Engineering Commons^™

Service Supply Chain Management : A Hierarchical Decision Modeling Approach, Roger Angel Solano-Cayama

Dissertations

A Service Supply Chain (SSC) may be described as a network of service provider facilities (in-house or outsourced), each of which is able to process one or more service tasks on an as needed basis. Two key characteristics of a SSC are (i) the business service is decomposable into several sequential tasks that can be processed by different service providers, and (ii) the primary capacity resource is skilled labor. SSCs are increasingly being developed by companies that experience a high variability of demand for their services (e.g., loan processing, analytical consulting services, emergency repair crews, claims processing, etc.). Typically, the …

Investigation Into The Acupuncture And Meridian System, Jingong Pan

Dissertations

The Meridian system conceived by the ancient Chinese has been described and referenced for more than a thousand years. The Meridians meaning paths are the main trunks that run longitudinally within the body. The Meridian system consists of about 400 acupuncture nodes and 20 Meridian channels connecting most of these points. It deals with the routing and distribution of certain signals that may affect physiological functions. It integrates meridians, tissues and organs into a complex system.

Initially, modeling of the acupuncture system is investigated. The physical effect of injecting an acupuncture needle at a node is suggested by an equivalent …

Modeling Edge Effects Of Mesa Diodes For Silicon Photovoltaics, Jesse S. Appel

Dissertations

A mesa diode has been modeled and its performance under dark and illuminated conditions has been simulated using a commercial finite element software package. These simulations have led to a determination of the self-consistent solution to the continuity equations for electrons and holes using the steady-state drift-diffusion model for carrier dynamics coupled with electric potential determined from Poisson's equation. The purpose of these simulations has been to determine the influence of edge conditions on the overall performance of mesa diodes under dark and illuminated conditions.

Mesa diode arrays are fabricated on crystalline silicon solar cells. They are an array of …

Probing Spin, Charge And Lattice Coupling In Manganites, Zhiqiang Chen

Dissertations

Complex oxides such as the manganites exhibit an intimate coupling of the electron spin, charge and lattice degrees of freedom. The characteristic feature of these materials is the existence of a ground state topology with many closely lying minima. The system can be switched from one minimum to another by the application of external parameters such as strain, temperature, magnetic fields, or electrical fields. These materials thus exhibit large responses to these external parameters and can be used as novel sensors in data storage and other applications. Understanding the couplings will have an impact on the fundamental science of highly …

Novel Polypropylene Based Microporous Membranes Via Spherulitic Deformation, Kuan-Yin Lin

Dissertations

A novel method for creating a microporous polypropylene membrane via spherulitic deformation is described. The microporous structure was generated by the combination of intra-spherulitic and inter-spherulitic deformations. Polypropylene was selected due to its unique cross-hatched lamellar morphology facilitating inter-spherulitic deformation. A precursor film with a spherulitic structure was made under low-stress melt processing condition. A tangential lamellae-rich spherulite was created and identified with a positive birefringence sign. A sequential annealing process improved the crystalline structure, and in particular the thickness of the tangential lamellae. The annealing process proved to be critical for initiating the inter-spherulitic deformation. The post-extrusion process conditions …

Ionic Liquids As Additives For Biodegradable Polyactic Acid, Ku-Il Park

Dissertations

In this study, two ionic liquids (IL) with different anions (decanoate, tetrafluoroborate) but with the same phosphonium based cation were evaluated as potential plasticizers and lubricants for polylactic acid (PLA) and also for their effects on its hydrolytic and thermal degradation. Both ILs at 5wt% were well dispersible and partly miscible with PLA as evidenced by scanning electron microscopy/energy dispersive x-ray scattering, SEMIEDX, and glass transition temperature, T_g, characterization, as well as from solubility parameters calculations.

The effects of the IL containing a decanoate anion were more pronounced on lubrication and degradation as evidenced by reduced melt viscosities …

Multi-Functional, Self-Sensing And Automated Real-Time Non-Contact Liquid Dispensing System, Qiong Shen

Dissertations

Liquid dispensing in the order of pico-liter has become more and more important in biology, electronics and micro-electronic-mechanical-system (MEMS) during the past two decades due to the rapid progress of researches on the deoxyribonucleic acid (DNA) microarray, compact and low-cost direct write technology (DWT), organic semiconductors and nano-particles.

