Condensed Matter Physics Commons^™

Plasma Based Synthesis And Surface Modification Of Graphene., Rong Zhao

Electronic Theses and Dissertations

Graphene, an atom thick layer of carbon, has attracted intense scientific interest due to its exceptional electrical, mechanical and chemical properties. Especially, it provides a perfect platform to explore the unique electronic properties in absolute two-dimension. Pristine graphene possesses zero band gap and weakens its competitiveness in the field of semiconductors. In order to induce a band gap and control its semiconducting properties, functionalization and doping are two of the most feasible methods. In the context of functionalization, large area monolayer graphene synthesized by chemical vapor deposition was subjected to controlled and sequential fluorination using radio frequency plasma while monitoring …

Localization And Scrambling Of Quantum Information With Applications To Quantum Computation And Thermodynamics, Adrian Kristian Chapman

Physics & Astronomy ETDs

As our demand for computational power grows, we encounter the question: "What are the physical limits to computation?" An answer is necessarily incomplete unless it can incorporate physics at the smallest scales, where we expect our near-term high-performance computing to occur. Microscopic physics -- namely, quantum mechanics -- behaves counterintuitively to our everyday experience, however. Quantum matter can occupy superpositions of states and build stronger correlations than are possible classically. This affects how quantum computers and quantum thermodynamic engines will behave.

Though these properties may seem to overwhelmingly defeat our attempts to build a quantum computer at-first-glance, what is remarkable …

Effects Of B And C Doping On Tunneling Magnetoresistance In Cofe/Mgo Magnetic Tunnel Junctions, Andy Paul Chen, John D. Burton, Evgeny Y. Tsymbal, Yuan Ping Feng, Jingsheng Chen

Evgeny Tsymbal Publications

Using density-functional theory calculations, we investigate the dominant defects formed by boron (B) and carbon (C) impurities in a CoFe/MgO/CoFe magnetic tunnel junction (MTJ) and their influence on conductivity and tunneling magnetoresistance (TMR). We find that, in the O-poor conditions relevant to experiment, B forms the substitutional defect B_Co and C forms the interstitial site C_i at the CoFe/MgO interface. The C-doped MTJ is predicted to have a significantly higher TMR than the B-doped MTJ. This is due to interface state densities associated with the majority spin Δ₁-symmetry bands being more heavily suppressed by the B …

Persistent Spin Texture Enforced By Symmetry, Lingling Tao, Evgeny Y. Tsymbal

Evgeny Tsymbal Publications

Persistent spin texture (PST) is the property of some materials to maintain a uniform spin configuration in the momentum space. This property has been predicted to support an extraordinarily long spin lifetime of carriers promising for spintronics applications. Here, we predict that there exists a class of noncentrosymmetric bulk materials, where the PST is enforced by the nonsymmorphic space group symmetry of the crystal. Around certain high symmetry points in the Brillouin zone, the sublattice degrees of freedom impose a constraint on the effective spin–orbit field, which orientation remains independent of the momentum and thus maintains the PST. We illustrate …

Laser-Induced Recoverable Surface Patterning On Ni50ti50 Shape Memory Alloys, Saidjafarzoda Ilhom

Masters Theses & Specialist Projects

Shape memory alloys (SMAs) are a unique class of smart materials exhibiting extraordinary properties with a wide range of applications in engineering, biomedical, and aerospace technologies. In this study, an advanced, efficient, low-cost, and highly scalable laser-assisted imprinting method with low environmental impact to create thermally controllable surface patterns is reported. Two different imprinting methods were carried out mainly on Ni50Ti50 (at. %) SMAs by using a nanosecond pulsed Nd:YAG laser operating at 1064 nm wavelength and 10 Hz frequency. First, laser pulses at selected fluences were directly focused on the NiTi surface, which generated pressure pulses of up to …

Towards Fundamental Understanding Of Thermoelectric Properties In Novel Materials Using First Principles Simulations, Artem R. Khabibullin

