Open Access. Powered by Scholars. Published by Universities.®
- Discipline
-
- Engineering (38)
- Optics (13)
- Aerospace Engineering (11)
- Materials Science and Engineering (10)
- Electrical and Computer Engineering (9)
-
- Atmospheric Sciences (8)
- Oceanography and Atmospheric Sciences and Meteorology (8)
- Electromagnetics and Photonics (6)
- Semiconductor and Optical Materials (5)
- Atomic, Molecular and Optical Physics (4)
- Nuclear Engineering (4)
- Computer Sciences (3)
- Propulsion and Power (3)
- Aerodynamics and Fluid Mechanics (2)
- Astrophysics and Astronomy (2)
- Signal Processing (2)
- Applied Mathematics (1)
- Astrodynamics (1)
- Biological and Chemical Physics (1)
- Chemical Engineering (1)
- Chemistry (1)
- Condensed Matter Physics (1)
- Controls and Control Theory (1)
- Engineering Science and Materials (1)
- Industrial Technology (1)
- Mathematics (1)
- Mechanical Engineering (1)
- Institution
- Keyword
-
- Semiconductor lasers (9)
- Laser beams (7)
- Lasers--Military applications (6)
- High power lasers (5)
- Laser weapons (5)
-
- Optical fibers (5)
- Raman effect (5)
- #csra (4)
- Atmospheric turbulence (4)
- Brillouin scattering (4)
- Gas lasers (4)
- Glow discharges (4)
- Lasers (4)
- Chemical kinetics (3)
- Electric propulsion (3)
- Ionosphere (3)
- Laser beams--Scattering (3)
- Laser pulses (3)
- Light--Scattering (3)
- Optical pumping (3)
- Plasma (Ionized gases) (3)
- Shock waves (3)
- Solid-state lasers (3)
- Actuators (2)
- Adaptive optics (2)
- Beam optics (2)
- Boltzmann equation (2)
- Bromine (2)
- Cesium (2)
- Diodes (2)
Articles 91 - 120 of 122
Full-Text Articles in Plasma and Beam Physics
Laser Intensity Scaling Through Stimulated Scattering In Optical Fibers, Timothy H. Russell
Laser Intensity Scaling Through Stimulated Scattering In Optical Fibers, Timothy H. Russell
Theses and Dissertations
The influence of stimulated scattering on laser intensity in fiber optic waveguides is examined. Stimulated Brillouin scattering (SBS) in long, multimode optical waveguides is found to generate a Stokes beam that propagates in the fiber LP01 mode. Additionally, the same process is found to combine multiple laser beams into a single spatially coherent source. Limitations in beam cleanup and combining are also investigated to identify ways to overcome them. The last portion of the dissertation theoretically examines suppression of stimulated Raman scattering in fibers to eliminate the restriction this imposes on the power of a fiber laser or amplifier. The …
Attenuation And Refraction Of An Electromagnetic Wave In An Electron Beam Generated Plasma, Nathaniel P. Lockwood
Attenuation And Refraction Of An Electromagnetic Wave In An Electron Beam Generated Plasma, Nathaniel P. Lockwood
Theses and Dissertations
Artificially generated plasmas may be employed to alter the propagation characteristics of electromagnetic waves. The purpose of this report is to study the propagation of electromagnetic waves in an electron beam generated plasma. To understand the physics related to this concept requires the development of computational tools dealing with a plasma created by an electron beam, an assessment of the temporal and spatial evolution of the plasma, and a characterization of the refraction and attenuation of electromagnetic (EM) waves in a collisional plasma. Three computer programs were developed to characterize the effectiveness of an electron beam generated plasma in refracting …
Investigation Of Laser Beam Combining And Cleanup Via Seeded Stimulated Brillouin Scattering In Multimode Optical Fibers, Bryan J. Choi
Investigation Of Laser Beam Combining And Cleanup Via Seeded Stimulated Brillouin Scattering In Multimode Optical Fibers, Bryan J. Choi
Theses and Dissertations
The purpose of this thesis research was to determine if stimulated Brillouin scattering amplification in multimode optical fibers would exhibit the same laser beam combining and clean-up properties exhibited by SBS oscillation, and to characterize the Brillouin amplification process in a multimode optical fiber. Beam combining in multimode fibers via SBS is being considered as a method of combining low power laser beams into a single beam having higher power and superior spatial coherence for applications such as electro-optic countermeasures. Experimental results demonstrate seeding a 9.5 mm fiber significantly reduced the pump power required to initiate SBS. An amplified Stokes …
A Numerical Simulation Of A Carbon Black Suspension Cell Via A Time-Reversed, Double Layer Compute Algorithm, Gregg T. Anderson
A Numerical Simulation Of A Carbon Black Suspension Cell Via A Time-Reversed, Double Layer Compute Algorithm, Gregg T. Anderson
