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Articles 1 - 14 of 14
Full-Text Articles in Engineering
Seeding Effects Of Submicron Caal-No3 Ldh Particles On The Hydration And Properties Of Portland Cement And Sulfoaluminate Cement Pastes, Sukanta K. Mondal, Monday Uchenna Okoronkwo
Seeding Effects Of Submicron Caal-No3 Ldh Particles On The Hydration And Properties Of Portland Cement And Sulfoaluminate Cement Pastes, Sukanta K. Mondal, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
Layered Double Hydroxide (LDH) Is Reported To Improve The Durability Of Concretes, Primarily Due To Its Ability To Exchange Anionic Species, Including Chloride, Which Is Implicated In Corrosion-Driven Durability Issues. However, There Is No Comprehensive Study Investigating The Effect Of LDH On The Properties Of Different Cement Systems At Both Early And Mature Ages. In This Study, The Early Age And Mature Age Properties Of Portland Cement (OPC) And Calcium Sulfoaluminate (CSA) Cement Pastes Seeded With Submicron-Sized Calcium Aluminum-NO3 LDH (CaAl-NO3 LDH) Were Investigated. The Effects Of The 1–5%mass Dosage Of LDH On The Hydration Of Both Cement Systems Were …
Assessing Hydrolysis Performance Of Ce(Oh)4@Pim-1 Composites Functionalized With Amidoxime, Aldoxime, And Carboxylate Groups Toward Dimethyl 4-Nitrophenylphosphonate, A Nerve Agent Simulant, Peter O. Aina, Sukanta K. Mondal, Ali A. Rownaghi, Fateme Rezaei
Assessing Hydrolysis Performance Of Ce(Oh)4@Pim-1 Composites Functionalized With Amidoxime, Aldoxime, And Carboxylate Groups Toward Dimethyl 4-Nitrophenylphosphonate, A Nerve Agent Simulant, Peter O. Aina, Sukanta K. Mondal, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
In recent years, significant attention has been directed toward evaluating the reactivity of diverse polymers to gauge their catalytic activity against hazardous chemicals. Among these polymers, pim-1 has emerged as an exceptional candidate due to its noteworthy attributes including high surface area, excellent solubility, and the capability to fine-tune the nitrile functional groups along its polymeric backbone. In this study, we explored the impact of different functional groups, such as amidoxime (ax), aldoxime (ox), and carboxylate (cooh), on the degradation of dimethyl 4-nitrophenylphosphonate (dmnp) in comparison to pure pim-1 and their respective ce(oh)4-loaded polymer composites. Remarkably, the pim-1-ax analog exhibited …
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Highly Efficient Dopamine Sensing With A Carbon Nanotube-Encapsulated Metal Chalcogenide Nanostructure, Harish Singh, Jiandong Wu, Kurt A.L. Lagemann, Manashi Nath
Chemical and Biochemical Engineering Faculty Research & Creative Works
Carbon nanotube-encapsulated nickel selenide composite nanostructures were used as nonenzymatic electrochemical sensors for dopamine detection. These composite nanostructures were synthesized through a simple, one-step, and environmentally friendly chemical vapor deposition method, wherein the CNTs were formed in situ from pyrolysis of a carbon-rich metallo-organic precursor. The composition and morphology of these hybrid NiSe2-filled carbon nanostructures were confirmed by powder X-ray diffraction, Raman, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy images. Electrochemical tests demonstrated that the as-synthesized hybrid nanostructures exhibited outstanding electrocatalytic performance toward dopamine oxidation, with a high sensitivity of 19.62 μA μM-1 cm-2, low detection limit, broad linear …
Challenges And Opportunities In Electrification Of Adsorptive Separation Processes, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei
Challenges And Opportunities In Electrification Of Adsorptive Separation Processes, Abdullah Al Moinee, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
