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Articles 1 - 30 of 570
Full-Text Articles in Engineering
Seeding Effects Of Submicron Caal-No3 Ldh Particles On The Hydration And Properties Of Portland Cement And Sulfoaluminate Cement Pastes, Sukanta K. Mondal, Monday Uchenna Okoronkwo
Seeding Effects Of Submicron Caal-No3 Ldh Particles On The Hydration And Properties Of Portland Cement And Sulfoaluminate Cement Pastes, Sukanta K. Mondal, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
Layered Double Hydroxide (LDH) Is Reported To Improve The Durability Of Concretes, Primarily Due To Its Ability To Exchange Anionic Species, Including Chloride, Which Is Implicated In Corrosion-Driven Durability Issues. However, There Is No Comprehensive Study Investigating The Effect Of LDH On The Properties Of Different Cement Systems At Both Early And Mature Ages. In This Study, The Early Age And Mature Age Properties Of Portland Cement (OPC) And Calcium Sulfoaluminate (CSA) Cement Pastes Seeded With Submicron-Sized Calcium Aluminum-NO3 LDH (CaAl-NO3 LDH) Were Investigated. The Effects Of The 1–5%mass Dosage Of LDH On The Hydration Of Both Cement Systems Were …
Assessing Hydrolysis Performance Of Ce(Oh)4@Pim-1 Composites Functionalized With Amidoxime, Aldoxime, And Carboxylate Groups Toward Dimethyl 4-Nitrophenylphosphonate, A Nerve Agent Simulant, Peter O. Aina, Sukanta K. Mondal, Ali A. Rownaghi, Fateme Rezaei
Assessing Hydrolysis Performance Of Ce(Oh)4@Pim-1 Composites Functionalized With Amidoxime, Aldoxime, And Carboxylate Groups Toward Dimethyl 4-Nitrophenylphosphonate, A Nerve Agent Simulant, Peter O. Aina, Sukanta K. Mondal, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
In recent years, significant attention has been directed toward evaluating the reactivity of diverse polymers to gauge their catalytic activity against hazardous chemicals. Among these polymers, pim-1 has emerged as an exceptional candidate due to its noteworthy attributes including high surface area, excellent solubility, and the capability to fine-tune the nitrile functional groups along its polymeric backbone. In this study, we explored the impact of different functional groups, such as amidoxime (ax), aldoxime (ox), and carboxylate (cooh), on the degradation of dimethyl 4-nitrophenylphosphonate (dmnp) in comparison to pure pim-1 and their respective ce(oh)4-loaded polymer composites. Remarkably, the pim-1-ax analog exhibited …
Challenges And Opportunities In Electrification Of Adsorptive Separation Processes, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei
Challenges And Opportunities In Electrification Of Adsorptive Separation Processes, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
A global energy transition from fossil-based to renewable-based systems requires advancements in various energy sectors. Current chemical separation processes are quite energy-intensive and require significant advancement to make this transition happen. In the energy transition era, reducing the dependency of separation processes on fossil-based thermal energy seems inevitable for transitioning smoothly and meeting the stringent timelines. In particular, adsorption-based separation processes have the potential to be fully electrified through innovative strategies in developing stimuli-responsive adsorbents and swing processes. In this review, we discuss the recent efforts in electrification of adsorption processes and provide an overview of emerging materials and processes. …
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Chemical and Biochemical Engineering Faculty Research & Creative Works
Carbon nanotube-encapsulated nickel selenide composite nanostructures were used as nonenzymatic electrochemical sensors for dopamine detection. These composite nanostructures were synthesized through a simple, one-step, and environmentally friendly chemical vapor deposition method, wherein the CNTs were formed in situ from pyrolysis of a carbon-rich metallo-organic precursor. The composition and morphology of these hybrid NiSe2-filled carbon nanostructures were confirmed by powder X-ray diffraction, Raman, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy images. Electrochemical tests demonstrated that the as-synthesized hybrid nanostructures exhibited outstanding electrocatalytic performance toward dopamine oxidation, with a high sensitivity of 19.62 μA μM-1 cm-2, low detection limit, broad linear …
