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2016

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Articles 31 - 60 of 61

Full-Text Articles in Fresh Water Studies

Drougthscape, Summer 2016, National Drought Mitigation Center Jul 2016

Drougthscape, Summer 2016, National Drought Mitigation Center

DroughtScape: Quarterly Newsletter of the National Drought Mitigation Center (2007–2023)

Contents

NDMC adds two employees

Second quarter drought summary: Drought slowly spreading

Second quarter drought impacts: Drought intensifies across US

First comprehensive drought

indices guidebook released

Drought Impact Reporter updates increase usability

Create a custom DIR view

Drought center co-leads MENA region project

McCook, Nebraska, tackles drought resilience

Arizona groups improve public lands drought planning

NDMC founder Don Wilhite retires


Bella Vista Lakes Project: Fertility Management, J. Thad Scott Jun 2016

Bella Vista Lakes Project: Fertility Management, J. Thad Scott

Arkansas Water Resources Center Technical Reports

No abstract provided.


Umphlett Qci June 2016, Natalie Umphlett Jun 2016

Umphlett Qci June 2016, Natalie Umphlett

High Plains Regional Climate Center: Staff Publications

Highlights for the Basin

Temperature and Precipitation Anomalies

Snowpack and Streamflow

Limited Frost Damage to Crops this Spring

Wet Conditions Cause Mixed Impacts

3-Month Precipitation and Temperature Outlooks

U.S. Seasonal Drought Outlook


Cockatoo Sands In The Victoria Highway And Carlton Hill Areas, East Kimberley: Hydrogeology, Aquifer Properties And Groundwater Chemistry, D L. Bennett, John Andrew Simons, Richard J. George Dr, Paul Raper May 2016

Cockatoo Sands In The Victoria Highway And Carlton Hill Areas, East Kimberley: Hydrogeology, Aquifer Properties And Groundwater Chemistry, D L. Bennett, John Andrew Simons, Richard J. George Dr, Paul Raper

Resource management technical reports

Cockatoo Sands are recognised as potentially suitable for irrigated agriculture because they are generally well drained and not subject to waterlogging or inundation. These characteristics allow them to be cultivated and prepared for planting various crops during the wet and dry seasons of northern Australia. Expanding agricultural production onto the Cockatoo Sands around Kununurra will increase opportunities for agriculture by increasing the overall scale of agriculture, allowing year-round agricultural enterprise, new crops and new market opportunities.

DAFWA has assessed the soil characteristics and agriculturally suitable areas of Cockatoo Sands in the Victoria Highway and Carlton Hill areas near Kununurra. Potential …


Dietary Effects On The Stoichiometry Of Growth, Regulation, And Wastes Of Ozark Stream Insect Detritivores, Halvor Matthew Halvorson May 2016

Dietary Effects On The Stoichiometry Of Growth, Regulation, And Wastes Of Ozark Stream Insect Detritivores, Halvor Matthew Halvorson

Graduate Theses and Dissertations

A widespread stressor, anthropogenic nitrogen (N) and phosphorus (P) pollution can increase resource nutrient content and alter animal community composition in freshwater ecosystems. In this dissertation, I used ecological stoichiometry theory to examine effects of diet nutrient content and leaf litter type on growth, regulation, and wastes of aquatic invertebrate detritivores. I tested effects of leaf litter diet carbon:phosphorus (C:P) on growth and stoichiometric regulation of the detritivorous caddisfly Pycnopsyche lepida and used results to determine a threshold elemental ratio of oak litter C:P=1620 that confers peak growth of this species. This empirical, growth-based approach provided a more accurate estimate …


Drinking Water Treatment: Salt-Free Water “Softener” Options, Bruce I. Dvorak May 2016

Drinking Water Treatment: Salt-Free Water “Softener” Options, Bruce I. Dvorak

Department of Civil and Environmental Engineering: Faculty Publications

New no-salt technologies may be effective in treating hard water, but consumers should carefully investigate product claims prior to buying a specific treatment device.

Hard water is not a health risk, but many Nebraska consumers find hard water to be a nuisance because of mineral buildup on plumbing fixtures, including water heaters; unsightly film on glass and crystal wares; and poor soap and/or detergent performance. Water described as “hard” contains high amounts of dissolved calcium and magnesium, which are positively charged contaminants called cations.

