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Full-Text Articles in Engineering

Removal Of Methylene Blue By Adsorption Of Water Hyacinth Derived Active Carbon Embedded With Cobalt Nanoparticles, Hany A. Elazab, A. O. Okasha, M. A. Radwan, M. A. Sadek, Amin Firouzi, Tamer T. El-Idreesy Dec 2021

Removal Of Methylene Blue By Adsorption Of Water Hyacinth Derived Active Carbon Embedded With Cobalt Nanoparticles, Hany A. Elazab, A. O. Okasha, M. A. Radwan, M. A. Sadek, Amin Firouzi, Tamer T. El-Idreesy

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this research, active carbon-based catalyst synthesis and characterization were tested for potential catalysts to be used in dye removal of methylene blue (MB). Water hyacinth is one of the major problems that is facing humankind and especially here in Egypt. One of the implications of industrial activities is environmental pollution. Dyes used in the production of textiles, paper, and clothes are one of the major pollutants. The waste of those dyes discharged into water supplies without treatment or with ineffective treatment harmfully impacts the environment. In this research, the treatment is implemented using active carbon-based catalysts using embedded nanoparticles. …


Antibody-Drug Nanoparticle Induces Synergistic Treatment Efficacies In Her2 Positive Breast Cancer Cells, Muhammad Raisul Abedin, Kaitlyne Powers, Rachel Aiardo, Dibbya Barua, Sutapa Barua Dec 2021

Antibody-Drug Nanoparticle Induces Synergistic Treatment Efficacies In Her2 Positive Breast Cancer Cells, Muhammad Raisul Abedin, Kaitlyne Powers, Rachel Aiardo, Dibbya Barua, Sutapa Barua

Chemical and Biochemical Engineering Faculty Research & Creative Works

Chemotherapeutic drugs suffer from non-specific binding, undesired toxicity, and poor blood circulation which contribute to poor therapeutic efficacy. In this study, antibody–drug nanoparticles (ADNs) are engineered by synthesizing pure anti-cancer drug nanorods (NRs) in the core of nanoparticles with a therapeutic monoclonal antibody, Trastuzumab on the surface of NRs for specific targeting and synergistic treatments of human epidermal growth factor receptor 2 (HER2) positive breast cancer cells. ADNs were designed by first synthesizing ~ 95 nm diameter × ~ 500 nm long paclitaxel (PTX) NRs using the nanoprecipitation method. The surface of PTXNRs was functionalized at 2′ OH nucleophilic site …


Aiche Virtual Communities Of Practice – Supporting Faculty During The Covid-19 Pandemic, Christi L. Patton (Luks) Nov 2021

Aiche Virtual Communities Of Practice – Supporting Faculty During The Covid-19 Pandemic, Christi L. Patton (Luks)

Chemical and Biochemical Engineering Faculty Research & Creative Works

In response to the COVID-19 pandemic, chemical engineering departments from around the world shifted their course offerings from in-person to online almost instantaneously. The AIChE Education Division immediately responded to this educational shift by developing five Virtual Communities of Practice (VCPs) that allowed faculty to share experiences and best practices as well as provide a network for emotional support. Community creation, methods and materials shared, and surveys related to the impact of this initiative will be discussed.


A Conceptual Efficient Design Of Energy Recovery Systems Using A New Energy-Area Key Parameter, Ibrahim H. Alhajri, Mamdouh A. Gadalla, Hany A. Elazab Nov 2021

A Conceptual Efficient Design Of Energy Recovery Systems Using A New Energy-Area Key Parameter, Ibrahim H. Alhajri, Mamdouh A. Gadalla, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

Energy integration in petrochemical and refining industries is an effective concept to minimize dependence on heating and cooling utilities through networks of exchanger equipment. Pinch Analysis is very popular and successful technique to optimize heat recovery between heat sources and sinks. Yet, design of networks of exchangers is challenging and requires careful attention to energy consumption and exchanger areas. This work presents a graphical methodology to design exchanger networks taking into account both heat loads and transfer areas of exchanger units in one single information. A new parameter is introduced for design that is the ratio between the heat load …


Pairing Experimental And Mathematical Modeling Studies On Fluidized Beds For Enhancement Of Models Predictive Quality: A Current Status Overview, Sebastián Uribe, Muthanna H. Al-Dahhan Oct 2021