Pd-Modified Cuo-Zno-Al2o3 Catalysts Via Mixed-Phases-Containing Precursor For Methanol Synthesis From Co2 Hydrogenation Under Mild Conditions, Xiao Fan, Kaiying Wang, Xiaoqing He, Shiguang Li, Miao Yu, Xinhua Liang
Pd-Modified Cuo-Zno-Al2o3 Catalysts Via Mixed-Phases-Containing Precursor For Methanol Synthesis From Co2 Hydrogenation Under Mild Conditions, Xiao Fan, Kaiying Wang, Xiaoqing He, Shiguang Li, Miao Yu, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
A series of palladium-modified (Pd-modified) CuO-ZnO-Al2O3 (CZA) catalysts with various Pd loadings (0.3 wt% to 2.4 wt%) were prepared using the wetness impregnation method, on two CZA supports with different structures that are CZA-aged precursor composed of a mixture of zincian-malachite and hydrotalcite-like phases (CZA-zH), and CuO-ZnO-Al2O3 metal oxide nanoparticles (CZA-MO). Enhancement on catalytic activity can be observed on both Pd-modified CZA catalysts in a temperature range of 180–240 °C for methanol synthesis via CO2 hydrogenation. Pd/CZA-zH catalysts exhibited a more efficient and stable production of methanol at a relatively low reaction temperature of 180 °C for 100 hrs. of …
Advancement In Heavy Oil Upgrading And Sustainable Exploration Emerging Technologies, Youssef Yatimi, Jihane Mendil, Meena Marafi, Ahmed Alalou, Muthanna H. Al-Dahhan
Advancement In Heavy Oil Upgrading And Sustainable Exploration Emerging Technologies, Youssef Yatimi, Jihane Mendil, Meena Marafi, Ahmed Alalou, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Upgrading heavy oil is a subject of high importance for fossil fuel industry due to the rapid depletion of light oil reservoirs and the consequent increased demand for upgrading heavy oil. In this review, the advancement made in heavy oil upgrading and the proposed sustainable emerging technologies dedicated to heavy oil processing have been discussed in a comprehensive and informative manner with consideration to the encountered associated with properties of heavy oil including its significant content of undesirable large molecular weight hydrocarbons, its high viscosity, and its elevated impurity level. The shortcomings of conventional crude oil upgrading technologies are outlined, …
Physio-Chemical Modifications To Re-Engineer Small Extracellular Vesicles For Targeted Anticancer Therapeutics Delivery And Imaging, Rahmat Asfiya, Lei Xu, Anjugam Paramanantham, Kuanysh Kabytaev, Anna Chernatynskaya, Grace Mccully, Hu Yang, Akhil Srivastava
Physio-Chemical Modifications To Re-Engineer Small Extracellular Vesicles For Targeted Anticancer Therapeutics Delivery And Imaging, Rahmat Asfiya, Lei Xu, Anjugam Paramanantham, Kuanysh Kabytaev, Anna Chernatynskaya, Grace Mccully, Hu Yang, Akhil Srivastava
Chemical and Biochemical Engineering Faculty Research & Creative Works
Cancer theranostics developed through nanoengineering applications are essential for targeted oncologic interventions in the new era of personalized and precision medicine. Recently, small extracellular vesicles (sEVs) have emerged as an attractive nanoengineering platform for tumor-directed anticancer therapeutic delivery and imaging of malignant tumors. These natural nanoparticles have multiple advantages over synthetic nanoparticle-based delivery systems, such as intrinsic targeting ability, less immunogenicity, and a prolonged circulation time. Since the inception of sEVs as a viable replacement for liposomes (synthetic nanoparticles) as a drug delivery vehicle, many studies have attempted to further the therapeutic efficacy of sEVs. This article discusses engineering strategies …
Rab7 Deficiency Impairs Pulmonary Artery Endothelial Function And Promotes Pulmonary Hypertension, Bryce Piper, Srimathi Bogamuwa, Tanvir Hossain, Daniela Farkas, Lorena Rosas, Adam C. Green, Geoffrey Newcomb, Nuo Sun, Jose A. Ovando-Ricardez, Jeffrey C. Horowitz, Aneel R. Bhagwani, Hu Yang, Tatiana V. Kudryashova, Mauricio Rojas