Water hardness often is expressed as grains of hardness per gallon of water (gpg) or milligrams …


The Role Of Hydrologic Regimes In Driving Morphologic Divergence And The Trait Compositions Of Fish Assemblages, Lindsey A. Bruckerhoff May 2016

The Role Of Hydrologic Regimes In Driving Morphologic Divergence And The Trait Compositions Of Fish Assemblages, Lindsey A. Bruckerhoff

Graduate Theses and Dissertations

The hydrologic regime is an important determinant of the ecological integrity of a stream. Hydrologic regimes are defined by the magnitude, timing, frequency, rate of change, and duration of high and low flow events and capture long term patterns of variability and predictability of water movement in a stream. Flow regimes influence many aspects of the biophysical environment in lotic systems; therefore organisms have adapted to natural flow patterns. We investigated how fish have adapted to flow regimes at both a population and community level. In the first study presented in this thesis, we hypothesized fish exhibit phenotypic divergence to …


A Method Comparison And Stressor-Response Experimental Study Of Nitrogen And Phosphorus Impacts To Periphyton In Ozark Streams, Ashley Renee Rodman May 2016

A Method Comparison And Stressor-Response Experimental Study Of Nitrogen And Phosphorus Impacts To Periphyton In Ozark Streams, Ashley Renee Rodman

Graduate Theses and Dissertations

Stream bioassessment is important for understanding algal-nutrient relationships and the development of scientifically defensible numeric nutrient criteria. However, multiple methods of periphyton data collection are currently used, and little is known about the comparability of resulting datasets. Literature also suggests other factors besides nutrients (i.e. variable grazing, light, and flow) can confound algal-nutrient relationships. A one-year method comparison study and 31-day algal biomass-nutrient manipulative experiment were conducted in the southern Ozarks of Arkansas. The method comparison study was implemented using two common bioassessment procedures (whole-surface and delimiter-reduced periphyton removal) to assess the potential for combining datasets. During the manipulative experiment, …


Droughtscape, Spring 2016, National Drought Mitigation Center Apr 2016

Droughtscape, Spring 2016, National Drought Mitigation Center

DroughtScape: Quarterly Newsletter of the National Drought Mitigation Center (2007–2023)

Contents

Director’s report

First quarter drought summary

First quarter drought impacts

Drought Risk Management Research Center

Kenyan official visits

DrIVER eyes forecasting

Drought scenario exercise

Student projects

Drought tournament

Response and recovery guide

Drought Portal

Network of drought observers

Caribbean “writeshops”

Communications staff grows


Flood-Inundation Maps For A 12.5-Mile Reach Of Big Papillion Creek At Omaha, Nebraska, Kellan R. Strauch, Benjamin J. Dietsch, Kayla J. Anderson Mar 2016

Flood-Inundation Maps For A 12.5-Mile Reach Of Big Papillion Creek At Omaha, Nebraska, Kellan R. Strauch, Benjamin J. Dietsch, Kayla J. Anderson

United States Geological Survey: Water Reports and Publications

Digital flood-inundation maps for a 12.5-mile reach of the Big Papillion Creek from 0.6 mile upstream from the State Street Bridge to the 72nd Street Bridge in Omaha, Nebraska, were created by the United States Geological Survey (USGS) in cooperation with the Papio-Missouri River Natural Resources District. The flood-inundation maps, which can be accessed through the USGS Flood Inundation Mapping Science Web site at http://water.usgs.gov/osw/flood_inundation/, depict estimates of the areal extent and depth of flooding corresponding to selected water levels (stages) at the USGS streamgage on the Big Papillion Creek at Fort Street at Omaha, Nebraska (station 06610732). Near-real-time …


Effects Of Streamflows On Stream-Channel Morphology In The Eastern Niobrara National Scenic River, Nebraska, 1988–2010, Nathaniel J. Schaepe, Jason S. Alexander, Kiernan Folz-Donahue Mar 2016

Effects Of Streamflows On Stream-Channel Morphology In The Eastern Niobrara National Scenic River, Nebraska, 1988–2010, Nathaniel J. Schaepe, Jason S. Alexander, Kiernan Folz-Donahue

United States Geological Survey: Water Reports and Publications

The Niobrara River is an important and valuable economic and ecological resource in northern Nebraska that supports ecotourism, recreational boating, wildlife, fisheries, agriculture, and hydroelectric power. Because of its uniquely rich resources, a 122-kilometer reach of the Niobrara River was designated as a National Scenic River in 1991, which has been jointly managed by the United States Fish and Wildlife Service and National Park Service (NPS). To assess how the remarkable qualities of the National Scenic River may change if consumptive uses of water are increased above current levels, the United States Geological Survey (USGS), in cooperation with the NPS, …


