Engineering Commons^™

Transport Phenomena Of Copper Ions Through An Electromembrane, Ren-Fu Cheng

Theses

A separation process based on a new class of membrane ( the electromembrane ) was studied. Experiments were performed using three types of electromembrane to remove copper ions from aqueous solution. A Separation Cell Unit was designed and set up to investigate the transport of copper ions through the electromembranes under the influence of both an electric field and a concentration gradient. Fluxes achieved were much greater than those reported for other membrane processes, and the energy consumption was one half that of electrolytic deposition.

Scheduling Effects Of 5-(3,3-Dimethyl-1-Triazeno)Imidazole-4-Carboxamide (Dtic) And 1,3-Bis-Chloroethyl-1-Nitrosourea (Bcnu) On Mouse Melanoma Cells B16cl5, Gracie V. Coffey

Theses

DTIC and BCNU have been demonstrated to have enhanced chemotherapeutic effects in mice bearing Bl6 mouse melanoma cells. The order of administration seems to be important in maintaining optimum effects. This was shown is a study by Hill et al. (unpublished).

In the present study, mouse melanoma cells, Bl6CL4, were treated with either DTIC or BCNU. The drug was allowed to remain on the cells for 2, 3, or 4 days. The drug-containing media were then removed, the cells were washed and fresh medium was added. The cells were incubated in an atmosphere of 5% CO2 and 95% air at …

The Kinetics And Hepatotoxicity Of Benzyl Chloride Vapor In Rats, Hari V. Rao

Theses

Male Sprague Dawley rats (250g) were exposed to benzyl chloride vapor at a concentration of 220 ppm for 6 hours. During inhalation, the blood benzyl chloride concentration increased to reach a steady state level of 9-10 ug/ml between 4 and 6 hours of exposure. A small concentration of benzyl chloride (0.86 ug/ml) was present in the blood four hours after the termination of exposure. The absorption half life was 0.53 hours (0.39-0.81) and the elimination half life was l.12 hour (0.93-l.40).

The absorbed benzyl chloride was largely retained in the blood and some of it (0.22 ug/g) was sequestered into …

Improving The Capabilities Of The Chemical Engineering Simulation System (Chess) Computer Program, Thomas Zvolensky

Theses

Chemical process simulation programs have become an indispensable tool to chemical engineers in the preparation of heat and material balances, and energy conservation studies. Since the 1960's several dozen process simulators have been developed which are in use today within companies and through computer service bureaus. Due to advances in the areas of unit operation analysis and thermodynamic relations, these programs require periodic modification. This thesis describes the programming modifications made to the Chemical Engineering Simulation System (CHESS) version 2.0, computer program. This undertaking was considered warranted since no improvements have been made to CHESS since its release in 1971. …

Digitally Implemented Klapper-Kratt Fm Detector Using The Intel-292o Digital Signal Processor, Chang-Hwan Park

Theses

This thesis describes and analyses a digitally implemented FM detector, which is a new member of the family of FM detectors introduced by Drs. Klapper and Kratt.

The properties of the new detector are low delay, excellent sensitivity, extreme linearity, and compatibility of components with integrated circuit technology.

A working model is implemented by adapting FIR digital s signal processing methods, and is realized using the Single-Chip Digital Signal Processor Intel-2920 which is comprised of micro-processor, scratch-pad data RAMs, program store EPROMs, A/D and D/A conversion circuitry, and I/O circuitry.

The performance of the working model shows very good linearity …

An Analysis Of The Heating And Densification Process During Rotational Molding Of A Thermoplastic Powder In A Uniaxially Rotating Cylindrical Cavity, Floyd Steven Ribe

Dissertations

This dissertation presents the results of an experimental and theoretical investigation of the heating and densification portion of the rotational molding process in a uniaxial, cylindrical mold.

A thorough literature survey is included which reviewed past analysis of the rotational molding process and other areas that assisted in understanding of the process.