Rab7 Deficiency Impairs Pulmonary Artery Endothelial Function And Promotes Pulmonary Hypertension, Bryce Piper, Srimathi Bogamuwa, Tanvir Hossain, Daniela Farkas, Lorena Rosas, Adam C. Green, Geoffrey Newcomb, Nuo Sun, Jose A. Ovando-Ricardez, Jeffrey C. Horowitz, Aneel R. Bhagwani, Hu Yang, Tatiana V. Kudryashova, Mauricio Rojas
Chemical and Biochemical Engineering Faculty Research & Creative Works
Pulmonary arterial hypertension (PAH) is a devastating and progressive disease with limited treatment options. Endothelial dysfunction plays a central role in the development and progression of PAH, yet the underlying mechanisms are incompletely understood. The endosome-lysosome system is important to maintain cellular health, and the small GTPase RAB7 regulates many functions of this system. Here, we explored the role of RAB7 in endothelial cell (EC) function and lung vascular homeostasis. We found reduced expression of RAB7 in ECs from patients with PAH. Endothelial haploinsufficiency of RAB7 caused spontaneous pulmonary hypertension (PH) in mice. Silencing of RAB7 in ECs induced broad …
Reactive Capture And Conversion Of Co2 Into Hydrogen Over Bifunctional Structured Ce1-Xcoxnio3/Ca Perovskite-Type Oxide Monoliths, Khaled Baamran, Shane Lawson, Ali A. Rownaghi, Fateme Rezaei
Reactive Capture And Conversion Of Co2 Into Hydrogen Over Bifunctional Structured Ce1-Xcoxnio3/Ca Perovskite-Type Oxide Monoliths, Khaled Baamran, Shane Lawson, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Carbon capture, utilization, and storage (CCUS) technologies are pivotal for transitioning to a net-zero economy by 2050. In particular, conversion of captured CO2 to marketable chemicals and fuels appears to be a sustainable approach to not only curb greenhouse emissions but also transform wastes like CO2 into useful products through storage of renewable energy in chemical bonds. Bifunctional materials (BFMs) composed of adsorbents and catalysts have shown promise in reactive capture and conversion of CO2 at high temperatures. In this study, we extend the application of 3D printing technology to formulate a novel set of BFMs composed …
Retraction Notice To “High Density Conductive Lifepo4 Cathode With Enhanced High-Rate And High Temperature Performance” [Mater. Chem. Phys. 232 (2019) 367–373, (S0254058419304110), (10.1016/J.Matchemphys.2019.05.014)], David Seung-Hyun Lee, Won Bin Im, Xinhua Liang
Retraction Notice To “High Density Conductive Lifepo4 Cathode With Enhanced High-Rate And High Temperature Performance” [Mater. Chem. Phys. 232 (2019) 367–373, (S0254058419304110), (10.1016/J.Matchemphys.2019.05.014)], David Seung-Hyun Lee, Won Bin Im, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
This article has been retracted: please see Elsevier Policy on Article Withdrawal (https://www.elsevier.com/about/policies/article-withdrawal). This article has been retracted at the request of the Editor-in-Chief. The Editor-in-Chief found that the corresponding author of this article submitted the manuscript to the journal without the consent of the two individuals named as "co-authors", using invented email addresses to impersonate them. In addition, based on the raw materials presented to the journal by the second co-author and the Editor-in-Chief's own investigation, the Editor-in-Chief believes that some results in the paper are fabricated. Based on these two findings, the Editor-in-Chief has decided to retract the …
Gas-Phase Adsorption Of Dimethyl Methylphosphonate Over Ce(Oh)4@Pim-1 Composites Prepared Via Matrix Incorporation And Surface Coating Methods, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Gas-Phase Adsorption Of Dimethyl Methylphosphonate Over Ce(Oh)4@Pim-1 Composites Prepared Via Matrix Incorporation And Surface Coating Methods, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
This Study Investigated the Potential of Polymer of Intrinsic Microporosity (PIM-1) and Ce(OH)4@PIM-1 Composites for Adsorption of the Nerve Agent Simulant, Dimethyl Methylphosphonate (DMMP). through Experimental Investigations It Was Demonstrated that These Composite Adsorbents Exhibit Excellent Gas-Phase DMMP Adsorption Performance, with High Uptake Capacities and Relatively Fast Kinetics. This Study Further Examined the Effect of Two Composite's Preparation Methods, Namely Matrix Incorporation and Surface Coating, on the DMMP Adsorption Performance of Ce(OH)4@PIM-1. the Results Revealed that Coating of Ce(OH)4 on the PIM-1 Surface Gives Rise to Faster Adsorption Kinetics Than its Incorporation into the Polymer Matrix at Fixed 30 Wt …
