Oceanography Commons^™

A New Phase Speciation Leaching Procedure For The Determination Of Metals In Oxic And Anoxic Sediments, Brandon R. Gipson

OES Theses and Dissertations

Toxic trace elements such as cadmium, lead, chromium, and arsenic released by human activities can accumulate in marine and estuarine sediments, where these metals are often sequestered until local environmental changes (e.g., redox, salinity, and/or pH) allow these elements to be reintroduced into the food web. In order to assess the extent of toxic trace element contamination in sediment, numerous leaching schemes have been developed that separate sediment-bound trace metals into operationally defined geochemical phases. These "phase speciation" leaching schemes are typically designed with the purpose of being used on either oxic or anoxic sediments. However, natural sediments often contain …

Benthic Ecology From Space: Optics And Net Primary Production In Seagrass And Benthic Algae Across The Great Bahama Bank, Heidi M. Dierssen, Richard C. Zimmerman, Lisa A. Drake, David J. Burdige

OES Faculty Publications

Development of repeatable and quantitative tools are necessary for determining the abundance and distribution of different types of benthic habitats, detecting changes to these ecosystems, and determining their role in the global carbon cycle. Here we used ocean color remote sensing techniques to map different major groups of primary producers and estimate net primary productivity (NPP) across Great Bahama Bank (GBB). Field investigations on the northern portion of the GBB in 2004 revealed 3 dominant types of benthic primary producers: seagrass, benthic macroalgae, and microalgae attached to sediment. Laboratory measurements of NPP ranged from barely net autotrophic for grapestone sediment …

Rates Of Carbonate Dissolution In Permeable Sediments Estimated From Porewater Profiles: The Role Of Sea Grasses, David J. Burdige, Richard C. Zimmerman, Xinping Hu

OES Faculty Publications

In this study we estimate sediment carbonate dissolution rates for sandy sea grass sediments on the Bahamas Bank using an inverse pore-water advection/diffusion/reaction model constrained by field observations. This model accounts for sea grass O₂ input to these sediments, and also parameterizes pore-water advection through these permeable sediments as a nonlocal exchange process. The resulting rates of carbonate dissolution are positively correlated with sea grass density, and are comparable with previous rate estimates for Florida Bay sediments. In contrast, the advective uptake of O₂ by these sediments decreased with increasing sea grass density. This suggests that the competing …

Correlating Late Pleistocene Deposits On The Coastal Plain Of Virginia With The Glacial-Eustatic Sea-Level Curve, Timothy Wullschleger Scott

OES Theses and Dissertations

Late Pleistocene sediments mapped along Virginia's southeastern coastal plain record deposition by high-frequency cycles during isotope stages 5 to 1. Correlations between several geologic units both south (S) and east (E) of the Chesapeake Bay have proven difficult due to insufficient dating methods. To improve these regional correlations, two members of the Tabb Formation on Virginia's southside and two formations on the southern Delmarva Peninsula were selected for stratigraphic analyses. Ground penetrating radar provided geologic details in areas where samples were collected for optically stimulated luminescence (OSL) dating. The stratigraphically older units, Sedgefield Member of the Tabb Formation (S) and …

Evaluating The Deep-Sea Coral Acanella From Hawaii As A Paleoceanographic Archive, Geraldine Hourigan Lantier

Geology Theses and Dissertations

Deep-sea corals have emerged as potential proxies of changing paleoceanographic properties. The utility of deep-sea corals for the purpose of interpreting paleoclimatic reconstructions is still in the discovery phase. However, long life spans, a relatively stable habitat, and unique growth geometry provide support to the growing body of research that has identified deep-sea corals as indicators of past climate and ocean properties. Two colonies of Acanella were collected from the permanent thermocline at depths between 414 and 437 m in the Makapuu Coral Bed, Oahu, HI in 1997 by submersible. Here I present results from a pilot study of the …

Interaction Of Sea Ice Sediments And Surface Sea Water In The Arctic Ocean: Evidence From Excess 210Pb, M. Baskaran

Environmental Science and Geology Faculty Research Publications

We measured the activities of ²¹⁰Pb, ²²⁶Ra, ²³⁸U and ¹³⁷Cs in a suite of ice-rafted sediments (IRS) from the Arctic Ocean in an attempt to assess the interaction of sea ice sediments and surface water. The concentrations of these nuclides were compared to those of the benthic sediments in the coastal and shelf regions of the Arctic Ocean, which are believed to be the major source region for the IRS. The concentration factors (CF = activity of a nuclide in IRS/average activity in benthic sediments) are ∼1 and 4-92 for ¹³⁷Cs and ²¹⁰Pb, respectively. …

Burial Of Terrestrial Organic Matter In Marine Sediments: A Re-Assessment, David J. Burdige

