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Articles 1 - 30 of 41
Full-Text Articles in Oceanography
Changes In Land, Ocean, Atmospheric Parameters Associated With The 2025 Myanmar (Mw 7.7) Earthquake, Feng Jing, Akshansa Chauhan, Ashwani Raju, Ramesh P. Singh
Changes In Land, Ocean, Atmospheric Parameters Associated With The 2025 Myanmar (Mw 7.7) Earthquake, Feng Jing, Akshansa Chauhan, Ashwani Raju, Ramesh P. Singh
Mathematics, Physics, and Computer Science Faculty Articles and Research
Multiple parameters associated with the land, atmosphere, and ocean were analyzed to study short-term and immediate pre-earthquake changes associated with the 28 March 2025 Myanmar earthquake (Mw 7.7). Anomalous clear-sky outgoing longwave radiation (ClrOLR) and trace gases (CH₄, CO, and O₃) were detected within two months prior to the mainshock. Vertical changes at different pressure levels suggest a possible underground source. High-temporal-resolution observations of the infrared brightness temperature and surface air pressure revealed short-lived fluctuations shortly before the earthquake, which may reflect localized stress adjustments and surface latent heat flux release during the final stage of earthquake preparation. In the …
Autonomous Float Data Reveal Decoupled Trends In Chlorophyll And Stratification In The Indian Ocean, Marufa Ishaque, Sophie Clayton, John Klinck
Autonomous Float Data Reveal Decoupled Trends In Chlorophyll And Stratification In The Indian Ocean, Marufa Ishaque, Sophie Clayton, John Klinck
OES Faculty Publications
Recent studies have shown that the Indian Ocean is warming significantly, but how this warming impacts primary production is largely unresolved due to a relative lack of depth-resolved biological observations. In this study, we have used Biogeochemical-Argo data from 2013 to 2022, comprising over 9,000 individual profiles, to examine regional patterns and trends in depth-integrated chlorophyll, depth-integrated net primary production and stratification in the northern and Equatorial Indian Ocean. Our analysis shows that water column stratification is increasing in the majority of the study area, with the highest rate of increase observed in the western Bay of Bengal. At the …
Results Of The Second Ice Shelf-Ocean Model Intercomparison Project (Isomip+), Claire K. Yung, Xylar S. Asay-Davis, Alistair Adcroft, Christopher Y. S. Bull, Jan De Rydt, Michael S. Dinniman, Benjamin K. Galton-Fenzi, Daniel Goldberg, David E. Gwyther, Robert Hallberg, Matthew Harrison, Tore Hattermann, David M. Holland, Denise Holland, Paul R. Holland, James R. Jordan, Nicolas C. Jourdain, Kazuya Kusahara, Gustavo Marques, Pierre Mathiot, Adele K. Morrison, Yoshihiro Nakayama, Olga Sergienko, Robin S. Smith, Alon Stern, Ralph Timmermann, Qin Zhou
Results Of The Second Ice Shelf-Ocean Model Intercomparison Project (Isomip+), Claire K. Yung, Xylar S. Asay-Davis, Alistair Adcroft, Christopher Y. S. Bull, Jan De Rydt, Michael S. Dinniman, Benjamin K. Galton-Fenzi, Daniel Goldberg, David E. Gwyther, Robert Hallberg, Matthew Harrison, Tore Hattermann, David M. Holland, Denise Holland, Paul R. Holland, James R. Jordan, Nicolas C. Jourdain, Kazuya Kusahara, Gustavo Marques, Pierre Mathiot, Adele K. Morrison, Yoshihiro Nakayama, Olga Sergienko, Robin S. Smith, Alon Stern, Ralph Timmermann, Qin Zhou
CCPO Publications
Ocean-driven basal melting of Antarctic ice shelves plays an important role in the mass loss of the Antarctic Ice Sheet. Ice shelf cavity-resolving ocean models are a valuable tool for understanding ice shelf-ocean interactions and for simulating projections of ice shelf and ocean states under future climate. Designed to assess the current state of ice shelf–ocean modelling, the second Ice Shelf–Ocean Model Intercomparison Project, ISOMIP+, consists of 12 ocean model configurations submitted with a common, idealised experimental setup. Here, we focus on the experiments Ocean0–2 (Asay-Davis et al., 2016), which are ocean models with idealised, static ice …