Thermal Decomposition And Kinetic Parameters Of Three Biomass Feedstocks For The Performance Of The Gasification Process Using A Thermogravimetric Analyzer, Rania Almusafir, Joseph D. Smith
Thermal Decomposition And Kinetic Parameters Of Three Biomass Feedstocks For The Performance Of The Gasification Process Using A Thermogravimetric Analyzer, Rania Almusafir, Joseph D. Smith
Chemical and Biochemical Engineering Faculty Research & Creative Works
Thermogravimetric analysis (TGA) is a powerful technique and useful method for characterizing biomass as a non-conventional fuel. A TGA apparatus has been utilized to experimentally investigate the impact of biomass feedstock diversity on the performance of the gasification of hardwood (HW), softwood (SW) pellets, and refuse-derived fuel (RDF) materials. The solid conversion rate and the volatile species formation rate have been estimated to quantify the rates of devolatilization for each material. In addition, the combustion kinetic characteristics of the three biomass feedstocks were investigated using TGA at different heating rates, and a thermal kinetic analysis was conducted to describe the …
Liposomes-Encapsulating Double-Stranded Nucleic Acid (Poly I:C) For Head And Neck Cancer Treatment, Vidit Singh, Anna Chernatynskaya, Lin Qi, Hsin Yin Chuang, Tristan Cole, Vimalin Mani Jeyalatha, Lavanya Bhargava, W. Andrew Yeudall, Laszlo Farkas, Hu Yang
Liposomes-Encapsulating Double-Stranded Nucleic Acid (Poly I:C) For Head And Neck Cancer Treatment, Vidit Singh, Anna Chernatynskaya, Lin Qi, Hsin Yin Chuang, Tristan Cole, Vimalin Mani Jeyalatha, Lavanya Bhargava, W. Andrew Yeudall, Laszlo Farkas, Hu Yang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Polyriboinosinic acid-polyribocytidylic acid (Poly I:C) serves as a synthetic mimic of viral double-stranded dsRNA, capable of inducing apoptosis in numerous cancer cells. Despite its potential, therapeutic benefits, the application of Poly I:C has been hindered by concerns regarding toxicity, stability, enzymatic degradation, and undue immune stimulation, leading to autoimmune disorders. To address these challenges, encapsulation of antitumor drugs within delivery systems such as cationic liposomes is often employed to enhance their efficacy while minimizing dosages. In this study, we investigated the potential of cationic liposomes to deliver Poly I:C into the Head and Neck 12 (HN12) cell line to induce …
Flow Regimes In Bubble Columns With And Without Internals: A Review, Ayat N. Mahmood, Amer A. Abdulrahman, Laith S. Sabri, Abbas J. Sultan, Hasan Shakir Majdi, Muthanna H. Al-Dahhan
Flow Regimes In Bubble Columns With And Without Internals: A Review, Ayat N. Mahmood, Amer A. Abdulrahman, Laith S. Sabri, Abbas J. Sultan, Hasan Shakir Majdi, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Hydrodynamics characterization in terms of flow regime behavior is a crucial task to enhance the design of bubble column reactors and scaling up related methodologies. This review presents recent studies on the typical flow regimes established in bubble columns. Some effort is also provided to introduce relevant definitions pertaining to this field, namely, that of "void fraction" and related (local, chordal, cross-sectional and volumetric) variants. Experimental studies involving different parameters that affect design and operating conditions are also discussed in detail. In the second part of the review, the attention is shifted to cases with internals of various types (perforated …
A Novel Renewable Energy Powered Zero Liquid Discharge Scheme For Ro Desalination Applications, Mamdouh A. Gadalla, Amr Abdel Fatah, Hany A. Elazab
A Novel Renewable Energy Powered Zero Liquid Discharge Scheme For Ro Desalination Applications, Mamdouh A. Gadalla, Amr Abdel Fatah, Hany A. Elazab
Chemical and Biochemical Engineering Faculty Research & Creative Works
