP enhancement to …

Experimental Testing Of A 3d-Printed Metamaterial Slow Wave Structure For High Power Microwave Generation, Antonio B. De Alleluia

Electrical and Computer Engineering ETDs

A metamaterial (MTM) high power microwave (HPM) vacuum electron device (VED) was developed using 3D printing technology. The specific geometric pattern of the source can produce both negative permittivity and permeability to interact with a relativistic electron beam. The electron beam is generated using a pulsed electron accelerator with a maximum energy of 700 keV and lasting approximately 16 ns. The design of this novel VED consists of a circular waveguide loaded with complementary split-ring resonators in a linear periodic arrangement in which the relativistic beam travels guided by a magnetic field. The electrons interact with the MTM producing electromagnetic …

Organic/Inorganic Interfacial Interactions Affecting Metal Reactivity: Water Treatment And Sensor Applications, Mohamed Nabil Shaikh

Civil Engineering ETDs

The aim of this dissertation was to investigate the interactions occurring at the organic – inorganic interface between solid media and aqueous contaminants for water treatment and sensor applications. The gaps in current literature on these interfacial organic-inorganic interactions must be bridged in order to develop advanced water treatment and monitoring technologies for improving water quality and thus, restore and protect the contaminated water resources. As a part of this dissertation, manganese oxides-based composites and electrospun polymer mats were developed and investigated for gaining mechanistic insights of organic (bisphenol A and acetaminophen) and inorganic (uranium) contaminants removal, respectively. These reactions …

Tailored Frequency Comb Structures And Their Sensing Applications, James Hendrie

Optical Science and Engineering ETDs

The focus of this dissertation is the development and investigation of nested cavity mode-locked lasers and their resultant tailored frequency combs. A nested cavity is made up of two cavities, known as parents. One parent is a larger, active, 100MHz Ti:Saph oscillator and the other is a smaller, passive, 7GHz Fabry-Perot Etalon (FPE). Unlike standard frequency combs that are continuous, a tailored comb’s teeth are distributed in equally spaced groups where the center of each group corresponds to the resonance of the FPE and the side bands are determined by the resonances of the Ti:Saph. This unique coupling of the …

Computational Investigation Of The Interactions Between Bioactive Compounds And Biological Assemblies, Tye D. Martin

Biomedical Engineering ETDs

Small, biologically active molecules with unique properties and applications are potential solutions to a wide range of threats to global health including infectious agents and neurodegenerative disease. Experimental studies on a class of oligomeric p-phenylene ethynylenes (OPEs) have shown potential both as bioactive antimicrobials and fluorescent sensing agents for tracking amyloid-β (Aβ) aggregates found in Alzheimer’s Disease (AD). A second type of small molecule with potential applications in AD therapy, curcumin, has been found to interfere with Aβ fibril growth. Curcumin also attenuates Aβ-membrane interactions and Aβ toxicity. Our goal has been to use computational techniques to better understand the …

Characterization Of Single- And Multi-Phase Shock-Accelerated Flows, Patrick John Wayne

Mechanical Engineering ETDs

Experiments conducted in the Shock Tube Facility at the University of New Mexico are focused on characterization of shock-accelerated flows. Single-phase (gaseous) initial conditions consist of a heavy gas column of sulfur hexafluoride seeded with approximately 11% acetone gas by mass. Visualization of the image plane for gaseous initial conditions is accomplished via planar laser-induced fluorescence (PLIF) with a high-powered Nd:YAG ultraviolet laser and an Apogee Alta U-42 monochrome CCD camera, with a quantum efficiency > 90%. Multi-phase (gas-solid) initial conditions consist of glass micro-beads deposited on small 1-cm diameter discs of specific surface chemistry, mounted flush with the bottom wall …

Symmetry And Dopant Diffusion In Inverted Nanopyramid Arrays For Thin Crystalline Silicon Solar Cells, Seok Jun Han

