Oceanography Commons^™

Biogeochemical Cycling Of Selenium In The Arctic Ocean, Kyle M. Mcquiggan

OES Theses and Dissertations

Changes in the global climate may have a pronounced effect on the biogeochemical cycling of trace elements like selenium (Se) in the Arctic Ocean. This study described the first quantitative examination of the biogeochemical cycle of selenium in the Amerasian Basin, providing the baseline from which future changes can be identified. Aerosol, dissolved and particulate water samples were collected for Se determinations during the U.S. GEOTRACES GN01 Arctic expedition that sampled the two parts of the Amerasian Basin in 2015: The Makarov Basin on the way to the North Pole and the Canada Basin on the return trip to Dutch …

Regional Sea Level Rise Along The United States Coasts, Alessandra G. Burgos

OES Theses and Dissertations

Over the past several years, there has been several studies focused on reconstructing global mean sea level (GMSL) for the 20th century, along with projecting rates out into the future. Of greater importance for mitigation and adaptation plans, however, is the rate of local or regional sea level (RSL) rise. Ocean dynamics along with changes in Earth’s gravitational field can cause RSL to deviate from the change in GMSL. During the satellite altimeter era covering the past two decades, RSL trends can be four times the global average, with much of this spatial variation due to internal climate variability. Isolating …

Wet And Dry Atmospheric Deposition Of Nutrients And Bioactive Trace Metals To Coastal Waters Of The Mid-Atlantic Bight, Christine Sookhdeo

OES Theses and Dissertations

Atmospheric deposition provides a significant source of nutrients and bioactive trace metals to the surface ocean, including the seasonally oligotrophic waters of the Mid-Atlantic Bight. These atmospherically derived nutrients and trace metals enter the surface ocean via dry deposition of aerosols and wet deposition in rain. To estimate the aeolian input of nutrients and trace metals to coastal waters east of the Delmarva Peninsula, wet and dry atmospheric deposition samples were collected over a one-year time series at the Anheuser-Busch Coastal Research Center, Oyster, Virginia. Weekly composite samples were collected from May 2014 through June 2015. Nutrient species examined were …

Selenium Distribution And Cycling In The Eastern Equatorial Pacific Ocean, Zoe Wambaugh

OES Theses and Dissertations

Oxygen minimum zones in oceanic waters have become increasingly important to the marine environment and society. Low oxygen waters affect not only the distribution and abundance of marine organisms, but also impact the solubility and transport of trace elements that are of biological importance, with the chemical speciation and solubility depending on the actual redox poise of the waters. One redox sensitive trace element of interest is selenium, which can be both toxic and essential for organisms, depending on its chemical speciation. In 2013, the US GEOTRACES program completed the GP16 transect from Peru to Tahiti, going through the oxygen …

Analysis Of Virginia Barrier Island Shoreline Movement And Correlations To Sea Level, Wave Height Changes, And Teleconnection Patterns, James Daniel Haluska

OES Theses and Dissertations

The Virginia barrier islands stretch from Assateague Island in the north to Fisherman’s Island in the south. This string of islands is subject to frequent North Atlantic extra-tropical storm and hurricane influence. In addition, sea level rise has the potential to cause continued shoreline loss and inlet widening for this island group. This dissertation describes the effect of sea level rise, changes in wave height, and teleconnection pattern (AO, NAO, and MEI) correlations to shoreline location changes to the islands and inlet location and width changes. Locations of island shorelines were determined from satellite and aircraft images using ArcGIS software …

Influence Of Tides And Mesoscale Eddies In The Ross Sea, Stefanie Lynn Mack

OES Theses and Dissertations

The Ross Sea is the most biologically productive region in the Southern Ocean. Primary production is controlled by dissolved iron (dFe), a limiting micronutrient. The main focus of this thesis, motivated by the PRISM-RS project, is to investigate how tides and mesoscale eddies affect the pathways of dFe to the surface ocean.