The existing approaches, commercialized or experimental, to liquid dispensing in minute amounts have one common shortcoming: open loop control, i.e., they have no direct control on the quality of dispensed liquid. In contrast, the SmartPin has intrinsic self-sensing capability to not only control the process of liquid dispensing, but also the results …

Degradation Of Polylactic Acid In The Presence Of Microsize And Nanosize Fillers, Quyuan Zhou

Dissertations

Polylactide (PLA)-cationic (montmorillonite, MMT) and anionic (hydrotalcite, HT) clay micro- or nanocomposites based on semicrystalline and amorphous polymers and unmodified and organomodified as well as calcined or non-calcined clays at 5wt% concentration are produced by melt mixing. Depending on the clay type, presence of organomodifiers and calcination, micro- or nanocomposites are produced, as confirmed by XRD and SEM analysis.

Unfilled polymers and their composites are subjected to isothermal degradation in air at 180°C and 200°C. Degradation rate constants are calculated from novel equations incorporating IV. Results show that the thermal degradation rate constants of the amorphous PLA and its composites …

Synthesis And Characterization Of Atmospheric Pressure Chemically Vapor Deposited Aluminum, Sipeng Gu

Dissertations

This study investigates the use of atmospheric pressure chemical vapor deposition (APCVD) to produce high quality aluminum coatings for corrosion protection of steel. The coatings were produced through thermal decomposition of tri-isobutyl-aluminum (TIBAL) over the 275 to 300°C temperature range. Under optimal deposition conditions, growth rates as high as 1.2 um/min were achieved. X-ray photoelectron spectroscopy, auger electron spectroscopy, glow discharge optical emission spectroscopy and nuclear reaction analysis revealed that the coatings consisted essentially of pure aluminum (~99 at.%) with oxygen and carbon present as minor constituents. The coatings were characterized in terms of their morphological, structural, electrical, and mechanical …

A Two Dimensional Model Of Magnetic Field Assisted Assembly, Gaurev Devrani

Theses

A simplified model to simulate the magnetic field distribution for applications in magnetic field assisted assembly of semiconductor device structures, using commercial software (Vizimag), has been implemented. Solenoids have been utilized to serve as electromagnets that are responsible for the assembly process. Magnetic shielding techniques have been deployed to isolate the influence of one solenoid over another. These solenoids are used to move the devices that need to be placed in recesses within the substrate. The bottom of the devices and the recesses are coated with magnetic materials to facilitate the movement and placement of devices within the recesses in …

Precipitation Of Ultrafine Particles Using Liquid Antisolvent With Concentric Ultrasonic Nozzle And Subcritical Co2, Satya Chaitanya Kunchala

Theses

Nanotechnology has become more relevant in the pharmaceutical industry. Almost 40% of the drugs developed by pharmaceutical industries are poorly soluble in water which limits the bioavailability of these drugs in body fluids. Hence, it is necessary to reduce the particle size, which increases the interfacial surface area. This work focuses on micronization of class ii drug Griseofulvin which is poorly water soluble. Two processes namely, liquid antisolvent precipitation using ultrasonic nozzle and other process using subcritical CO₂ have been used to produce ultrafine particles of this drug.