OES Faculty Publications

Calculations based on recent observations indicate that approximately one third of the organic matter presently being buried in marine sediments may be of terrestrial origin, with the majority of this terrestrial organic matter (TOM) burial occurring in muddy, deltaic sediments. These calculations further suggest that the remineralization of terrestrial organic matter in the oceans is also much less efficient than that of marine organic matter. These two underappreciated observations have important implications in terms of our understanding of the controls on the global carbon cycle. From a paleoceanographic perspective, the results presented here also suggest that changes in TOM burial …

Modifications Of The C37 Alkenone And Alkenoate Composition In The Water Column And Sediment: Possible Implications For Sea Surface Temperature Estimates In Paleoceanography, Joan O. Grimalt, Jürgen Rullkötter, Marie-Alexandrine Sicre, Roger Summons, John Farrington, H. Rodger Harvey, Miguel Goñi, Ken Sawada

OES Faculty Publications

The literature pertaining to C37 alkenone and C37 and C38 alkenoate production and diagenesis has been reviewed and evaluated for issues that might jeopardize their usefulness in paleotemperature estimation. We also examined the use of the C37 alkenones as paleoproductivity indicators, the stability of their δ13C isotopic compositions, and their incorporation into the nonsolvent extractable organic matter fraction. Biological transformation of organic matter by bacteria and zooplankton does not appear to cause significant changes to the ratio of C37:2 and C37:3 alkenones, but there are major alterations in the relative composition of alkenoates. Studies of water column processes and postdepositional …

Alteration Processes Of Alkenones And Related Lipids In Water Columns And Sediments, H. Rodger Harvey

OES Faculty Publications

Alkenones produced by the haptophyte algae are currently being used as indices of sea surface temperature in recent and past ocean environments, but limited information is available concerning the impact of biotic and abiotic processes on the integrity of these long chain lipids. This synthesis provides selected background information on major alteration processes that must be considered before such indices can be used with confidence. A number of processes in the water column and surface sediments have the potential to impact the structural integrity of alkenones and compromise their ability as temperature markers. Processes discussed include the alteration of alkenone …

The Biogeochemical Cycling Of Dissolved Organic Nitrogen In Estuarine Sediments, David J. Burdige, Shilong Zheng

OES Faculty Publications

Benthic fluxes and pore-water profiles of dissolved organic nitrogen and carbon (DON and DOC, respectively) were determined in seasonal studies at contrasting sites in Chesapeake Bay. Pore-water dissolved organic matter (DOM) concentrations were elevated over bottom-water values, generally increased with depth, and ranged from 15 to similar to 160 μM for DON and ~200-2000 μM for DOC. Pore-water DOM concentrations and the C:N ratio of this material showed spatial (depth) and temporal changes that varied among the sites studied. These trends appeared to be related to differences in the types of sediment organic matter (SOM) undergoing remineralization, as well as …

Fluxes Of Copper-Complexing Ligands From Estuarine Sediments, Stephen A. Skrabal, John R. Donat, David J. Burdige

OES Faculty Publications

Most studies of the organic complexation of Cu in natural waters have focused on distributions and processes in the water column, where a significant fraction of Cu-complexing ligands may be biologically produced. We present direct evidence for a flux of Cu-complexing ligands from estuarine sediments, demonstrating that sediments are a significant, yet previously unrecognized source of the ligands. Fluxes of Cu-complexing ligands from Chesapeake Bay sediments range from 300 to 1,200 nmol m^-2 d^-1, exceeding fluxes of total dissolved Cu by 3->40-fold, suggesting that any Cu fluxing from the sediments is likely to be organically complexed. …

The Implications Of Turbidite-Driven Redox Changes In Sediments Of The Iberia Abyssal Plain, Timothy J. Shaw, P. A. Meyers

Faculty Publications

No abstract provided.

The Dinoflagellate Flora Of The Late Oligocene - Early Miocene Old Church Formation Mid-Atlantic Coastal Plain, Alan P. Hoffmeister

OES Theses and Dissertations

The Old Church Formation contains the only presently known exposed Oligocene sediments in the North American mid-Atlantic Coastal Plain. Some ambiguity concerning the exact age of the Old Church Formation exists because it may include both Oligocene and Miocene sediments. Two outcrops and four cores containing the Old Church Formation were examined for dinoflagellates to determine the composition of the dinoflagellate flora in the Old Church Formation, the age of the Old Church Formation as indicated by this flora, general depositional environment of the Old Church Formation and correlative relationships of the Old Church Formation with other Coastal Plain units. …

Paleobathymetric Interpretation Of Pleistocene Sediments In The South Padre Island Area, Northwestern Gulf Of Mexico, Using Benthic Foraminiferal Morphology, Karen Ianthe Kruebbe-Belwood