Theses and Dissertations
A numerical simulation of a carbon black suspension cell is explored which models a laser-induced plasma within a liquid ethanol medium of approximately 1 mm thickness. The simulation model assumes a laser pulse with a pulse width of approximately 9 nsecs propagating in the left-to-right direction striking the front surface of the medium and focusing to a spot within the liquid volume. When the energy density within a given irradiated volume is sufficiently high, it ignites the carbon particles and generates a large number of free electrons, i.e., a plasma. The plasma couples with the in-coming laser energy on a …
A Continuous Wave Atomic Bromine Laser Produced By Photolysis Of Iodine Monobromide, Brian A. Smith
A Continuous Wave Atomic Bromine Laser Produced By Photolysis Of Iodine Monobromide, Brian A. Smith
Theses and Dissertations
An apparatus to generate continuous wave (CW) lasing at 2.714 µm by Br(2P1/2) atoms produced from photodissociation of IBr was designed, constructed and tested. A frequency doubled Nd:YAG laser firing 8 ns, 850 mJ pulses at 532 nm was used to photodissociate static IBr vapor inside a flow nozzle. The CaF2 windows on either side of the nozzle proved to have a damage threshold below the threshold for lasing. Pulsed lasing in static mode was not observed. Therefore, CW lasing in flow mode, using an Ar+ laser at 488 nm, could not be investigated.
Numerical Solutions To The Two Dimensional Boltzmann Equation, Christopher G. Smithtro
Numerical Solutions To The Two Dimensional Boltzmann Equation, Christopher G. Smithtro
Theses and Dissertations
A strict kinetic, two-dimensional model of the electron kinetics within a glow discharge positive column is developed. The problem is solved in cylindrical geometry using the standard two-term Legendre expansion of the electron velocity distribution function. The model establishes a steady state solution, such that the net ionization rate is exactly balanced by the wall loss. In addition to a thorough analytic development, we present the numerical techniques used to solve the resulting elliptic partial differential equation, including an efficient method to treat sparse banded matrices. The model is validated against published results, local and nonlocal kinetic approximations, and a …
Laser Beam Combining And Cleanup Via Stimulated Brillouin Scattering In Multi-Mode Optical Fibers, Blake C. Rodgers
Laser Beam Combining And Cleanup Via Stimulated Brillouin Scattering In Multi-Mode Optical Fibers, Blake C. Rodgers
Theses and Dissertations
The main objective of this thesis was to demonstrate the feasibility of combining and cleaning up multiple laser beams via Stimulated Brillouin Scattering (SBS) in a multi-mode optical fiber. Beam combining via SBS in an optical fiber is of interest because of the low SBS threshold power in an optical fiber allowing low power diode laser beams to be combined into one high power beam. SBS theory and some of the important historical results are described briefly. The experimental results clearly indicate that SBS in multi-mode optical fiber can indeed combine laser beams and clean up the beams at the …
Double Layer Effects On Shock Wave Propagation, Shannon L. Walker
Double Layer Effects On Shock Wave Propagation, Shannon L. Walker
Theses and Dissertations
An analysis and assessment of two mechanisms in plasma shock interactions was conducted under conditions typically encountered in a weakly ionized glow discharge. The mechanisms of a spatially-dependent electron temperature and additional electron impact ionization at the shock front were examined for effects on shock structure and propagation. These mechanisms were incorporated into an existing one-dimensional, time-dependent, fluid dynamics code that uses the Riemami problem as a basis and numerically solves the Euler equations for two fluids: the neutral gas and the charged component. The spatial variation in electron temperature was modeled as a shock-centered rise in temperature. Additional ionization …
Performance Of Imaging Laser Radar In Rain And Fog, Kathleen M. Campbell
Performance Of Imaging Laser Radar In Rain And Fog, Kathleen M. Campbell
Theses and Dissertations
The Air Force is currently developing imaging laser radar systems (ladar) for use on precision guided munitions and other imaging systems. Scientists at Eglin Air Force Base, in conjunction with Wright Laboratories, are testing a 1.06-um wavelength ladar system and need to understand the weather effects on the ladar images. As the laser beam propagates through the atmosphere, fog droplets and raindrops can cause image degradation, and these image degradations are manifested as either dropouts or false returns. An analysis of the dropouts and false returns helped to quantify the performance of the system in adverse weather conditions. Statistical analysis …