A regional ocean model with four hindcast simulations are used. Tidal forcing is added to simulations and mesoscale eddies are resolved by changing the horizontal grid resolution from 5 to 1.5 km. Simulations cover 1.5 years, ending at the time of the PRISM-RS cruise in early 2012. An …

Groundwater And Tidal Controls On Wetland Hydrology, Julie J. Metz Wetland Mitigation Bank, Woodbridge, Virginia, Benjamin Stuart Hiza

OES Theses and Dissertations

Julie J. Metz Wetlands Mitigation Bank, a 92-hectare freshwater wetland located in Woodbridge, Virginia, borders the tidally-influenced Neabsco Creek. Seven pods separated by earthen berms were built by Wetland Studies and Solutions Inc. (WSSI) in 1995 and 1997 by removing the toe of small sandy alluvial fans and covering the underlying coarse gravel bed with a low permeability cap. The basal Quaternary gravels were deposited in a creek valley incised into a thick sand-and-clay Cretaceous delta. The alluvial-fan apron developed at the base of steep slopes along the sides of the valley. Pressure transducer data from five monitoring wells along …

Distributions Of Euphausia Superba, Euphausia Crystallorophias, And Pleuragramma Antarcticum With Correlations To Environmental Variables In The Western Ross Sea, Antarctica, Linnea Brynn Davis

OES Theses and Dissertations

Antarctic krill (Euphausia superba), crystal krill (Euphausia crystallorophias), and Antarctic silverfish (Pleuragramma antarcticum) are key mid-trophic level species in the Ross Sea food web that provide connectivity between primary production and the upper trophic levels. Distributions of these species were constructed from net-based and acoustic observations collected in the western Ross Sea from 1988-2004. Distributions of environmental conditions in the Ross Sea were obtained from a high-resolution circulation model (temperature, mixed layer depth, surface speed) and satellite-derived observations (chlorophyll, sea ice cover). These distributions were analyzed with a range of statistical methods to determine …

Potential Impacts Of Climate Change On Photochemistry Of Zostera Marina L., Billur Celebi

OES Theses and Dissertations

Seagrasses account for approximately 10% of the ocean’s total carbon storage, although photosynthesis of seagrasses is carbon limited at today’s oceanic pH. Therefore, increasing atmospheric CO₂ concentration, which results in ocean acidification/carbonation, is predicted to have a positive impact on seagrass productivity. Previous studies have confirmed the positive influence of increasing CO₂ on photosynthesis and survival of the temperate eelgrass Zostera marina L., but the acclimation of photoprotective mechanisms in this context has not been characterized. This study aimed to quantify the long-term impacts of ocean acidification on photochemical control mechanisms that promote photosynthesis while simultaneously protecting …

The Marine Cyanate Cycle, Brittany Widner

OES Theses and Dissertations

Cyanate (OCN-) is a reduced nitrogen compound with the potential to serve as a nitrogen and carbon source for marine microbes. Evidence from genomes and culture studies indicated that several marine cyanobacterial groups, including representatives of the globally important genera Synechococcus and Prochlorococcus, might be capable of cyanate assimilation. However, prior to this study, the distribution, bioavailability, and production pathways of cyanate were unknown in natural systems due to the absence of a sensitive cyanate assay; and the ability of organisms to assimilate cyanate on relevant timescales was unknown because we lacked a suitable tracer for measuring uptake. I developed …

A Survey Of Aquatic Organisms For The Cyanotoxin Beta-Methylamino-L-Alanine (Bmaa), Ian M. Sammler

OES Theses and Dissertations

Cyanobacteria blooms are increasing globally as a result of eutrophication. Many cyanobacteria are potentially harmful, not only because of the oxygen depleted zones created when they decay, but also because of the toxins they produce. β- Methylamino-L-alanine (BMAA), reportedly produced by many species of cyanobacteria, is a non-proteinogenic amino acid that has been linked to the development of neurodegenerative diseases (amyotrophic lateral sclerosis (ALS) and Alzheimer's) in humans. This study presents results from an assessment of BMAA in cyanobacteria and their grazers from the lower Chesapeake Bay and Lake Erie regions. BMAA was analyzed in samples prepared with the EZ:Faast™ …

Doppler Shifted Internal Waves In A Shallow Water Region, William D. Boll

OES Theses and Dissertations

Measurements of velocity fields from a high frequency ( 1.2 MHz) vertical acoustic doppler current profiler (V ADCP) along with density and temperature profiles were taken in coastal waters on the New Jersey shelf. Time series span six consecutive months from May through October 2003, capturing the transition of the water column from a highly stratified summer into a fully mixed winter season. Barotropic tides interact with variations in local bathymetry causing disturbances within the fluid medium which govern internal wave characteristics. During the months of June, July, and August, a high number of internal wave signals were observed. Spectra …

Predation Thresholds In Marine Microbial Communities Applied To Environments With Low Prey Abundances, Bonnie Bailey

