Atomic, Molecular and Optical Physics Commons^™

Constructing A Laser Stabilization System For Frequency Metrology, Stephanie Letourneau

UNLV Theses, Dissertations, Professional Papers, and Capstones

Frequency metrology and quantum control, which uses light as a tool for measurement and manipulation, relies on spectrally narrow, stable lasers. Often thought of as being perfectly monochromatic and coherent, in reality, the free-running instantaneous linewidth of lasers can be on the order of hundreds of kHz in the millisecond time-frame and drift on the order of tens of MHz over hours. To correct for these instabilities in real-time, a variety of laser stabilization methods have been implemented, including the Pound-Drever-Hall (PDH) method, saturation absorption spectroscopy (SAS), and dichroic atomic vapor laser locking (DAVLL). All of these methods rely on …

A Simple And Low-Cost Method For Generating Short Laser Pulses, Daniel Fisher

Undergraduate Research Symposium Posters

A simple, portable method is described and demonstrated for generating short optical pulses (~ 1 μsec) from a continuous wave (CW) source using a rotating pinhole. A CW 633nm HeNe beam was focused onto a 225 μm diameter stainless steel pinhole, which was rotated up to 1000 Hz using an optical chopper wheel. The pulsed light was then focused onto a silicon photodetector and read by an oscilloscope. This novel setup aims to bridge the gap between pulsed laser performance and price for wide application in spectroscopy methods, industrial laser peening, and medical treatments. This will be the first publication …

Developing A Remote Gamma-Ray Spectra Collection System (Rgscs) By Coupling A High Purity Germanium (Hpge) Detector With A Cosmicguard Background Reduction Device, Zaijing Sun, Krishnakumar Divakar Nangeelil, Haven Searcy

Health Physics and Diagnostic Sciences Faculty Research

Despite being widely used for high-resolution spectral analysis and quantifying low activity in natural samples, the operations and data analysis of High Purity Germanium (HPGe) gamma-ray detectors are seldom fully automated due to the excessive costs associated with commercially available automatic sample changing systems. This paper introduces the design and implementation of a cost-effective, customized remote gamma-ray spectra collection system centered around the HPGe detector coupled to a cosmic-ray veto background reduction device. The HPGe detector system, equipped with a Lynx DSA, is seamlessly integrated with an economically viable automatic sample changer. This sample vial changer is controlled by a …

Trapping And Cooling Of Ca+ For Cold Ion-Radical Collisions, Bernardo Gutierrez

Undergraduate Research Symposium Posters

Free radicals are molecules that contain an unpaired valence electron which induces high reactivity. Ion radical reactions are typically exothermic and have low (or zero) activation energy. It is for these reasons that ion-radical reactions are believed to dominate in interstellar clouds where temperatures hover around 3-10K. State-to-state measurements require precision control of both reactants.

Combining Freestanding Ferroelectric Perovskite Oxides With Two-Dimensional Semiconductors For High Performance Transistors, Sergio Puebla, Thomas Pucher, Victor Rouco, Gabriel Sanchez-Santolino, Yong Xie, Victor Zamora, Fabian A. Cuellar, Federico J. Mompean, Carlos Leon, Carlos O. Island, Mar Garcia-Hernandez, Jacobo Santamaria, Carmen Munuera, Andres Castellanos-Gomez

Physics & Astronomy Faculty Research

We demonstrate the fabrication of field-effect transistors based on single-layer MoS2 and a thin layer of BaTiO3 (BTO) dielectric, isolated from its parent epitaxial template substrate. Thin BTO provides an ultrahigh-κ gate dielectric effectively screening Coulomb scattering centers. These devices show mobilities substantially larger than those obtained with standard SiO2 dielectrics and comparable with values obtained with hexagonal boron nitride, a dielectric employed for fabrication of high-performance two-dimensional (2D) based devices. Moreover, the ferroelectric character of BTO induces a robust hysteresis of the current vs gate voltage characteristics, attributed to its polarization switching. This hysteresis is strongly suppressed when the …