Ocean And Coastal Acidification Monitoring Priorities For The Northeast Us And Eastern Canada, Christopher Hunt, Austin Pugh, Jake Kritzer, Samantha Siedlecki, Kumiko Azetsu-Scott, Parker Gassett, Diane Lavoie, Adam Pimenta, Amy Trice, Elizabeth Turner
Ocean And Coastal Acidification Monitoring Priorities For The Northeast Us And Eastern Canada, Christopher Hunt, Austin Pugh, Jake Kritzer, Samantha Siedlecki, Kumiko Azetsu-Scott, Parker Gassett, Diane Lavoie, Adam Pimenta, Amy Trice, Elizabeth Turner
Faculty Publications
The Interagency Working Group on Ocean Acidification Monitoring Prioritization Plan 2024 calls for Coastal Acidification Networks to identify the ocean and coastal acidification (OCA) monitoring needs most important for their regions. The Northeast Coastal Acidification Network (NECAN) organized a webinar series to study regional needs, which culminated with a workshop in November 2023. This workshop led to the identification of six priority new Monitoring Needs in addition to the maintenance of current monitoring efforts:
• Improve spatial and temporal scale of monitoring co-located OCA variables and biological measurements to better resolve variability of acidification dynamics in concert with biological processes …
Unveiling Hidden Mercury And Methylmercury Sources: The Role Of Submarine Groundwater Discharge In Coastal Lagoons, Céline Lavergne, Júlia Rodriguez-Puig, Clara Ruiz-González, Maria Montero-Curiel, Gemma Casas, Daniel Romano-Gude, Irene Alorda-Montiel, Júlia Dordal-Soriano, Aaron Alorda-Kleinglass, Marc Diego-Feliu, Javier Gilabert, Alex Campillo-De La Maza, Cristina Romera-Castillo, Natalia Torres-Rodriguez, Lars-Eric Heimbürger-Boavida, Jordi Garcia-Orellana, Valenti Rodellas, Andrea G. Bravo
Unveiling Hidden Mercury And Methylmercury Sources: The Role Of Submarine Groundwater Discharge In Coastal Lagoons, Céline Lavergne, Júlia Rodriguez-Puig, Clara Ruiz-González, Maria Montero-Curiel, Gemma Casas, Daniel Romano-Gude, Irene Alorda-Montiel, Júlia Dordal-Soriano, Aaron Alorda-Kleinglass, Marc Diego-Feliu, Javier Gilabert, Alex Campillo-De La Maza, Cristina Romera-Castillo, Natalia Torres-Rodriguez, Lars-Eric Heimbürger-Boavida, Jordi Garcia-Orellana, Valenti Rodellas, Andrea G. Bravo
OES Faculty Publications
Mercury loads from Submarine Groundwater Discharge (SGD) may represent an overlooked source of methylmercury (MeHg) to the ocean, affecting human and ecosystem health. The SGD process involves the flow of fresh, saline, or mixed groundwater from coastal aquifers into the oceans classified in different components. Existing studies rarely report the fluxes supplied by the different SGD components; therefore, the relevance of SGD as a source of mercury remains unclear. We aimed to quantify SGD-driven mercury/methylmercury fluxes to the coast, focusing on the largest coastal lagoon in the western Mediterranean. We measured total dissolved mercury and MeHg in surficial and porewaters …
Dust Deposition To The Sargasso Sea: A Comparison Of Estimates Using Aluminum In The Surface Ocean Versus Aerosols And Rainwater, T. E. Williams, P. N. Sedwick, B. M. Sohst, K. N. Buck, S. Caprara, R. J. Johnson, D. C. Ohnemus, J. A. Resing, L. E. Sofen, A. Tagliabue, B. S. Twining
Dust Deposition To The Sargasso Sea: A Comparison Of Estimates Using Aluminum In The Surface Ocean Versus Aerosols And Rainwater, T. E. Williams, P. N. Sedwick, B. M. Sohst, K. N. Buck, S. Caprara, R. J. Johnson, D. C. Ohnemus, J. A. Resing, L. E. Sofen, A. Tagliabue, B. S. Twining
OES Faculty Publications