OES Theses and Dissertations

Prokaryotes (Bacteria and Archaea) comprise the largest component of biomass in the world's oceans. Their abundances are controlled by resource availability, viral infections and protist grazing. Many pico- and nano-eukaryotic predators grow almost as quickly as their prey, and greatly increase in numbers as soon as their prey do, leading in tum to depletion in prokaryotes. It is still unclear however, as to what extent microbial predators are able to feed in low prey environments, most prominently in the largest biome on Earth, the deep sea (below l 000 m depth). It has been hypothesized that in low prey environments, …

Organic Copper Binding Ligands And Thiol Compounds Produced By Bacteria And In The Elizabeth River, Virginia, Christina Louise Dryden

OES Theses and Dissertations

This dissertation presents work focusing on copper and organic copper binding ligands in laboratory cultures and the Elizabeth River, Virginia. Laboratory cultures of the marine bacterium Vibrio parahaemolyticus were used to demonstrate the influence of elevated copper concentrations on copper-complexing ligand and thiol production. Copper-complexing ligands similar in binding strength to the strongest natural ligands were detected in V. parahaemolyticus cultures (log K′_CuL = 11.8–13.2). A strong correlation (r² = 0.973) was found between total thiol and copper-complexing ligand concentrations at all copper concentrations examined.

A yearlong seasonal study was undertaken in a heavily polluted estuary to ascertain …

A Comprehensive Evaluation Of C25 Highly Branched Isoprenoid Alkenes Of Marine Diatoms As Proxies For Sea Ice Extent In The Arctic Ocean, Tetiana Muniak

OES Theses and Dissertations

Sea Ice extent is one of the major factors regulating carbon cycling and ecosystem function in the modern Arctic Ocean. It is an essential component of climate models and is crucial for the evaluation of various oceanographic processes that influence a particular region. Yet it is also one of the most difficult attributes of the ocean with respect to our ability for its accurate reconstruction from paleo records. The lack of the detailed records prior to satellite information has encouraged the development of new proxy records for the reconstruction of past

sea ice conditions. In recent years, a new monounsaturated …

Spatial And Temporal Variability In Net Community Metabolism In The Middle Atlantic Bight, Georges Bank, And Gulf Of Maine: Observations Of Net Heterotrophic Phases In The Highly Productive Coastal Zone, Cory James Staryk

OES Theses and Dissertations

Net community metabolism (NCM), the balance between primary production and community respiration, was measured during two cruises, June 2011 and August 2012, in the Middle Atlantic Bight, Georges Bank and Gulf of Maine. Net heterotrophy was observed in Georges Bank and Gulf of Maine during the June 2011 cruise. During the August 2012 cruise, net heterotrophy was observed in the Middle Atlantic Bight and net autotrophy was observed in Georges Bank and the Gulf of Maine. Dark community respiration increased (DCR) with biomass and temperature. Gross community production (GCP) also increased with Chl a, bicarbonate uptake, and temperature. Net …

Implications Of Climate Change For Cyanobacteria Over The Western Florida Shelf In The Gulf Of Mexico, Ivy Mara Ozmon

OES Theses and Dissertations

Concentrations of atmospheric CO₂ are expected to double by year 2100 as a result of anthropogenic activities. Under elevated CO₂ conditions, cyanobacteria may reallocate energy from active accumulation and transport of dissolved inorganic carbon (C) required for photosynthesis to other growth processes. Stimulation of cyanobacterial production on the Western Florida Shelf in the Gulf of Mexico (GOM) could lead to improved nutritional status for the toxic, mixotrophic dinoflagellate Karenia brevis that utilizes newly fixed N₂ from co-occurring diazotrophic cyanobacteria and consumes unicellular cyanobacteria via grazing for growth. Culture studies performed by other researchers on the climate induced …

Comparison Of Two Separation Methods For Biological Particles: Field-Flow Fractionation (Fff) And Sucrose Density Gradients, Cody E. Garrison

OES Theses and Dissertations

Sucrose gradient centrifugation and Field-flow fractionation (FFF) are two different particle separation methods that overcome the problems of similar size microorganisms clumping together during standard filtration methods. FFF separates particles based on size and density via the parabolic velocity profile of laminar flow in a ribbon-like channel. The sucrose method separates particles via centrifugation in a density gradient. Both techniques worked well in separating eukaryotic from prokaryotic microbes, with the preferred method depending on the type and relative abundance of organisms to be separated. Minicells were separated from mother cells in transformed Escherichia coli cultures, heterotrophic flagellates (e.g., Diplonema papillatum …