Coexistence Of Vitreous And Crystalline Phases Of H2o At Ambient Temperature, Ali K. Shargh, Aude Picard, Rostislav Hrubiak, Dongzhou Zhang, Russell J. Hemley, Shanti Deemyad, Niaz Abdolrahim, Saveez Saffarian

Life Sciences Faculty Research

Formation of vitreous ice during rapid compression of water at room temperature is important for biology and the study of biological systems. Here, we show that Raman spectra of rapidly compressed water at greater than 1 GPa at room temperature exhibits the signature of high-density amorphous ice, whereas the X-ray diffraction (XRD) pattern is dominated by crystalline ice VI. To resolve this apparent contradiction, we used molecular dynamics simulations to calculate full vibrational spectra and diffraction patterns of mixtures of vitreous ice and ice VI, including embedded interfaces between the two phases. We show quantitatively that Raman spectra, which probe …

Dispersion In High Temperature Superconductors, Lazar Novakovic

Undergraduate Research Symposium Podium Presentations

Superconductors are used in many different industries: Efficient power transmission, Maglev train, MRIs

Separating Non-Linear Optical Signals Of A Sample From High Harmonic Radiation In A Soft X-Ray Free Electron Laser, Toshihide Sumi, Masafumi Horio, Tomoaki Senoo, Tetsuya Wada, Yuki Tsujikawa, Xiaoni Zhang, Paul Manset, Mihoko Araki, Yasuyuki Hirata, Walter S. Drisdell, John W. Freeland, Angelique Amadno, Michael Zuerch, Yuya Kubota, Shigeki Owada, Kensuke Tono, Makina Yabashi, Craig P. Schwartz, Iwao Matsuda

Nevada Extreme Conditions Laboratory Faculty Research

Second harmonic generation (SHG) is a unique non-linear optical effect that can be used to investigate chemical states of molecules at surfaces/interfaces. By the use of soft X-rays, SHG gains element selectivity through the inner-core excitation resonance. However, it is challenging to observe SHG signals separately from the second-order light generated from the undulator. Here, we report a new ellipsometry method for soft X-ray SHG to suppress the contribution of second-harmonic radiation from the light source. Through measurements of a GaAs(100) crystal, we demonstrate that pure SHG signals can be obtained for the horizontally polarized component. The present method is …

Accurate Flux Calibration Of Gw170817: Is The X-Ray Counterpart On The Rise?, E. Troja, B. O'Connor, G. Ryan, L. Piro, R. Ricci, B. Zhang, T. Piran, G. Bruni, S. B. Cenko, H. Van Eerten

Physics & Astronomy Faculty Research

X-ray emission from the gravitational wave transient GW170817 is well described as non-thermal afterglow radiation produced by a structured relativistic jet viewed off-axis. We show that the X-ray counterpart continues to be detected at 3.3 years after the merger. Such long-lasting signal is not a prediction of the earlier jet models characterized by a narrow jet core and a viewing angle ≈20 deg, and is spurring a renewed interest in the origin of the X-ray emission. We present a comprehensive analysis of the X-ray dataset aimed at clarifying existing discrepancies in the literature, and in particular the presence of an …

Dicationic Stilbazolium Salts: Structural, Thermal, Optical, And Ionic Conduction Properties, Pradip K. Bhowmik, Jung J. Koh, David King, Haesook Han, Benoît Heinrich, Bertrand Donnio, Daniel Zaton, Alfonso Martinez-Felipe

Chemistry and Biochemistry Faculty Research

Two series of new dicationic stilbazolium salts containing tosylate and triflimide counterions, respectively, were synthesized and characterized by spectroscopic techniques and elemental analysis. Despite of their promesogenic structures, none of these salts are mesomorphous, and instead they solely exhibit crystalline polymorphism, as deduced from differential scanning calorimetry, polarizing optical microscopy and variable temperature X-ray measurements. These salts were also found to be highly thermally stable with decomposition temperatures occurring well above 300 °C, and up to 367 °C for the triflimide salts, as determined by thermogravimetric analysis. UV–Vis absorption and photoluminescent properties were examined in both solution and in the …