This work proposes a conceptual model for a Zero Liquid Discharge (ZLD) for Reverse Osmosis (RO) desalination. The model describes a Process Flow Diagram (PFD). The proposed process relies on an RO followed by electrolyser, solar evaporator and mixing tank. The water reject from the RO is split into three fractions, one to an electrolyser to produce H2, another to solar evaporator to produce fresh water, third is remixed with water from the evaporator to reduce the salinity of the RO feed. The hydrogen produced in the electrolyser is burned and its energy is stored using cement blocks. The evaporator …
Graphical Analysis And Revamping Of Crude Distillation Units Under Variable Operational Scenarios, Amany G. Abo-Mousa, Dina A. Kamel, Hany A. Elazab, Mamdouh A. Gadalla, Mai K. Fouad
Graphical Analysis And Revamping Of Crude Distillation Units Under Variable Operational Scenarios, Amany G. Abo-Mousa, Dina A. Kamel, Hany A. Elazab, Mamdouh A. Gadalla, Mai K. Fouad
Chemical and Biochemical Engineering Faculty Research & Creative Works
Energy Cost Represents a Significant Part of the Total Operating Costs of Many Processing Units. Crude Distillation is an Energy Intensive Process. Energy Integration is a Typical Solution to Reduce Heating and Cooling Utilities through Maximizing the Target Temperature of Crude Oil Streams Before Entering the Furnace. over the Past Few Decades, Significant Progress Has Been Made in Energy Integration Methods Including Pinch Technology and Mathematical Programming Approaches. Very Recently, Graphical Techniques Have Been Developed for Revamping Studies and Energy Analysis. Such Diagrams Are Valuable in Energy Targeting to Identity Energy Inefficiencies and Are Key to Potential Modifications for Maximum …
New Dual Modality Technique Of Gamma-Ray Densitometry (Grd) And Optical Fiber Probe (Ofp) To Investigate Line-Averaged Diameter Profiles Of Gas, Liquid, And Solid Holdups Along The Height Of A Slurry Bubble Column, Omar Farid, Binbin Qi, Sebastián Uribe, Muthanna H. Al-Dahhan
New Dual Modality Technique Of Gamma-Ray Densitometry (Grd) And Optical Fiber Probe (Ofp) To Investigate Line-Averaged Diameter Profiles Of Gas, Liquid, And Solid Holdups Along The Height Of A Slurry Bubble Column, Omar Farid, Binbin Qi, Sebastián Uribe, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
A new hybrid measurement technique was developed and employed to study line-averaged three-phase holdup distribution in a Slurry Bubble Column Reactor (SBCR) using gamma-ray densitometry (GRD) and point optical fiber probe (OFP) techniques. The OFP technique was used to measure the local gas holdup at 45 nodes in the cross-section area of the SBCR at three different axial levels. Thus, the GRD technique measured the spectrum of the SBCR for two different orientations simultaneously with the OFP technique at the same operating conditions to determine the solid holdup distribution radially and axially. The line-averaged solid holdup for 25% solids loading …
Enhancing Heat Transfer Performance In Simulated Fischer–Tropsch Fluidized Bed Reactor Through Tubes Ends Modifications, Laith S. Sabri, Abbas J. Sultan, Jamal M. Ali, Hasan Shakir Majdi, Muthanna H. Al-Dahhan
Enhancing Heat Transfer Performance In Simulated Fischer–Tropsch Fluidized Bed Reactor Through Tubes Ends Modifications, Laith S. Sabri, Abbas J. Sultan, Jamal M. Ali, Hasan Shakir Majdi, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Fluidized bed reactors are essential in a wide range of industrial applications, encompassing processes such as Fischer–Tropsch synthesis and catalytic cracking. The optimization of performance and reduction in energy consumption in these reactors necessitate the use of efficient heat transfer mechanisms. The present work examines the considerable impact of tube end geometries, superficial gas velocity, and radial position on heat transfer coefficients within fluidized bed reactors. It was found that the tapered tube end configurations have been empirically proven to improve energy efficiency in fluidized bed reactors significantly. For example, at a superficial gas velocity of 0.4 m/s, the tapered …
Design And Simulation Of A Utility Oilfield Flare In Iraq/Kurdistan Region Using Cfd And Api-521 Methodology, Ahmed A. Maaroof, Joseph D. Smith, Mohammed H.S. Zangana
