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Articles 31 - 60 of 84
Full-Text Articles in Oceanography
Continuously Stratified Flow Dynamics Over A Hollow, David Salas-Monreal
Continuously Stratified Flow Dynamics Over A Hollow, David Salas-Monreal
OES Theses and Dissertations
Acoustic Doppler current profiles (ADCP) and density profiles were measured over three lower Chesapeake Bay bathymetric depressions (hollows) in order to determine the effects of a hollow on a continuously stratified flow. Measurements showed an acceleration of the near-bottom flow as it moved toward the deepest part of the hollows, in contrast to the deceleration expected from two-dimensional Bernoulli-type dynamics. The acceleration was attributed to lateral water intrusions that were most apparent during floods. The presence of lateral water intrusions was corroborated by observations in a transverse section that crossed the deepest part of the hollows. The observed deceleration of …
Tidally Induced Variability At The Chesapeake Bay Entrance, María Andrea Piñones
Tidally Induced Variability At The Chesapeake Bay Entrance, María Andrea Piñones
OES Theses and Dissertations
Time series of current velocity from 6 stations at the Chesapeake Bay entrance were used to study the variability of tidal currents. Particular emphasis was placed on the semidiurnal tidal currents, which explains ~ 70% of the variability of tidal currents. Four different deployments that spanned more than one year showed that the vertical structure of the semidiurnal tidal currents vary seasonally in response to changes in water column stratification. Under destratified conditions favored by wind forcing, the semidiurnal tidal currents rotated cyclonically throughout the water column, thus emulating a Kelvin wave. In contrast, during stratified conditions the tidal currents …
Substituting Otoliths For Chemical Analyses: Does Sagitta = Lapillus?, Nathan G. Smith, Cynthia M. Jones
Substituting Otoliths For Chemical Analyses: Does Sagitta = Lapillus?, Nathan G. Smith, Cynthia M. Jones
OES Faculty Publications
Chemical analysis of fish otoliths has become an important technique in fisheries science with widespread applications. Most research up to this point has focused predominantly on sagittal otoliths, but the underlying assumptions may also apply to lapilli. The goal of this study was to determine whether lapilli and sagittae have the same otolith chemistry and whether one can be substituted for the other for solution-based chemical analysis in wild-captured fish. We compared the stable isotope chemistry (δ13C and δ18O) of paired sagittae and lapilli of juvenile spotted seatrout Cynoscion nebulosus collected from Chesapeake Bay seagrass beds in 2002. …
Interannual Variation Of Stratification In Lower Chesapeake Bay, Christopher S. Katzenmiller
Interannual Variation Of Stratification In Lower Chesapeake Bay, Christopher S. Katzenmiller
OES Theses and Dissertations
Stratification in the water column can prove to be an important indicator to the state of the water column and ecosystem. The focus of this research is to evaluate trends in stratification in the Lower Chesapeake Bay. Detailed analysis was performed on a 14 year data set to study interannual variation in the region of study. Potential energy anomaly was used to quantify stratification. Potential energy anomaly is the amount of energy required to mix a water column. It is determined from the vertical density structure of density. Potential energy anomaly is the departure of potential energy from climate conditions. …
Chemistry Of Surface Waters: Distinguishing Fine-Scale Differences In Sea Grass Habitats Of Chesapeake Bay, Emmanis Dorval, Cynthia M. Jones