The results presented in this dissertation included an analysis of the densification process by use of Scanning Electronic Microscope (SEM) photography producing intermediate correlations between the physical properties of the densifying material and neck radius of adjacent coalescing spheres. In addition, a hybrid experimental procedure coupled with a …

Reactions Of Hydrogen With Chloroform And Trichloroethylene At High Temperatures, Burhan Mahmood

Theses

The reactions of chloroform and trichloroethylene with hydrogen in the temperature range 550 to 1000°C were studied using tubular flow reactors of varying diameters. The residence time range was from 0.05 to 3.0 seconds.Two different concentrations of the chlorinated species were used, each with hydrogen in large excess. Flat temperature profiles (+/- 5°C) were achieved over 80 to 85 per cent of the 45 cm long reaction zone, with inlet gases preheated to about 400°C.

No chlorinated hydrocarbons, products or reactants were observed at /above 850°C. The major products at these temperatures were C₂H₂, C_{2 …}

Conversion And Kinetics In The Reaction Of Chloroform With Water Vapor At High Temperatures, Chii-Guang Hwang

Theses

This is an experimental study on thermolytic reactions of chloroform with excess water vapor where kinetic parameters are determined and complete product analysis made at atmospheric pressure over a temperature range from 550to 1050°C. In this study, water vapor was introduced as a reactant to convert chlorine in chlorocarbons to stable HCl which is an easily neutralized end-product and thereby completely destroy chloroform. Substantial amounts of thermodynamically stable species: HCl, CO, CO₂, C(s) etc. were observed as products.

The reaction was studied in a 46cm tubular flow reactor mounted in a furnace that had three independently temperature-controlled heating …

A Comparison Of The Biodegradation Of Phenol And O-Chlorophenol Using A Municipal Mixed Liquor And Three Commercial Microbial Preparations, Nigel P. Mcmullen

Theses

The biodegradation of phenol and O-chlorophenol was studied in six-liter batch reactors, using a municipal mixed liquor (from the Livingston, NJ treatment plant) that had not previously been exposed to either of the substrates. In addition, three commercial microbial preparations: BI-CHEM (Sybron), Hydrobac (Polybac), and LLMO (General Environmental Science), were tested alone and in combination with the municipal mixed liquor.

It was found that the municipal mixed liquor performed significantly better than any of the commercial preparations by themselves. When the commercial preparations were mixed with the municipal mixed liquor in a ratio of 1:10 it was found that the …

Mode Of Communication And The "Risky Shift" : A Controlled Experiment With Computerized Conferencing And Anonymity In A Large Corporation, Computerized Conferencing & Communications Center, Starr Roxanne Hiltz, Murray Turoff, Kenneth Johnson

Computerized Conferencing and Communications Center Reports

Peer groups of five managers in a large company with a well developed corporate culture engaged in choice dilemma tasks using three modes of communication: face-to-face, synchronous computerized conferences with regular names, and synchronous computerized conferences with assigned pen names. This is the final technical report on the experiment, including documentation of all procedures, and reports of the tests of all hypotheses, including those which were not supported.

Choice behavior varied by problem and mode of communication. On a problem related to a major decision on the future of the company, conservative choices and conservative shifts dominated. On two choice …

Mathematical Simulation Of Proteins Separation In A Packed Bed, Jing James Huang

Dissertations

The generalized adsorption models are developed to simulate the unsteady state mass transfer behavior in a packed column. Based on the nature of adsorbent particles, the adsorption models may be classified into two categories: (1) the surface adsorption model, (2) the pore diffusion model. In the first model, it is assumed that the internal diffusion is negligible, and the adsorption rate is determined by external diffusion and surface adsorption. In the second model, the effect of internal diffusion is considered as significant as that of external diffusion. For both models, the effect of axial dispersion in fluid phase is emphasized. …

Mathematical Modeling Of Carrier Mediated Mass Transfer Through Liquid Membrane Systems, Keng Chao Wang

Dissertations

Dispersed liquid membrane systems are double emulsion drops. Two immiscible phases are separated by a third phase which is immiscible with the other two phases. The liquid membrane systems were classified into three types: (1) carrier mediated mass transfer, (2) mass transfer with reaction in the receiving phase, (3) mass transfer without any reaction involved. Copper extraction, phenol removal and solvent extraction were used as typical examples for each type of the membrane systems in the derivation of their mathematical models. Models with or without the consideration of film resistances were developed and compared. The models developed in this study …

X-Ray Fluorescence Spectroscopic Analysis Of Coal Ash, George Patrick Watson

Theses

Several coal ashes and prepared mixtures were analyzed by x-ray fluorescence spectroscopy. Various techniques were studied to determine the most reliable procedure for quantitatively estimating, from fluorescent peak intensities, the concentrations of seven major oxides typically present in the ash. These ashes were analyzed with only minimal sample preparation. In order to determine the self-consistency of the procedure, several mixtures of known composition were prepared containing the major elements present in an ash.