In liquid antisolvent precipitation, a combination of ultrasound, polymer and surfactant …

Photoplethysmorgraph-Derived Respiration, Priyanka Pankaj Shah

Theses

Stress & Motivated Behavioral Institute (SMBI) has developed a research program to provide an objective evaluation of the physiological and neurocognitive impact of human electromuscular muscular interference (HEMI) devices in humans. The initial step is to understand their physiological impact, which is characterized by vital signs. Volunteers are recruited from HEMI training programs with the provision that data collection can not interfere with training. Thus, an ambulatory system was assembled. There are two main issues in the current ambulatory system, one of which is the reliability of the respiration signal obtained using a strain gauge respiration band, mainly due to …

Biomechanical Testing Of Upright Range Of Motion Versus Overhead Supine Range Of Motion, Linda Uko

Theses

Rehabilitation of an elbow, following injury, is not a well-studied subject. Clinically, there is not a general consensus on which recovery method is optimal for healing an unstable elbow. When dealing with medial collateral ligament deficiency, many authors have proposed several forearm positions that will yield proper healing of the unstable elbow. Some researchers believe that active mobilization of the elbow with the arm in a vertical position is a safe protocol for rehabilitation with the forearm oriented in a supine pronated position. It was also mentioned that the compressive forces due to the active mobilization of the arm will …

Classification Of Hand Held Shapes And Locations In Continuous Signing, Swetha Karri

Theses

Sign language for the deaf and hearing impaired replaces speech with manually produced signs. Each sign has been categorized as being combinations of handshape, movement, orientation, location, and facial expressions. Of the five sign parameters, this thesis focuses on classification of two of the main parameters, the hand shapes and locations, in continuous signing.

Since the nature of hand shapes is transient and not static, neural networks was used as a classifier for hand shapes. And since locations in sign language are defined by linguistic variables rather than by hard core position values, fuzzy logic was used as a classifier …

Experimental Investigation Of The Effect Of Sonication On The Precipitation Of Grieseofluvin By Impinging Jets, Ankit H. Patel

Theses

Almost 80% of drugs on the market are manufactured as solid dosage forms, such as tablets. Drug bioavailability increases as the particle size decreases and the surface area per unit volume of drug increases. Therefore, there is a keen interest by the pharmaceutical industry to develop techniques that can be used to manufacture particles of active pharmaceutical ingredients (API) in the nano/micro particle range. Impinging jets is one of the most promising techniques to do so.

In this work, a submerged impinging jet system coupled with an ultrasonic probe (sonicator) was used to precipitate Griseofulvin, a common, poorly water-soluble antifungal …

Design And Fabrication Of A Microneedle For The Implantation Of Floating Microstimulators, Faysal Ahmed

Theses

Neural prosthetics are used to stimulate any remaining functional nervous tissue in order to restore function in visual, auditory, or other physiological components associated with the nervous system. Microelectrodes have been used in stimulating and detecting electrical activity in neurons. When stimulating or recording neural tissue activity using microelectrodes, there are usually many problems and difficulties in obtaining the correct functionality and results. There is great difficulty in placing these microelectrodes in a specific location in the central nervous system due to various problems with the methodology used. Many different techniques such as the traditional interconnected microelectrodes have been an …

Dem Simulated Radial And Axial Pressure In A Cylindrical Granular Column, Meng Cui

Theses

The study of packed beds of granular spheres and their applications are of great interest to industries, and one of the most important subjects that has been studied is cylindrical beds. In 1895, H. A. Janssen discovered that in a vertical cylinder the pressure measured at the bottom does not depend upon the height of the filling in contrast to Newtonian fluids that possess linear hydrostatic pressure equilibrium. One of assumptions of his theory stated that the horizontal pressure is proportional to the vertical. In this thesis, this physical hypothesis is investigated using Discrete Element Simulations of inelastic with a …

Density Relaxation Of Granular Matter Through Monte Carlo And Granular Dynamics Simulations, Oleksandr M. Dybenko

Dissertations

Granular materials are the principal ingredients of the industrial complex involved with the handling and processing of bulk solids including pharmaceuticals, chemicals, agricultural and mining materials. Despite the enormous importance of these materials in society, their behavior is not well-understood; in fact, there is no known model available that is capable of predicting the wide range of phenomenon that have been observed. One of the most important of these is known as density relaxation. Here, a granular material undergoes an increase in solids fraction as a result of the application of discrete taps or continuous vibrations.