Design And Simulation Of A Utility Oilfield Flare In Iraq/Kurdistan Region Using Cfd And Api-521 Methodology, Ahmed A. Maaroof, Joseph D. Smith, Mohammed H.S. Zangana
Chemical and Biochemical Engineering Faculty Research & Creative Works
This paper aims at reviewing and analyzing the operation and design of a utility flare in an oilfield in the Iraq/Kurdistan region. The flare supports a gas separation unit that separates 100 MMSCFD of natural gas from other liquid compounds in petroleum refining. The actual flare dimensions are 50 m high and 0.6 m diameter and works in summer where the crosswind speed is 9 m/s and a flow of 1.2 MMSCFD of treated natural gas is flaring through it. At the beginning, the flare design was performed using the API-521 recommended approach based on full operating capacity of the …
New Methodology For Benchmarking Hydrodynamics In Bubble Columns With Intense Internals Using The Radioactive Particle Tracking (Rpt) Technique, Omar J. Farid, Alexandre França Velo, Binbin Qi, Muthanna H. Al-Dahhan
New Methodology For Benchmarking Hydrodynamics In Bubble Columns With Intense Internals Using The Radioactive Particle Tracking (Rpt) Technique, Omar J. Farid, Alexandre França Velo, Binbin Qi, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
A new methodology for implementing radioactive particle tracking (RPT) in bubble columns with intense vertical rod internals was developed and implemented to investigate the effect of dense internals on hydrodynamics. The methodology utilizes a hybrid of Monte Carlo N-Particle (MCNP) simulation and an automated RPT calibration device to generate a large number of calibration points for accurate reconstruction of the instantaneous positions of radioactive particles using a similarity algorithm. Measurements were conducted in a 6-inch (15.24 cm) Plexiglas column using an air–water system at a superficial gas velocity of 40 cm/s. Vertical Plexiglas rods 0.5 in (1.27 cm) in diameter …
Experiments For A Computing Class, Christi L. Patton Luks
Experiments For A Computing Class, Christi L. Patton Luks
Chemical and Biochemical Engineering Faculty Research & Creative Works
The Course Description for Numerical Computing for Chemical Engineers Course at Missouri University of Science and Technology States that Students Will "Add to their Programming Skills by Exploring Numerical Computational Techniques for … Chemical Engineering Processes." the Challenge is that the Course is Taught Early in the Curriculum Before the Students Know What Those Chemical Engineering Processes Are. the Course Has Been Structured as a Flipped Class with Class Time Devoted to Solving Problems with the Numerical Tools. to Provide Relevance for the Material, an Experimental Component Has Been Added to the Course. in the Laboratory Sessions, the Students Conduct …
Drug Delivery On Mg-Mof-74: The Effect Of Drug Solubility On Pharmacokinetics, Neila Pederneira, Kyle Newport, Shane Lawson, Ali A. Rownaghi, Fateme Rezaei
Drug Delivery On Mg-Mof-74: The Effect Of Drug Solubility On Pharmacokinetics, Neila Pederneira, Kyle Newport, Shane Lawson, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Biocompatible metal-organic frameworks (MOFs) have emerged as potential nanocarriers for drug delivery applications owing to their tunable physiochemical properties. Specifically, Mg-MOF-74 with soluble metal centers has been shown to promote rapid pharmacokinetics for some drugs. In this work, we studied how the solubility of drug impacts the pharmacokinetic release rate and delivery efficiency by impregnating various amounts of ibuprofen, 5-fluorouracil, and curcumin onto Mg-MOF-74. The characterization of the drug-loaded samples via X-ray diffraction (XRD), N2 physisorption, and Fourier transform infrared (FTIR) confirmed the successful encapsulation of 30, 50, and 80 wt % of the three drugs within the MOF structure. …
Magnetic-Induced Swing Adsorption Over Iron Oxide/13x: Effects Of Particle Size And Oxide Phase On Sorbent Regeneration In Ethylene/Ethane Separation, Khaled Baamran, Ali A. Rownaghi, Fateme Rezaei