Pairing Experimental And Mathematical Modeling Studies On Fluidized Beds For Enhancement Of Models Predictive Quality: A Current Status Overview, Sebastián Uribe, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Modeling of gas-solid fluidized systems has been a prevailing challenge over the last few decades. With different approaches and implementing different sub-models to capture the essential multiphase and multiscale phenomena in these systems, major advances have been achieved, even though most models are only subject to a practical validation of macroscopic parameters. The current description of fluidized beds through mathematical models relies on the inclusion of vast sub-models, leading to an unquantifiable degree of uncertainty on the models' applicability for extrapolation studies. Furthermore, each closure and fitting parameter in the model represents a possible source of deviation, and their optimization, …


Solvent-Free Solid-State Lithium Battery Based On Lifepo₄ And Mwcnt/Peo/Pvdf-Hfp For High-Temperature Applications, Han Yu, Ye Jin, Guodong David Zhan, Xinhua Liang Oct 2021

Solvent-Free Solid-State Lithium Battery Based On Lifepo₄ And Mwcnt/Peo/Pvdf-Hfp For High-Temperature Applications, Han Yu, Ye Jin, Guodong David Zhan, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Rechargeable lithium-ion batteries (LIBs) have a wide range of applications but face challenges in harsh working or operating environments at high temperatures. In this work, a solid polymer electrolyte with MWCNT-COOH as an additive (MWCNT-SPE) was obtained. MWCNT-SPE has a high thermal stability and can be used in high-temperature operating environments. Solid-state lithium batteries based on MWCNT-SPE and LiFePO4 were assembled. The resulting lithium batteries exhibited excellent electrochemical properties at 70 and 120 °C, demonstrating a wide range of operations suitable for solid-state batteries with extreme demands. The symmetrical Li/MWCNT-SPE/Li cell operated for 1800 h with low polarization voltage …


Cement Bricks Based On Shredded Automobile Tires, Nour Waheed, Ibrahim M. Ibrahim, M. A. Radwan, M. A. Sadek, Hany A. Elazab Oct 2021

Cement Bricks Based On Shredded Automobile Tires, Nour Waheed, Ibrahim M. Ibrahim, M. A. Radwan, M. A. Sadek, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

The essential target of this is to make good, qualified bricks with economic background and to have several uses than ordinary brick that is utilized in construction of homes or any building. From these useful properties of those blocks are acoustic segregation and thermal insulation also with recovery of many wastes that don’t be benefit from them; create from them jobs to be reused and to make brick economically wise and to be applied for example the insulation. From those squandering, are the shredded used tires after being used and it can’t be used anymore. It was cleared that the …


Effect Of Addition Of Nano Silicon Dioxide To Cement Bricks: Preparation And Characterictics, Rehab Emad, Ibrahim M. Ibrahim, M. A. Radwan, M. A. Sadek, Hany A. Elazab Oct 2021

Effect Of Addition Of Nano Silicon Dioxide To Cement Bricks: Preparation And Characterictics, Rehab Emad, Ibrahim M. Ibrahim, M. A. Radwan, M. A. Sadek, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

The aim of the research is to design and produce a durable, and high load, bearing build constructing bricks based on cement, sand, and aggregates with the addition of Nano silica, studying the effect of the added materials to get a background about the impact of the Nano silica on the ability of using such a product. The cement used is 52.5 grade which represent the strength of the cement, sand with particle size 300-600 micrometer, aggregates with diameter lays between 0.5-1 cm better to use smaller size, water, and finally Nano-silica with particle size 17 nm with purity higher …


Comparative Evaluation Of Two Glass Polyalkenoate Cements: An In Vivo Pilot Study Using A Sheep Model, Leyla Hasandoost, Daniella Marx, Paul Zalzal, Oleg Safir, Mark Hurtig, Cina Mehrvar, Stephen D. Waldman, Marcello Papini, Mark R. Towler Sep 2021