Chemistry Of Surface Waters: Distinguishing Fine-Scale Differences In Sea Grass Habitats Of Chesapeake Bay, Emmanis Dorval, Cynthia M. Jones
OES Faculty Publications
We tested the hypothesis that the physical and chemical processes acting in sea grass habitats of the lower Chesapeake Bay are spatially structured and that dissolved elemental chemistry of sea grass-habitat surface waters have their own unique identity. We sampled surface waters from July to September 2001 in five sea grass habitats of the lower bay: Potomac, Rappahannock, York, Island (Tangier-Bloodsworth), and Eastern Shore. Dissolved Mg, Mn, Sr, and Ba concentrations were measured by sector field inductively coupled plasma-mass spectrometry. As expected, Mg, Sr, and Ba exhibited conservative behavior, but Mn exhibited nonconservative behavior along the salinity gradient. Spatial differences …
Biophysical Mechanisms Of Larval Fish Ingress Into Chesapeake Bay, Jonathan A. Hare, Simon Thorrold, Harvey Walsh, Christian Reiss, Arnoldo Valle-Levinson, Cynthia Jones
Biophysical Mechanisms Of Larval Fish Ingress Into Chesapeake Bay, Jonathan A. Hare, Simon Thorrold, Harvey Walsh, Christian Reiss, Arnoldo Valle-Levinson, Cynthia Jones
OES Faculty Publications
Selective tidal stream transport is hypothesized as a dominant mechanism by which larvae of marine animals move through estuarine openings. For larvae moving from the shelf to estuarine habitats, selective tidal stream transport proposes that larvae are higher in the water column during flood tide and lower in the water column during ebb tide. Although a number of studies conclude that selective tidal stream transport is the mechanism responsible for larval ingress, few studies consider alternative mechanisms or consider passive explanations for tidal patterns in larval distributions. We examined the biophysical mechanisms responsible for larval ingress into Chesapeake Bay using …
A Review Of Phytoplankton Composition Within Chesapeake Bay And Its Tidal Estuaries, Harold G. Marshall, Lubomira Burchardt, Richard Lacouture
A Review Of Phytoplankton Composition Within Chesapeake Bay And Its Tidal Estuaries, Harold G. Marshall, Lubomira Burchardt, Richard Lacouture
Biological Sciences Faculty Publications
Based on a continuous 20-year data base ofmonthly sampling in Chesapeake Bay and tidal regions of its major tributaries, 1454 phytoplankton taxa have been identified in these waters. They represent a diverse assemblage of species with a dominant diatom flora throughout the year, in addition to large seasonal representation by chlorophytes, cyanobacteria, cryptophytes and dinoflagellates. Included among this flora were 34 potential harmful or toxin producing species. The phytoplankton compositions associated with the seasonal successional patterns are discussed, in addition to characterizing the dominant floral relationships, with comparison to early composition records within the Bay. Several of the present day …
Relating Water And Otolith Chemistry In Chesapeake Bay, And Their Potential To Identify Essential Seagrass Habitats For Juveniles Of An Estuarine-Dependent Fish, Spotted Seatrout (Cynoscion Nebulosus), Emmanis Dorval
Biological Sciences Theses & Dissertations
A quantitative understanding of habitat use of estuarine-dependent fishes is critical to the conservation of their most essential habitats. Because recruitment and fitness may be influenced by the quality of juvenile habitats, developing methods to quantify habitat-specific survivorship is pivotal to such understanding. An initial step to quantify survivorship is to validate the habitat-specific natural tags contained in otoliths. To this aim I investigated the variability in the chemistry of surface waters and otoliths of juvenile spotted seatrout, Cynoscion nebulosus, in five seagrass habitats of Chesapeake Bay, namely: Potomac, Rappahannock, York, Island, and Eastern Shore. I measured Mg, Ca, …
