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Full-Text Articles in Condensed Matter Physics
Self Assembly And Interface Chemistry Of Non-Metallated Tetraphenyl Porphyrin, Geoffrey Rojas
Self Assembly And Interface Chemistry Of Non-Metallated Tetraphenyl Porphyrin, Geoffrey Rojas
Department of Physics and Astronomy: Dissertations, Theses, and Student Research
The study of the electronic properties and geometrical arrangement of 5, 10, 15, 20-tetraphenyl-21H, 23H-porphine on metal is presented. The systems were analyzed using both scanning tunneling microscopy and photoelectron spectroscopy and compared across surfaces to determine how the interface chemistry between the metal and molecule affect the self-assembly and band structure of the adsorbed species. The molecules are found to self-assemble and grow on the Ag(111) surface in a manner described by similar models to weakly bound metal/metal surface systems. The CH-pi bonds between molecules are found to largely determine the relative inter-molecular arrangement, while the more isotropic van …
Transport And Optical Properties Of Quantized Low-Dimensional Systems, Xiaoguang Li
Transport And Optical Properties Of Quantized Low-Dimensional Systems, Xiaoguang Li
Doctoral Dissertations
In this thesis, we present a systematic investigation of the static and dynamic response properties of low-dimensional systems, using a variety of theoretical techniques ranging from time dependent density functional theory to the recursive Green's function method.
As typical low-dimensional systems, metal nanostructures can strongly interact with an electric field to support surface plasmons, making their optical properties extremely attractive in both fundamental and applied aspects. We have investigated the energy broadening of surface plasmons in metal structures of reduced dimensionality, where Landau damping is the dominant dissipation channel and presents an intrinsic limitation to plasmonics technology. We show that …