A global energy transition from fossil-based to renewable-based systems requires advancements in various energy sectors. Current chemical separation processes are quite energy-intensive and require significant advancement to make this transition happen. In the energy transition era, reducing the dependency of separation processes on fossil-based thermal energy seems inevitable for transitioning smoothly and meeting the stringent timelines. In particular, adsorption-based separation processes have the potential to be fully electrified through innovative strategies in developing stimuli-responsive adsorbents and swing processes. In this review, we discuss the recent efforts in electrification of adsorption processes and provide an overview of emerging materials and processes. …
Pd-Modified Cuo-Zno-Al2o3 Catalysts Via Mixed-Phases-Containing Precursor For Methanol Synthesis From Co2 Hydrogenation Under Mild Conditions, Xiao Fan, Kaiying Wang, Xiaoqing He, Shiguang Li, Miao Yu, Xinhua Liang
Pd-Modified Cuo-Zno-Al2o3 Catalysts Via Mixed-Phases-Containing Precursor For Methanol Synthesis From Co2 Hydrogenation Under Mild Conditions, Xiao Fan, Kaiying Wang, Xiaoqing He, Shiguang Li, Miao Yu, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
A series of palladium-modified (Pd-modified) CuO-ZnO-Al2O3 (CZA) catalysts with various Pd loadings (0.3 wt% to 2.4 wt%) were prepared using the wetness impregnation method, on two CZA supports with different structures that are CZA-aged precursor composed of a mixture of zincian-malachite and hydrotalcite-like phases (CZA-zH), and CuO-ZnO-Al2O3 metal oxide nanoparticles (CZA-MO). Enhancement on catalytic activity can be observed on both Pd-modified CZA catalysts in a temperature range of 180–240 °C for methanol synthesis via CO2 hydrogenation. Pd/CZA-zH catalysts exhibited a more efficient and stable production of methanol at a relatively low reaction temperature of 180 °C for 100 hrs. of …
Advancement In Heavy Oil Upgrading And Sustainable Exploration Emerging Technologies, Youssef Yatimi, Jihane Mendil, Meena Marafi, Ahmed Alalou, Muthanna H. Al-Dahhan
Advancement In Heavy Oil Upgrading And Sustainable Exploration Emerging Technologies, Youssef Yatimi, Jihane Mendil, Meena Marafi, Ahmed Alalou, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Upgrading heavy oil is a subject of high importance for fossil fuel industry due to the rapid depletion of light oil reservoirs and the consequent increased demand for upgrading heavy oil. In this review, the advancement made in heavy oil upgrading and the proposed sustainable emerging technologies dedicated to heavy oil processing have been discussed in a comprehensive and informative manner with consideration to the encountered associated with properties of heavy oil including its significant content of undesirable large molecular weight hydrocarbons, its high viscosity, and its elevated impurity level. The shortcomings of conventional crude oil upgrading technologies are outlined, …
Physio-Chemical Modifications To Re-Engineer Small Extracellular Vesicles For Targeted Anticancer Therapeutics Delivery And Imaging, Rahmat Asfiya, Lei Xu, Anjugam Paramanantham, Kuanysh Kabytaev, Anna Chernatynskaya, Grace Mccully, Hu Yang, Akhil Srivastava
Physio-Chemical Modifications To Re-Engineer Small Extracellular Vesicles For Targeted Anticancer Therapeutics Delivery And Imaging, Rahmat Asfiya, Lei Xu, Anjugam Paramanantham, Kuanysh Kabytaev, Anna Chernatynskaya, Grace Mccully, Hu Yang, Akhil Srivastava
Chemical and Biochemical Engineering Faculty Research & Creative Works
Cancer theranostics developed through nanoengineering applications are essential for targeted oncologic interventions in the new era of personalized and precision medicine. Recently, small extracellular vesicles (sEVs) have emerged as an attractive nanoengineering platform for tumor-directed anticancer therapeutic delivery and imaging of malignant tumors. These natural nanoparticles have multiple advantages over synthetic nanoparticle-based delivery systems, such as intrinsic targeting ability, less immunogenicity, and a prolonged circulation time. Since the inception of sEVs as a viable replacement for liposomes (synthetic nanoparticles) as a drug delivery vehicle, many studies have attempted to further the therapeutic efficacy of sEVs. This article discusses engineering strategies …