OES Theses and Dissertations

This study tested the validity of using intraspecific variation in benthic foraminifera as a means for determining Pleistocene paleobathymetry. Canonical variate analysis was used as a means for determining visually undetectable but statistically significant differences in the morphology of selected species. Two species, Cassidulina subglobosa and Uvigerina peregrina, were collected from Pleistocene well cuttings from the northwest Gulf of Mexico. The canonical analysis involved comparing the intraspecific variation of these Pleistocene species to their counterparts occurring in the modern Gulf of Mexico, where intraspecific variation was previously analyzed and found to be sufficient to allow detection of bathymetric differences …

The Role Of Longshore Sediment Transport In The Loss Of Fill Material From An Estuarine Groin System, R. Neville Reynolds

OES Theses and Dissertations

The influence of shoreline structures on longshore sediment transport and the evolution of a stable beach planform was investigated at Willoughby Spit, Virginia following the placement of 410,590 cubic meters of beach fill within a groin system. Shoreline changes and wave conditions in a single groin compartment, and the growth rate of a downdrift terminal spit were monitored during 1985 and 1986. Short term fluctuations in the shoreline position within the groin compartment suggested an episodic westerly movement of sediment through the groin system. Primary sediment moving events were associated with northerly winds which produced waves up to 50 cm …

Nutrient Cycling In Bordenstake Bay Sediments: A Backbarrier Lagoon, Mark J. Herrenkohl

OES Theses and Dissertations

Six sets of sediment cores were collected over a one year period (June 1986 to July 1987) to examine nutrient cycling in Bordenstake Bay, a back barrier lagoon on Virginia's Eastern Shore Peninsula. The sampling times were chosen to examine any seasonal effects (e.g., temperature changes) which may affect the rates of metabolism in these sediments.

The sedimentation rate in Bordenstake Bay is 0.76 ± 0.21 cm/yr, leading to the annual deposition of 7. 05 moles of carbon, 0.46 moles of nitrogen, and 0.15 moles of phosphorus, per square meter of the sediment surface. The remineralization of organic matter in …

Hydrothermal Fluids And Petroleum In Surface Sediments Of Guaymas Basin, Gulf Of California: A Case Study, J. M. Gieskes, B. R. Simoneit, T. Brown, Timothy J. Shaw, Y. C. Wang, A. Magenheim

Faculty Publications

No abstract provided.

A Method For Determining Creosote Contamination Of Sediment From The Elizabeth River, Norfolk, Va, Elizabeth G. Merrill

OES Theses and Dissertations

Hydrocarbon input sources to the Elizabeth River were investigated. Carbonized coal products (creosote, coal tar, and roof tar), petroleum products (Kuwait Crude Oil, No. 2 Fuel Oil, and a fuel oil spill sample) and soot (woodstove and diesel engine) have unique hydrocarbon distributions. Elizabeth River sediment hydrocarbon distributions indicate that they are contaminated with both carbonized coal and petroleum products. Using a simple two member mixing model, greater than 65 percent of Elizabeth River sediments' resolved aromatic compounds were determined to originate from carbonized coal products. These aromatic hydrocarbons include the EPA priority pollutant polynuclear aromatic hydrocarbons which are known …

Input And Distribution Of Sewage Derived Sedimentary Material Adjacent To Chesapeake-Elizabeth Sewage Outfall, Virginia Beach, Virginia, Robert Carroll Brown

OES Theses and Dissertations

The concentrations of coprostanol and hydrocarbons were measured in the effluent from the Chesapeake-Elizabeth sewage treatment plant and surface sediments from the area surrounding the effluent discharge site. Most of the coprostanol (>84%) and hydrocarbons (>91%) were associated with particulates in the effluent. Some of these particles were incorporated into the sedimentary column within the study area, while some may have escaped from the area.

The study area is found to be a dynamic area where changes in the percentage and distribution of fine-grained sediments occur over periods of months. The movement of fine-grained sediments is an important …

The Distribution Of Cesium-137, Copper, Lead And Zinc In Various Sedimentary Environments Of The James River Estuary, Virginia, Colin Stevenson Moy

OES Theses and Dissertations

Ten grab samples and eight cores were obtained within a short stretch of the James River estuary. The distribution of CU, Pb, Zn, Cs-137, organic carbon (TOC) and fine-grained sediments in various depositional environments were examined. Within the past quarter of a century, these measured parameters have been accumulating preferentially in the low energy environment (Burwell Bay). The inventory of Cs-137 in the cores was linearly related to the inventory of heavy metals and TOC. The concentrations of Cs-137 in the surface sediments vary linearly to those of the other parameters suggesting that Cs-137 may be used as a tracer …

Paleoclimatic Implications Of Oxygen Isotope And Sedimentological Study Of Late Miocene And Early Pliocene Sediments From The South Atlantic, Western Indian Ocean, And The Gulf Of Aden, Kathryn M. Scanlon