Comparative Evaluation Of Two Glass Polyalkenoate Cements: An In Vivo Pilot Study Using A Sheep Model, Leyla Hasandoost, Daniella Marx, Paul Zalzal, Oleg Safir, Mark Hurtig, Cina Mehrvar, Stephen D. Waldman, Marcello Papini, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Poly(methyl methacrylate) (PMMA) is used to manage bone loss in revision total knee arthroplasty (rTKA). However, the application of PMMA has been associated with complications such as volumetric shrinkage, necrosis, wear debris, and loosening. Glass polyalkenoate cements (GPCs) have potential bone cementation applications. Unlike PMMA, GPC does not undergo volumetric shrinkage, adheres chemically to bone, and does not undergo an exothermic setting reaction. In this study, two different compositions of GPCs (GPCA and GPCB), based on the patented glass system SiO2-CaO-SrO-P2O5-Ta2O5, were investigated. Working and setting times, pH, ion release, …


Novel Method Of Manufacture Of Metal Nanoparticles And Metal Single-Atom Materials On Various Substrates And Novel Compositions, Xinhua Liang, Xiaofeng Wang Aug 2021

Novel Method Of Manufacture Of Metal Nanoparticles And Metal Single-Atom Materials On Various Substrates And Novel Compositions, Xinhua Liang, Xiaofeng Wang

Chemical and Biochemical Engineering Faculty Research & Creative Works

The present invention discloses a novel method and novel compositions comprising well-dispersed particulate metal materials, including metal nanoparticles and/or metal single-atom materials, on various substrates, said method comprising the use of atomic layer deposition (ALD) and optimization of the metal precursor dose time and the number of ALD cycles. Illustrative of the metals are Fe, Ni, Co, Ru, Rh, Ir, Os, Pt, Pd, and the like; and illustrative of the various substrates are carbon nanotubes (CNTs) (including multi-walled carbon nanotubes (MWCNTs), SiO2, TiO2, alumina, CeO2, ZnO, ZrO2, activated carbon, CuO, Fe2 …


In Vitro Osteogenic Performance Of Two Novel Strontium And Zinc-Containing Glass Polyalkenoate Cements, Daniella Marx, Alireza Rahimnejad Yazdi, Marcello Papini, Mark R. Towler Aug 2021

In Vitro Osteogenic Performance Of Two Novel Strontium And Zinc-Containing Glass Polyalkenoate Cements, Daniella Marx, Alireza Rahimnejad Yazdi, Marcello Papini, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Glass polyalkenoate cements (GPCs) are under investigation as potential bone adhesives, as they may provide an alternative to polymethylmethacrylate-based cements. GPCs containing strontium (Sr) and zinc (Zn) in place of aluminum (Al) are of particular interest because these ions are known stimulators of osteoprogenitor differentiation. GPCs have been manufactured from a novel bioactive glass (SiO2:0.48, ZnO:0.36, CaO:0.12, SrO:0.04) in the past, but, while such materials have been assessed for their influence on viability, their influence on osteogenic function has not been investigated until now. For this study, two GPCs were formulated from the same glass precursor evaluated in previous studies. …


A Gallium-Doped Cement For The Treatment Of Bone Cancers. The Effect Of Zno ↔ Ga2o3substitution Of An Ionomeric Glass Series On The Rheological, Mechanical, Ph And Ion-Eluting Properties Of Their Corresponding Glass Polyalkenoate Cements, Sunjeev Phull, Alireza Rahimnejad Yazdi, Mark R. Towler Jun 2021

A Gallium-Doped Cement For The Treatment Of Bone Cancers. The Effect Of Zno ↔ Ga2o3substitution Of An Ionomeric Glass Series On The Rheological, Mechanical, Ph And Ion-Eluting Properties Of Their Corresponding Glass Polyalkenoate Cements, Sunjeev Phull, Alireza Rahimnejad Yazdi, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

The primary treatment for patients suffering from bone cancers is resection of the tumor followed by reconstruction of the damaged bone. Despite the administration of post-operative chemotherapy, tumor recurrence continues to present itself as a severe complication leading to re-operation. Attempts to incorporate chemotherapeutic drugs into bone cements elicits local toxic effects on healthy bone, which could compromise implant fixation. Alternatively, the local administration of gallium (Ga) may prove to be more effective. This report considers the development of a Ga ionomeric glass series (0.48SiO2-0.355ZnO-0.06CaO-0.08SrO-0.02P2O5-0.005Ta2O5, with 0.01-0.05 mol% substitution for …