The Impact Of Multiple Nursery Areas On The Population Structure Of Atlantic Menhaden, Brevooria Tyrannus, Kristen A. Anstead

OES Theses and Dissertations

Understanding the population structure and patterns of connectivity in marine fishes is essential when making predictions about a species' resiliency and persistence in an increasingly changing environment. The Atlantic Menhaden Brevoortia tyrannus is a clupeid that plays a critical role in the marine food web and supports one of the largest fisheries on the US East Coast. In addition to a decrease in overall numbers and spawning stock biomass, recruitment levels have remained low since the 1990s. Menhaden use numerous estuaries along the Atlantic coast for juvenile development before recruiting to the adult population and the contribution of each of …

Phosphorus Cycling In Tropical Carbonate Sediment-Seagrass Systems, Zachary Howerton

OES Theses and Dissertations

This thesis presents two studies focusing on phosphorus cycling in calcium carbonate sediments inhabited by seagrasses. Phosphorus is a major limiting nutrient for primary productivity in these sediments as well as in the overlying waters. In large part this is due to removal of phosphate from solution by adsorption and precipitation reactions.

In chapter II, the relationship between the size of the sedimentary phosphorus pool and the abundance of seagrass on the Great Bahama Bank, as well as the relationship between phosphorus content and grain size in the sediments, were examined to better understand the biogeochemistry of carbonate sediments and …

Environmental And Physiological Influences On Productivity And Carbon Isotope Discrimination In Eelgrass (Zostera Marina L.), Meredith Leigh Mcpherson

OES Theses and Dissertations

A short-term longitudinal study was used to examine the relations of achievement motivation, general motivation, interest, and self-regulatory predictors to cognitive strategy use and academic performance. A total of 102 college undergraduates enrolled in their first college-level introductory psychology course completed an Achieving Tendency Scale of achievement motivation, the Motivated Strategies For Learning Questionnaire, and an Interest Profile in psychology during the first two weeks of the semester. At midterm they completed the Study Activity Survey of cognitive strategy use. At the end of the semester exam grades, total points earned in the course, and grade point average were obtained. …

Modeling Studies Of Antarctic Krill (Euphausia Superba) Survival During Transport Across The Scotia Sea And Environs, Bettina Andrea Fach

OES Theses and Dissertations

The Antarctic krill (Euphausia superba) populations at South Georgia, which is in the eastern Scotia Sea, are hypothesized to be sustained by import of individuals from upstream regions, such as the western Antarctic Peninsula. To test this hypothesis a modeling framework consisting of the Harvard Ocean Prediction System (HOPS) and a time-dependent, size-structured, physiologically-based krill growth model was developed. The simulated circulation fields obtained from HOPS were used with drifter studies to determine regions and pathways that allow transport of Antarctic krill to South Georgia. Pelagic phytoplankton concentrations along the simulated drifter trajectories were extracted from historical Coastal …

Response Of Natural Estuarine Algal Communities To Nitrogen Additions, Christopher Schweitzer

OES Theses and Dissertations

Coastal eutrophication resulting from nutrient over-enrichment plagues coastal waterways worldwide. In addition to dissolved inorganic N, many marine microbes, including phytoplankton, have the capacity to use certain dissolved organic nitrogen (DON) compounds. However, while we know that many specific DON compounds are labile, the bulk of the DON pool in nature is uncharacterized. The bioavailability of DON to estuarine microbes currently remains unclear.

It is becoming evident that natural phytoplankton assemblages in estuarine waters are capable of using both inorganic and organic N compounds for growth, both of which are present in anthropogenic point and non-point source discharges. Methods for …

Observations And Modeling Forcing Mechanisms For The Coastal Dynamics Of The Upper Gulf Of Thailand, Suriyan Saramul

OES Theses and Dissertations

A numerical model based on the Princeton Ocean Model (130M) with ∼1 km horizontal grid and 21 vertical layers has been used to study the influence of wind stresses, river discharges, surface heat fluxes and tides on the three-dimensional circulation of the upper Gulf of Thailand (UGOT). Analysis of observations, including sea level data, provided additional information to support the model simulations. The UGOT is a shallow coastal system, ∼1°×1° in size with the average depth of only 15 m. Sensitivity studies evaluate how the dynamics is affected by surface wind stresses, river discharges, and surface heat fluxes. The impact …