Geology Theses and Dissertations

Previous work by many authors has implied that the Antarctic ice sheet underwent a major expansion in the latest Miocene. It was intended in the present study to use the oxygen isotope event, which could be expected to accompany this glacial expansion, as a stratigraphic marker to aid in the correlation of several DSDP Sites. Samples were taken at approximately 100,000 year intervals throughout the latest Miocene and early Pliocene sections at Sites 237 and 249 in the western Indian Ocean, Site 360 in the South Atlantic and Site 231 in the Gulf of Aden. Oxygen isotope analyses were done …

Control Of Clay Mineral Distribution By Estuarine Circulation, James River Estuary, Virginia, Jean-Pierre Feuillet

OES Theses and Dissertations

A study was performed on the clay minerals of the James River estuary, Virginia, to determine the predominant factors that influence clay mineral distribution in the estuary. The factors of differential settling, flocculation, and diagenesis show minor or no effects on distribution, while estuarine circulation exerts the strongest influence upon the clay mineral distribution.

There are two clay suites in the James River estuary. The upper James River clay suite is a kaolinite, dioctahedral vermiculite, and mixed-layer suite, with kaolinite being the major mineral. The lower Chesapeake Bay clay suite is an illite, chlorite, and montmorillonite suite, with illite being …

Dynamics And Sedimentology Of Inner Middle Ground - Nine Foot Shoal, Chesapeake Bay, Virginia, Mitchell Alan Granat

OES Theses and Dissertations

The historical, hydrodynamic, and sedimentological development of Inner Middle Ground - Nine Foot Shoal indicates that it is presently in quasi-equilibrium with mutually evasive ebb and flood tidal currents. Bathymetric comparisons among six surveys taken during the past 122 years depict development of the shoal from two linear sand bodies to its present double parabolic morphology. Circulation paths are proposed for each survey.

Information from eight current meter stations on and adjacent to Inner Middle Ground - Nine Foot Shoal were used to determine near-surface and near-bottom tidal current asymmetries and directions. The concepts of bathymetrically diverted currents and mutual …

Heavy Mineral Distribution In The Lower Chesapeake Bay, Virginia, Frances Firek

OES Theses and Dissertations

Heavy minerals from 195 bottom sediment samples of the lower Chesapeake Bay, Virginia have been studied. In comparison with other areas such as the Gulf of Mexico, qualitative and qualitative mineralogical variations were subdued, because of the absence of widely divergent source areas. The effect of present-day drainage system on the mineralogical distribution patterns is not clear, largely because of the complex Pleistocene history of the study area.

Seven geographic provinces were defined and treated statistically. An analysis of variance was conducted on the seven provinces. The more significant mineral species from the study area are zircon, hornblende, pyroxene, and …

History Of Sedimentation In Montsweag Bay, Detmar Schnitker

Maine Collection

History of Sedimentation In Montsweag Bay

by Setmar Schnitker

Bulletin #25, Department of Forestry, Augusta, Maine, 1972.

Contents: Abstract / Introduction / Geographic Setting / Seismic Profiling / Pleistocene Sediments / Holocene Sediments / Actual Sedimentation /. Suspended Sediments / Recent Changes / Outlook / Acknowledgements / References

Quaternary Sedimentation On The Inner Atlantic Shelf Between Cape Henry And Cape Hatteras: A Preliminary Report, Donald J. P. Swift, Gerald L. Shideler, Nicholas F. Avignone, Barry M. Holliday, Charles E. Dill Jr.

OES Faculty Publications

The coast of the Middle Atlantic Bight of North America's Atlantic shelf consists of a series of spit - barrier island systems attached on their northern ends to eroding headlands. It has been suggested that these barriers were generated as coastwise-prograding spits (Fisher, 1967) or alternatively as mainland beaches detached by the Holocene rise of sea level (Hoyt, 1967). The shore face before the barriers consists of fine, seaward-fining sand. Locally, it is corrugated by oblique-trending ridges with up to 8 metres of relief — see for instance CSGS Chart 1109. Beyond the shore face lies a vast submarine sand …

A Fluorescent Tracer Study At A Tidal Inlet (Rudee Inlet, Virginia), James W. Bunch

OES Theses and Dissertations

Patterns and approximate rates of littoral transport south of Rudee Inlet. Virginia were investigated with fluorescent tracers. Sand movement was traced under a variety of longshore current and wave conditions. Patterns of tracer dispersal reflected the importance of wave height, breaker angle, and longshore current velocity on modes of littoral transport. A direct relationship between angle of breaker incidence. generated longshore current. and direction of tracer sand movement was found. Onshore offshore paths were taken by tracer material during periods of weak longshore currents and small breaker angles while alongshore paths were followed by tracer material during strong longshore currents …