As a major component of mineral aerosol that partially dissolves in seawater, aluminum (Al) has been used to estimate time-averaged dust fluxes to the ocean, based on dissolved aluminum (DAl) concentrations and an assumed replacement time of DAl (tau DAl) in the surface mixed layer, along with the fractional solubility (Als) and mass abundance of Al in dust. We apply this method in the Bermuda region using seasonal water-column DAl concentrations, and compare our results with fluxes estimated from Al measured in Bermuda aerosols and rain. Inventories of DAl over the maximum mixed-layer depth of 200 m and empirically derived …
Comparing Surface Currents Near The Mouth Of Three Bays Along The U.S. East Coast: Chesapeake Bay, Delaware Bay, And New York Bay, Tal Ezer, Teresa Updyke
Comparing Surface Currents Near The Mouth Of Three Bays Along The U.S. East Coast: Chesapeake Bay, Delaware Bay, And New York Bay, Tal Ezer, Teresa Updyke
CCPO Publications
Monthly surface currents at 2 km resolution near the mouths of three U.S. east coast bays were obtained from high-frequency radars (Coastal Ocean Dynamics Application Radar, CODAR) during 2012–2024. The currents near these bays, the Chesapeake Bay (CB), the Delaware Bay (DB) and the New York Bay (NB) were analyzed to infer similarity and differences, as well as potential common forcing from regional and basin-scale factors. The contribution to flow variability from local and remote forcing is evaluated by comparing surface currents with (a) river discharges into each bay, (b) with local and regional winds, and (c) with the North …
Multi-Model Estimate Of Antarctic Ice-Shelf Basal Mass Budget And Ocean Drivers, Benjamin K. Galton-Fenzi, Richard Porter-Smith, Sue Cook, Eva Cougnon, David E. Gwyther, Wilma G. C. Huneke, Madelaine G. Rosevear, Xylar Asay-Davis, Fabio Boeira Dias, Michael S. Dinniman, David Holland, Kazuya Kusahara, Kaitlin A. Naughten, Keith W. Nicholls, Charles Pelletier, Ole Richter, Hélène Seroussi, Ralph Timmerman
Multi-Model Estimate Of Antarctic Ice-Shelf Basal Mass Budget And Ocean Drivers, Benjamin K. Galton-Fenzi, Richard Porter-Smith, Sue Cook, Eva Cougnon, David E. Gwyther, Wilma G. C. Huneke, Madelaine G. Rosevear, Xylar Asay-Davis, Fabio Boeira Dias, Michael S. Dinniman, David Holland, Kazuya Kusahara, Kaitlin A. Naughten, Keith W. Nicholls, Charles Pelletier, Ole Richter, Hélène Seroussi, Ralph Timmerman
CCPO Publications
Societal adaptation to rising sea levels requires robust projections of the Antarctic Ice Sheet's retreat, particularly due to ocean-driven basal melting of its fringing ice shelves. Recent advances in ocean models that simulate ice-shelf melting offer an opportunity to reduce uncertainties in ice–ocean interactions. Here, we compare several community-contributed, circum-Antarctic ocean simulations to highlight inter-model differences, evaluate agreement with satellite-derived melt rates, and examine underlying physical processes. All but one simulation use a melting formulation depending on both thermal driving (T⋆) and friction velocity (u⋆), which together represent the thermal and ocean current forcings at the …
Seasonal Variability Of Surface Ocean Carbon Uptake And Chlorophyll-A Concentration In The West Antarctic Peninsula Over Two Decades, Jessica S. Turner, David R. Munro, Amanda Fay, Sharon Stammerjohn, Heather Kim, Oscar Schofield, Heidi Dierssen
Seasonal Variability Of Surface Ocean Carbon Uptake And Chlorophyll-A Concentration In The West Antarctic Peninsula Over Two Decades, Jessica S. Turner, David R. Munro, Amanda Fay, Sharon Stammerjohn, Heather Kim, Oscar Schofield, Heidi Dierssen
OES Faculty Publications