Spontaneous Emission In Microcavity Lasers, Dustin Philip Ziegler
Spontaneous Emission In Microcavity Lasers, Dustin Philip Ziegler
Theses and Dissertations
An understanding of spontaneous emission processes within microcavities is crucial in addressing the need to make tomorrow's microlasers more efficient. One approach to improving the device efficiency is to reduce the threshold input energy at which lasing begins to occur. It has been suggested that the threshold in a microcavity laser can be decreased by increasing the fraction of spontaneous emission into the lasing mode, this can be accomplished by preferentially coupling the gain medium of the laser to the electromagnetic cavity mode of interest. It therefore becomes necessary to understand the mechanism by which this coupling takes place. This …
Shock Waves In Nonequilibrium Gases And Plasmas, William M. Hilbun
Shock Waves In Nonequilibrium Gases And Plasmas, William M. Hilbun
Theses and Dissertations
An analysis and assessment of three mechanisms describing plasma/shock wave interactions was conducted under conditions typically encountered in a weakly ionized glow discharge. The mechanisms of ion-acoustic wave damping, post-shock energy addition and thermal inhomogeneities were examined by numerically solving the Euler equations with appropriate source terms adapted for each mechanism. Ion-acoustic wave damping was examined by modeling the partially ionized plasma as two fluids in one spatial dimension using the Riemann problem as a basis. Post-shock energy addition in the form of nonequilibrium vibrational energy relaxation was also examined in one spatial dimension using the Riemann problem as a …
Spectroscopic And Kinetic Studies Of Bismuth Dimers, Robert Eugene Frankin
Spectroscopic And Kinetic Studies Of Bismuth Dimers, Robert Eugene Frankin
Theses and Dissertations
The spectroscopy of high rotational levels (J ≤ 211) in Bi2 X(Og+) and A(Ou+) was investigated for 2≤v"≤5 and 0≤v'≤4 by observing total fluorescence from laser excitation. Dunham coefficients were derived that fit all observed rotational lines to within 0.01 cm-1. Franck-Condon factors were calculated and experimentally verified for transitions originating from the initially populated levels 0≤v'≤5. Vibrational energy transfer upon collision with rare gas collision partners was investigated for the low-lying vibrational levels of the A-state using spectrally resolved, continuous wave laser induced fluorescence. Vibrational transfer was adequately modeled by …
Investigation Of Ba, Bao, Sr And Sro Pulsed Laser-Induced Vapor Plumes In N2, O2, Microwave Discharged O2, And Vacuum At Low Laser Fluence, David L. Byers
Investigation Of Ba, Bao, Sr And Sro Pulsed Laser-Induced Vapor Plumes In N2, O2, Microwave Discharged O2, And Vacuum At Low Laser Fluence, David L. Byers
Theses and Dissertations
Ba, BaO, Sr and SrO were ablated by 248 nm laser pulses at fluences ranging from 270 mJ-/cm2 to 575 mJ-/cm2 in vacuum and in 25 mtorr atmospheres of N2, O2 and microwave-discharged O2. The spectral emissions of these plumes were compared for indications of ionization due to Ba or Sr collisions with each gas. The addition of a background gas increased the ion and neutral signature across the spectrum. SrO band emission was observed at 16,600-16,900/cm and possible BaO band emissions were observed in the 18,250-18,400/cm, 19,000-19700/cm and 19,800-20,000/cm regions. A screened plate ion probe …
Experimental Investigation And Computer Modeling Of Optical Switching In Distributed Bragg Reflector And Vertical Cavity Surface Emitting Laser Structures, Richard J. Bagnell
Experimental Investigation And Computer Modeling Of Optical Switching In Distributed Bragg Reflector And Vertical Cavity Surface Emitting Laser Structures, Richard J. Bagnell
Theses and Dissertations
The optical switching capabilities of Distributed Bragg Reflector (DBR) structures, including Vertical Cavity Surface Emitting Lasers (VCSELs) are examined. Reflectivity switching is demonstrated using both thermal and carrier generated effects to alter the DBR/VCSEL layers' refractive indices. Optical bistability is demonstrated at room temperature, under CW photopumped excitation. The optical bistability hysteresis is controllable by spectral location of the pump on the stop band edge. In the VCSEL, reflective bistability is also evidenced; additionally, this bistability is accompanied by a bistability in the VCSEL lasing output intensity, spot size, and wavelength. Modeling of the DBR/VCSEL thermally induced bistability was accomplished …