Dynamics In Drops As Confined Systems Containing Nanoparticles: Reformation Of Nanoparticles And Evaporation Of Water, Vijitha Mohan, Xianjie Qiu, Partho Neogi May 2021

Dynamics In Drops As Confined Systems Containing Nanoparticles: Reformation Of Nanoparticles And Evaporation Of Water, Vijitha Mohan, Xianjie Qiu, Partho Neogi

Chemical and Biochemical Engineering Faculty Research & Creative Works

Brine is used to displace crude oil in a reservoir and its performance improves when brine contains nanoparticles. It is the presence of nanoparticles in confinements, such as at dynamic contact lines and in thin films, which is of importance. The investigators here have determined a fast way to obtain confined systems by evaporating a small drop of water containing nanoparticles. Water droplets containing nanoparticles of alumina or silica were evaporated on surfaces of polyethylene terephthalate sheets, which are partially wet by water, and glass which is fully wet. After the liquid in the drops evaporated, the residues were examined …


In Vivo Analysis Of A Proprietary Glass-Based Adhesive For Sternal Fixation And Stabilization Using Rabbit And Sheep Models, Cina Mehrvar, Emily Deignan, Mark Hurtig, Gideon Cohen, Paul Zalzal, Oleg Safir, Adel Alhalawani, Marcello Papini, Mark R. Towler May 2021

In Vivo Analysis Of A Proprietary Glass-Based Adhesive For Sternal Fixation And Stabilization Using Rabbit And Sheep Models, Cina Mehrvar, Emily Deignan, Mark Hurtig, Gideon Cohen, Paul Zalzal, Oleg Safir, Adel Alhalawani, Marcello Papini, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Wire cerclage remains the standard method of care for sternal fixation, following median sternotomy, despite being beset with complications. An emerging treatment option has been to augment the wires with an adhesive. A patented ionomeric glass (mole fraction: SiO2:0.48, ZnO:0.36, CaO:0.12, SrO:0.04) has been used to formulate GPC+, a glass polyalkenoate cement (GPC), by mixing it with poly(acrylic) acid (PAA) and de-ionized water. In a human cadaver study, this material, when applied with wire cerclage, was able to significantly reduce sternal instability. However, the material has yet to be tested in pertinent animal models. Here, after a series …


Heavy Oil And Vapex Process: A Brief Review, Vijitha Mohan, Parthasakha Neogi, Baojun Bai May 2021

Heavy Oil And Vapex Process: A Brief Review, Vijitha Mohan, Parthasakha Neogi, Baojun Bai

Chemical and Biochemical Engineering Faculty Research & Creative Works

Heavy oil recovery requires either heat or solvent assistance to reduce its high viscosity first and then the less viscous oil can be recovered. Processes that use vapor assisted petroleum extraction (VAPEX) utilize vaporized solvent. Solvent vapors are introduced through a top injection well to induce viscosity reduction and the less viscous oil is collected at the bottom production well. It is noteworthy, that the solvent itself when recovered, can be seen as an integral part of oil. Exact molecular weight and chemistry of heavy oil is uncertain making analysis of thermodynamic properties difficult, however this is overcome by making …


Gagrank: Software For Glycosaminoglycan Sequence Ranking Using A Bipartite Graph Model, John D. Hogan, Jiandong Wu, Joshua A. Klein, Cheng Lin, Luis Carvalho, Joseph Zaia Apr 2021

Gagrank: Software For Glycosaminoglycan Sequence Ranking Using A Bipartite Graph Model, John D. Hogan, Jiandong Wu, Joshua A. Klein, Cheng Lin, Luis Carvalho, Joseph Zaia

Chemical and Biochemical Engineering Faculty Research & Creative Works

The Sulfated Glycosaminoglycans (GAGs) Are Long, Linear Polysaccharide Chains that Are Typically Found as the Glycan Portion of Proteoglycans. These GAGs Are Characterized by Repeating Disaccharide Units with Variable Sulfation and Acetylation Patterns Along the Chain. GAG Length and Modification Patterns Have Profound Impacts on Growth Factor Signaling Mechanisms Central to Numerous Physiological Processes. Electron Activated Dissociation Tandem Mass Spectrometry is a Very Effective Technique for Assigning the Structures of GAG Saccharides; However, Manual Interpretation of the Resulting Complex Tandem Mass Spectra is a Difficult and Time-Consuming Process that Drives the Development of Computational Methods for Accurate and Efficient Sequencing. …