The Southern Ocean plays a vital role in global CO₂ uptake, but the magnitude and even the sign of the flux remain uncertain, and the influence of phytoplankton phenology is underexplored. This study focuses on the West Antarctic Peninsula, a region experiencing rapid climate change, to examine shifts in seasonal carbon uptake. Using 20 years of in situ air-sea CO₂ flux and satellite-derived Chlorophyll-a, we observe that the seasonal cycles of both air-sea CO₂ flux and Chlorophyll-a intensify poleward. The amplitude of the seasonal cycle of the non-thermal component of surface ocean pCO₂ increases with increasing latitude, while the amplitude …
Intercalibration: A Cornerstone Of The Success Of The Geotraces Program, Ana Aguilar-Islas, Hélène Planquette, Maeve C. Lohan, Walter Geibert, Gregory Cutter
Intercalibration: A Cornerstone Of The Success Of The Geotraces Program, Ana Aguilar-Islas, Hélène Planquette, Maeve C. Lohan, Walter Geibert, Gregory Cutter
OES Faculty Publications
The international GEOTRACES program was developed to enhance knowledge about the distribution of trace elements and their isotopes (TEIs) in the ocean and to reduce the uncertainty about their sources, sinks, and internal cycling. Recognizing the importance of intercalibration from the outset, GEOTRACES implemented intercalibration efforts early in the program, and consensus materials were generated that included the full range of TEIs dissolved in seawater, in suspended particles, and from aerosols. The GEOTRACES section cruises include “crossover station(s)” that are occupied by two or more sections and whereby all aspects of sample collection, preservation, and processing can be compared and …
Supporting Data For Figures In "Wind-Enhanced Separation Of Large-Scale River Plumes From Coastal Corners", Michael M. Whitney
Supporting Data For Figures In "Wind-Enhanced Separation Of Large-Scale River Plumes From Coastal Corners", Michael M. Whitney
Department of Marine Sciences
This archive contains the supporting data for figures in the manuscript "Wind-enhanced separation of large-scale river plumes from coastal corners" by Michael M. Whitney. This study analyzes idealized models to quantify how large-scale river plumes and wind-driven currents interact at perpendicular coastal corners. Data are from the Regional Ocean Modeling System (ROMS) results for idealized model configurations. The Zip file (Figure_data.zip) contains MATLAB data files, which are named FigureXX_data.mat. Variable names and units correspond to graphed data of each figure in manuscript. Full descriptions of research methods and results are included in manuscript.
Supporting Dataset For Observed And Projected Global Warming Pressure On Coastal Hypoxia, Michael M. Whitney
Supporting Dataset For Observed And Projected Global Warming Pressure On Coastal Hypoxia, Michael M. Whitney
Department of Marine Sciences
This archive contains the supporting dataset for the Biogeosciences article “Observed and projected global warming pressure on coastal hypoxia” by Michael M. Whitney. The main objective of the article is studying global patterns exacerbating coastal hypoxia by analyzing linear trends in SST, surface oxygen capacity (saturation concentration), and (vertical-minimum) oxygen concentration. Observations from a satellite-derived SST global climate dataset are analyzed to provide a context of coastal SST and oxygen-capacity trends observed over the last four decades. New analysis of 21st century projections from the Community Earth System Model (CESM) Large Ensemble Project is completed for coastal areas. Observed and …
Emerging Technologies And Approaches For In Situ, Autonomous Observing In The Arctic, Craig M. Lee, Michael Degrandpre, John Guthrie, Victoria Hill, Ron Kwok, James Morison, Christopher J. Cox, Hanumant Singh, Timothy P. Stanton, Jeremy Wilkinson
