Atomic, Molecular and Optical Physics | Open Access Articles

Charge Transfer Mediated Triplet Excited State Formation In Donor-Acceptor-Donor Bodipy: Application For Recording Of Holographic Structures In Photopolymerizable Glass, Tatsiana Mikulchyk, Safakath Karuthedath, Catherine S.P. De Castro, Andrey A. Buglak, Aimee Sheehan, Aaron Wieder, FréDéRic Laquai, Izabela Naydenova, Mikhail Filatov

Articles

Donor–acceptor–donor BODIPY triads bearing anthracene or pyrene as electron donating subunits were prepared through a stepwise synthesis. Photoinduced electron transfer and formation of long-lived triplet excited states via spin–orbit charge transfer intersystem crossing (SOCT-ISC) was studied by steady-state and ultrafast pump-probe spectroscopy and further supported by DFT computations. New BODIPYs were found to form triplet states and sensitize singlet oxygen in both polar and non-polar solvents which is unusual for photosensitizers operating via SOCT-ISC. BODIPY-anthracene triad (ABA) was used as a photosensitizer component in a photopolymerizable glass that was prepared by a four-step sol–gel process. ABA in combination with N …

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Giant Acoustically-Induced Synthetic Hall Voltages In Graphene, Pai Zhao, Chithra H. Sharma, Renrong Liang, Christian Glasenapp, Lev Mourokh, Vadim M. Kovalev, Patrick Huber, Marta Prada, Lars Tiemann, Robert H. Blick

Publications and Research

Any departure from graphene’s flatness leads to the emergence of artificial gauge fields that act on the motion of the Dirac fermions through an associated pseudomagnetic field. Here, we demonstrate the tunability of strong gauge fields in nonlocal experiments using a large planar graphene sheet that conforms to the deformation of a piezoelectric layer by a surface acoustic wave. The acoustic wave induces a longitudinal and a giant synthetic Hall voltage in the absence of external magnetic fields. The superposition of a synthetic Hall potential and a conventional Hall voltage can annihilate the sample’s transverse potential at large external magnetic …

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Periodic Trends In The Infrared And Optical Absorption Spectra Of Metal Chalcogenide Clusters, Alain Ward

Theses and Dissertations

We have investigated the Optical absorption, Infrared spectra, Binding Energies, and various other cluster properties to determine the existence of periodic trend for Transition Metal Chalcogenide Clusters ligated with CO ligands. We were motivated to answer the question of whether periodic behavior can be observed in properties of octahedral metal-chalcogenide clusters. We have used the Amsterdam Density Functional code to calculate the electronic structure of Transition Metal Chalcogenide Clusters using gradient-corrected density functional theory. We determined the existence of several periodic trends in properties of octahedral Transition Metal Chalcogenide Clusters TM₆Se₈(CO)₆. To investigate these …

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Imaging Based Beam Steering For Optical Communication And Lidar Applications, Sajad Saghaye Polkoo

Electronic Theses and Dissertations, 2020-2023

Optical beam steering is a key component in any application that requires dynamic (i.e. realtime control) of beam propagation through free-space. Example applications include remote sensing, spectroscopy, laser machining, targeting, Lidar, optical wireless communications (OWC) and more. The pointing control requirements for many of these applications can be met by traditional mechanical steering techniques; however, these solutions tend to be bulky, slow, expensive, power hungry and prone to mechanical failures leading to short component lifetimes. Two emerging applications, Lidar imaging and OWC, truly need improved beam-steering capabilities to flourish and support the advancement of self-driving cars or relieve the congestion …

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Characterization Of Nanoparticles Using Inductively-Coupled Plasma Mass Spectrometry, Jabez D. Campbell

Graduate Theses/Dissertations

Nanomaterials are a relatively new class of materials that have many applications which span a wide host of fields from medical products to consumer products. The possible compositions and forms of nanomaterials are just as varied as the applications. Therefore, a versatile characterization method is needed for researchers and regulators alike to ensure nanomaterials are properly used. Single Particle Inductively Coupled Plasma Mass Spectrometry (SP-ICP-MS) is a functional method that could fill the characterization need in the nanomaterial research field. Using data from both SP-ICP-MS tests and data from literature established characterization methods, the viability of making SP-ICP-MS the standard …

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Measuring The Diphoton Production From Higgs Boson Decays And In Association With Heavy Flavor Jets, Brianna Lynn Dwyer

Graduate Research Theses & Dissertations

In this dissertation, two important measurements are presented related to diphoton production, the differential cross-section measurement of the Higgs boson in the diphoton decay channel as well as a measurement on inclusive diphoton production with associated heavy-flavor jets. Selections between the two analyses are complimentary, making them a natural pairing in the context of this dissertation. The cross-section measurement is performed in a fiducial region of phase space to closely matches experimental selections. This allows for a largely model-independent measurement, providing a meticulous test of the Standard Model as well as other theoretical predictions. The production of diphoton + heavy-flavor …