USF Tampa Graduate Theses and Dissertations

Thermoelectric materials play an important role in energy conversion as they represent environmentally safe and solid state devices with a great potential towards enhancing their efficiency. The ability to generate electric power in a reliable way without using non-renewable resources motivates many experimentalists as well as computational physicists to search and design new thermoelectric materials. Several classes of materials have been identified as good candidates for high efficient thermoelectrics because of their inherently low thermal conductivity. The complex study of the crystal and electronic structures of such materials helps to reveal hidden properties and give fundamental understanding, necessary for the …

Aftershocks In Slowly Compressed Bulk Metallic Glasses: Experiments And Theory, Louis W. Mcfaul, Wendelin Wright, Xiaojun Gu, Jonathan T. Uhl, Karin A. Dahmen

Faculty Journal Articles

We observe two distinct interevent time patterns in the slip avalanches of compressed bulk metallic glasses (BMGs). Small slip avalanches cluster together in time, but large slip avalanches recur roughly periodically. We compare the timing patterns of BMG slip avalanches with timing patterns of earthquakes and with the predictions of a mean-field model. The time clustering of small avalanches is similar to the known time clustering of earthquake foreshocks and aftershocks.

Modeling Recombination In Solar Cells, Paul Chery

Macalester Journal of Physics and Astronomy

Solar cells are a competitive alternative to nonrenewable energy sources such as fossil fuels. However, the efficiency of these devices is limited by photogenerated carrier recombination. We use a finite difference numerical model to study recombination phenomena in the absorber layer of solar cells including alternate recombination models and the effects of spatial distribution of recombination centers. We compare the effect of using the constant lifetime approximation for recombination to the full Shockley-Read-Hall expression in Silicon solar cells and find that the constant lifetime approximation holds for high defect densities but not for high photon flux densities. Finally, we simulate …

Wireless Antenna Detection Of Electrostatic Discharge Events, Allen Andersen, Jr Dennison

Conference Proceedings

Wireless intra-spacecraft communication technology is being developed as a weight-saving and design-simplifying measure for signal transfer on space missions. One consideration for this new technology is its interaction with space-environment induced electrostatic discharges (ESD). The short time scales of spacecraft ESD events results in broad frequency signals that can interact with wireless antennae. These interactions present a source of signal noise. However, they may also present a possibility of in-flight wireless ESD monitoring.

We present laboratory measurements of arcing on common spacecraft insulators using commercially available single band 2.4 GHz and dual band 2.4/5.8 GHz Wi-Fi antennas. These wireless detections …

Surface And Interface Effects Of Magnetoimpedance Materials At High Frequency, Tatiana M. Eggers

USF Tampa Graduate Theses and Dissertations

Amorphous and nanocrystalline transition metal magnetic alloys (TMMAs) have been the subjects of fundamental and applied study due to their unique structure. The lack of long-range order in these materials sets the stage for their soft magnetic properties to be tuned for a variety of technological applications, such as sensitive magnetic field sensors, high frequency transformers, and stress sensors. Fundamental investigation of the magnetic and structural properties of these materials is also motivated by their unique amorphous or nanocrystalline-embedded amorphous matrix morphology, which has consequences on both the magnetism seen from both the atomic and macro-scale. The surfaces of these …

Secondary Electron Yield Measurements Of Carbon Nanotube Forests: Dependence On Morphology And Substrate, Brian Wood, Justin Christensen, Gregory Wilson, Jr Dennison, T. -C. Shen

Posters

No abstract provided.

Parameterization Of Secondary And Backscattered Electron Yields For Spacecraft Charging, Justin Christensen, Phil Lundgreen, Jr Dennison

Posters

No abstract provided.