Non-Adiabatic Quantum Interference In The Ultracold Li + Lina → Li2+ Na Reaction, Brian K. Kendrick, Hui Li, Ming Li, Svetlana Kotochigova, James F.E. Croft, Naduvalath Balakrishnan

Chemistry and Biochemistry Faculty Research

Electronically non-adiabatic effects play an important role in many chemical reactions. However, how these effects manifest in cold and ultracold chemistry remains largely unexplored. Here for the first time we present from first principles the non-adiabatic quantum dynamics of the reactive scattering between ultracold alkali-metal LiNa molecules and Li atoms. We show that non-adiabatic dynamics induces quantum interference effects that dramatically alter the ultracold rotationally resolved reaction rate coefficients. The interference effect arises from the conical intersection between the ground and an excited electronic state that is energetically accessible even for ultracold collisions. These unique interference effects might be exploited …

X-Spec: A 70 Ev To 15 Kev Undulator Beamline For X-Ray And Electron Spectroscopies, Lothar Weinhardt, Ralph Steininger, Dagmar Kreikemeyer-Lorenzo, Stefan Mangold, Dirk Hauschild, David Batchelor, Thomas Spangenberg, Clemens Heske

Chemistry and Biochemistry Faculty Research

X-SPEC is a high-flux spectroscopy beamline at the KIT (Karlsruhe Institute of Technology) Synchrotron for electron and X-ray spectroscopy featuring a wide photon energy range. The beamline is equipped with a permanent magnet undulator with two magnetic structures of different period lengths, a focusing variable-line-space plane-grating monochromator, a double-crystal monochromator and three Kirkpatrick-Baez mirror pairs. By selectively moving these elements in or out of the beam, X-SPEC is capable of covering an energy range from 70 eV up to 15 keV. The flux of the beamline is maximized by optimizing the magnetic design of the undulator, minimizing the number of …

Response Of The Mode Grüneisen Parameters With Anisotropic Compression: A Pressure And Temperature Dependent Raman Study Of Β-Sn, Jasmine K. Hinton, Christian Childs, Dean Smith, Paul B. Ellison, Keith V. Lawler, Ashkan Salamat

Physics & Astronomy Faculty Research

The lattice dynamic response of body-centered tetragonal β−Sn (I41/amd) under high pressure and -temperature conditions is determined using experimental optical vibration modes. Raman scattering is used to map the phase stability region of β−Sn to perform mode Grüneisen analysis, and we demonstrate the necessity of an optical intensity calibration for Raman thermometry. The Grüneisen tensor is evaluated along a set of isotherms to address shortcomings of single-mode Grüneisen parameters with respect to anisotropic deformations of this tetragonal structured soft metal. The changes observed here in the Grüneisen tensor as a function of temperature are related to anharmonicity and denote potential …

Toughening A Superstrong Carbon Crystal: Sequential Bond-Breaking Mechanisms, Hui Liang, Hefei Li, Quan Li, Changfeng Chen

Physics & Astronomy Faculty Research

A complex orthorhombic carbon allotrope in Pbam symmetry with 32 atoms in its unit cell, thus termed Pbam-32 carbon, was recently predicted [C. Y. He et al., Phys. Rev. Lett. 121, 175701 (2018)]. Its crystal structure comprises alternating fivefold, sixfold, and sevenfold carbon rings and exhibits reduced bonding anisotropy compared to diamond, raising the prospects of finding a superstrong material with distinct and favorable mechanical properties. Here we report findings from first-principles calculations that reveal peculiar stress-strain relations in Pbam-32 carbon. The obtained stress responses under various tensile and shear strains display outstanding characteristics contrasting those of traditional superhard materials …

Hyperpolarizability Dispersion Measured For Cs2 Vapor, Rodrigo N. Fernandez, David P. Shelton

Physics & Astronomy Faculty Research

The second hyperpolarizability (��) of carbon disulfide (CS2) is measured by gas-phase electric-field-induced second-harmonic generation for laser wavelengths in the range 765–1064 nm. The observed hyperpolarizability is decomposed into electronic (����) and vibrational (����) contributions, and the dispersion curve for ���� is extrapolated to the static limit, with the result of ����0=12558±93 atomic units =7.83±0.06×10−61C4m4J−3=6.33±0.0×10−36 esu (Taylor series convention). The results of this experiment agree with other recent nonlinear optical measurements and theoretical calculations.