Magnetic-Induced Swing Adsorption Over Iron Oxide/13x: Effects Of Particle Size And Oxide Phase On Sorbent Regeneration In Ethylene/Ethane Separation, Khaled Baamran, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Magnetic induction has emerged as a viable method for regeneration of sorbents during separation processes. In this work, we investigated the efficacy of magnetic sorbents comprising iron oxide and zeolite 13X in ethylene/ethane separation via a magnetic induction process. The electromagnetic properties of the sorbents were tuned by varying the iron oxide (Fe2O3) particle size (30 nm, 100 nm, 5 μm) and iron oxide phase structure (FeO, Fe2O3, Fe3O4) at 20 wt % loading. The effects of these parameters on adsorption capacity, selectivity, and desorption rates were systematically …
Ultra-Thin Zro2 Overcoating On Cuo-Zno-Al2o3 Catalyst By Atomic Layer Deposition For Improved Catalytic Performance Of Co2 Hydrogenation To Dimethyl Ether, Xiao Fan, Baitang Jin, Xiaoqing He, Shiguang Li, Xinhua Liang
Ultra-Thin Zro2 Overcoating On Cuo-Zno-Al2o3 Catalyst By Atomic Layer Deposition For Improved Catalytic Performance Of Co2 Hydrogenation To Dimethyl Ether, Xiao Fan, Baitang Jin, Xiaoqing He, Shiguang Li, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
An Ultra-Thin overcoating of Zirconium Oxide (ZrO2) Film on CuO-ZnO-Al2O3 (CZA) Catalysts by Atomic Layer Deposition (ALD) Was Proved to Enhance the Catalytic Performance of CZA/HZSM-5 (H Form of Zeolite Socony Mobil-5) Bifunctional Catalysts for Hydrogenation of CO2 to Dimethyl Ether (DME). under Optimal Reaction Conditions (I.e. 240 °C and 2.8 MPa), the Yield of Product DME Increased from 17.22% for the Bare CZA/HZSM-5 Catalysts, to 18.40% for the CZA Catalyst after 5 Cycles of ZrO2 ALD with HZSM-5 Catalyst. All the Catalysts Modified by ZrO2 ALD Displayed Significantly Improved Catalytic Stability …
Transport Phenomena With Reactions In Drug Delivery: Towards A Quantitative Description, Xianjie Qiu, Parthasakha Neogi
Transport Phenomena With Reactions In Drug Delivery: Towards A Quantitative Description, Xianjie Qiu, Parthasakha Neogi
Chemical and Biochemical Engineering Faculty Research & Creative Works
A Distributed System Called a Krogh Cylinder is Used Here to Quantify the Transport of a Solute from the Capillary into the Extravascular Tissue. the Capillary Network is Broken Down into Cylindrical Cells, Each Containing a Capillary and an Appropriate Amount of Extravascular Tissue. the Flow in the Cylinder Model Has Two-Dimensional Velocities, Which Are in the Axial and Radial Directions. All Parameters of the System, together with the Geometric Ones, Have Been Included in the Model. for a Given Bioavailability, the Uptakes of Reactive and Nonreactive Solutes Have Been Obtained. Very Large or Massive Molecules Have Been Considered. the …
Dynamic And Equilibrium Contribution Of Nematic Order In Wetting And Contact Angles, Partho Neogi, Xianjie Qiu, Amer Al-Shareef
Dynamic And Equilibrium Contribution Of Nematic Order In Wetting And Contact Angles, Partho Neogi, Xianjie Qiu, Amer Al-Shareef
Chemical and Biochemical Engineering Faculty Research & Creative Works
A Model for the Dynamic Contact Angles and the Spreading Kinetics of Nematic Liquid Crystals on a Solid Surface is Presented for the First Time using the Continuum Theory of Liquid Crystals. the Equations of Motion for This System Are Integrated for a Wedge or a Drop that is Thin and Moves Slowly. the Dynamic Contact Angle is Found to Depend on the Capillary Number that Represents the Importance of Viscocapillarity and on the Elasticity Number that is the Ratio between the Elastic and Surface Forces. the Model Provides an Explanation for the Extra Volume Dependence that is Reported in …
Engineering Oxygen Vacancy-Rich Ceox Overcoating Onto Ni/Al2o3 By Atomic Layer Deposition For Bi-Reforming Of Methane, Baitang Jin, Kaiying Wang, Han Yu, Xiaoqing He, Xinhua Liang
Engineering Oxygen Vacancy-Rich Ceox Overcoating Onto Ni/Al2o3 By Atomic Layer Deposition For Bi-Reforming Of Methane, Baitang Jin, Kaiying Wang, Han Yu, Xiaoqing He, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Atomic Layer Deposition (ALD) Was Applied to Develop CeOx-Overcoated Ni/Al2O3 Catalyst for Bi-Reforming of Methane (BRM), as the Combination of Dry Reforming of Methane (DRM) and Steam Reforming of Methane (SRM). Non-Stoichiometric CeOx Thin Films Were Successfully Deposited on Ni/Al2O3 Particles by ALD, Which Constructed a Beneficial Ni-CeOx Interface and Modified the Catalyst Property. Ascribed to the Unique ALD Growth Mode, a High Amount of Ce(III) and Oxygen Vacancies Existed in the ALD-Deposited CeOx overcoating. a Reduction Process Before the BRM Reaction Contributed to the Further Reduction of Ce(IV) …