Because of inter-element absorption and enhancement effects, several computational techniques were used to calculate composition from spectrum peak intensities. The method that yielded the most accurate estimates …

Stability Of Bicomponet Polymeric Liquids In Poiseuille Flow, Chin-Chang Jeng

Theses

Polymer processing, involving two or more components, has become more popular recently in industrial plants. However, product Quality is affected very much by the fluid stability. Some theoretical and experimental results concerning Newtonian and non-Newtonian flow in rectangular coordinates, have been published, and the fluid-fluid interfaces were observed to be unstable by some researchers.

In this paper, the linear stability of bicomponent non-Newtonian fluids flowing in a cylindrical tube was investigated by using the Ellis model. Only the very long wave and the axisymmetric disturbances were considered. The Ellis zero-shear-rate viscosity ratio, m( = η02 / η01 )destabilizing. The half-zero-shear-rate-viscosity …

Homogenous Reaction Kinetics Of Reduction Of Sulfur Dioxide, Satyanarayana Manthani

Theses

Homogeneous reduction of sulfur dioxide by carbon monoxide was investigated in the temperature range between 700 and 1000°C, initial sulfur dioxide concentration of about 3000 ppm, typical of a flue gas from coal fired power plants, and excess carbon monoxide concentration, in a 12 mm O.D. quartz tubular reactor. Over ninty percent reduction of sulfur dioxide was obtained at temperatures above 900°C and space times of the order of about 3.5 seconds. Substantial carbonyl sulfide was also produced.

A Comparison Of The Biodegradation Of Nitrobenzene, 1-Butanol, And 2,4-Dichlorphenoxyacetic Acid Using A Municipal Mixed Liquor And Three Commercial Bacterial Preparations, Salvatore P. Salerno

Theses

The biological degradation of nitrobenzene, 1-butanol, and 2,4-dichlorophenoxyacetic acid (2,4-D) was studied in aerated 6 liter batch reactors using activated sludge from the Livingston, NJ wastewater treatment plant-- by itself and in a 10:1 by volume mixture with each of three commercial bacterial preparations: Hydrobac, BI-CHEM DC-1006/7, and Liquid Live Microorganisms (LLMO). Air stripping and adsorption were determined to be insignificant removal mechanisms for the three compounds studied. None of the bacterial mixtures were able to degrade 10 ppm nitrobenzene to any significant extent. A small but noticeable improvement in degradation rates occurred when the Livingston sludge was mixed with …

The Biodegradation Of Phenol And O-Chlorophenol Using Activated Sludge Bacteria, Jeffery Colish

Theses

The biological degradation of phenol up to 500 ppm and 0-chlorophenol up to 40 ppm was studied in an aerated 4.0 liter hatch reactor using activated sludge bacteria from the Livingston, N.J. wastewater treatment plant. From the concentration versus time data, kinetic rate constants were determined for phenol (@ 100 ppm) and o-chlorophenol (@ 20 ppm and 40 ppm). Air stripping was determined to be an insignificant removal mechanism for the compounds studied.

It was noted that the acclimation times decreased with repeated exposure to a particular concentration of phenol or o-chlorophenol, and that the activated sludge bacteria first had …

Microbial Characteristics Of An Activated Sludge And Three Commercial Preparations After Exposure To Phenolics, Laurie Gneiding

Theses

The biological characteristics of four microbial mixtures were examined after successive exposure to phenol and 2-chlorophenol at room temperature. One of the microbial mixtures was an activated sludge from the Livingston, NJ municipal wastewater treatment plant. The other three mixtures were commercial preparations sold by Polybac Corp.(Hydrobac), Sybron Corp. (BI-CHEM DC 1006/1007), and General Environmental Sciences(LLMO).