Black Carbon In Estuarine And Coastal Ocean Dissolved Organic Matter, Antonio Mannino, H. Rodger Harvey
Black Carbon In Estuarine And Coastal Ocean Dissolved Organic Matter, Antonio Mannino, H. Rodger Harvey
OES Faculty Publications
We measured black carbon (BC) in ultrafiltered, high-molecular weight dissolved organic matter (UDOM) in surface waters of Delaware Bay, Chesapeake Bay, and the adjacent Atlantic Ocean (U.S.A.) to investigate the importance of riverine and estuarine dissolved organic matter (DOM) as a source of BC to the ocean. BC was 5-72% of UDOM-C (27 ± 17%), which corresponds to 8.9 ± 6.5% of dissolved organic carbon (DOC), with higher values in the heavily urbanized midbay region of the Delaware Estuary and lower yields in the river and coastal ocean. The spatial and seasonal distributions of BC along the salinity gradient of …
Chromium Tolerant Microbial Communities From The Chesapeake Bay Watershed, Kristine L. Lowe, Ruth E. Fliflet, Tony Ly, Brenda J. Little, Joanne Jones-Meehan
Chromium Tolerant Microbial Communities From The Chesapeake Bay Watershed, Kristine L. Lowe, Ruth E. Fliflet, Tony Ly, Brenda J. Little, Joanne Jones-Meehan
Virginia Journal of Science
Chromium tolerant bacteria were enumerated from portions of the Chesapeake Bay watershed and examined for their potential to reduce Cr(VI). Water and sediment samples were collected from various locations in Baltimore Harbor and Bear Creek, as well as Sandy Point State Park in Maryland and the Anacostia River in Washington, DC. Samples were spread onto agar plates with CrO42- (5 ppm) as the sole terminal electron acceptor. Plates were incubated anaerobically and colony forming units (CFU) enumerated. CFU arising on minimal-CrO42- medium ranged from 103-104 mL-1 or g-1 and community estimates …
Sea Level Slopes And Volume Fluxes Produced By Atmosphere Forcing In Chesapeake Bay, David Salas Monreal
Sea Level Slopes And Volume Fluxes Produced By Atmosphere Forcing In Chesapeake Bay, David Salas Monreal
OES Theses and Dissertations
Year long time series at eight stations in the Chesapeake Bay and inner shelf were used to determine the relative influence of wind, barometric pressure and thermosteric effects on subtidal sea level variability and slopes. Special emphasis was placed on the lower Chesapeake Bay, where inverse barometric effects accounted for up to 33% of the subtidal sea level variations and thermosteric effects accounted for less than 1 % of the variations. The greatest thermosteric influence was noted at the southernmost, saltier and shallower location (Chesapeake Bay Bridge Tunnel). Wind forcing accounted for most of this station's variability, making up more …
Vertical Distributions Of Zooplankton At The Mouth Of Chesapeake Bay And Calibration Of Backscatter From An Acoustic Doppler Current Profiler, Arthur Keith Jenkins
Vertical Distributions Of Zooplankton At The Mouth Of Chesapeake Bay And Calibration Of Backscatter From An Acoustic Doppler Current Profiler, Arthur Keith Jenkins
Biological Sciences Theses & Dissertations
This study investigated the physical factors influencing the vertical distribution of zooplankton at the mouth of the Chesapeake Bay and attempted to derive biological data from acoustic Doppler current profiler (ADCP) backscatter. A single site was occupied in the North Channel at the mouth of Chesapeake Bay (37° 04' N, 75° 58' W) from 17.0–19.7 November 1999. Temperature, salinity, fluorescence, light transmission, current velocity and backscatter were measured throughout the sampling period. Plankton samples were collected every hour from 3.5, 7.5, and 11.5 m.
