Atomic, Molecular and Optical Physics Commons^™

Monoclinic Optical Constants, Birefringence, And Dichroism Of Slanted Titanium Nanocolumns Determined By Generalized Ellipsometry, Daniel Schmidt, Benjamin Booso, Tino Hofmann, Eva Schubert, Andrew Sarangan, Mathias Schubert

Electrical and Computer Engineering Faculty Publications

Generalized spectroscopic ellipsometry determines the principal monoclinic optical constants of thin films consisting of slanted titanium nanocolumns deposited by glancing angle deposition under 85° incidence and tilted from the surface normal by 47°. Form birefringence measured for wavelengths from 500 to 1000 nm renders the Ti nanocolumns monoclinic absorbing crystals with c-axis along the nanocolumns, b-axis parallel to the film interface, and 67.5° monoclinic angle between the aand c-axes. The columnar thin film reveals anomalous optical dispersion, extreme birefringence, strong dichroism, and differs completely from bulk titanium. Characteristic bulk interband transitions are absent in the spectral range investigated.

Experimental Study Of The Response Of Semiconductor Detectors For Edxrf Analysis., Sunil Kumar Valaparla

Open Access Theses & Dissertations

This present work relates to the study and characterization of the response function of an energy-dispersive x-ray spectrometer. The problems of energy, efficiency and resolution calibration of the system operating in the energy (5-60 keV) range are discussed. We present the operation characteristics of the portable pyro-electric x-ray generator (COOL-X) and the application of the calibrated response spectrum in the elemental analysis using X-ray Fluorescence (XRF).

We study the response of the Si(Li)-Pin XR-100CR semiconductor detector to low energy photons. The photopeak efficiency was determined experimentally by using radioisotopes and compared against a theoretical efficiency curve. The efficiency for gamma …

Electron Attachment To Trans-Azobenzene, Alberto Modelli, Paul Burrow

Paul Burrow Publications

The temporary anion states of gas-phase trans-azobenzene are characterized by means of electron transmission spectroscopy (ETS) in the 0–6 eV range. The measured energies of vertical electron attachment are compared with the energies of the π* virtual orbitals of the neutral molecule supplied by HF (at MP2 optimized geometries) and B3LYP calculations. The calculated energies, scaled with empirical equations, reproduce quantitatively the energies of the corresponding spectral features and predict a positive vertical electron affinity of 0.83 eV.

The total anion current at the walls of the collision chamber and the mass-selected molecular anion current are also reported as …

Anisotropic Magnetoresistance And Planar Hall Effect In Epitaxial Films Of La0.7Ca0.3Mno3, N. Naftalis, Y. Bason, J. Hoffman, X. Hong, C. H. Ahn, L. Klein

Xia Hong Publications

We measured the anisotropic magnetoresistance (AMR) and the planar Hall effect (PHE) in a [001] oriented epitaxial thin film of La_0.7Ca_0.3MnO₃ (LCMO) as a function of magnetic field, temperature, and current direction relative to the crystal axes. We find that both AMR and PHE in LCMO depend strongly on the current orientation relative to the crystal axes, and we demonstrate the applicability of AMR and PHE equations based on a fourth order magnetoresistance tensor consistent with the film symmetry.

High-Mobility Few-Layer Graphene Field Effect Transistors Fabricated On Epitaxial Ferroelectric Gate Oxides, X. Hong, A. Posadas, K. Zou, C. H. Ahn, J. Zhu

Xia Hong Publications

The carrier mobility μ of few-layer graphene (FLG) field-effect transistors increases tenfold when the SiO₂ substrate is replaced by single-crystal epitaxial Pb(Zr_0.2Ti_0:8)O₃ (PZT). In the electron-only regime of the FLG, μ reaches 7 X 10⁴ cm² / Vs at 300 K for n = 2.4 X 10¹²=cm², 70% of the intrinsic limit set by longitudinal acoustic (LA) phonons; it increases to 1.4 X 10⁵ cm² / Vs at low temperature. The temperature-dependent resistivity p(T) reveals a clear signature of LA phonon scattering, yielding …

Quantum Scattering Time And Its Implications On Scattering Sources In Graphene, X. Hong, K. Zou, J. Zhu

Xia Hong Publications

We determine the quantum scattering time T_q in six graphene samples with mobility of 4 400<μ <17 000 cm² /V s over a wide range of carrier density (1.2<n<6X10¹²/cm2). T_q derived from Shubnikov–de Haas oscillation ranges ~25–74 fs, corresponding to a single-particle level broadening of 4.5–13 meV. The ratio of the transport to quantum scattering time T_t /T_q spans 1.5–5.1 in these samples, which can be quantitatively understood combining scattering from short-ranged centers and charged impurities located within 2 nm of the graphene sheet. Our results suggest that charges residing on the SiO …

Partial Ion Yield Sspectroscopy Around The Cl 2p And C 1s Ionization Thresholds In Cf3cl, D. Ceolin, Maria Novella Piancastelli, Wayne C. Stolte, Dennis W. Lindle

Chemistry and Biochemistry Faculty Research

We present a partial ion yield experiment on freon 13, CF₃Cl, excited in the vicinity of the C 1s and Cl 2p ionization thresholds. We have collected a large amount of cationic fragments and a few anionic fragments at both edges. We have observed a strong intensity dependence of Rydberg transitions with ion fragment size for the CF_nCl⁺ and CF_n⁺/F⁺ (n=0–3) series at both the Cl 2p and C 1s ionization edges. Selectivity in the fragmentation processes involving the C–Cl and C–F bonds are highlighted by the intensities of the C …