Rab7 Deficiency Impairs Pulmonary Artery Endothelial Function And Promotes Pulmonary Hypertension, Bryce Piper, Srimathi Bogamuwa, Tanvir Hossain, Daniela Farkas, Lorena Rosas, Adam C. Green, Geoffrey Newcomb, Nuo Sun, Jose A. Ovando-Ricardez, Jeffrey C. Horowitz, Aneel R. Bhagwani, Hu Yang, Tatiana V. Kudryashova, Mauricio Rojas
Rab7 Deficiency Impairs Pulmonary Artery Endothelial Function And Promotes Pulmonary Hypertension, Bryce Piper, Srimathi Bogamuwa, Tanvir Hossain, Daniela Farkas, Lorena Rosas, Adam C. Green, Geoffrey Newcomb, Nuo Sun, Jose A. Ovando-Ricardez, Jeffrey C. Horowitz, Aneel R. Bhagwani, Hu Yang, Tatiana V. Kudryashova, Mauricio Rojas
Chemical and Biochemical Engineering Faculty Research & Creative Works
Pulmonary arterial hypertension (PAH) is a devastating and progressive disease with limited treatment options. Endothelial dysfunction plays a central role in the development and progression of PAH, yet the underlying mechanisms are incompletely understood. The endosome-lysosome system is important to maintain cellular health, and the small GTPase RAB7 regulates many functions of this system. Here, we explored the role of RAB7 in endothelial cell (EC) function and lung vascular homeostasis. We found reduced expression of RAB7 in ECs from patients with PAH. Endothelial haploinsufficiency of RAB7 caused spontaneous pulmonary hypertension (PH) in mice. Silencing of RAB7 in ECs induced broad …
Reactive Capture And Conversion Of Co2 Into Hydrogen Over Bifunctional Structured Ce1-Xcoxnio3/Ca Perovskite-Type Oxide Monoliths, Khaled Baamran, Shane Lawson, Ali A. Rownaghi, Fateme Rezaei
Reactive Capture And Conversion Of Co2 Into Hydrogen Over Bifunctional Structured Ce1-Xcoxnio3/Ca Perovskite-Type Oxide Monoliths, Khaled Baamran, Shane Lawson, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Carbon capture, utilization, and storage (CCUS) technologies are pivotal for transitioning to a net-zero economy by 2050. In particular, conversion of captured CO2 to marketable chemicals and fuels appears to be a sustainable approach to not only curb greenhouse emissions but also transform wastes like CO2 into useful products through storage of renewable energy in chemical bonds. Bifunctional materials (BFMs) composed of adsorbents and catalysts have shown promise in reactive capture and conversion of CO2 at high temperatures. In this study, we extend the application of 3D printing technology to formulate a novel set of BFMs composed …
Retraction Notice To “High Density Conductive Lifepo4 Cathode With Enhanced High-Rate And High Temperature Performance” [Mater. Chem. Phys. 232 (2019) 367–373, (S0254058419304110), (10.1016/J.Matchemphys.2019.05.014)], David Seung-Hyun Lee, Won Bin Im, Xinhua Liang
Retraction Notice To “High Density Conductive Lifepo4 Cathode With Enhanced High-Rate And High Temperature Performance” [Mater. Chem. Phys. 232 (2019) 367–373, (S0254058419304110), (10.1016/J.Matchemphys.2019.05.014)], David Seung-Hyun Lee, Won Bin Im, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
This article has been retracted: please see Elsevier Policy on Article Withdrawal (https://www.elsevier.com/about/policies/article-withdrawal). This article has been retracted at the request of the Editor-in-Chief. The Editor-in-Chief found that the corresponding author of this article submitted the manuscript to the journal without the consent of the two individuals named as "co-authors", using invented email addresses to impersonate them. In addition, based on the raw materials presented to the journal by the second co-author and the Editor-in-Chief's own investigation, the Editor-in-Chief believes that some results in the paper are fabricated. Based on these two findings, the Editor-in-Chief has decided to retract the …
Gas-Phase Adsorption Of Dimethyl Methylphosphonate Over Ce(Oh)4@Pim-1 Composites Prepared Via Matrix Incorporation And Surface Coating Methods, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Gas-Phase Adsorption Of Dimethyl Methylphosphonate Over Ce(Oh)4@Pim-1 Composites Prepared Via Matrix Incorporation And Surface Coating Methods, Sukanta K. Mondal, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