Laboratory-Scale Research Of Non-Catalyzed Supercritical Alcohol Process For Continuous Biodiesel Production, Aso A. Hassan, Joseph D. Smith Apr 2021

Laboratory-Scale Research Of Non-Catalyzed Supercritical Alcohol Process For Continuous Biodiesel Production, Aso A. Hassan, Joseph D. Smith

Chemical and Biochemical Engineering Faculty Research & Creative Works

This work investigates the non-catalyzed supercritical methanol (SCM) process for continuous biodiesel production. The lab-scale setup was designed and used for biodiesel production in the temperature range of 520–650 K and 83–380 bar with an oil-to-methanol molar ratio ranging from 1:5 to 1:45. The experiments were performed in the coiled plug flow tubular reactor. The volumetric flow rate of the methanol/oil ranged from 0.1-10 mL/min. This work examines a new reactor technology involving preheating and pre-mixing of the methanol/oil mixture to reduce setup cost and increase biodiesel yield under the same reaction conditions. Work performed showed that FAME’s yield increased …


Bone Cement As A Local Chemotherapeutic Drug Delivery Carrier In Orthopedic Oncology: A Review, Sunjeev S. Phull, Alireza Rahimnejad Yazdi, Michelle Ghert, Mark R. Towler Feb 2021

Bone Cement As A Local Chemotherapeutic Drug Delivery Carrier In Orthopedic Oncology: A Review, Sunjeev S. Phull, Alireza Rahimnejad Yazdi, Michelle Ghert, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Metastatic bone lesions are common among patients with advanced cancers. While chemotherapy and radiotherapy may be prescribed immediately after diagnosis, the majority of severe metastatic bone lesions are treated by reconstructive surgery, which, in some cases, is followed by postoperative radiotherapy or chemotherapy. However, despite recent advancements in orthopedic surgery, patients undergoing reconstruction still have the risk of developing severe complications such as tumor recurrence and reconstruction failure. This has led to the introduction and evaluation of poly (methyl methacrylate) and inorganic bone cements as local carriers for chemotherapeutic drugs (usually, antineoplastic drugs (ANPDs)). The present work is a critical …


In Vitro Evaluation Of Novel Titania-Containing Borate Bioactive Glass Scaffolds, Romina Shafaghi, Omar Rodriguez, Anthony W. Wren, Loraine Chiu, Emil H. Schemitsch, Paul Zalzal, Stephen D. Waldman, Marcello Papini, Mark R. Towler Feb 2021

In Vitro Evaluation Of Novel Titania-Containing Borate Bioactive Glass Scaffolds, Romina Shafaghi, Omar Rodriguez, Anthony W. Wren, Loraine Chiu, Emil H. Schemitsch, Paul Zalzal, Stephen D. Waldman, Marcello Papini, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Titanium-containing borate bioactive glass scaffolds (0, 5, 15, and 20 mol %, identified as BRT0, BRT1, BRT3, and BRT4) with a microstructure similar to that of human trabecular bone were prepared and evaluated in vitro for potential bone loss applications in revision total knee arthroplasty (rTKA). Methyl thiazolyl tetrazolium (MTT) cell viability assays of scaffold ion release extracts revealed that BRT0 scaffolds (0 mol % titanium) inhibited cell proliferation and activity at day 14. At day 30, all scaffold extracts decreased cell proliferation and activity significantly. However, live/dead cell assay results demonstrated that degradation products from all the scaffolds had …


Coating Compositions And Methods For Using The Same, Fateme Rezaei, Thomas P. Schuman, Glenn Morrison Jan 2021

Coating Compositions And Methods For Using The Same, Fateme Rezaei, Thomas P. Schuman, Glenn Morrison

Chemical and Biochemical Engineering Faculty Research & Creative Works

Coating compositions and methods for using the same are disclosed. The coating compositions can include an aminosilica adsorbent. The coating compositions can adsorb CO2.