Emerging Technologies And Approaches For In Situ, Autonomous Observing In The Arctic, Craig M. Lee, Michael Degrandpre, John Guthrie, Victoria Hill, Ron Kwok, James Morison, Christopher J. Cox, Hanumant Singh, Timothy P. Stanton, Jeremy Wilkinson
OES Faculty Publications
Understanding and predicting Arctic change and its impacts on global climate requires broad, sustained observations of the atmosphere-ice-ocean system, yet technological and logistical challenges severely restrict the temporal and spatial scope of observing efforts. Satellite remote sensing provides unprecedented, pan-Arctic measurements of the surface, but complementary in situ observations are required to complete the picture. Over the past few decades, a diverse range of autonomous platforms have been developed to make broad, sustained observations of the ice-free ocean, often with near-real-time data delivery. Though these technologies are well suited to the difficult environmental conditions and remote logistics that complicate Arctic …
Estimating The Risk Of Future Plastic Marine Debris Resulting From The Urban Coastal Built Environment, Kelly C. Jones
Estimating The Risk Of Future Plastic Marine Debris Resulting From The Urban Coastal Built Environment, Kelly C. Jones
OES Theses and Dissertations
The growing urban built environment in the coastal zone poses an unknown risk to the marine biosphere as a source of marine debris. Plastic, since its introduction in the mid- 1900s, is now used in nearly all aspects of human life. Growth in human population and urbanization in coastal zones has resulted in the accumulation of large stocks of plastic in the coastal built environment, and these stocks are still growing exponentially. The coastal zone is exposed to a number of hazards including storms, tsunamis, and sea level rise, and most of these hazards are expected to change in the …
Law Library Blog (December 2021): Legal Beagle's Blog Archive, Roger Williams University School Of Law
Law Library Blog (December 2021): Legal Beagle's Blog Archive, Roger Williams University School Of Law
Law Library Newsletters/Blog
No abstract provided.
Organic Sulfur: A Spatially Variable And Understudied Component Of Marine Organic Matter, Krista Longnecker, Lisa Oswald, Melissa C. Kido Soule, Gregory A. Cutter, Elizabeth B. Kujawinski
Organic Sulfur: A Spatially Variable And Understudied Component Of Marine Organic Matter, Krista Longnecker, Lisa Oswald, Melissa C. Kido Soule, Gregory A. Cutter, Elizabeth B. Kujawinski
OES Faculty Publications
Sulfur (S) is a major heteroatom in organic matter. This project evaluated spatial variability in the concentration and molecular-level composition of organic sulfur along gradients of depth and latitude. We measured the concentration of total organic sulfur (TOS) directly from whole seawater. Our data reveal high variability in organic sulfur, relative to established variability in total organic carbon or nitrogen. The deep ocean contained significant amounts of organic sulfur, and the concentration of TOS in North Atlantic Deep Water (NADW) decreased with increasing age while total organic carbon remained stable. Analysis of dissolved organic matter extracts by ultrahigh resolution mass …
A Pre-Industrial Sea-Level Rise Hotspot Along The Atlantic Coast Of North America, W. R. Gehrels, Sönke Dangendorf, N. L. M. Barlow, M. H. Saher, A. J. Long, P. L. Woodworth, C. G. Piecuch, K. Berk
A Pre-Industrial Sea-Level Rise Hotspot Along The Atlantic Coast Of North America, W. R. Gehrels, Sönke Dangendorf, N. L. M. Barlow, M. H. Saher, A. J. Long, P. L. Woodworth, C. G. Piecuch, K. Berk
CCPO Publications