Laser Beam Propagation In Non-Kolmogorov Atmospheric Turbulence, Bruce E. Stribling
Laser Beam Propagation In Non-Kolmogorov Atmospheric Turbulence, Bruce E. Stribling
Theses and Dissertations
Several observations of atmospheric turbulence statistics have been reported which do not obey Kolmogorov's power spectral density model. These observations have prompted the study of optical propagation through turbulence described by non-classical power spectra. This thesis presents an analysis of optical propagation through turbulence which causes index of refraction fluctuations to have spatial power spectra that obey arbitrary power laws. The spherical and plane wave structure functions are derived using Mellin transform techniques and are applied to the field mutual coherence function (MCF) using the extended Huygens-Fresnel principle. The MCF is used to compute the Strehl ratio of a focused, …
Analysis Of Instability Growth And Collisionless Relaxation In Thermionic Converters Using 1-D Pic Simulations, Bret B. Kreh
Analysis Of Instability Growth And Collisionless Relaxation In Thermionic Converters Using 1-D Pic Simulations, Bret B. Kreh
Theses and Dissertations
This work investigates the role that the beam-plasma instability may play in a thermionic converter. The traditional assumption of collisionally dominated relaxation is questioned, and the beam-plasma instability is proposed as a possible dominant relaxation mechanism. Theory is developed to describe the beam-plasma instability in the cold-plasma approximation, and the theory is tested with two common Particle-in- Cell (PIC) simulation codes. The theory is first confirmed using an unbounded plasma PIC simulation employing periodic boundary conditions, ES1. The theoretically predicted growth rates are on the order of the plasma frequencies, and ESl simulations verity these predictions within the order of …
Generation Of A Single-Lobe, Far-Field Intensity Pattern From A Laser Diode Array Using An Optical Delay Line, Thomas A. Summers
Generation Of A Single-Lobe, Far-Field Intensity Pattern From A Laser Diode Array Using An Optical Delay Line, Thomas A. Summers
Theses and Dissertations
A simple and practical technique is demonstrated to generate a stable, single-lobe, far-field intensity pattern from a one-dimensional, antiphased, laser diode array with gain-guided elements. The two far-field lobes of the array are combined after introducing an optical delay line into the path of one of the lobes to make the lobes mutually incoherent. The incoherent superposition of intensities produces a near-diffraction-limited, single-lobe, far-field intensity pattern containing 84% of the power, exceeding any previous (known) phase control experiments. This technique compares favorably with more elaborate schemes advanced previously using integrated phase plates, etc. The method is directly applicable to one-dimensional …
A Three Region Analysis Of A Bounded Plasma Using Particle In Cell And Fluid Techniques, Don F. Nichols
A Three Region Analysis Of A Bounded Plasma Using Particle In Cell And Fluid Techniques, Don F. Nichols
Theses and Dissertations
A detailed collisionless sheath theory and a three-region collisional model of a bounded plasma are presented, and the suitability of the collisional model for analysis of ignited mode thermionic converters is investigated. The sheath theory extends previous analyses to regimes in which the sheath potential and electron temperatures are comparable in magnitude. In all operating regimes typical of a ignited mode thermionic converter, the predicted sheaths extend several mean-free paths. The apparent collisionality of the sheaths prompted development of a collisional, three-region model of the converter plasma. By interfacing Particle-in-Cell regions for the sheaths and fluid regions for the bulk …
Failure Mechanisms Of High Temperature Semiconductor Lasers, David H. Leicester
Failure Mechanisms Of High Temperature Semiconductor Lasers, David H. Leicester
Theses and Dissertations
The primary intent of this research was to determine the influence of three common degradation mechanisms, dark area defects, facet degradation, and contact degradation, on the operational lifetime of GaAs edge-emitting semiconductor lasers driven by continuous current at 100°C. Inherent to this work was the quantified characterization of the lasers during their operation. This characterization arose as the power output as a function of driving current at room temperature before and after laser exposure to 100°C ambient temperature. These power vs. current characterizations were conducted at room temperature on each laser before and after exposure to 100°C as well as …