Comparative Study Of Forward And Diffusely Scattered Light In A Coherently Prepared Ultracold Rubidium Gas, Rocio Gisel Olave Gonzalez

Physics Theses & Dissertations

A comparison between forward and diffusely scattered light propagating in a coherently prepared ultracold ⁸⁷Rb atomic vapor is presented. This research is part of the ongoing effort to characterize the processes, such as diffusion, that contribute to coherence loss in atomic media under conditions of electromagnetically induced transparency, for applications in realistic systems. Toward this end, a magneto optical trap (MOT) of ⁸⁷Rb has been built, and the atomic vapor sample characterized in terms of atomic density, shape and size, temperature, and optical depth. Next, two co-propagating beams were sent through the sample, to establish an electromagnetically induced …

Computational Modeling Studies Of The Structures And Properties Of Organotin(Iv) And Stannyl-Thioether Systems With Comparisons To X-Ray Crystallography, Michelle R. Stem Joseph

Open Access Theses & Dissertations

Controlling the toxic effects of organotin(IV) compounds involves engineering the structure of the molecules to optimize their properties. Molecular engineering, coupled with improved capabilities to generate reliable computational optimization models (COMs), will enable researchers to have greater success at harnessing the highly specific cytotoxicity of organotins. For example, as the thio_n ligand phenyl groups were replaced with Cl atoms, the S-Sn intramolecularity was strengthened, the bond distance decreased, and the stannyl tetrahedral structure was deformed from its triphenyl conformation. With each substitution, conformation deformations lowered the damaging bioactivity levels of thio_n. Bonding various ligands to organotin(IV) compounds …

Yttrium And Hydrogen Superstructure And Correlation Of Lattice Expansion And Proton Conductivity In The Bazr0.9y0.1o2.95 Proton Conductor, A. Braun, A. Ovalle, V. Pomjakushin, A. Cervellino, S. Erat, Wayne C. Stolte, T. Graule

Chemistry and Biochemistry Faculty Research

Bragg reflections in Y-resonant x-ray diffractograms of BaZr_0.9Y_0.1O_2.95 (BZY10) reveal that Y is organized in a superstructure. Comparison with neutron diffraction superstructure reflections in protonated/deuterated BZY10 suggests that both superstructures are linked, and that protons move in the landscape imposed by the Y. The thermal lattice expansion decreases abruptly for protonated BZY10 at T≥648±20 K, coinciding with the onset of lateral proton diffusion and suggesting a correlation of structural changes and proton conductivity. The chemical shift in the Y L₁-shell x-ray absorption spectra reveals a reduction from Y³⁺ toward Y²⁺ upon …

The Use Of A Lock-In Amplifier To Stabilize The Frequency Of A Laser Diode, Jose M. Juarez

College Honors Program

We have designed, constructed, and tested a lock-in amplifier with readily available electronic components and homebuilt analog circuits. Its performance is comparable to that of a commercial unit, but it costs significantly less and is much more compact. The various components of our lock-in amplifier are discussed and the basic principles behind the function and operation of this versatile device are explained. We have also assembled a laser system and used the output signal of our lock-in amplifier in a negative feedback loop to stabilize the frequency of our laser to an atomic reference frequency.

Light Scattering In Ultracold High Density Rubidium Vapor, Salim Balik

Physics Theses & Dissertations

Recent developments in laser cooling and trapping opened the door to a world full of new opportunities for research in atomic, molecular and optical physics as well as condensed matter physics. It became possible to do experiments under conditions that are hard to achieve in condensed matter systems but recently have been observed in atomic systems. Bose Einstein Condensation, the Mott insulator transition, and superfluidity are examples of such achievements. Another considerable interest to both condensed matter and atomic physics is Anderson localization of light. The localization phenomenon is named after P. W. Anderson who suggested the possibility of localization …

Imaging-Based Parametric Resonance In An Optical Dipole-Atom Trap, S. Balik, A. L. Win, M. D. Havey

Physics Faculty Publications

We report sensitive detection of parametric resonances in a high-density sample of ultracold ⁸⁷Rb atoms confined to a far-off-resonance optical dipole trap. Fluorescence imaging of the expanded ultracold atom cloud after a period of parametric excitation shows significant modification of the atomic spatial distribution and has high sensitivity compared with traditional measurements of parametrically driven trap loss. Using this approach, a significant shift of the parametric resonance frequency is observed and attributed to the anharmonic shape of the dipole trap potential. 2009 The American Physical Society.

Precise Measurement Of The Neutron Magnetic Form Factor Gnm In The Few-Gev² Region, Clas Collaboration, J. Lachniet, H. Bagdasaryan, S. Bültmann, N. Kalantarians, G. E. Dodge, T. A. Forest, G. Gavalian, C. E. Hyde-Wright, A. Klien, S. E. Kuhn, M. R. Niroula, R. A. Niyazov, L. M. Qin, L. B. Weinstein, J. Zhang

Physics Faculty Publications

The neutron elastic magnetic form factor was extracted from quasielastic electron scattering on deuterium over the range Q² = 1.0–4.8  GeV² with the CLAS detector at Jefferson Lab. High precision was achieved with a ratio technique and a simultaneous in situ calibration of the neutron detection efficiency. Neutrons were detected with electromagnetic calorimeters and time-of-flight scintillators at two beam energies. The dipole parametrization gives a good description of the data