The Breakup Of A Helium Cluster After Removing Attractive Interaction Among A Significant Number Of Atoms In The Cluster, Tao Pang

Physics & Astronomy Faculty Research

The breakup of a quantum liquid droplet is examined through a 4He cluster by removing the attractive tail in the interaction between some of the atoms in the system with the diffusion quantum Monte Carlo simulation. The ground-state energy, kinetic energy, cluster size, and density profile of the cluster are evaluated against the percentage of the atoms without the attractive tail. The condition for the cluster to lose its ability to form a quantum liquid droplet at zero temperature is found and analyzed. The cluster is no longer able to form a quantum liquid droplet when about two-thirds of pairs …

Smooth Flow In Diamond: Atomistic Ductility And Electronic Conductivity, Chang Liu, Xianqi Song, Quan Li, Yanming Ma, Changfeng Chen

Physics & Astronomy Faculty Research

Diamond is the quintessential superhard material widely known for its stiff and brittle nature and large electronic band gap. In stark contrast to these established benchmarks, our first-principles studies unveil surprising intrinsic structural ductility and electronic conductivity in diamond under coexisting large shear and compressive strains. These complex loading conditions impede brittle fracture modes and promote atomistic ductility, triggering rare smooth plastic flow in the normally rigid diamond crystal. This extraordinary structural change induces a concomitant band gap closure, enabling smooth charge flow in deformation created conducting channels. These startling soft-and-conducting modes reveal unprecedented fundamental characteristics of diamond, with profound …

Gamma-Ray Bursts Induced By Turbulent Reconnection, A. Lazarian, Bing Zhang, Siyao Xu

Physics & Astronomy Faculty Research

We revisit the Internal-Collision-induced MAgnetic Reconnection and Turbulence model of gamma-ray bursts (GRBs) in view of the advances made in understanding of both relativistic magnetic turbulence and relativistic turbulent magnetic reconnection. We identify the kink instability as the most natural way of changing the magnetic configuration to release the magnetic free energy through magnetic reconnection, as well as driving turbulence that enables fast turbulent reconnection. We show that this double role of the kink instability is important for explaining the prompt emission of GRBs. Our study confirms the critical role that turbulence plays in boosting reconnection efficiency in GRBs and …

Rotational Quenching Of Hd Induced By Collisions With H2 Molecules, Yier Wan, Nadulvalath Balakrishnan, B. H. Yang, R. C. Forrey, P. C. Stancil

Chemistry and Biochemistry Faculty Research

Rate coefficients for rotational transitions in HD induced by H2 impact for rotational levels of HD j ≤ 8 and temperatures 10 K ≤ T ≤ 5000 K are reported. The quantum mechanical close-coupling (CC) method and the coupled-states (CS) decoupling approximation are used to obtain the cross-sections employing the most recent highly accurate H2–H2 potential energy surface (PES). Our results are in good agreement with previous calculations for low-lying rotational transitions The cooling efficiency of HD compared with H2 and astrophysical applications are briefly discussed.

The Purported Square Ice In Bilayer Graphene In A Nanoscale, Monolayer Object, Tod A. Pascal, Craig P. Schwartz, Keith V. Lawler, David Prendergast

Chemistry and Biochemistry Faculty Research

The phase diagram of water is complex, and interfacial effects can stabilize unusual structures at the nanoscale. Here, we employ bond order accelerated molecular dynamics simulations to show that upon encapsulation within bilayer graphene, water can spontaneously adopt a two-dimensional (monomolecular) layer of “square ice” at ambient conditions, instead of an encapsulated water droplet. Free energy calculations show that this motif is thermodynamically stable up to diameters of approximately 15 nm due to enhanced hydrogen bonding and favorable binding to the graphene sheets. Entropic losses due to solidification and reduced graphene–graphene binding enthalpy are opposing thermodynamic forces that conspire to …