Fluorination Of Al₂O₃ Coating For Lithium-Ion Battery, Xinhua Liang, Han Yu Jan 2021

Fluorination Of Al₂O₃ Coating For Lithium-Ion Battery, Xinhua Liang, Han Yu

Chemical and Biochemical Engineering Faculty Research & Creative Works

Improving the performance of cathodes by using surface coatings has proven to be an effective method for improving the stability of Li-ion batteries (LIBs), while a high quality film satisfying all requirements of electrochemical inertia, chemical stability, and lithium ion conductivity has not been found. A composite film composed of AI2O3 and AIF3 layers was coated on the surface of Li-rich NMC based electrodes by atomic layer deposition (ALD). The electrochemical characterization results indicated that the coating with 1 cycle of AIF3 ALD on 5 cycles of AI2O3 ALD (1 A1 F3-5AI2O …


Isolation And Purification Of Glycoglycerolipids To Induce Apoptosis In Breast Cancer Cells, Muhammad Raisul Abedin, Sutapa Barua Jan 2021

Isolation And Purification Of Glycoglycerolipids To Induce Apoptosis In Breast Cancer Cells, Muhammad Raisul Abedin, Sutapa Barua

Chemical and Biochemical Engineering Faculty Research & Creative Works

Monogalactosyldiacylglycerol (MGDG) is the most abundant type of glycoglycerolipid found in the plant cell membrane and mostly in the chloroplast thylakoid membrane. The amphiphilic nature of MGDG is attractive in pharmaceutical fields for interaction with other biological molecules and hence exerting therapeutic anti-cancer, anti-viral, and anti-inflammatory activities. In this study, we investigated the therapeutic efficacy of cyanobacteria derived MGDG to inhibit breast cancer cell growth. MGDG was extracted from a cyanobacteria Synechocystis sp. PCC 6803 followed by a subsequent fractionation by column chromatographic technique. The purity and molecular structure of MGDG were analyzed by nuclear magnetic resonance (NMR) spectroscopy analysis. …


The 3-O-Sulfation Of Heparan Sulfate Modulates Protein Binding And Lyase Degradation, Pradeep Chopra, Apoorva Joshi, Jiandong Wu, Weigang Lu, Tejabhiram Yadavalli, Margreet A. Wolfert, Deepak Shukla, Joseph Zaia, Geert Jan Boons Jan 2021

The 3-O-Sulfation Of Heparan Sulfate Modulates Protein Binding And Lyase Degradation, Pradeep Chopra, Apoorva Joshi, Jiandong Wu, Weigang Lu, Tejabhiram Yadavalli, Margreet A. Wolfert, Deepak Shukla, Joseph Zaia, Geert Jan Boons

Chemical and Biochemical Engineering Faculty Research & Creative Works

Humans Express Seven Heparan Sulfate (HS) 3-O-Sulfotransferases that Differ in Substrate Specificity and Tissue Expression. Although Genetic Studies Have Indicated that 3-O-Sulfated HS Modulates Many Biological Processes, Ligand Requirements for Proteins Engaging with HS Modified by 3-O-Sulfate (3-OS) Have Been Difficult to Determine. in Particular, the Context in Which the 3-OS Group Needs to Be Presented for Binding is Largely Unknown. We Describe Herein a Modular Synthetic Approach that Can Provide Structurally Diverse HS Oligosaccharides with and Without 3-OS. the Methodology Was Employed to Prepare 27 Hexasaccharides that Were Printed as a Glycan Microarray to Examine Ligand Requirements of a …


Water Absorption Enhancement Of Sodium Poly Acrylate And Poly(2-Acrylamido-2-Methylpropane Sulphonic Acid) Based Hydrogel Mixtures, Sohair A. Darwish, Ibrahim M. Ibrahim, Nasser Y. Mostafa, Mostafa A. Radwan, Mohamed A. Sadek, Hany A. Elazab Jan 2021

Water Absorption Enhancement Of Sodium Poly Acrylate And Poly(2-Acrylamido-2-Methylpropane Sulphonic Acid) Based Hydrogel Mixtures, Sohair A. Darwish, Ibrahim M. Ibrahim, Nasser Y. Mostafa, Mostafa A. Radwan, Mohamed A. Sadek, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