Granular Convection And Crystallization Of A Two-Dimensional Granular Medium, Donley S. Cormode

Honors Projects

Granular media are everywhere from beaches to factories to your kitchen cabinets. There are a rich array of phenomena to study with granular media. These include granular convection, jamming, and crystallization. The systems tend to be macroscopic, so it is easy to collect data. The supplies are low-cost and easy to obtain. Studying granular media gives researchers the opportunity to explore foundational ideas in fields such as crystallography and condensed matter. This paper describes a simple, low cost apparatus used to study a vertically shaken two-dimensional granular medium of glass beads. This paper will also describe a few preliminary studies …

Pseudo Power Law Statistics In A Jammed, Amorphous Solid, Jacob Brian Hass

Physics

Simulations have shown that in many solid materials, rearrangements within the solid obey power-law statistics. A connection has been proposed between these statistics and the ability of a system to reach a limit cycle under cyclic driving. We study experimentally a 2D jammed solid that reaches such a limit cycle. Our solid consists of microscopic plastic beads adsorbed at an oil-water interface and cyclically sheared by a magnetically driven needle. We track each particles trajectory in the solid to identify rearrangements. By associating particles both spatially and temporally, we can measure the extent of each rearrangement. We study specifically the …

Simulating The Electrical Properties Of Random Carbon Nanotube Networks Using A Simple Model Based On Percolation Theory, Roberto Abril Valenzuela

Physics

Carbon nanotubes (CNTs) have been subject to extensive research towards their possible applications in the world of nanoelectronics. The interest in carbon nanotubes originates from their unique variety of properties useful in nanoelectronic devices. One key feature of carbon nanotubes is that the chiral angle at which they are rolled determines whether the tube is metallic or semiconducting. Of main interest to this project are devices containing a thin film of randomly arranged carbon nanotubes, known as carbon nanotube networks. The presence of semiconducting tubes in a CNT network can lead to a switching effect when the film is electro-statically …

Kelvin-Mach Wake In A Two-Dimensional Fermi Sea, Eugene B. Kolomeisky, Joseph P. Straley

Physics and Astronomy Faculty Publications

The dispersion law for plasma oscillations in a two-dimensional electron gas in the hydrodynamic approximation interpolates between Ω ∝ √q and Ω ∝ q dependences as the wave vector q increases. As a result, downstream of a charged impurity in the presence of a uniform supersonic electric current flow, a wake pattern of induced charge density and potential is formed whose geometry is controlled by the Mach number M. For 1 < M ≤ √2, the wake consists of transverse wave fronts confined within a sector, whose angle is given by the classic Mach condition. An additional wake of …

Quadrupolar Quantum Criticality On A Fractal, Jonathan D'Emidio, Simon Lovell, Ribhu K. Kaul

Physics and Astronomy Faculty Publications

We study the ground state ordering of quadrupolar ordered S = 1 magnets as a function of spin dilution probability p on the triangular lattice. In sharp contrast to the ordering of S = 1/2 dipolar Néel magnets on percolating clusters, we find that the quadrupolar magnets are quantum disordered at the percolation threshold, p = p^∗. Further we find that long-range quadrupolar order is present for all p < p^∗ and vanishes first exactly at p^∗. Strong evidence for scaling behavior close to p^∗ points to an unusual quantum criticality without fine tuning that …

An Analysis Of Frenkel Defects And Backgrounds Modeling For Supercdms Dark Matter Searches, Matthew Stein

Physics Theses and Dissertations

Years of astrophysical observations suggest that dark matter comprises more than ~80 % of all matter in the universe. Particle physics theories favor a weakly-interacting particle that could be directly detected in terrestrial experiments. The Super Cryogenic Dark Matter Search (SuperCDMS) Collaboration operates world-leading experiments to directly detect dark matter interacting with ordinary matter. The SuperCDMS Soudan experiment searched for weakly interacting massive particles (WIMPs) via their elastic-scattering interactions with nuclei in low-temperature germanium detectors.