We found little association between ADCP backscatter and plankton concentrations, but stronger correlations between backscatter and …
Tidal And Subtidal Lateral Structures Of Density And Velocity In The Chesapeake Bay Entrance, Austreberto Cristobal Reyes-Hernandez
Tidal And Subtidal Lateral Structures Of Density And Velocity In The Chesapeake Bay Entrance, Austreberto Cristobal Reyes-Hernandez
OES Theses and Dissertations
Hydrographic and velocity data collected along the Chesapeake Bay Entrance during seven 25-hours cruises centered around neap or spring tides, were used to assess the fortnightly variability in the transverse structure of the tidal and subtidal density and velocity fields. Amplitude and phase of the semidiurnal and diurnal harmonics reflected the influence of bathymetry, buoyancy conditions and fortnightly variability. Tidal amplitudes were almost twice as large in springs than in neaps. Both Chesapeake and North Channels had similar along-channel amplitudes, which suggested a higher vertically integrated mixing energy in North Channel. Tidal velocity convergences were more intense for springs than …
Can An Optical Plankton Counter Produce Reasonable Estimates Of Zooplankton Abundance And Biovolume In Water With High Detritus?, X. Zhang, M. Roman, A. Sanford, H. Adolf, C. Lascara, R. Burgett
Can An Optical Plankton Counter Produce Reasonable Estimates Of Zooplankton Abundance And Biovolume In Water With High Detritus?, X. Zhang, M. Roman, A. Sanford, H. Adolf, C. Lascara, R. Burgett
CCPO Publications
The Optical Plankton Counter (OPC) has been used in oceanic and fresh waters to estimate zooplankton abundance and biovolume. However, it is not clear whether the OPC can produce accurate estimates of zooplankton abundance and biovolume in waters with high detritus. In order to test the capability of the OPC to estimate zooplankton abundance and biovolume in Chesapeake Bay, two sets of laboratory experiments were conducted using water with high detritus concentrations collected from the upper Choptank estuary of Chesapeake Bay and laboratory cultured Artemia. Our results suggest that the OPC is able to produce accurate estimates of zooplankton biovolume …
Estuarine Relationships Between Zooplankton Community Structure And Trophic Gradients, Gyung Soo Park, Harold G. Marshall
Estuarine Relationships Between Zooplankton Community Structure And Trophic Gradients, Gyung Soo Park, Harold G. Marshall
Biological Sciences Faculty Publications
Zooplankton and water quality parameters were investigated at eight mesohaline stations in the lower Chesapeake Bay and Elizabeth River from January through December 1994 to identify the changes of zooplankton community structure with increased eutrophication. The total micro- and mesozooplankton biomass decreased with the increase of eutrophication. However, the relative proportion of microzooplankton increased with increased eutrophication. Within highly eutrophied waters, the small oligotrichs (m) and rotifers dominated the total zooplankton biomass (as carbon). However, tintinnids, copepod nauplii and mesozooplankton significantly decreased with the increase of eutrophication. These patterns were consistent throughout the seasons and had significant relationships statistically. These …
A Two-Dimensional Analytic Tidal Model For A Narrow Estuary Of Arbitrary Lateral Depth Variation: The Intratidal Motion, Chunyan Li, Arnoldo Valle-Levinson
A Two-Dimensional Analytic Tidal Model For A Narrow Estuary Of Arbitrary Lateral Depth Variation: The Intratidal Motion, Chunyan Li, Arnoldo Valle-Levinson
CCPO Publications
An innovative method is introduced to solve a two-dimensional, depth-averaged analytic model for narrow estuaries or tidal channels with arbitrary lateral depth variations. The solution is valid if the lateral variation of the amplitude of tidal elevation (\Delta a\) is small, i.e., \Delta a\ much less than a, where a is the amplitude of the tidal elevation. This assumption is supported by a 60-day observation of elevation in the James River Estuary using pressure sensors at both sides of a cross section of the estuary. The error introduced by the solution is of the order of \Delta a\/a, which has …
Age, Growth, And Mortality Of Black Drum, Pogonias Cromis, In The Chesapeake Bay Region, Cynthia M. Jones, Brian Wells
Age, Growth, And Mortality Of Black Drum, Pogonias Cromis, In The Chesapeake Bay Region, Cynthia M. Jones, Brian Wells
OES Faculty Publications
We used otolith ageing to describe the population dynamics of black drum, Pogonias cromis, collected over a three-year period from the Chesapeake Bay region's commercial and recreational fisheries. Black drum average age, total length, and weight were 26 years, 109.5 cm, and 22.1 kg respectively. The oldest fish was 59 years and fish older than 50 years were present in the catch from 1990 to 1992. Growth in length slowed by age 20, whereas growth in weight did not slow until age 45. A von Bertalanffy growth function was fitted to our data (L(infinity) = 117.3 cm, …
Non-Volatile Dissolved Organic Iodine In Marine Water, Xianhao Cheng
Non-Volatile Dissolved Organic Iodine In Marine Water, Xianhao Cheng
OES Theses and Dissertations
An analytical scheme for the determination of marine DOI has been established. The concentration of DOI is estimated as total iodine (TI) minus total inorganic iodine (TII). The concentration of total iodine is determined as [special characters omitted] after DOI has been oxidized to inorganic iodine quantitatively by intensive UV-irradiation and all the inorganic iodine in the samples had been converted to [special characters omitted] by the addition of NaClO.