The characteristics examined were relative counts and species of gram negative/gram positive bacteria, yeast and fungi, protozoa, and higher organisms. For the gram negative bacteria and yeasts, culturing techniques and diagnostic tubes were used to determine the predominant species. Biochemical tests were done on …

An Experimental Investigation Of The Kinetics And Thermal Properties Of Poly(Ethylene) Terephthalate And Its Related Di-Acid Modified Copolymers, Satish Baliga

Theses

Poly(ethylene) Terephthalate , PET, is synthesized from purified Bis-hydroxyethyl Terephthalate,(BHET), in the presence of antimony oxide catalyst. Rate constant for the polycondensation reaction, based on a second order kinetic model is found to be 152.4/mol/hr.

A new modified polyester Polyethylene Adipic Terephthalate (PEAT) is synthesized from BHET and adipic acid. The effect of adipic acid content in the copolymer,on the rate of polycondensation is studied. Adipic acid is shown to improve the activity of the polymer chain ends thereby increasing the apparent reaction rate constants.

The modified polyesters are observed to melt at a lower temperature than PET. Moreover, the …

Synthesis Of Trimethylpropane-Tolylene-2,4-Diisocyanate Adduct And Its Blocked Monomers, Farhad Forohar

Theses

A trimethylolpropane adduct of tolylene-2,4-diisocyanate (TMP-TDI) was prepared by reaction in a heterogeneous solvent system. The isocyanate functional groups of the TMP-TDI adduct were blocked with the following blocking agents: p-cresol, eugenol, o-chlorophenol, and one to one mole ratio of mixtures of 2-hydroxyethyl methacrylate (HEMA) and each of the three preceding blocking agents. A sample of TMP-TDI adduct blocked with only HEMA was also prepared. The products were characterized by melting point, infrared spectroscopy, and elemental analysis. Monomers of TMP-TDI blocked with 50% HEMA and 50% blocking agents may be very useful as dental restorative materials.

Mixing Effect On Chemical Reaction In Liquid Phase, Ming-Teh Hsu

Dissertations

Mathematical models for the mixing phenomenon are proposed in this study. First model deals Newtonian and non-Newtonian fluid without chemical reaction. The new terminology " degree of mixing " is define in this model for the time-dependency of mixing toward its completeness. The velocity profile and boundary conditions are given, then the degree of mixing can be calculated by the mathematical model. The degree of mixing is influenced by fluid motion and it is function of time.

Second model deals with first-order reaction effected by mixing. A mean fractional conversion is defined to investigate the rate of bhemical reaction. Results …

Simulation Of Particle Size Distribution In Continuous Emulsion Polymerization Through A Modified Population Balance Approach, Ying-Yuh Lu

Theses

A detailed mathematical model for particle size distribution in continuous emulsion polymerization of styrene and vinyl acetate is proposed on the basis of the population balance in the presence of several kinetic and mass transfer processes. This study is limited to the Smith-Ewart case II, which assumes instantaneous free radical termination within polymer particles. Radical desorption mechanism from polymer particles is included in the model and the desorption rate is formulated from the diffusion theory which suggests that the rate coefficient should be inversely proportional to the surface area of polymer particles.

Mathematical Modeling Of Unsteady State Photo-Polymerization, Rong-Fa Liang

Dissertations

Mathematical modeling of unsteady state photopolymerization in an isothermal batch reactor has been investigated. An analytical solution of the distribution of active polymers as a function of reaction time has been determined. It is verified that the quasi-stationary state approximation is valid in the photopolymerization process.

The free radical polymerization of styrene is forced periodically by on-off UV light regulation to the reactor. The effect of operating condition, the ratio of light-off period to light on/off period, on the polydispersity and molecular weight distribution are theoretically and numerically investigated. Significant broadening on molecular weight distribution can be obtained during the …

The Effects Of Pressure On The Kinetics And Mechanisms Of The Bod Reaction, Peter Sereico

Dissertations

The research was concerned with the kinetics and mechanisms of BOD reduction due to pressurization. The initial investigations involved attempts to reproduce and interpret the results of previous investigators. Thereafter, actual wastewater samples were pressurized and changes in the wastewater characteristics were analyzed and recorded. Based on the findings, possible mechanisms for creating the changes noted were proposed.