Chemical and Biological Engineering ETDs

In this dissertation, we enhance the efficiency of thin flexible monocrystalline silicon solar cells by breaking symmetry in light trapping nanostructures and improving homogeneity in dopant concentration profile. These thin cells are potentially less expensive than conventional thick silicon cells by using less silicon material and making the cells more convenient to be handled when supported on polymer films. Moreover, these cells are widely applicable due to their flexibility and lightweight. However, for high efficiencies, these cells require effective light trapping and charge collection. We achieve these in cells based on 14-mm-thick free-standing silicon films with light-trapping arrays of nanopyramidal …

Multifunctional Properties Of Gan Nws Applied To Nanometrology, Nanophotonics, And Scanning Probe Microscopy/Lithography, Mahmoud Behzadirad

Optical Science and Engineering ETDs

GaN nanowires are promising for optical and optoelectronic applications because of their waveguiding properties and large optical bandgap. Recent researches have shown superior mechanical properties of GaN nanowires which promises their use in new research areas e.g. nanometrology. In this work, we develop a scalable two-step top-down approach using interferometric lithography as well a bottom-up growth of NWs using MOCVD, to manufacture highly-ordered arrays of nanowires with atomic surface roughness and desired aspect-ratios to be used in nanophotonics and atomic precision metrology and lithography. Using this method, uniform nanowire arrays were achieved over large-areas (~1 mm²) with aspect-ratio …

Fluid Transport In Porous Media For Engineering Applications, Eric M. Benner

Chemical and Biological Engineering ETDs

This doctoral dissertation presents three topics in modeling fluid transport through porous media used in engineering applications. The results provide insights into the design of fuel cell components, catalyst and drug delivery particles, and aluminum- based materials. Analytical and computational methods are utilized for the modeling of the systems of interest. Theoretical analysis of capillary-driven transport in porous media show that both geometric and evaporation effects significantly change the time dependent behavior of liquid imbibition and give a steady state flux into the medium. The evaporation–capillary number is significant in determining the time-dependent behavior of capillary flows in porous media. …

Generation And Use Of Femtosecond, Gigawatt, Near Infrared Laser Pulses From An Amplified, Mode-Locked, Ti:Sapphire Laser, David Anthony Valdés

Optical Science and Engineering ETDs

This work modeled the early to middle successes achieved in the field of ultrafast, high peak power optics, beginning with the work of Nobel Prize winners Donna Strickland and Gérard Mourou in 1985. In our work, 100 fs light pulses of around 800 nm were generated by a Ti:Sapphire oscillator, then amplified to approximately 30 GW peak power using a chirped pulse amplification system that included regenerative and multi-pass amplifiers. As a verification of our pulses having high peak powers and ultrashort durations, they were then used to strike water, glass, and a Kerr Cell. Supercontinuum generation was observed as …

Modeling Multiphase Flow And Substrate Deformation In Nanoimprint Manufacturing Systems, Andrew Cochrane

Nanoscience and Microsystems ETDs

Nanopatterns found in nature demonstrate that macroscopic properties of a surface are tied to its nano-scale structure. Tailoring the nanostructure allows those macroscopic surface properties to be engineered. However, a capability-gap in manufacturing technology inhibits mass-production of nanotechnologies based on simple, nanometer-scale surface patterns. This gap represents an opportunity for research and development of nanoimprint lithography (NIL) processes. NIL is a process for replicating patterns by imprinting a fluid layer with a solid, nano-patterned template, after which ultraviolet cure solidifies the fluid resulting in a nano-patterned surface. Although NIL has been demonstrated to replicate pattern features as small as 4 …

An Experimental And Numerical Investigation Of Flow Accelerated Flibe Corrosion, David B. Weitzel

Nuclear Engineering ETDs

Renewed interest in molten salt reactor technology has brought to light the need for a better understanding of FLiBe corrosion. To this end a flowing FLiBe corrosion test loop was designed to test the flow effects of FLiBe corrosion. The loop consists of a pump, melt tank, and stainless-steel tubing assembly that heats the molten salt to high temperatures and circulates it over test specimens. The experiment has been constructed and has completed initial shakedown testing.

To support the flowing FLiBe experiment, a numerical corrosion model that couples FLiBe electrochemistry, solid metal diffusion, and mass transport was implemented. The model …