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Doctoral Dissertations

2010

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Articles 91 - 93 of 93

Full-Text Articles in Engineering

Experimental And Computational Investigations Of Hydrogen Safety, Dispersion And Combustion For Transportation Applications, Shravan K. Vudumu Jan 2010

Experimental And Computational Investigations Of Hydrogen Safety, Dispersion And Combustion For Transportation Applications, Shravan K. Vudumu

Doctoral Dissertations

"Hydrogen is an energy carrier that can be produced from a variety of sources, offering one of the viable solutions to the increasing demands for clean and sustainable energy. Compared to the conventional fuels, hydrogen has distinct properties that need to be properly accounted for during its safer storage and delivery as well as more efficient and cleaner utilization. The broader objective of this study is to contribute to the scientific knowledge necessary to overcome key technical barriers to the widespread implementation of hydrogen in transportation applications. Specifically, lower flammability limit of hydrogen is first measured with an enhanced experimental …


Molecular Simulation Of The Infrared Absorption Cross Section And Thermophysical Properties Of A Polyatomic Fluid, Zhi Liang Jan 2010

Molecular Simulation Of The Infrared Absorption Cross Section And Thermophysical Properties Of A Polyatomic Fluid, Zhi Liang

Doctoral Dissertations

"The work presented in this dissertation aims at ab initio calculations of the infrared absorption cross section, heat capacity, self-diffusion coefficient, shear viscosity and thermal conductivity of a polyatomic fluid with the aid of statistical mechanics. The simulation is firstly focused on calculating single-molecule properties such as molecular structure, vibrational energy eigen values and transition dipole moments using an efficient method based on the density functional theory. Based on these ab initio results, the infrared absorption cross sections are determined by the Fermi's Golden rule, and the thermophysical properties are determined from molecular dynamics simulations. Using carbon dioxide as an …


Solid Oxide Fuel Cell Electrode Characterization And Improvement For Fuel Flexibility And Supplemental Power Production, Isaiah D. Kellogg Jan 2010

Solid Oxide Fuel Cell Electrode Characterization And Improvement For Fuel Flexibility And Supplemental Power Production, Isaiah D. Kellogg

Doctoral Dissertations

"Solid oxide fuel cells (SOFC) were fabricated and the electrodes tested for their individual catalytic effectiveness in various fuels by exposing each electrode to mixed gas while the opposite electrode was exposed to its respective pure gas. Mixed hydrogen and oxygen gas was successfully utilized as fuel in a single chamber SOFC (SC-SOFC). The conditions at which the porous nickel-yttria-stabilized zirconia (Ni-YSZ) cermet anode performed well did not significantly overlap the conditions at which the La₀.₈Sr₀.₂Fe₀.₈Co₀.₂ oxide (LSCF) cathode performed well, but there was significant catalytic activity at both electrodes which increased the open circuit voltage (OCV) beyond that predicted …