Upscaling Methane Emission Hotspots In Boreal Peatlands, Fabio Cresto Aleina, Benjamin R. K. Runkle, Tim Brucher, Thomas Kleinen, Victor Brovkin Mar 2016

Upscaling Methane Emission Hotspots In Boreal Peatlands, Fabio Cresto Aleina, Benjamin R. K. Runkle, Tim Brucher, Thomas Kleinen, Victor Brovkin

Biological and Agricultural Engineering Faculty Publications and Presentations

Upscaling the properties and effects of small-scale surface heterogeneities to larger scales is a challenging issue in land surface modeling. We developed a novel approach to upscale local methane emissions in a boreal peatland from the micro-topographic scale to the landscape scale. We based this new parameterization on the analysis of the water table pattern generated by the Hummock–Hollow model, a microtopography resolving model for peatland hydrology. We introduce this parameterization of methane hotspots in a global model-like version of the Hummock–Hollow model that underestimates methane emissions. We tested the robustness of the parameterization by simulating methane emissions for the …


Dissolved Oxygen Monitoring In Kings River And Leatherwood Creek, Eric Cummings, Erin E. Scott, Marty Matlock, Brian E. Haggard Mar 2016

Dissolved Oxygen Monitoring In Kings River And Leatherwood Creek, Eric Cummings, Erin E. Scott, Marty Matlock, Brian E. Haggard

Arkansas Water Resources Center Technical Reports

The Clean Water Act (CWA) establishes the basic structure used to regulate water quality. Under the CWA, States are required to assess water bodies relative to water‐quality standards and designated beneficial uses and then to submit lists of impaired bodies every other year to the US Environmental Protection Agency (USEPA). In 2015, at least 4,800 water bodies were listed as impaired by dissolved oxygen across the US (USEPA, 2015). Aquatic species like fish and macroinvertebrates depend on adequate dissolved oxygen for survival. Low dissolved oxygen can lead to fish kills, reduced aquatic diversity, and nuisance smells from anaerobic conditions – …


Umphlett Qci March 2016, Natalie Umphlett Mar 2016

Umphlett Qci March 2016, Natalie Umphlett

High Plains Regional Climate Center: Staff Publications

Highlights for the Basin

Temperature and Precipitation Anomalies

Vegetation Conditions

Early Signs of Spring

Winter Wheat Breaks Dormancy

3-Month Precipitation and Temperature Outlooks

Percent of Average Precipitation: Strong El Niños


Water Balance Monitoring For Two Bioretention Gardens In Omaha, Nebraska, 2011–14, Kellan R. Strauch, David L. Rus, Kent E. Holm Feb 2016

Water Balance Monitoring For Two Bioretention Gardens In Omaha, Nebraska, 2011–14, Kellan R. Strauch, David L. Rus, Kent E. Holm

United States Geological Survey: Water Reports and Publications

Document abstract

Bioretention gardens are used to help mitigate stormwater runoff in urban settings in an attempt to restore the hydrologic response of the developed land to a natural predevelopment response in which more water is infiltrated rather than routed directly to urban drainage networks. To better understand the performance of bioretention gardens in facilitating infiltration of stormwater in eastern Nebraska, the United States Geological Survey (USGS), in cooperation with the Douglas County Environmental Services and the Nebraska Environmental Trust, assessed the water balance of two bioretention gardens located in Omaha, Nebraska by monitoring the amount of stormwater entering and …


Sediment Loads And Transport At Constructed Chutes Along The Missouri River-Upper Hamburg Chute Near Nebraska City, Nebraska, And Kansas Chute Near Peru, Nebraska, Brenda K. Densmore, David L. Rus, Matthew T. Moser, Brent M. Hall, Michael J. Andersen Feb 2016

Sediment Loads And Transport At Constructed Chutes Along The Missouri River-Upper Hamburg Chute Near Nebraska City, Nebraska, And Kansas Chute Near Peru, Nebraska, Brenda K. Densmore, David L. Rus, Matthew T. Moser, Brent M. Hall, Michael J. Andersen