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Search For Charged Higgs Bosons In The Tau+Nu Final State With 139 Inverse Fb Of Pp Collision Data At Sqrt(S)=13 Tev With The Atlas Experiment, Elliot Wesley Parrish

Graduate Research Theses & Dissertations

This dissertation uses 139 inverse fb of pp collision data collected at a center of mass energy of sqrt(s)=13 TeV by the ATLAS detector to search for charged Higgs bosons decaying to a tau lepton and a neutrino in association with a top quark. Two subchannels are defined based on the leptonic decay (tau+lepton) or hadronic decay (tau+jets) of the associated top quark. Parameterized Neural Networks are investigated and optimized to improve signal separation from background in both subchannels across a wide charged Higgs boson mass range of 80 GeV to 3000 GeV. Expected exclusion limits at 95% confidence on …

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Studies Of Vector Boson Scattering In The Semileptonic Zv Channel With The Cms Detector At √S = 13 Tev, Ramanpreet Singh

Graduate Research Theses & Dissertations

This dissertation reports on the search for the vector boson scattering (VBS) in semileptonicZV channel, where the Z boson decays to a pair of leptons (electrons or muons), and the other vector boson V (either W or Z) decays hadronically to a pair of jets, in association of two large pseudorapidity jets i.e. ZVjj → l+l−jjjj, l = e or μ. The search used 137 fb−1 of proton-proton collision data collected by the Compact Muon Solenoid (CMS) experiment at the Large Hadron Collider (LHC) with center-of-mass energy (√s) of 13 TeV from 2016 to 2018. VBS is a key process …

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Photonics Of Time-Varying Media, Emanuele Galiffi, Romain Tirole, Shixiong Yin, Huanan Li, Stefano Vezzoli, Paloma A. Huidobro, Mário G. Silveirinha, Riccardo Sapienza, Andrea Alù, J. B. Pendry

Advanced Science Research Center

Time-varying media have recently emerged as a new paradigm for wave manipulation, due to the synergy between the discovery of highly nonlinear materials, such as epsilon-near-zero materials, and the quest for wave applications, such as magnet-free nonreciprocity, multimode light shaping, and ultrafast switching. In this review, we provide a comprehensive discussion of the recent progress achieved with photonic metamaterials whose properties stem from their modulation in time. We review the basic concepts underpinning temporal switching and its relation with spatial scattering and deploy the resulting insight to review photonic time-crystals and their emergent research avenues, such as topological and non-Hermitian …

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Moiré-Driven Topological Transitions And Extremeanisotropy In Elastic Metasurfaces, Simon Yves, Matheus Inguaggiato Nora Nora Rosa, Mohit Gupta, Massimo Ruzzene, Andrea Alù

Advanced Science Research Center

The twist angle between a pair of stacked 2D materials has been recently shown to control remarkable phenomena, including the emergence of flat-band superconductivity in twisted graphene bilayers, of higher-order topological phases in twisted moiré superlattices, and of topological polaritons in twisted hyperbolic metasurfaces. These discoveries, at the foundations of the emergent field of twistronics, have so far been mostly limited to explorations in atomically thin condensed matter and photonic systems, with limitations on the degree of control over geometry and twist angle, and inherent challenges in the fabrication of carefully engineered stacked multilayers. Here, this work extends twistronics to …

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Application Of Image Processing Programs In Color Analysis Of Wood Photodegradation, Gabriel Joseph D. Plata, Ramon M. Delos Santos

Physics Faculty Publications

In general, polymer photodegradation is an important aspect of polymer science that is of great interest to chemistry, materials science, biology, and physics students who engage in this field of research. Wood consists of three main polymers, which makes it a good candidate for such photodegradation studies. Aside from structural changes based on chemical analysis, color change assessment can also be employed to check any extent of degradation on wood without the need for sophisticated analytical equipment. This study presents the application of two image processing programs in color analysis of wood photodegradation: ImageJ and Colormath library, which are Java-based …

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Coupled Dynamics Of Spin Qubits In Optical Dipole Microtraps: Application To The Error Analysis Of A Rydberg-Blockade Gate, L. V. Gerasimov, R. R. Yusupov, A. D. Moiseevsky, I. Vybornyi, K. S. Tikhonov, S. P. Kulik, S. S. Straupe, Charles I. Sukenik, D. V. Kupriyanov