Controlling The Stereodynamics Of Cold Molecular Collisions, Balakrishnan Naduvalath, J. F. E. Croft, Meng Huang, Hua Guo

Chemistry and Biochemistry Faculty Research

We report numerically-exact quantum scattering calculations for low-energy collisions of quantum-state prepared HD with H2. Excellent agreement is obtained with recent measurements of Perreault et al. for the angular distribution of scattered HD at a collision energy of 1 K. By state-preparation of the HD molecules, control of the angular distribution of scattered HD was demonstrated. The stereo-dynamic control is achieved by the ability to choose a single or a coherent superposition of quantum states. We present a first-principles simulation of the experiment which enables us to attribute the main features of the observed angular distribution to a single L …

Kondo Signatures Of A Quantum Magnetic Impurity In Topological Superconductors, Rui Wang, Wei-Yi Su, Jian-Xin Zhu, Chin-Sen Ting, Hai Li, Changfeng Chen, Baigeng Wang, Xiaoqun Wang

Physics & Astronomy Faculty Research

We study the Kondo physics of a quantum magnetic impurity in two-dimensional topological superconductors (TSCs), either intrinsic or induced on the surface of a bulk topological insulator, using a numerical renormalization group technique. We show that, despite sharing the p+ip pairing symmetry, intrinsic and extrinsic TSCs host different physical processes that produce distinct Kondo signatures. Extrinsic TSCs harbor an unusual screening mechanism involving both electron and orbital degrees of freedom that produces rich and prominent Kondo phenomena, especially an intriguing pseudospin Kondo singlet state in the superconducting gap and a spatially anisotropic spin correlation. In sharp contrast, intrinsic TSCs support …

Optimization Of Useful Hard X-Ray Photochemistry, David Lewis Goldberger

UNLV Theses, Dissertations, Professional Papers, and Capstones

X-ray induced damage is generally considered a nuisance, but in the field of Useful Hard X-ray Photochemistry we harness the highly ionizing and penetrating properties of hard X-rays (> 7 keV) to initiate novel photochemical decomposition and synthesis at ambient and extreme conditions. Preliminary experiments suggest that the energy of irradiating photons and the sample pressure play roles in determining the nature of X-ray induced damage. Here, we present the X-ray energy dependence of damage induced in strontium oxalate, strontium nitrate, and barium nitrate, as well as the pressure dependence of X-ray induced damage of strontium oxalate. Our results indicate …

Pressure Effect On The Antiferromagnetic Compound Ce2ni3ge5, Jun Gouchi, Yuki Nakamura, Miho Nakashima, Tasushi Amako, Ravhi Kumar, Yoshiya Uwatoko

Physics & Astronomy Faculty Research

In this study, the electrical resistivity and magnetization of a single crystal of Ce2Ni3Ge5 heavy fermion compound were performed under pressure. The resistivity and magnetization showed two antiferromagnetic transitions at ambient pressure. On applying pressure, the transitions merged at 1 GPa. At higher pressures, the antiferromagnetic transition temperature decreases, and disappears. It is suggesting that the critical pressure of Ce2Ni3Ge5 was 4.1 GPa.

A Case For Chiral Contributions To Nondipole Effects In Photoionization Using Linearly Polarized Soft X-Rays, Kyle Patrick Bowen

UNLV Theses, Dissertations, Professional Papers, and Capstones

Modelling angular distributions of photoelectrons requires making accurate approximations of both the incoming light and the behavior of bound electrons. The experimental determination of photoelectron angular distributions is crucial to the development of accurate theoretical models governing the light-matter interaction. To date, many models have relied upon the dipole approximation, which assumes a constant electric field as the source of ionization. Despite knowing that the dipole approximation would break down as photon energy increased, the precise limit was unclear. Over the past two decades, a strong case has been made that corrections to the dipole approximation are necessary for accurately …