In this dissertation, the …

Production Of Nanocrystalline Rdx By Ress : Development And Material Characterization, Victor Stepanov

Dissertations

The aim of the present work was to address the hazardous vulnerability of energetic materials to accidental initiation. An improved form of the explosive RDX with a significantly reduced sensitivity to stimuli including shock and impact was sought. The direction of this research was to investigate the effect of RDX crystal size reduction down to nano-scale dimensions on the sensitivity characteristics. Although size reduction of energetic crystals has been demonstrated often to result in a sensitivity reduction, the effect at the nano-scale particle size has not been investigated.

To generate nanocrystalline RDX a recrystallization process was developed based on rapid …

Optimal Allocation Of Blood Products, Godson A. Tetteh

Dissertations

The high cost of collection and the short shelf life of apheresis platelets demand efficient inventory management to reduce outdates and shortages. Apheresis platelets are licensed for seven days, and blood centers are keen on knowing the consequences of various product collection and distribution strategies. To reduce outdates, inventory managers typically distribute the older units first, thereby following first-in first-out (FIFO) policy; however, hospital blood banks would prefer that the blood center issues out the freshest units first, equivalent to a last-in first-out (LIFO) policy. This study addresses the optimal distribution policy to achieve a desired outdate, shortage and average …

Optical Properties And Carrier Transport In Si/ Si1-Xgex Nanostructures, Eun Kyu Lee

Dissertations

Defect-free epitaxial growth of Ge on a ~4 % lattice-mismatched single-crystal Si substrate is achieved using reduced dimension nanoscale heterostructures, where efficient structural relaxation might occur due to an enhanced adatom migrations and high surface-to-volume ratio. For development of novel electronic or optical devices based on these novel structures, understanding of their electrical and optical properties is crucial. This study explores the optical properties and carrier transport in two different types of Si/Si _1-xGe _xnanostructures: Ge nanowires (NWs) forming nanoscale heterojunctions with Si substrates and multilayers of SiGe clusters embedded into a Si matrix.

Micron-long Ge nanowires grown …

Micro, Meso And Macro Materials Processing Using High-Speed Liquid Projectiles, Veljko Samardzic

Dissertations

The objective of this research is developmentof aknowledge base of materials processing by the impact of high-speed liquid projectiles. The work involved experimental study of generation and applications of high-speed liquid projectiles. The projectiles were generated by the launchers, which used gunpowder as an energy source. The experiments were carried out at the low (O.35g of the powder), middle (1.2g) and high (10g to 70g) levels of energy consumptions and at several different launchers modification.

Experimental investigation of effect of gun powder mass on energy of projectile was conducted for ductile and brittle targets. An array of experimental …

Removal And Recovery Of Fermentation-Produced Volatile Organic Compounds By A Novel Liquid Membrane-Based Pervaporation Technique, Atsawin Thongsukmak

Dissertations

Pervaporation is an energy -- efficient alternative to distillation for removing volatile organic compounds (VOCs) from water especially solvents from their dilute solutions in a fermentation broth. Liquid membranes have high selectivities for removing solvents from aqueous solutions compared with polymeric membranes or ceramic membranes; however liquid membranes have stability problems due to various losses. The loss of liquid membrane (LM) to the feed solution leads to toxicity for the organisms in a fermentation broth. A new liquid membrane based pervaporation technique has been developed to achieve high selectivity, ensure stability and prevent contamination of the fermentation broth. Trioctylamine (TOA) …

Modeling Inventory And Responsiveness Costs In A Supply Chain, Robert Nearier

Dissertations

Evaluation of supply chain performance is often complicated by the various interrelationships that exist within the network of suppliers. Currently many supply chain metrics cannot be analytically determined. Instead, metrics are derived from monitoring historical data, which is commonly referred to as Supply Chain Analytics. With these analytics it is possible to answer questions such as: What is the inventory cost distribution across the chain? What is the actual inventory turnover ratio? What is the cost of demand changes to individual suppliers? However, this approach requires a significant amount of historical data which must be continuously extracted from the associated …

Vector Support For Multicore Processors With Major Emphasis On Configurable Multiprocessors, Hongyan Yang