Physics Faculty Publications

Single atoms in dipole microtraps or optical tweezers have recently become a promising platform for quantum computing and simulation. Here we report a detailed theoretical analysis of the physics underlying an implementation of a Rydberg two-qubit gate in such a system—a cornerstone protocol in quantum computing with single atoms. We focus on a blockade-type entangling gate and consider various decoherence processes limiting its performance in a real system. We provide numerical estimates for the limits on fidelity of the maximally entangled states and predict the full process matrix corresponding to the noisy two-qubit gate. We consider different excitation geometries and …

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Ring Bose–Einstein Condensate Atomtronic Rotation Sensor, Oluwatobi I. Adeniji

College of Graduate Studies: Theses & Dissertations

We propose a design for an atomtronic rotation sensor consisting of an array of Bose– Einstein condensates (BECs) confined in a double–target–array potential. The purpose of the sensor is to measure the rotation speed, Ω_R, of the sensor’s rest frame with respect to the “fixed stars.” The atomtronic system consists of an ultracold gas of sodium atoms compressed, using laser light, into a thin horizontal sheet and subjected to a double–target– array potential within the horizontal plane. A “target” BEC consists of a disk–shaped condensate surrounded by a concentric ring–shaped condensate. A “double–target” BEC is two adjacent target …

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Angular Distribution Of Electron-Helium Scattering In The Presence Of A 1.17 Ev Laser Field, Brian N. Kim

Theses and Dissertations--Physics and Astronomy

We have measured relative differential cross sections for 350 eV electrons scattered by a helium target in the presence of 1.17 eV photons from an Nd:YAG laser. We report an angular distribution of free-free electrons that were scattered elastically at angles between 15^o and 80^o and of free-free electrons that underwent the process of electron-impact excitation of helium to its unresolved (1s2s)¹S and (1s2p)¹P excited states at angles between 1^o and 80^o. Our experiments test the momentum transfer dependence and the relationship between elastic and inelastic scattering in the Kroll-Watson approximation. …

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Atomic, Molecular and Optical Physics Commons^™

Full-Text Articles in Atomic, Molecular and Optical Physics

Articles

Giant Acoustically-Induced Synthetic Hall Voltages In Graphene, Pai Zhao, Chithra H. Sharma, Renrong Liang, Christian Glasenapp, Lev Mourokh, Vadim M. Kovalev, Patrick Huber, Marta Prada, Lars Tiemann, Robert H. Blick

Publications and Research

Periodic Trends In The Infrared And Optical Absorption Spectra Of Metal Chalcogenide Clusters, Alain Ward

Theses and Dissertations

Imaging Based Beam Steering For Optical Communication And Lidar Applications, Sajad Saghaye Polkoo

Electronic Theses and Dissertations, 2020-2023

Characterization Of Nanoparticles Using Inductively-Coupled Plasma Mass Spectrometry, Jabez D. Campbell

Graduate Theses/Dissertations

Measuring The Diphoton Production From Higgs Boson Decays And In Association With Heavy Flavor Jets, Brianna Lynn Dwyer

Graduate Research Theses & Dissertations

Search For Charged Higgs Bosons In The Tau+Nu Final State With 139 Inverse Fb Of Pp Collision Data At Sqrt(S)=13 Tev With The Atlas Experiment, Elliot Wesley Parrish

Graduate Research Theses & Dissertations

Studies Of Vector Boson Scattering In The Semileptonic Zv Channel With The Cms Detector At √S = 13 Tev, Ramanpreet Singh

Graduate Research Theses & Dissertations

Photonics Of Time-Varying Media, Emanuele Galiffi, Romain Tirole, Shixiong Yin, Huanan Li, Stefano Vezzoli, Paloma A. Huidobro, Mário G. Silveirinha, Riccardo Sapienza, Andrea Alù, J. B. Pendry

Advanced Science Research Center

Moiré-Driven Topological Transitions And Extremeanisotropy In Elastic Metasurfaces, Simon Yves, Matheus Inguaggiato Nora Nora Rosa, Mohit Gupta, Massimo Ruzzene, Andrea Alù

Advanced Science Research Center

Application Of Image Processing Programs In Color Analysis Of Wood Photodegradation, Gabriel Joseph D. Plata, Ramon M. Delos Santos

Physics Faculty Publications

Coupled Dynamics Of Spin Qubits In Optical Dipole Microtraps: Application To The Error Analysis Of A Rydberg-Blockade Gate, L. V. Gerasimov, R. R. Yusupov, A. D. Moiseevsky, I. Vybornyi, K. S. Tikhonov, S. P. Kulik, S. S. Straupe, Charles I. Sukenik, D. V. Kupriyanov

Physics Faculty Publications

Ring Bose–Einstein Condensate Atomtronic Rotation Sensor, Oluwatobi I. Adeniji

College of Graduate Studies: Theses & Dissertations

Angular Distribution Of Electron-Helium Scattering In The Presence Of A 1.17 Ev Laser Field, Brian N. Kim

Theses and Dissertations--Physics and Astronomy