During the operation of the SuperCDMS Soudan experiment, ²¹⁰Pb sources were installed to study background rejection of the Ge detectors. Data from these sources …

Development Of Metallic Magnetic Calorimeters And Paramagnetic Alloys Of Ag And Er For Gamma-Ray Spectroscopy, Linh N. Le

Physics & Astronomy ETDs

A Metallic Magnetic Calorimeter (MMC) is a cryogenic calorimetric particle detector that employs a metallic paramagnetic alloy as the temperature sensor material. MMCs are used in many different applications, but this work will focus on their uses in high energy resolution gamma-ray spectroscopy. This technology is of great interest to the field of Nuclear Forensics and Nuclear Safeguards as a non-destructive assay for isotopic analysis of nuclear samples. The energy resolution of MMCs is an order of magnitude higher than the benchmark High Purity Germanium (HPGe) detectors that are currently used in the field and MMCs are also poised to …

Ambipolar Ferromagnetism By Electrostatic Doping Of A Manganite, L. M. Zheng, X. Renshaw Wang, W. M. Lü, C. J. Li, Tula R. Paudel, Z. Q. Liu, Z. Huang, S. W. Zeng, Kun Han, Z. H. Chen, X. P. Qiu, M. S. Li, Shize Yang, B. Yang, Matthew F. Chisholm, L. W. Martin, S. J. Pennycook, Evgeny Y. Tsymbal, J. M. D. Coey, W. W. Cao

Evgeny Tsymbal Publications

Complex-oxide materials exhibit physical properties that involve the interplay of charge and spin degrees of freedom. However, an ambipolar oxide that is able to exhibit both electron-doped and hole-doped ferromagnetism in the same material has proved elusive. Here we report ambipolar ferromagnetism in LaMnO₃, with electron–hole asymmetry of the ferromagnetic order. Starting from an undoped atomically thin LaMnO₃ film, we electrostatically dope the material with electrons or holes according to the polarity of a voltage applied across an ionic liquid gate. Magnetotransport characterization reveals that an increase of either electron-doping or hole-doping induced ferromagnetic order in this …

Chiral Topological Insulator Of Magnons, Bo Li, Alexey Kovalev

Department of Physics and Astronomy: Faculty Publications

We propose a magnon realization of 3D topological insulator in the AIII (chiral symmetry) topological class. The topological magnon gap opens due to the presence of Dzyaloshinskii-Moriya interactions. The existence of the topological invariant is established by calculating the bulk winding number of the system. Within our model, the surface magnon Dirac cone is protected by the sublattice chiral symmetry. By analyzing the magnon surface modes, we confirm that the backscattering is prohibited. By weakly breaking the chiral symmetry, we observe the magnon Hall response on the surface due to opening of the gap. Finally, we show that by changing …

Vibrational Relaxation Theory For Systems Embedded In Microscopically Specified Reservoirs, Anastasia Aemilia Ierides

Physics & Astronomy ETDs

This dissertation is a study of the theoretical framework of the practical as well as fundamental problem of the process of relaxation to equilibrium of quantum mechanical systems. The fundamental aspect is concerned with the simultaneous occurrence of decoherence and population equilibration. The practical aspect deals with experimental observations of vibrational relaxation of molecules embedded in liquids or solids. The systems include, but are not limited to, the nondegenerate dimer and harmonic oscillator, in one case weak and in the other strong, interaction with a thermal bath. The time dependence of the energy and the temperature dependence of the relaxation …

Lattice Dynamical Origins Of Structural Negative Thermal Expansion, Connor A. Occhialini

Honors Scholar Theses

Most materials, upon heating, expand into a larger volume through an effect known as thermal expansion. However, some materials do not obey this intuitive phenomenon and instead exhibit negative thermal expansion (NTE), which describes the anomalous propensity of these materials to shrink when warmed. Since its discovery, NTE has been found in a wide variety of materials with an array of magnetic, electronic and structural properties. In some cases, the NTE originates from the electronic degrees of freedom in the system or through magnetic phase competition, but we here focus on a particular class of NTE which originates solely from …

Space Environment Effects: Payoffs Of Unsgc Research Infrastructure Awards, Jr Dennison, Elizabeth Vargis

Presentations

No abstract provided.