Li+ Ion Transport In Select Lithium-Rich Antiperovskites, John William Howard

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lithium-Rich Antiperovskites (LiRAPs) have been shown to possess relatively high ionic conductivity at room temperature, and become superionic conductors at elevated temperatures. These materials generally have a stoichiometry Li3BX, where B is a doubly deficient anion, and X is a monovalent anion. Ideally they belong to the high symmetry space group Pm-3m where lithium atoms occupy octahedral corners, B anions occupy octahedral centers, and X anions occupy the interstitial centers between the octahedra. LiRAPs were synthesized using several different methods and characterized by XRD, EIS, DSC, TGA, FTIR, and INS techniques. Chemical analyses were performed to determine the stoichiometries of …

Transparent Actuator Made With Few Layer Graphene Electrode And Dielectric Elastomer, For Variable Focus Lens, Taeseon Hwang, Hyeok-Yong Kwon, Joon-Suk Oh, Jung-Pyo Hong, Seung-Chul Hong, Youngkwan Lee, Hyouk Ryeo Choi, Kwang J. Kim, Mainul Hossain Bhuiya, Jae Do Nam

Mechanical Engineering Faculty Research

A transparent dielectric elastomer actuator driven by few-layer-graphene (FLG) electrode was experimentally investigated. The electrodes were made of graphene, which was dispersed inN-methyl-pyrrolidone. The transparent actuator was fabricated from developed FLG electrodes.The FLG electrode with its sheet resistance of 0.45 kΩ/sq (80 nm thick) was implemented to mask silicone elastomer. The developed FLG-driven actuator exhibited an optical transparency of over 57% at a wavenumber of 600 nm and produced bending displacement performance ranging from 29 to 946 μm as functions of frequency and voltage. The focus variation was clearly demonstrated under actuation to study its application-feasibility in …

A Gauge Theoretic Treatment Of Rovibrational Motion In Diatoms, Gregory Colarch

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Born-Oppenheimer approximation has long been the standard approach to solving the Schrödinger equation for diatomic molecules. In it, nuclear and electronic motions are separated into "slow" and "fast" degrees of freedom and couplings between the two are ignored. The neglect of non-adiabatic couplings leads to an incomplete description of diatomic motion, and in a more refined approach, non-adiabatic couplings are uncoupled by transforming the angular momentum of the molecule and electrons into the body-fixed frame.

In this thesis we examine a "modern" form of the Born-Oppenheimer approximation by exploiting a gauge theoretic approach in a description of molecular motion. …

Hybrid Plasmonic Nanoantennas: Fabrication, Characterization, And Application, Shengjie Zhai

UNLV Theses, Dissertations, Professional Papers, and Capstones

As optical counterpart of microwave antennas, plasmonic nanoantennas are important nanoscale devices for converting propagating optical radiation into confined/enhanced electromagnetic fields. Presently, nanoantennas, with a typical size of 200-500 nm, have found their applications in bio-sensing, bio-imaging, energy harvesting, and disease cure and prevention. With the device feature size of next generation IC goes down to 22 nm or smaller, and biological/chemical sensing reaches the Gene’s level, the sizes of the corresponding nanoantennas have to be scaled down to sub-100nm level. In the literature, these sub-100nm nanoantennas are referred as deep subwavelength nanoantennas as size of such miniaturized nanoantennas is …

Measured Rates Of D2 Abstraction In H2o+ , D2 Substitution In H2do+ And Charge Transfer Of He2+ With Noble And Other Gases At <1ev, Chrysanthos Kyriakides

UNLV Theses, Dissertations, Professional Papers, and Capstones

Experimental determination of the rate coefficient values of deuterium abstraction in water ions and deuterium substitution in hydronium ions can improve the understanding of D/H in water at planetary atmospheres, cometary atmospheres, and interstellar medium. Using a cylindrical ion trap, (CIT) and time of flight (TOF) mass spectrometry, a number of measurements at energies below 1 eV have been performed. The deuterium abstraction rate coefficient in water ions, H₂O⁺, and an upper limit for the hydrogen-deuterium substitution rate coefficient in monodeuterated hydronium ion, H₂DO⁺, have been measured. Both the abstraction and substitution …