Dissertations

It recently became increasingly difficult to build higher speed uniprocessor chips because of performance degradation and high power consumption. The quadratically increasing circuit complexity forbade the exploration of more instruction-level parallelism (JLP). To continue raising the performance, processor designers then focused on thread-level parallelism (TLP) to realize a new architecture design paradigm. Multicore processor design is the result of this trend. It has proven quite capable in performance increase and provides new opportunities in power management and system scalability. But current multicore processors do not provide powerful vector architecture support which could yield significant speedups for array operations while maintaining …

Raman Scattering In Free Standing Porous Si Films, Thenappan Chidambaram

Theses

In this thesis, Raman Scattering of free standing porous silicon on sapphire samples of controllably varying porosity is studied. The free standing, fully crystalline porous silicon films were prepared by electrochemical etching and the porous structure were lifted-off by a procedure based on electro-polishing. During Raman scattering measurements, the samples are exposed to relatively high intensity laser radiation. Free-standing porous Si sample temperature and thermal conductivity are calculated by comparing intensities of Stokes and anti-Stokes Raman peaks. Compared to crystalline Si, we find strong decrease in thermal conductivity accompanied by a change in the phonon spectra. Also, comparing Stokes and …

Thermal And Morphological Analysis Of Collagen-Plla Electrospun Blends, Angana Banerjee

Theses

Electrospinning of bovine Type I collagen and Poly (L-lactic acid) produces blended nanofiber scaffolds that may have application in tissue engineering, wound dressing and drug delivery.

The goal of this research work was to produce and characterize blended nanofibers of a protein, collagen, and a synthetic polymer, poly (L-lactic acid). This study focuses on the in-depth analysis of the appearance of the structural relaxation occurring at the glass transition temperature of PLLA in the collagen-PLLA blended electrospun mats. It is speculated that occurrence of this thermal event is more prominent in PLLA with high molecular weight due to the presence …

Synthesis Of Corn-Derived Carbohydrate Derivatives As Effective Multifunctional Sunscreen, Xianhong Feng

Theses

The eighty-years-old sunscreen industry is sustained by the growing incidence of skin cancer and the continual exploration of skin aging. From the UVB-induced erythema to the UVA-induced persistent pigment darkening, scientists have used versatile methods to reveal that not only does UVB damage skin but also that longer wavelengths such as UVAIL (290nm ~ 340nm) and UVAL rays (340nm ~ 400nm) trigger skin cancer, premature skin aging and immunosuppression.

To meet a significant demand for improved photoprotection, a broad-spectrum sunscreen with a high extinction coefficient has been desired. As part of our ongoing studies on isosorbide-cinnamate derivatives, this work have …

Experimental Investigation Of The Fluid Velocity Distribution In Stirred Tank Reactors Equipped With Retreat-Blade Impellers Using Laser Doppler Velocimetry, Deepak Rajesh Madhrani

Theses

Stirred tank reactors are commonly used in the pharmaceutical industry for synthesis of Active Pharmaceutical Ingredients (API's) and their intermediates. Typically, these vessels are glass-lined and are provided with a single retreat-blade glass-lined impeller and a single baffle. Despite their ubiquitous utilization in the pharmaceutical industry for at least the past 40 years, the mixing characteristics of these systems have not been studied to any great extent, making it difficult to predict mixing performance in any given operation.

In this work, the velocity distribution inside the typical glass-lined vessel/impeller system was experimentally quantified using Laser Doppler Velocimetry (LDV), which is …

Synthesis And Analysis Of Carbon Nanowalls And Their Raman Spectroscopy, Amit Mahajan

Theses

Growth of Carbon Nanowalls has been carried out by Radio Frequency Chemical Vapor Deposition (RF-PECVD) on various substrates. Hydrogen was used as an active gas for the growth where as Ethanol bubbled with Argon was used as carbon source for formation of Carbon Nanowalls (CNW). The growth was then confinned by Raman Spectroscopy and Scanning Electron Microscope (SEM) images. Also the need of using catalyst in CNW has been analyzed. The intensities of D and G bands obtained from Raman spectrum have been related to the length of Graphene walls, to study the CNW's length on different substrates.

The growth …