The Atlantic coast of North America north of Cape Hatteras has been proposed as a “hotspot” of late 20th century sea‐level rise. Here we test, using salt‐marsh proxy sea‐level records, if this coast experienced enhanced sea‐level rise over earlier multidecadal‐centennial periods. While we find in agreement with previous studies that 20th century rates of sea‐level change were higher compared to rates during preceding centuries, rates of 18th century sea‐level rise were only slightly lower, suggesting that the “hotspot” is a reoccurring feature for at least three centuries. Proxy sea‐level records from North America (Iceland) are negatively (positively) correlated with centennial …
Constraining An Ocean Model Under Getz Ice Shelf, Antarctica, Using A Gravity‐Derived Bathymetry, Romain Millan, Pierre St-Laurent, Eric Rignot, Mathieu Morlighem, Jeremie Mouginot, Bernd Scheuchl
Constraining An Ocean Model Under Getz Ice Shelf, Antarctica, Using A Gravity‐Derived Bathymetry, Romain Millan, Pierre St-Laurent, Eric Rignot, Mathieu Morlighem, Jeremie Mouginot, Bernd Scheuchl
CCPO Publications
Getz Ice Shelf, the largest producer of ice shelf meltwater in Antarctica, buttresses glaciers that hold enough ice to raise sea level by 22 cm. We present a new bathymetry of its sub‐ice shelf cavity using a three‐dimensional inversion of airborne gravity data constrained by multibeam bathymetry at sea and a reconstruction of the bedrock from mass conservation on land. The new bathymetry is deeper than previously estimated with differences exceeding 500 m in a number of regions. When incorporated into an ocean model, it yields a better description of the spatial distribution of ice shelf melt, specifically along glacier …
Induced Magnetic Dipole On Jupiter’S Moon Europa, Luke Francis, Michele Zanolin
Induced Magnetic Dipole On Jupiter’S Moon Europa, Luke Francis, Michele Zanolin
Student Works
Physics can have some of the most unique and extraordinary applications of basic principles applied on a larger scale. This paper will explore the properties of induced magnetic dipoles and will examine this phenomenon directly from Jupiter's moon, Europa. These properties will be used to determine if there is liquid water beneath its icy surface and how this conclusion was verified. This will be accomplished using the concepts of magnetic dipoles and induced currents. Recent missions have also revealed estimates of the depth of Europa's subsurface ocean. There have been many measurements taken of Europa's magnetic field, and they are …
Trash Talk: The Effects Of Plastic Pollution On Seabirds In Narragansett Bay, Erin A. O'Neill
Trash Talk: The Effects Of Plastic Pollution On Seabirds In Narragansett Bay, Erin A. O'Neill
Pell Scholars and Senior Theses
Plastic pollution in the ocean is a global concern with more than 8 million tons of plastic dumped into our oceans every year. This policy paper assesses plastic pollution in Narragansett Bay and the negative implications it holds on local seabird populations. Also, essential background information on plastic production and throwaway culture is provided. Moreover, the biological significance of seabirds is described, highlighting the vital role such populations play in local ecosystems such as Narragansett Bay. This paper contributes research to the global issue of plastic pollution by observing declining native wildlife life populations, such as seabirds, on a local …
Sea Squad, Liam Geary Baulch
Sea Squad, Liam Geary Baulch
The Goose
The Sea Squad is a band of cheerleaders against climate change. Taking action as a team in formation, they gather momentum, inviting all people to cheer with them, mimicking the infinitely expandable nature of the seas' molecular structure. The work was developed and performed as a bilingual project at Est-Nord-Est in Saint-Jean-Port-Joli, Quebec, Canada, and has since been performed and exhibited internationally. The following poems are some of the chants that Sea Squad use to get a crowd cheering together against climate change.