Production of DOI in seawater can be via both non-phytoplankton and phytoplankton related processes. In the former, iodide is converted to DOI. In the latter, most likely, iodate is converted …
Distribution Of Free Marine Viruses Of Lower Chesapeake Bay And Their Effects On Life-History Parameters Of The Estuarine Copepod Acartia Tonsa Dana, Lisa A. Drake
OES Theses and Dissertations
Naturally occurring viruses are very abundant in fresh, estuarine, and marine waters, with densities on the order of 105-108 viruses ml-1. Research has focused on virus effects on bacteria, cyanobacteria, and phytoplankton, as well as mechanisms of virus production and decay. However, little is known about the distribution of viruses in benthic environments or virus effects on organisms in higher trophic levels.
To determine the distribution of virus-like particles (VLPs) and bacteria in the lower Chesapeake Bay, vertical profiles of VLPs and bacteria were determined through the water column and 15-25 cm into the sediment …
Small-Scale Settlement Patterns Of The Oyster Crassostrea Virginica On A Constructed Intertidal Reef, Ian K. Bartol, Roger Mann
Small-Scale Settlement Patterns Of The Oyster Crassostrea Virginica On A Constructed Intertidal Reef, Ian K. Bartol, Roger Mann
Biological Sciences Faculty Publications
The construction of three-dimensional, intertidal reefs resembling those widely present during colonial times in the Chesapeake Bay, but now absent due to years of overharvesting, may provide a more ecologically advantageous environment for oyster settlement and subsequent survival than present subtidal, two-dimensional habitats. We examined settlement processes on a constructed, 210 x 30 m intertidal reef composed of oyster shell. The reef was destructively and non-destructively sampled weekly throughout the summer and fall at tidal heights ranging from 30 cm above to 90 cm below mean low water (MLW) and at two substrate levels (reef surface and 10 cm below …
A Feasibility Study Of Dynamical Assimilation Of Tide Gauge Data In The Chesapeake Bay, Yvette H. Spitz
A Feasibility Study Of Dynamical Assimilation Of Tide Gauge Data In The Chesapeake Bay, Yvette H. Spitz
OES Theses and Dissertations
The feasibility of dynamical assimilation of surface elevation from tide gauges is investigated to estimate the bottom drag coefficient and surface stress as a first step in improving modeled tidal and wind-driven circulation in the Chesapeake Bay. A two-dimensional shallow water model and an adjoint variational method with a limited memory quasi-Newton optimization algorithm are used to achieve this goal.