Measuring The Double Layer Capacitance Of Electrolytes With Varied Concentrations, Geoffrey Rath

Senior Theses

When electric potentials are applied from an electrolytic fluid to a metal, a double layer capacitor, C_dl, develops at the interface. The layer directly at the interface is called the Stern layer and has a thickness equal to roughly the size of the ions in the fluid. The next layer, the diffuse layer, arises from the gathering of like charges in the Stern layer. This layer is the distance needed for ionic charges to return to equilibrium. This distance, called the Debye length, λ, depends on the square root of the electrolyte concentration. To study the properties of …

Magnetic Anisotropy And Exchange Bias In L10 Fept/Nio Bilayer Thin Films, Zachary B. Leuty

Graduate Theses/Dissertations

Perpendicular exchange bias (PEB), particularly when it persists in nanomaterials to room temperature, is highly useful for applications in spintronic devices and for advancing the development of high-information-density magnetic random access memory. A complete mechanistic and theoretical understanding of exchange bias has evaded scientists. The quest to discover novel materials for magnetic and spintronic device applications has stimulated investigation into nanomaterials having optimal and/or tailored magnetic properties that are based on the exchange bias effect. In this study, pulsed laser deposition was used to grow epitaxial PEB systems of ferromagnetic FePt thin film layers that are interfaced with antiferromagnetic NiO …

Optimization Of Cuinxga1-Xse2 Solar Cells With Post Selenization, Zehra Cevher

Dissertations, Theses, and Capstone Projects

The chalcopyrite semiconductor CuIn_xGa_1-xSe₂ is considered as the most promising material for high efficiency thin film solar cells due to its exceptional radiation stability, tunable direct bandgap, high light absorption coefficient and low cost preparation methods. In this thesis, we present the systematic investigation of the deposition conditions to optimize the CuIn_xGa_1-xSe₂ device performance using the two-step deposition method. Further, we utilized nonlinear optical methods to investigate the deposition parameters to optimize the bulk and interface properties of photovoltaic devices.

First, we investigated the deposition parameters to optimize the structural, …

Hartmann Characterization Of The Peem-3 Aberration-Corrected X-Ray Photoemission Electron Microscope, A. Scholl, M. A. Marcus, A. Doran, J. R. Nasiatka, A. T. Young, A. A. Macdowell, R. Streubel, N. Kent, J. Feng, W. Wan, H. A. Padmore

Robert Streubel Papers

Aberration correction by an electron mirror dramatically improves the spatial resolution and transmission of photoemission electron microscopes. We will review the performance of the recently installed aberration corrector of the X-ray Photoemission Electron Microscope PEEM-3 and show a large improvement in the efficiency of the electron optics. Hartmann testing is introduced as a quantitative method to measure the geometrical aberrations of a cathode lens electron microscope. We find that aberration correction leads to an order of magnitude reduction of the spherical aberrations, suggesting that a spatial resolution of below 100 nm is possible at 100% transmission of the optics when …

Properties Of Epitaxial Sr0.5ba0.5mno3 Films From First-Principles, Temuujin Bayaraa

Graduate Theses and Dissertations

Magnetoelectric multiferroics, that possess coupled magnetic and electric degrees of freedom, have been receiving ever renewed attention for more than 15 years since they hold promise for the design of novel devices exploiting their cross-coupling.

In this thesis, we present the results of first-principles studies on physical properties of multiferroic Sr0.5Ba0.5MnO3 films under epitaxial compressive and tensile strains, and chemical ordering. We start by reviewing multiferroic materials, a magnetoelectric coupling mechanism and then we give a brief introduction to the first-principles computational methods that are involved in this study.

Here, we report that Sr0.5Ba0.5MnO3 (SBM) films under compressive strain become …

Standard And Anomalous Wave Transport Inside Random Media, Xujun Ma

Dissertations, Theses, and Capstone Projects

This thesis is a study of wave transport inside random media using random matrix theory. Anderson localization plays a central role in wave transport in random media. As a consequence of destructive interference in multiple scattering, the wave function decays exponentially inside random systems. Anderson localization is a wave effect that applies to both classical waves and quantum waves. Random matrix theory has been successfully applied to study the statistical properties of transport and localization of waves. Particularly, the solution of the Dorokhov-Mello-Pereyra-Kumar (DMPK) equation gives the distribution of transmission.

For wave transport in standard one dimensional random systems in …