This Study Investigated the Potential of Polymer of Intrinsic Microporosity (PIM-1) and Ce(OH)4@PIM-1 Composites for Adsorption of the Nerve Agent Simulant, Dimethyl Methylphosphonate (DMMP). through Experimental Investigations It Was Demonstrated that These Composite Adsorbents Exhibit Excellent Gas-Phase DMMP Adsorption Performance, with High Uptake Capacities and Relatively Fast Kinetics. This Study Further Examined the Effect of Two Composite's Preparation Methods, Namely Matrix Incorporation and Surface Coating, on the DMMP Adsorption Performance of Ce(OH)4@PIM-1. the Results Revealed that Coating of Ce(OH)4 on the PIM-1 Surface Gives Rise to Faster Adsorption Kinetics Than its Incorporation into the Polymer Matrix at Fixed 30 Wt …
Flow Regimes In Bubble Columns With And Without Internals: A Review, Ayat N. Mahmood, Amer A. Abdulrahman, Laith S. Sabri, Abbas J. Sultan, Hasan Shakir Majdi, Muthanna H. Al-Dahhan
Flow Regimes In Bubble Columns With And Without Internals: A Review, Ayat N. Mahmood, Amer A. Abdulrahman, Laith S. Sabri, Abbas J. Sultan, Hasan Shakir Majdi, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Hydrodynamics characterization in terms of flow regime behavior is a crucial task to enhance the design of bubble column reactors and scaling up related methodologies. This review presents recent studies on the typical flow regimes established in bubble columns. Some effort is also provided to introduce relevant definitions pertaining to this field, namely, that of "void fraction" and related (local, chordal, cross-sectional and volumetric) variants. Experimental studies involving different parameters that affect design and operating conditions are also discussed in detail. In the second part of the review, the attention is shifted to cases with internals of various types (perforated …
Liposomes-Encapsulating Double-Stranded Nucleic Acid (Poly I:C) For Head And Neck Cancer Treatment, Vidit Singh, Anna Chernatynskaya, Lin Qi, Hsin Yin Chuang, Tristan Cole, Vimalin Mani Jeyalatha, Lavanya Bhargava, W. Andrew Yeudall, Laszlo Farkas, Hu Yang
Liposomes-Encapsulating Double-Stranded Nucleic Acid (Poly I:C) For Head And Neck Cancer Treatment, Vidit Singh, Anna Chernatynskaya, Lin Qi, Hsin Yin Chuang, Tristan Cole, Vimalin Mani Jeyalatha, Lavanya Bhargava, W. Andrew Yeudall, Laszlo Farkas, Hu Yang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Polyriboinosinic acid-polyribocytidylic acid (Poly I:C) serves as a synthetic mimic of viral double-stranded dsRNA, capable of inducing apoptosis in numerous cancer cells. Despite its potential, therapeutic benefits, the application of Poly I:C has been hindered by concerns regarding toxicity, stability, enzymatic degradation, and undue immune stimulation, leading to autoimmune disorders. To address these challenges, encapsulation of antitumor drugs within delivery systems such as cationic liposomes is often employed to enhance their efficacy while minimizing dosages. In this study, we investigated the potential of cationic liposomes to deliver Poly I:C into the Head and Neck 12 (HN12) cell line to induce …
Thermal Decomposition And Kinetic Parameters Of Three Biomass Feedstocks For The Performance Of The Gasification Process Using A Thermogravimetric Analyzer, Rania Almusafir, Joseph D. Smith
Thermal Decomposition And Kinetic Parameters Of Three Biomass Feedstocks For The Performance Of The Gasification Process Using A Thermogravimetric Analyzer, Rania Almusafir, Joseph D. Smith
Chemical and Biochemical Engineering Faculty Research & Creative Works
Thermogravimetric analysis (TGA) is a powerful technique and useful method for characterizing biomass as a non-conventional fuel. A TGA apparatus has been utilized to experimentally investigate the impact of biomass feedstock diversity on the performance of the gasification of hardwood (HW), softwood (SW) pellets, and refuse-derived fuel (RDF) materials. The solid conversion rate and the volatile species formation rate have been estimated to quantify the rates of devolatilization for each material. In addition, the combustion kinetic characteristics of the three biomass feedstocks were investigated using TGA at different heating rates, and a thermal kinetic analysis was conducted to describe the …