Assimilation of tide gauge observations from ten permanent stations in the Bay and use of a two-dimensional model adequately estimate the bottom drag coefficient, wind stress and surface elevation at the Bay mouth. Subsequent use of these estimates in the …
Assessment Of Genetic Diversity Of Seagrass Populations Using Dna Fingerprinting: Implications For Population Stability And Management, Randall S. Alberte, Gregory K. Suba, Gabriele Procaccini, Richard C. Zimmerman, Steven R. Fain
Assessment Of Genetic Diversity Of Seagrass Populations Using Dna Fingerprinting: Implications For Population Stability And Management, Randall S. Alberte, Gregory K. Suba, Gabriele Procaccini, Richard C. Zimmerman, Steven R. Fain
OES Faculty Publications
Populations of the temperate seagrass, Zostera marina L. (eelgrass), often exist as discontinuous beds in estuaries, harbors, and bays where they can reproduce sexually or vegetatively through clonal propagation. We examined the genetic structure of three geographically and morphologically distinct populations from central California (Elkhorn Slough, Tomales Bay, and Del Monte Beach), using multilocus restriction fragment length polymorphisms (DNA fingerprints). Within-population genetic similarity (Sw) values for the three eelgrass populations ranged from 0.44 to 0.68. The Tomales Bay population located in an undisturbed, littoral site possessed a within-population genetic similarity (Sw = 0.44) that was significantly lower …
Identification And Quantitation Of Volatile Amines In Chesapeake Bay Sediments, Neeraja Y. Krishna
Identification And Quantitation Of Volatile Amines In Chesapeake Bay Sediments, Neeraja Y. Krishna
Chemistry & Biochemistry Theses & Dissertations
Sediments from different parts of the Chesapeake Bay were analyzed to determine the presence of volatile amines. A HF-HCl extraction method was used to extract both exchangeable and fixed amines from the sediments and a purge-and-trap technique was used to concentrate the amines. Following derivatization with heptafluorobutyric anhydride (HFBA), the HFBA-amines were analyzed by gas chromatography with electron capture detection and with mass spectrometric detection. One primary amine, i-amylamine with a concentration ranging from 0. 78 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty seven samples collected on three different dates in 1993. Another primary amine, 2-methylbutylamine with a concentration ranging from 0.18 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty three samples collected on three different dates in 1993. A secondary amine, diethylamine was detected but could not be quantified in a total of seven samples collected in September 1993. The concentrations of these amines varied with location in the Bay, depth in the sediment, and time of year the sediments were collected. The origin of i-amylamine and 2-methylbutylamine might be from the biological decarboxylation of amino acids leucine and isoleucine, respectively. The origin of diethylamine is unknown.
Description, Distribution, And Abundance Of The Blue Crab, Callinectes Sapidus (Rathbun), Spawning Stock Of The Lower Chesapeake Bay, Patrick John Geer
Description, Distribution, And Abundance Of The Blue Crab, Callinectes Sapidus (Rathbun), Spawning Stock Of The Lower Chesapeake Bay, Patrick John Geer
OES Theses and Dissertations
The lower Chesapeake Bay spawning stock of the blue crab, Callinectes sapidus, (Rathbun), is examined for seven years (1986 - 1992) in an attempt to better understand stock behavior. Three methods of post-stratification are used to describe the distribution and movement of the population over time. The three methods, density strata, geographic zones, and depth strata, did well in explaining movements of the population, indicating a trend of increased concentration of blue crabs near the eastern Bay late in the spawning season - October. The data suggest a bimodal period of spawning and a trimodal period of abundance. The …
Age, Growth, And Mortality Of Atlantic Croaker, Micropogonias Undulatus, In The Chesapeake Bay Region, With A Discussion Of Apparent Geographic Changes In Population Dynamics, Luiz R. Barbieri, Mark E. Chittenden Jr., Cynthia M. Jones
Age, Growth, And Mortality Of Atlantic Croaker, Micropogonias Undulatus, In The Chesapeake Bay Region, With A Discussion Of Apparent Geographic Changes In Population Dynamics, Luiz R. Barbieri, Mark E. Chittenden Jr., Cynthia M. Jones
OES Faculty Publications
Atlantic croaker, Micropogonias undulatus, collected from commercial catches in Chesapeake Bay and in Virginia and North Carolina coastal waters during 1988-1991 (n=1,967) were aged from transverse otolith sections. Ages 1-8 were recorded, but eight-year-old fish were rare. Marginal increment analysis showed that for ages 1-7, annuli are formed once a year during the period April-May. Otolith age readings were precise: >99% agreement within and between readers. Observed lengths-at-age were highly variable and growth rate decreased after the first year. Despite the high variability in sizes-at-age, observed lengths for ages 1-7 fit the von Bertalanffy growth model (r2=0.99; n=753) well. …
Spatial And Temporal Occurrence Of Spanish Mackerel Scomberomorus Maculatus In Chesapeake Bay, Mark E. Chittenden Jr., Luiz R. Barbieri, Cynthia M. Jones
Spatial And Temporal Occurrence Of Spanish Mackerel Scomberomorus Maculatus In Chesapeake Bay, Mark E. Chittenden Jr., Luiz R. Barbieri, Cynthia M. Jones
OES Faculty Publications
No abstract provided.