United States Geological Survey: Water Reports and Publications

The United States Geological Survey (USGS), in cooperation with the United States Army Corps of Engineers, monitored suspended sediment within constructed Missouri River chutes during March through October 2012. Chutes were constructed at selected river bends by the US Army Corps of Engineers to help mitigate aquatic habitat lost through the creation and maintenance of the navigation channel on the Missouri River. The restoration and development of chutes is one method for creating shallow-water habitat within the Missouri River to meet requirements established by the amended 2000 Biological Opinion. Understanding geomorphic channel-evolution processes and sediment transport is important for the …


Agriculture Causes Nitrate Fertilization Of Remote Alpine Lakes, Elizabeth J. Hundey, Sam S.D. Russell, Fred Longstaffe, Katrina A. Moser Feb 2016

Agriculture Causes Nitrate Fertilization Of Remote Alpine Lakes, Elizabeth J. Hundey, Sam S.D. Russell, Fred Longstaffe, Katrina A. Moser

Earth Sciences Publications

Humans have altered Earth’s nitrogen cycle so dramatically that reactive nitrogen (Nr) has doubled. This has increased Nr in aquatic ecosystems, which can lead to reduced water quality and ecosystem health. Apportioning sources of Nr to specific ecosystems, however, continues to be challenging, despite this knowledge being critical for mitigation and protection of water resources. Here we use D17O, d18O and d15N from Uinta Mountain (Utah, USA) snow, inflow and lake nitrate in combination with a Bayesian-based stable isotope mixing model, to show that at least 70% of nitrates in aquatic systems are anthropogenic …


Detection, Occurrence And Fate Of Emerging Contaminants In Agricultural Environments, Daniel D. Snow, David A. Cassada, Shannon L. Bartelt-Hunt, Xu Li, Matteo D'Alessio, Yun Zhang, Yuping Zhang, J. Brett Sallach Jan 2016

Detection, Occurrence And Fate Of Emerging Contaminants In Agricultural Environments, Daniel D. Snow, David A. Cassada, Shannon L. Bartelt-Hunt, Xu Li, Matteo D'Alessio, Yun Zhang, Yuping Zhang, J. Brett Sallach

Nebraska Water Center: Faculty Publications

A total of 59 papers published in 2015 were reviewed ranging from detailed descriptions of analytical methods, to fate and occurrence studies, to ecological effects and sampling techniques for a wide variety of emerging contaminants likely to occur in agricultural environments. New methods and studies on veterinary pharmaceuticals, steroids, antibiotic resistance genes in agricultural environments continue to expand our knowledge base on the occurrence and potential impacts of these compounds. This review is divided into the following sections: Introduction, Analytical Methods, Steroid Hormones, Pharmaceutical Contaminants, Transformation Products, and “Antibiotic Resistance, Drugs, Bugs and Genes”.


The Spatial Sensitivity Analysis Of Evapotranspiration Using Penman-Monteith Method At Grid Scale, Sivarajah Mylevaganam, Chittaranjan Ray Jan 2016

The Spatial Sensitivity Analysis Of Evapotranspiration Using Penman-Monteith Method At Grid Scale, Sivarajah Mylevaganam, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

The need to allocate the existing water in a sustainable manner, even with the projected population growth, has made to assess the consumptive use or evapotranspiration (ET), which determines the irrigation demand. As underscored in the literature, Penman-Monteith method which is a combination of aerodynamic and energy balance method is widely used and accepted as the method of estimation of ET. However, the application of Penman-Monteith relies on many climate parameters such as relative humidity, solar radiation, temperature, and wind speed. Therefore, there exists a need to determine the parameters that are most sensitive and correlated with dependent variable ( …


A Spatial Evapotranspiration Tool At Grid Scale, Sivarajah Mylevaganam, Chittaranjan Ray Jan 2016

A Spatial Evapotranspiration Tool At Grid Scale, Sivarajah Mylevaganam, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

The drastic decline in groundwater table and many other detrimental effects in meeting irrigation demand, and the projected population growth have force to evaluate consumptive use or evapotranspiration (ET), the rate of liquid water transformation to vapor from open water, bare soil, and vegetation, which determines the irrigation demand. As underscored in the literature, Penman- Monteith method which is based on aerodynamic and energy balance method is widely used and accepted as the method of estimation of ET. However, the estimation of ET is oftentimes carried out using meteorological data from climate stations. Therefore, such estimation of ET may vary …