The Effects Of Optical Feedback On Polarization Of Vertical Cavity Surface Emitting Lasers, Gregory J. Vansuch
The Effects Of Optical Feedback On Polarization Of Vertical Cavity Surface Emitting Lasers, Gregory J. Vansuch
Theses and Dissertations
Vertical Cavity Surface Emitting Lasers VCSELs are a type of semiconductor laser with a cavity oriented orthogonally to the planes of material growth. These lasers differ from conventional edge emitting lasers in several important ways. They have symmetric output beams and they are easily built into two dimensional arrays, making them very attractive as photonic components. The characteristic of interest in this thesis is polarization. While the asymmetric cavities of edge emitters exhibit a clear preference for light polarized in a particular direction, the cylindrically symmetric cavity of a VCSEL has no clear preference. Therefore, it should be relatively easy …
Optimal Control Of The Starfire Beam Director, Troy V. Lanier
Optimal Control Of The Starfire Beam Director, Troy V. Lanier
Theses and Dissertations
The Starfire Beam Director (SBD) is located at the Starfire Optical Range at Kirtland Air Force Base in Albuquerque, New Mexico. The SBD capabilities include tracking celestial objects and active or passive tracking of artificial satellites to support the Phillips Laboratory Ground Based Laser Acquisition, Tracking, and Pointing (GBL ATP) program. The pointing and tracking accuracy needed to support such experiments is micron rad to sub-grad level. To accomplish this goal requires precise pointing of the massive 6 ton 1 -meter clear aperture coelostat. The purpose of this thesis is to use optimal control design techniques to develop a controller …
Design And Characterization Of Optically Pumped Vertical Cavity Surface Emitting Lasers, Richard J. Bagnell
Design And Characterization Of Optically Pumped Vertical Cavity Surface Emitting Lasers, Richard J. Bagnell
Theses and Dissertations
Vertical Cavity Surface Emitting Lasers (VCSELs) are a form of semiconductor laser which have their cavity oriented orthogonally to the plane of the wafer. The orientation necessitates short cavities, highly reflective mirrors and a relatively high gain/loss ratio. Even so, the resultant superior exit beam characteristics and the tight packing density of the finished lasers provide strong motivation for pursuing the growth of these structures. This thesis details the design of an optically pumped InGaAs multiple quantum well periodic gain structure VCSEL with a 950 nm lasing wavelength. These growths were to be a first attempt at VCSEL construction, so …
Laser Phase Front Measurements Using A Phase Conjugate Twyman-Green Interferometer, William J. Mandeville
Laser Phase Front Measurements Using A Phase Conjugate Twyman-Green Interferometer, William J. Mandeville
Theses and Dissertations
This study demonstrated the use of a phase conjugate TwymanGreen interferometer for measuring the phase fronts of beams emitted by infrared diode lasers operating at 830 nm. This interferometer successfully measured the phase front of a single element diode laser, providing better resolution than its conventional counterpart. The phase conjugate mirror compensated for aberrations introduced by imperfect optics in the phase conjugating arm of the interferometer. This interferometer was unable to measure the phase front of a diode array due to the array's inability to create a phase conjugate return. The array's short coherence length is believed to be the …
Multi-Ion Ambipolar Diffusion, Thomas E. Gist
Multi-Ion Ambipolar Diffusion, Thomas E. Gist
Theses and Dissertations
The continuity and momentum equations for electrons and multiple ion species are solved analytically and numerically using a new model for ambipolar diffusion. The general form of the model is valid for any quasi-neutral plasma for which the diffusion approximation is appropriate, including positive or negative ions, arbitrary geometries, and time dependence. The model provides criteria for determining when single ion diffusion theory is appropriate for describing multi-ion discharges, when a multi-ion proportional model is appropriate, and when a multi-ion nonproportional model is necessary. An expression is developed which provides a necessary condition for proportionality and provides the proportionality constant …
Silicon Carbide Thin Film Deposition By Reactive Ion-Beam Sputtering, Larry G. Sills
Silicon Carbide Thin Film Deposition By Reactive Ion-Beam Sputtering, Larry G. Sills