Seasonal Relationships Between Phytoplankton Composition, Abundance, And Primary Productivity In Three Tidal Rivers Of The Lower Chesapeake Bay, Harold G. Marshall, Kneeland K. Nesius
Seasonal Relationships Between Phytoplankton Composition, Abundance, And Primary Productivity In Three Tidal Rivers Of The Lower Chesapeake Bay, Harold G. Marshall, Kneeland K. Nesius
Biological Sciences Faculty Publications
The seasonal abundance and successional patterns of phytoplankton, including autotrophic picoplankton, are compared to spring, summer, and fall primary production maxima that occurred in three tidal rivers. The tidal freshwaters were dominated by diatoms, chlorophytes, and cyanobacteria during a late spring through early fall period of maximum growth. In contrast, downstream assemblages were dominated by estuarine diatoms, dinoflagellates, and cryptomonads which developed spring pulses and a protracted summer-fall maximum. Autotrophic picoplankton produced a major summer pulse at all river stations with reduced abundance during other seasons. The mean annual productivity rates for the tidal James, Rappahannock, and York rivers were …
Development And Standardization Of A Short-Term Assay For Evaluating Polluted Estuarine And Coastal Environments: The Medaka Embryo-Larval Assay, Michael Frederick Helmstetter
Development And Standardization Of A Short-Term Assay For Evaluating Polluted Estuarine And Coastal Environments: The Medaka Embryo-Larval Assay, Michael Frederick Helmstetter
OES Theses and Dissertations
The eggs of the Japanese medaka (Oryzias latipes) were employed in a number of studies to develop a routine, standardized assay which can assess the acute and sublethal impacts of individual toxicants and complex mixtures. The eggs of this Cyprinodont minnow were topically treated with each toxicant or mixture dissolved in membrane permeable dimethylsulfoxide (DMSO) solvent. Nine chemicals were initially evaluated with two, pentachlorophenol (PCP) and tributyltin chloride (TBTCl), subsequently selected for extensive evaluations of salinity tolerance and the accuracy of the topical exposure method for representing a typical immersion exposure. The amount of material actually penetrating the eggs was …
Processes Affecting The Behavior Of Redox-Sensitive Elements In Chesapeake Bay, Maria Lourdes San Diego-Mcglone
Processes Affecting The Behavior Of Redox-Sensitive Elements In Chesapeake Bay, Maria Lourdes San Diego-Mcglone
OES Theses and Dissertations
Several processes can affect variations in the chemical composition of an estuary, including (1) biogeochemical reactions in the water column, (2) advective transport, and (3) diffusion from underlying sediments.
The purpose of the study was to establish whether estuarine redox reactions are controlled by a complex interaction of processes 1 to 3. Short-term and long-term studies were conducted in Chesapeake Bay. Redox species involved in redox cycling include oxygen, iron, manganese, hydrogen sulfide, nitrogen species, arsenic and antimony species, while phosphate is indirectly involved in redox cycles. Silicate was used as a non-redox tracer.
For the short-term study, a Lagrangian …
The Kinetics Of Organic Matter Mineralization In Anoxic Marine Sediments, David J. Burdige
The Kinetics Of Organic Matter Mineralization In Anoxic Marine Sediments, David J. Burdige
OES Faculty Publications
The kinetics of sulfate reduction and inorganic nutrient production (ΣCO2, ammonium, and phosphate) were examined in the sediments at five sites in the southern Chesapeake Bay, using long term (> 200 d) sediment decomposition experiments. Average first order rate constants for these processes (at 25oC) decreased from 8.2 to 3.7 yr-1 in the surface sediments (0-2 cm), to 2.1 to 0.2 yr-1 at 12-14 cm. The C/N and C/P ratios of the organic matter undergoing decomposition also increased with depth at these sites. Taken together, these results indicate that the reactivity of the organic matter …