Biogeochemical Cycling Of Selenium In The Arctic Ocean, Kyle M. Mcquiggan
Biogeochemical Cycling Of Selenium In The Arctic Ocean, Kyle M. Mcquiggan
OES Theses and Dissertations
Changes in the global climate may have a pronounced effect on the biogeochemical cycling of trace elements like selenium (Se) in the Arctic Ocean. This study described the first quantitative examination of the biogeochemical cycle of selenium in the Amerasian Basin, providing the baseline from which future changes can be identified. Aerosol, dissolved and particulate water samples were collected for Se determinations during the U.S. GEOTRACES GN01 Arctic expedition that sampled the two parts of the Amerasian Basin in 2015: The Makarov Basin on the way to the North Pole and the Canada Basin on the return trip to Dutch …
Mixing It Up In The Ocean Carbon Cycle And The Removal Of Refractory Dissolved Organic Carbon, Yuan Shen, Ronald Benner
Mixing It Up In The Ocean Carbon Cycle And The Removal Of Refractory Dissolved Organic Carbon, Yuan Shen, Ronald Benner
Faculty Publications
A large quantity of reduced carbon is sequestered in the ocean as refractory dissolved molecules that persist through several circuits of global overturning circulation. Key aspects of the cycling of refractory dissolved organic carbon (DOC) remain unknown, making it challenging to predict how this large carbon reservoir will respond to climate change. Herein we investigate mechanisms that remove refractory DOC using bioassay experiments with DOC isolated from surface, mesopelagic and deep waters of the Atlantic Ocean. The isolated DOC was refractory to degradation by native microbial communities, even at elevated concentrations. However, when the refractory DOC was introduced to a …
A Recent Project Shows That The Microbial Carbon Pump Is A Primary Mechanism Driving Ocean Carbon Uptake, Jing M. Chen, Louis Legendre, Ronald Benner
A Recent Project Shows That The Microbial Carbon Pump Is A Primary Mechanism Driving Ocean Carbon Uptake, Jing M. Chen, Louis Legendre, Ronald Benner
Faculty Publications
No abstract provided.
Exploring The Link Between Otolith Growth And Function Along The Biological Continuum In The Context Of Ocean Acidification, Eric D. Wilcox Freeburg
Exploring The Link Between Otolith Growth And Function Along The Biological Continuum In The Context Of Ocean Acidification, Eric D. Wilcox Freeburg
Graduate Doctoral Dissertations
Oceans are acidifying as atmospheric CO2 is drawn down. This process, known as ocean acidification (OA), is well known and documented. Over the next 100 years, pH of the surface ocean is projected to decrease by up to 0.35 units. This CO2 draw down has a direct effect on dissolved inorganic carbon (DIC) balance in the ocean. OA is expected to impact calcifying organisms that rely on constituencies of the DIC system, specifically carbonate ion [CO32-]. It is clear that externally calcified structures, such as coral skeletons, bivalve shells, etc., will be significantly affected as pH, …
The Impact Of Changing Surface Ocean Conditions On The Dissolution Of Aerosol Iron, Matthew P. Fishwick, Peter N. Sedwick, Maeve C. Lohan, Paul J. Worsfold, Kristen N. Buck, Thomas M. Church, Simon J. Ussher
The Impact Of Changing Surface Ocean Conditions On The Dissolution Of Aerosol Iron, Matthew P. Fishwick, Peter N. Sedwick, Maeve C. Lohan, Paul J. Worsfold, Kristen N. Buck, Thomas M. Church, Simon J. Ussher
OES Faculty Publications
The proportion of aerosol iron (Fe) that dissolves in seawater varies greatly and is dependent on aerosol composition and the physicochemical conditions of seawater, which may change depending on location or be altered by global environmental change. Aerosol and surface seawater samples were collected in the Sargasso Sea and used to investigate the impact of these changing conditions on aerosol Fe dissolution in seawater. Our data show that seawater temperature, pH, and oxygen concentration, within the range of current and projected future values, had no significant effect on the dissolution of aerosol Fe. However, the source and composition of aerosols …
Global Estimates Of Mineral Dust Aerosol Iron And Aluminum Solubility That Account For Particle Size Using Diffusion-Controlled And Surface-Area-Controlled Approximations, Qin Han, Charles S. Zender, J. Keith Moore, Clifton S. Buck, Ying Chen, Anne Johansen, Christopher I. Measures