Theses and Dissertations
In this study, hydrogenated amorphous silicon carbide thin films were deposited by reactive ion-beam sputtering under varying conditions to determine whether a film's optical properties can be controlled, focusing on refractive index. Using a Kaufman type ion source to sputter a pure silicon target, three distinct series of films were grown. The first series varied the mixture of methane and argon used in the ion-beam. holding all other parameters constant. For the second series the gas mix was fixed, and only the beam energy (beam voltage) was varied. The final series also varied beam energy, but was grown with a …
Plasma Transport In A Magnetic Multicusp Negative Hydrogen Ion Source, Ricky G. Jones
Plasma Transport In A Magnetic Multicusp Negative Hydrogen Ion Source, Ricky G. Jones
Theses and Dissertations
An analysis of plasma transport through the magnetic filter in tandem magnetic multicusp negative hydrogen ion sources was conducted to determine the mechanism of thermal electron diffusion, explain thermal electron cooling, describe the transport of primary electrons through the filter, and model positive ion species transport. The thermal electron flux was shown to exceed its classical value by one to three orders of magnitude. The flux variation with temperature was best described using a Coulomb-like temperature gradient drag term, consistent with diffusion due to ion-sound-like turbulence. Thermal electron energy flux loss was shown to be dominated by inelastic collisions at …
Collisional Dynamics Of The B3Π(O+) State Of Bromine Of Monofluoride, David W. Melton
Collisional Dynamics Of The B3Π(O+) State Of Bromine Of Monofluoride, David W. Melton
Theses and Dissertations
When Bromine is combined with flourine atoms and discharged oxygen in a flow tube is produced in a highly non thermal distribution peaking at v'=3. The emission was linearly dependent on the concentration. The observed dependence of the BrF(B) emission on Bromine and atomic oxygen is inconsistent with a steady state prediction of a sequential excitation mechanism, where BrF(X) is excited by successive collisions with singlet oxygen. The experimental data are consistent with a three body mechanism involving Br and F atoms. Electronic quenching of BrF(B) by a number of collision partners (Br2, CO2, O2 …
An Evolution Operator Solution For A Nonlinear Beam Equation, Carl E. Crockett
An Evolution Operator Solution For A Nonlinear Beam Equation, Carl E. Crockett
Theses and Dissertations
A nonlinear partial differential equation, motivated by the transverse vibration of a beam, is shown to have a unique solution. The existence theory, which is in the setting of semigroups and evolution operators, is a composite and synthesis of theorems of Kato. The formulation of the problem and the verification that the formulation leads to a solution are new. The introductory chapter provides background on the topic generally. Chapter 2 provides detailed formulations for the constant coefficient case. Chapter 3 describes nonautonomous cases. The general theorem is presented here. In Chapter 4, a more general case is considered. Namely, Kelvin …
Computer Model Of An Injection Locked Pulsed Co2 Laser, Allen M. Susie
Computer Model Of An Injection Locked Pulsed Co2 Laser, Allen M. Susie
Theses and Dissertations
With the discovery of the laser there have been continual attempts to increase the 'spectral brightness' of a laser for applications such as signal processing and lidar. To this end techniques using either passive or active cavity elements have been developed to isolate a single longitudinal mode in both continuous and pulsed laser systems. Although passive elements have useful applications in continuous systems their use in pulsed systems is difficult to control. The injection of an external signal has proved very successful.
An Optically Pumped Molecular Bromine Laser, Jon W. Morrison
An Optically Pumped Molecular Bromine Laser, Jon W. Morrison
Theses and Dissertations
An optically pumped molecular bromine laser was studied to investigate the quenching kinetics state of Br2. This included characterization of the pressure dependence of the laser output power. The approach was to excite molecular bromine in a sealed cell with a Nd:YAG pumped dye laser. Unresolved side fluorescence and amplified stimulated emission (ASE) spectra were recorded. ASE offered the advantage of a simpler optical system with no externally induced wavelength dependencies. Stimulated emission as a signal monitor offered greater resolution than side fluorescence spectra and facilitated spectroscopic assignment.