Constituent Loads And Trends In The Upper Illinois River Watershed And Upper White River Basin, Erin E. Scott, Zach P. Simpson, Brian E. Haggard Jan 2016

Constituent Loads And Trends In The Upper Illinois River Watershed And Upper White River Basin, Erin E. Scott, Zach P. Simpson, Brian E. Haggard

Arkansas Water Resources Center Technical Reports

Water chemistry can greatly influence the quality of surface waters and affect the ability for streams and rivers to meet their designated use(s). In Arkansas, many streams and rivers were placed on the 2008 303(d) list of impaired water bodies due to excess levels of nutrients, chlorides, sulfates, and sediments (ADEQ, 2008). These constituents continue to be listed as the potential cause for water‐quality impairments through the most recent draft 303(d) list (ADEQ, 2014). The Arkansas Non‐Point Source (NPS) Management Program wants to reduce poll‐ utant loading from the landscape and improve water quality, where funding for projects is targeted …


Climate-Relevant Land Use And Land Cover Change Policies, Rezaul Mahmood, Roger A. Pielke Sr., Clive Mcalpine Jan 2016

Climate-Relevant Land Use And Land Cover Change Policies, Rezaul Mahmood, Roger A. Pielke Sr., Clive Mcalpine

High Plains Regional Climate Center: Staff Publications

Both observational and modeling studies clearly demonstrate that land-use and land-cover change (LULCC) play an important biogeophysical and biogeochemical role in the climate system from the landscape to regional and even continental scales. Without comprehensively considering these impacts, an adequate response to the threats posed by human intervention into the climate system will not be adequate. Public policy plays an important role in shaping local- to national-scale land-use practices. An array of national policies has been developed to influence the nature and spatial extent of LULCC. Observational evidence suggests that these policies, in addition to international trade treaties and protocols, …


Support For Drought Response And Community Preparedness: Filling The Gaps Between Plans And Action, Kelly Helm Smith, Crystal J. Stiles, Michael Hayes, Christopher Carparelli Jan 2016

Support For Drought Response And Community Preparedness: Filling The Gaps Between Plans And Action, Kelly Helm Smith, Crystal J. Stiles, Michael Hayes, Christopher Carparelli

High Plains Regional Climate Center: Staff Publications

This chapter examines which levels of government handle various aspects of drought, as well as interactions between levels of government, providing examples from states across the western United States. It also takes a look at aspects of drought that fall outside traditional lines of authority and disciplinary boundaries. As part of a discussion on how states support local drought response, the chapter details and contrasts how California and Colorado track public water supply restrictions, and describes Colorado’s process for incorporating input from river basins across the state into its water plan. Case studies focus on drought planning in the Klamath …


The Conflict Resolution Case Study In Urban Life: Bull Run Watershed Case, Chang-Yu Hong Jan 2016

The Conflict Resolution Case Study In Urban Life: Bull Run Watershed Case, Chang-Yu Hong

Geography Faculty Publications and Presentations

The City of Portland and the United States Department of Agriculture (USDA) Forest Service are working together, along with citizens, to formulate a comprehensive new policy to guide joint management of the Bull Run watershed at Mt. Hood National Forest. This process has brought about four decades of conflict, resulting from differences between the federal view of multiple use and the local view of exclusive use for producing high quality water. The new policy is being formulated by the City of Portland and the Forest Service through negotiation of a comprehensive Memorandum of Understanding that structures the parties’ roles, responsibilities, …


Juvenile Survival And Adult Return As A Function Of Freshwater Rearing Life History For Coho Salmon In The Klamath River Basin, Molly Gorman Jan 2016

Juvenile Survival And Adult Return As A Function Of Freshwater Rearing Life History For Coho Salmon In The Klamath River Basin, Molly Gorman

Cal Poly Humboldt theses and projects

The Scott and Shasta rivers, Klamath River tributaries, experience spatial disparity in habitat quality in spring and summer as a result of historical and current land-use. Juvenile Coho Salmon (Oncorhynchus kisutch) born in the upper tributary reaches often rear in natal streams before migrating to sea. However, those born in the lower reaches often encounter unsuitable habitat and emigrate during their first spring to seek non-natal rearing habitats. It is assumed that these early outmigrants are population losses. This study evaluated first-summer survival, and contribution to the adult population, of non-natal rearing juveniles in the Klamath River Basin. …