Global Estimates Of Mineral Dust Aerosol Iron And Aluminum Solubility That Account For Particle Size Using Diffusion-Controlled And Surface-Area-Controlled Approximations, Qin Han, Charles S. Zender, J. Keith Moore, Clifton S. Buck, Ying Chen, Anne Johansen, Christopher I. Measures
All Faculty Scholarship for the College of the Sciences
Mineral aerosol deposition is recognized as the dominant source of iron to the open ocean and the solubility of iron in the dust aerosol is highly variable, with measurements ranging from 0.01–80%. Global models have difficulty capturing the observed variations in solubility, and have ignored the solubility dependence on aerosol size. We introduce two idealized physical models to estimate the size dependence of mineral aerosol solubility: a diffusion‐controlled model and a surface‐area‐controlled model. These models produce differing time‐ and space‐varying solubility maps for aerosol Fe and Al given the dust age at deposition, size‐resolved dust entrainment fields, and the aerosol …
Variations In Synechococcus Cell Quotas Of Phosphorus, Sulfur, Manganese, Iron, Nickel, And Zinc Within Mesoscale Eddies In The Sargasso Sea, Benjamin S. Twining, Daliangelis Nunez-Milland, Stefan Vogt, Rodney S. Johnson, Peter N. Sedwick
Variations In Synechococcus Cell Quotas Of Phosphorus, Sulfur, Manganese, Iron, Nickel, And Zinc Within Mesoscale Eddies In The Sargasso Sea, Benjamin S. Twining, Daliangelis Nunez-Milland, Stefan Vogt, Rodney S. Johnson, Peter N. Sedwick
OES Faculty Publications
The quotas of P, S, Mn, Fe, Ni, and Zn in individual Synechococcus cells collected from the surface and deep chlorophyll maximum (DCM) layer of three mesoscale eddies in the Sargasso Sea were measured using synchrotron X-ray fluorescence microscopy. Cells in a mode-water eddy had significantly higher P (57 +/- 10 amol) and Mn (28 +/- 7 zmol) cell quotas than cells collected from a cyclone (22 +/- 2 amol and 10 +/- 1 zmol, respectively) or anticyclone (25 +/- 3 amol and 18 +/- 3 zmol, respectively). Conversely, Ni and Zn quotas were significantly higher in the cells from …
Air-Sea Gas Exchange Of Co2 And Dms In The North Atlantic By Eddy Covariance, Scott Miller, Christa Marandino, Warren J. De Bruyn, Eric S. Saltzman
Air-Sea Gas Exchange Of Co2 And Dms In The North Atlantic By Eddy Covariance, Scott Miller, Christa Marandino, Warren J. De Bruyn, Eric S. Saltzman
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
We report the first simultaneous eddy covariance flux measurements of CO2 and dimethylsulfide (DMS) over the open ocean for two North Atlantic cruises. After normalization for Schmidt number, the two gases give essentially identical gas transfer coefficients and wind speed dependences for the wind speed range 2-10 ms(-1). The data indicate a linear relationship between the gas transfer coefficient and mean wind speed, with measured gas transfer coefficients slightly above the Wanninkhof (1992) parameterization, particularly at low wind speeds. Citation: Miller, S., C. Marandino, W. de Bruyn, and E. S. Saltzman (2009), Air-sea gas exchange of CO2 and DMS in …
A Chemical Ionization Mass Spectrometer For Continuous Underway Shipboard Analysis Of Dimethylsulfide In Near-Surface Seawater, Eric S. Saltzman, Warren J. De Bruyn, M. J. Lawler, Christa Marandino, C. A. Mccormick
A Chemical Ionization Mass Spectrometer For Continuous Underway Shipboard Analysis Of Dimethylsulfide In Near-Surface Seawater, Eric S. Saltzman, Warren J. De Bruyn, M. J. Lawler, Christa Marandino, C. A. Mccormick
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
A compact, low-cost atmospheric pressure, chemical ionization mass spectrometer ('mini-CIMS') has been developed for continuous underway shipboard measurements of dimethylsulfide (DMS) in seawater. The instrument was used to analyze DMS in air equilibrated with flowing seawater across a porous Teflon membrane equilibrator. The equilibrated gas stream was diluted with air containing an isotopically-labeled internal standard. DMS is ionized at atmospheric pressure via proton transfer from water vapor, then declustered, mass filtered via quadrupole mass spectrometry, and detected with an electron multiplier. The instrument described here is based on a low-cost residual gas analyzer (Stanford Research Systems), which has been modified …