To test the mechanisms considered, samples of pure compounds were prepared and pressurized. The results of this analysis eliminated all of the mechanisms but the actual one. The mechanism responsible for changes in BOD profile under pressure conditions is the hydrolysis of …

Mathematical Modeling Of Distillation Operation From Non-Equilibrium Approach, Wen-Dow Pan

Dissertations

A new method for mathematical modeling of a distillation operation from non-equilibrium approach has been studied. The primary purpose of the study was to develop a model to simulate the mechanism of mass transfer between a continuous phase and the bubbles of a dispersed phase in a distillation column. The second major purpose of this work was to utilize and test the model of estimating the tray efficiency.

Distillation was considered to be purely a mass transfer process, where the less volatile component is transferred from vapor to liquid phase, and the more volatile component from liquid to vapor phase. …

Use Of An Optical Probe To Measure Bubble Characteristics In Gas Fluidized Beds, Thomas Tai-Pai Chu

Dissertations

A novel optical probe has been developed and used for on-line monitoring of the bubble characteristics in a three-dimensional gas fluidized bed. The probe sensor has a major dimension of 1.8 cm, and contains an LED and a photo-cell separated by a gap of 2.5 mm. Coupled with a non-inverting comparator circuit with hysteresis as a noise filter, the probe has been very effective in characterizing the size distribution, shape and velocity of gas bubbles.

A 96 liter rectangular fluidized bed was used, containing glass beads with a size fraction of 355μ to 250μ. Air was the fluidizing medium, with …

Three Studies On Airborne Polycyclic Aromatic Hydrocarbons, Carol Sophia Eveleens

Theses

Three studies have been conducted on polycyclic aromatic hydrocarbons found on airborne particulate matter. The first investigation involves the determination of fly ash "activity" in the reaction of two PAHs adsorbed on its surface. Mass spectrometry is used to monitor the exchange of hydrogen and deuterium atoms between anthracene and anthracene-d10. The results indicate that some fly ashes exhibit "activity" in the reactions of PAHs adsorbed on its surface. The second investigation involves the determination of cyclopenta[cd]pyrene (CcdP) and benzo[ghi]flouranthene (BghiF) on samples of airborne particulate material collected from two automobile traffic tunnels. Glass capillary gas chromatography with a precolumn …

Calibration Of Flame Ionization Detector For Chlorinated Hydrocarbons, Nahid Jabalameli

Theses

Relative Responses and Calibration Factors were developed for several volatile organic (mostly chlorinated) priority pollutant species in order to use one single stable compound (e.g.Benzene) for daily instrument calibration. This would replace the procedure of using a standard mixture of target compounds (25-35). This is of particular advantage because the standard mixture may not have all species stable or may show loss of some components relative to others due to wall adsorption in the standard (compressed gas) stainless steel cylinder.

The use of a single standard species was made possible by developing "accurate" relative response and calibration factors of all …

Characterization Of Tdi-Hema Homopolymer Prepared Via An Immiscible Solvent System. Synthesis And Investigation Of Oligodichloroketene, Manuel Montero

Theses

The objective of this thesis has been divided in two parts.

The first part is subdivided into two areas. First a "Universal" calibration curve for gel permeation chromatography (GPC) was construc-ted using different molecular weight standards of PMMA and MMA-HEMA co-polymers. By measuring the viscosity of the different molecular weight solutions and calculating the Vr, (retention volume), from GPC data, plots of In [ η ] Mw against Vr and In Mw against Vr are obtained. These curves can be used to obtain the molecular weight of any linear (not crosslinked) copolymer by simple measurements of viscosity and GPC data. …

Reliability Studies On Solid Tantalum Electrolytic Capacitors, Hamed Nassar

Theses

The primary objective of this thesis is to determine and analyze the failure mechanisms of solid tantalum capacitors, pinpoint the causes, and suggest the precautionary measures that prevent the occurrence of these failures. To achieve this goal, the study went in two directions, theoretical and experimental. The theoretical part-is a comprehensive review of the work -done on tantalum capacitors since 1960 up to date.

The experimental part of the study is a life test (1000 hours) of solid tantalum capacitors under humidity and high temperature. To avoid the misconception that could happen by investigating a particular manufacturer's product, units from …