Droughtscape, Winter 2016, Kelly Smith Jan 2016

Droughtscape, Winter 2016, Kelly Smith

DroughtScape: Quarterly Newsletter of the National Drought Mitigation Center (2007–2023)

Contents

Director’s column

California drought FAQ

October-December 2015 drought

October-December 2015 impacts

2015 drought impacts in review

NDMC hiring geospatial analyst

CA drought exposes social vulnerability

UA helps Arizona ranchers, Forest Service work together

NDMC and partners help southern Plains ranchers manage drought

Chickasaw ranching workshop


Invertebrate Drift In The Upper Columbia River With Implications For Young-Of-The-Year White Sturgeon, Ryan W. Reihart Jan 2016

Invertebrate Drift In The Upper Columbia River With Implications For Young-Of-The-Year White Sturgeon, Ryan W. Reihart

EWU Masters Thesis Collection

"White sturgeon (Acipenser transmontanus) in the upper Columbia River have been in decline for over 60 years and are listed as critically endangered by the International Union for Conservation of Nature. Annual spawning produces dispersing larvae; however, recruitment into the juvenile age class has not occurred since the early 1970s. One hypothesis to explain this failure in recruitment is that larvae may not find adequate prey. Little is known about diet and prey availability for white sturgeon larvae, especially in Lake Roosevelt, a reservoir of the Columbia River. The Spokane Tribe of Indians collected littoral and mid-channel benthic drift samples …


A Step In The Right Direction: Streambank Restoration Efforts At The Botanical Garden Of The Ozarks, Dylan S. Milholen, Madison Brown, Steven Thao, Lisa S. Wood Jan 2016

A Step In The Right Direction: Streambank Restoration Efforts At The Botanical Garden Of The Ozarks, Dylan S. Milholen, Madison Brown, Steven Thao, Lisa S. Wood

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

The Botanical Garden of the Ozarks (BGO) is a unique destination in Northwest Arkansas that draws more than 80,000 visitors a year. While the BGO manages low-input practices, run-off from pesticide application and synthetic fertilizers containing phosphorus and nitrogen are of concern to water quality, habitat, and overall ecological interactions of the BGO streambanks and adjacent Hilton Creek, which flows directly into Lake Fayetteville. One way to reduce pollution to waterbodies is through the use of riparian buffers. This project sought to establish a riparian buffer immediately adjacent to a portion of Hilton Creek in an effort to improve ecological …


River Report. State Of The Lower St. Johns River Basin, Florida: Water Quality, Fisheries, Aquatic Life, Contaminants, 2016, Environmental Protection Board, City Of Jacksonville, University Of North Florida, Jacksonville University, Gerry Pinto, Nisse Goldberg, Radha Pyati, Peter Bacopoulos, Anthony Ouellette, Gretchen Bielmyer-Fraser, An-Phong Le, Ray Oldakowski Jan 2016

River Report. State Of The Lower St. Johns River Basin, Florida: Water Quality, Fisheries, Aquatic Life, Contaminants, 2016, Environmental Protection Board, City Of Jacksonville, University Of North Florida, Jacksonville University, Gerry Pinto, Nisse Goldberg, Radha Pyati, Peter Bacopoulos, Anthony Ouellette, Gretchen Bielmyer-Fraser, An-Phong Le, Ray Oldakowski

State of the River Report

No abstract provided.


Studies On Hydroxyl Radical Formation And Correlated Photoflocculation Process Using Degraded Wood Leachate As A Cdom Source, Luni Sun, Kenneth Mopper Jan 2016

Studies On Hydroxyl Radical Formation And Correlated Photoflocculation Process Using Degraded Wood Leachate As A Cdom Source, Luni Sun, Kenneth Mopper

Chemistry & Biochemistry Faculty Publications

In this study, we examined hydroxyl radical (•OH) formation with respect to photoreactivity of colored dissolved organic matter (CDOM), the Fenton reaction, and photoflocculation using leachate from decaying wood. The relationship between •OH photoproduction rate and leachate optical properties (UV-visible absorption and fluorescence excitation-emission matrices (EEMS)) was studied during irradiation using a UV solar simulator. The results showed that the •OH photochemical formation rate is strongly related to humic-like fluorescence as characterized by parallel factor analysis (PARAFAC), and that these fluorescence components are more photolabile than most of the other CDOM components. Fourier transform infrared spectroscopy (FT-IR) indicated the photodegradation …