A P53-Tlr3 Axis Ameliorates Pulmonary Hypertension By Inducing Bmpr2 Via Irf3, Aneel R. Bhagwani, Mehboob Ali, Bryce Piper, Mingjun Liu, Jaylen Hudson, Neil Kelly, Srimathi Bogamuwa, Hu Yang, James D. Londino, Joseph S. Bednash, Daniela Farkas, Rama K. Mallampalli, Mark R. Nicolls, John J. Ryan
A P53-Tlr3 Axis Ameliorates Pulmonary Hypertension By Inducing Bmpr2 Via Irf3, Aneel R. Bhagwani, Mehboob Ali, Bryce Piper, Mingjun Liu, Jaylen Hudson, Neil Kelly, Srimathi Bogamuwa, Hu Yang, James D. Londino, Joseph S. Bednash, Daniela Farkas, Rama K. Mallampalli, Mark R. Nicolls, John J. Ryan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Pulmonary arterial hypertension (PAH) features pathogenic and abnormal endothelial cells (ECs), and one potential origin is clonal selection. We studied the role of p53 and toll-like receptor 3 (TLR3) in clonal expansion and pulmonary hypertension (PH) via regulation of bone morphogenetic protein (BMPR2) signaling. ECs of PAH patients had reduced p53 expression. EC-specific p53 knockout exaggerated PH, and clonal expansion reduced p53 and TLR3 expression in rat lung CD117+ ECs. Reduced p53 degradation (Nutlin 3a) abolished clonal EC expansion, induced TLR3 and BMPR2, and ameliorated PH. Polyinosinic/polycytidylic acid [Poly(I:C)] increased BMPR2 signaling in ECs via enhanced binding of interferon regulatory …
A P53-Tlr3 Axis Ameliorates Pulmonary Hypertension By Inducing Bmpr2 Via Irf3, Aneel R. Bhagwani, Mehboob Ali, Bryce Piper, Mingjun Liu, Jaylen Hudson, Neil Kelly, Srimathi Bogamuwa, Hu Yang, James D. Londino, Joseph S. Bednash, Daniela Farkas, Rama K. Mallampalli, Mark R. Nicolls, John J. Ryan
A P53-Tlr3 Axis Ameliorates Pulmonary Hypertension By Inducing Bmpr2 Via Irf3, Aneel R. Bhagwani, Mehboob Ali, Bryce Piper, Mingjun Liu, Jaylen Hudson, Neil Kelly, Srimathi Bogamuwa, Hu Yang, James D. Londino, Joseph S. Bednash, Daniela Farkas, Rama K. Mallampalli, Mark R. Nicolls, John J. Ryan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Pulmonary arterial hypertension (PAH) features pathogenic and abnormal endothelial cells (ECs), and one potential origin is clonal selection. We studied the role of p53 and toll-like receptor 3 (TLR3) in clonal expansion and pulmonary hypertension (PH) via regulation of bone morphogenetic protein (BMPR2) signaling. ECs of PAH patients had reduced p53 expression. EC-specific p53 knockout exaggerated PH, and clonal expansion reduced p53 and TLR3 expression in rat lung CD117+ ECs. Reduced p53 degradation (Nutlin 3a) abolished clonal EC expansion, induced TLR3 and BMPR2, and ameliorated PH. Polyinosinic/polycytidylic acid [Poly(I:C)] increased BMPR2 signaling in ECs via enhanced binding of interferon regulatory …
Sra Inhibition Improves Antitumor Potency Of Antigen-Targeted Chaperone Vaccine, Jie Qian, Xiaofei Yu, Zheng Liu, Jinyang Cai, Masoud H. Manjili, Hu Yang, Chunqing Guo, Xiang Yang Wang
Sra Inhibition Improves Antitumor Potency Of Antigen-Targeted Chaperone Vaccine, Jie Qian, Xiaofei Yu, Zheng Liu, Jinyang Cai, Masoud H. Manjili, Hu Yang, Chunqing Guo, Xiang Yang Wang
Chemical and Biochemical Engineering Faculty Research & Creative Works
We Have Previously Demonstrated that Scavenger Receptor a (SRA) Acts as an Immunosuppressive Regulator of Dendritic Cell (DC) Function in Activating Antitumor T Cells. Here We Investigate the Potential of Inhibiting SRA Activity to Enhance DC-Targeted Chaperone Vaccines Including One that Was Recently Evaluated in Melanoma Patients. We Show that Short Hairpin RNA-Mediated SRA Silencing Significantly Enhances the Immunogenicity of DCs that Have Captured Chaperone Vaccines Designed to Target Melanoma (I.e., Hsp110-Gp100) and Breast Cancer (I.e., Hsp110-HER/Neu-ICD). SRA Downregulation Results in Heightened Activation of Antigen-Specific T Cells and Increased CD8+ T Cell-Dependent Tumor Inhibition. Additionally, Small Interfering RNA (SiRNA) Complexed …