Assessing Movement Of Fish Through Spectral Analysis Of Otolith Life History Scans, Renee Reilly Hoover

OES Theses and Dissertations

The ability to accurately measure movement timing across environmental gradients is fundamental for testing hypotheses in marine ecology that deal with ingress, egress, and migration of fish. Timing and patterns of movement have been estimated using life-history scans of the chemical signatures encoded in fish otoliths (ear stones). I provide a quantitative approach to examining life history scan data using spectral analysis, which retrospectively measures the movement timing for individual fish. Sagittal otoliths from juvenile Atlantic croaker (Micropogonias undulates) and adult black sea bass (Centropristis striata) were sampled using laser ablation inductively coupled plasma mass spectrometry …

Population Structure And Connectivity Of An Important Pelagic Forage Fish In The Antarctic Ecosystem, Pleuragramma Antarcticum In Relation To Large Scale Circulation, Jason W. Ferguson

OES Theses and Dissertations

Ocean circulation has been identified as a major process controlling the distribution of biological material in marine systems. Large-scale transport by the Antarctic Circumpolar Current (ACC), the Ross and Weddell Gyres, and the Antarctic Coastal Current can promote spatially complex population structure in the Southern Ocean through advection. Antarctic silverfish (Pleuragramma antarcticum), a pelagic, neutrally buoyant notothenioid fish species, are distributed around the shelf systems of Antarctica and are considered an important species rivaling krill as prey for many birds, seals, whales, and other fish. We asked whether silverfish are distributed in independent, discrete populations along the shelf systems of …

Modeling The Dispersion Of Eastern Oyster Larvae (Crassostrea Virginica) And Its Effects On The Movement Of Disease Resistant Genes In The Delaware Bay Estuary, Diego A. Narvaez

OES Theses and Dissertations

This study combines several models to address two primary research questions. How does the interaction of larval biology and environmental variability determine the spatial distribution of oyster larvae in Delaware Bay? What is the role of larval dispersion in the transference of disease-resistant genes? The particle-tracking module in the Regional Ocean Modeling System (ROMS) was converted into an Individual-Based model representing Eastern oyster larvae that has growth and vertical migration. Exchange of larvae between natural oyster reefs was estimated and used in an Individual-Based genetic model that simulates the genetic structure of eastern oysters. Particles were released from a number …

Eukaryotic Microbes In The Deep Sea: Abundance, Diversity, And The Effect Of Pressure, Danielle Morgan-Smith

OES Theses and Dissertations

The dark ocean is vast, high in pressure, cold, and scarce in resources, but has been shown to support a diverse and active microbial community wherever it is studied. Such studies, however, are scarce due to the difficulty of sampling at such depths, and are difficult to interpret due to compounding effects of pressure and temperature on physiology. Protists, functionally defined as the microbial portion of the domain Eukarya, are particularly neglected in studies of deep-sea microbiology. Here, I present three studies on microbial eukaryotes in the deep sea: first, a study of the abundance of microbial eukaryotes in the …

Grazing On Synechococcus Spp. By The Red-Tide Dinoflagellate Karenia Brevis: Implications For Bloom Dynamics In The Gulf Of Mexico, Leo A. Procise

OES Theses and Dissertations

Karenia brevis, the toxic dinoflagellate responsible for massive red tides in the Gulf of Mexico (GOM), causes fish kills, shellfish poisoning, and acute respiratory irritation in humans. Bloom initiation and maintenance have been linked to the physical environment as well as various nutrient input mechanisms. To date, efforts to quantify nitrogen (N) sources fueling K. brevis blooms in the GOM have not included mixotrophic grazing although many dinoflagellates, including K. brevis, are known to be capable of mixotrophy. This dissertation reports field and laboratory results demonstrating that natural bloom populations and K. brevisisolates from the West Florida …

A New Phase Speciation Leaching Procedure For The Determination Of Metals In Oxic And Anoxic Sediments, Brandon R. Gipson

OES Theses and Dissertations

Toxic trace elements such as cadmium, lead, chromium, and arsenic released by human activities can accumulate in marine and estuarine sediments, where these metals are often sequestered until local environmental changes (e.g., redox, salinity, and/or pH) allow these elements to be reintroduced into the food web. In order to assess the extent of toxic trace element contamination in sediment, numerous leaching schemes have been developed that separate sediment-bound trace metals into operationally defined geochemical phases. These "phase speciation" leaching schemes are typically designed with the purpose of being used on either oxic or anoxic sediments. However, natural sediments often contain …