Introduction: Hydrogels are hydrophilic polymers which are cross-linked to form three-dimensional structures, which can absorb, swell and retain huge amounts of water or aqueous fluids. Objective: This paper reports the preparation and characterization of Poly (2-Acrylamido-2-Methylpropane Sulphonic Acid) (PAMPS) hydrogel with different crosslinking intensities. Methodology: 2-Acrylamido-2-methylpropane sulfonic acid (AMPS) monomer was purchased from Alfa Aesar Company as reagent grade. It was used as received (>98% purity) without any further purification. PAMPS hydrogel was prepared by free radical crosslinking solution polymerization of AMPS in water at room temperature under a nitrogen blanket in cylindrical glass tubes. The characteristics of the …


Better Heat And Power Integration Of An Existing Gas-Oil Plant In Egypt Through Revamping The Design And Organic Rankine Cycle, Mamdouh A. Gadalla, Alaa Elmasry, Ibrahim Alhajri, Fatma H. Ashour, Hany A. Elazab Jan 2021

Better Heat And Power Integration Of An Existing Gas-Oil Plant In Egypt Through Revamping The Design And Organic Rankine Cycle, Mamdouh A. Gadalla, Alaa Elmasry, Ibrahim Alhajri, Fatma H. Ashour, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

Objective: The current study aims mainly to Maximize Condensate Recovery (NGLs), focusing on a gas processing train of Gas-Oil Separation Plant (GOSP) located in Egypt with a capacity of 4,230 kmole/h. Methods: The research study accounts for the constraint of Reid Vapor Pressure (RVP) specification, which makes the storage in floating roof tanks is of a great risk. The study proposes the installation of the cryogenic train that recovers condensates (C4+). This train comprises of compression unit, expansion unit, three-phase separators and a re-boiled absorber. The problem of RVP will no longer exist because of the re-boiled absorber achieving RVP …


Equilibrium And Kinetic Study On The Biosorption Of Trypan Blue From Aqueous Solutions Using Avocado Seed Powder, Tamer T. El-Idreesy, Omar Khoshala, Amin Firouzi, Hany A. Elazab Jan 2021

Equilibrium And Kinetic Study On The Biosorption Of Trypan Blue From Aqueous Solutions Using Avocado Seed Powder, Tamer T. El-Idreesy, Omar Khoshala, Amin Firouzi, Hany A. Elazab

Chemical and Biochemical Engineering Faculty Research & Creative Works

This research aims to investigate the removal of trypan blue dye from aqueous solutions by employing ground avocado seeds powder, a low-cost biowaste adsorbent (biosorbent), under various experimental conditions. The effect of contact time, initial dye concentration, and adsorbent dose on dye removal were studied. The experimental kinetic data were fitted to pseudo-first order and pseudo-second-order kinetic models. Results imply that adsorption of trypan blue on the avocado seed adsorbent nicely followed the pseudo-second-order kinetic model. Equilibrium isotherms were analyzed by Langmuir and Freundlich isotherms, where Langmuir isotherm described the isotherm data with a high-correlation coefficient (R2=0.9948) closer to unity, …


Enhancing Emulsion Liquid Membrane System (Elm) Stability And Performance For The Extraction Of Phenol From Wastewater Using Various Nanoparticles, Faris H. Al-Ani, Qusay F. Alsalhy, Muthanna H. Al-Dahhan Jan 2021

Enhancing Emulsion Liquid Membrane System (Elm) Stability And Performance For The Extraction Of Phenol From Wastewater Using Various Nanoparticles, Faris H. Al-Ani, Qusay F. Alsalhy, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Emulation liquid membrane (ELM) technology has recently garnered attention as an efficient alternative for separating pollutants, but it faces the problem of instability during the application, as well as emulsion breaking. With this in mind MgO, Al2O3, and three magnetic Fe2O3 nanoparticles (of different sizes) were utilized to fabricate a new Pickering ELM system (PELM). The extraction efficiency of phenol from aqueous solution by PELM was studied with different NPs types and with different phenol concentrations (1,000; 500; 100; and 50 ppm). It was found that the type of NPs and concentration of …